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  • Kinetika Reaksi Esterifikasi Minyak Sawit

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    Freddy Manullang
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    1. The document describes the preparation of 0.5 N KOH solution and 0.1 N oxalic acid solution and the standardization of KOH solution using oxalic acid. The KOH solution concentration was determined to be 0.51 N. 2. Reaction ratios of 1:3 and 1:10 of oil to methanol were calculated along with the volume of catalyst H2SO4 needed for a 1:10 ratio. The percentage acid level (ALB) and conversion (X) were also calculated for different reaction times and temperatures varying the ratio and temperature. 3. Maximum conversions of 50% and 33.6% were achieved for a 1:3 ratio at 60 minutes and a

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    Lampiran A

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    1. The document describes the preparation of 0.5 N KOH solution and 0.1 N oxalic acid solution and the standardization of KOH solution using oxalic acid. The KOH solution concentration was determined to be 0.51 N. 2. Reaction ratios of 1:3 and 1:10 of oil to methanol were calculated along with the volume of catalyst H2SO4 needed for a 1:10 ratio. The percentage acid level (ALB) and conversion (X) were also calculated for different reaction times and temperatures varying the ratio and temperature. 3. Maximum conversions of 50% and 33.6% were achieved for a 1:3 ratio at 60 minutes and a

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    © All Rights Reserved
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    10 views3 pages

    Kinetika Reaksi Esterifikasi Minyak Sawit

    Uploaded by

    Freddy Manullang
    1. The document describes the preparation of 0.5 N KOH solution and 0.1 N oxalic acid solution and the standardization of KOH solution using oxalic acid. The KOH solution concentration was determined to be 0.51 N. 2. Reaction ratios of 1:3 and 1:10 of oil to methanol were calculated along with the volume of catalyst H2SO4 needed for a 1:10 ratio. The percentage acid level (ALB) and conversion (X) were also calculated for different reaction times and temperatures varying the ratio and temperature. 3. Maximum conversions of 50% and 33.6% were achieved for a 1:3 ratio at 60 minutes and a

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    of 3

    LAMPIRAN A

    1.1

    Pembuatan larutan KOH 0.5 N (Mr KOH = 56).


    gr 1000
    0.5 N= x
    56 250
    gr=7 gram

    1.2

    pembuatan larutan Asam Oksalat 0.1 N (Mr As. Oksalat =126.07).


    gr
    1000
    0.1 N =
    x
    126.07 500
    gr=6.3 gram

    1.3

    Standarisasi larutan KOH oleh Asam Oksalat.


    V as .oksalat =10 ml
    N as .oksalat =0.1 ml
    V KOH =1.9 ml
    V as .oksalat x N as. oksalat =V KOH x N KOH
    1.9 x N as .oksalat =10 x 0.1
    N as .oksalat =0.51 N

    1.4

    Perhitungan rasio 1:3, 1:10 dan katalis.


    a. Rasio 1:3
    Mr minyak =256 gr/ mol

    Mrmetanol =32 gr / mol

    minyak =0.82 gr/ ml

    metanol=0.792 gr / ml

    n=

    gr
    Mr

    n=

    gr
    Mr

    1=

    gr
    256 gr /mol

    3=

    gr
    32 gr /mol

    gr=256 gr

    V=

    m
    256 gr
    =
    =278.26 ml
    0.92 gr /ml

    gr=96 gr

    V=

    m
    96 gr
    =
    =121.2 ml
    0.792 gr /ml

    b. Rasio 1:10
    Asumsi umpan = 100 gr
    m
    100 gr
    V minyak = =
    =113.8 ml

    gr
    0.8788
    ml
    katalis H 2 SO 4=3 x V minyak =0.03 x 113.8 ml=3.414 ml
    xV 0.8788 x 113.8
    nminyak =
    =
    =0.39
    Mr
    256

    nmetanol =10 x nminyak


    nmetanol =10 x 0.39=3.9
    Mr x nmetanol 32 x 3.9
    V metanol=
    =
    =157.57 ml

    0.792
    1.5

    Perhitungan ALB dan konversi


    a. ALB (minyak awal/bahan baku)
    3 ml x 0.1 x 256
    %ALBo=
    x 100 =2.56
    3 x 1000
    b. ALB (1:3, 30 menit, T=60oC)
    2.35 ml x 0.1 x 256
    %ALB1=
    x 100 =2.01
    3 x 1000
    %ALB0%ALB 1
    2.562.01
    X 1=
    x 100 =
    x 100 =21.48
    ALB 0
    2.56
    c. ALB (1:3, 45 menit, T=60oC)
    1.92ml x 0.1 x 256
    %ALB2=
    x 100 =1.64
    3 x 1000
    %ALBo %ALB 2
    2.561.64
    X 2=
    x 100 =
    x 100 =35.9
    ALB o
    2.56
    d. ALB (1:3, 60 menit, T=60oC)
    0.3 ml x 0.5 x 256
    %ALB3=
    x 100 =1.28
    3 x 1000
    %ALBo %ALB 3
    2.561.28
    X 3=
    x 100 =
    x 100 =50
    ALB o
    2.56
    e. ALB (1:10, 30 menit, T=60oC)
    0.5 ml x 0.5 x 256
    %ALB4 =
    x 100 =2.13
    3 x 1000
    %ALBo%ALB 4
    2.562.13
    X4=
    x 100 =
    x 100 =16.79
    ALB o
    2.56
    f. ALB (1:10, 45 menit, T=60oC)
    0.45 x 0.5 x 256
    %ALB5=
    x 100 =1.92
    3 x 1000
    %ALBo %ALB 5
    2.561.92
    X 5=
    x 100 =
    x 100 =25
    ALB o
    2.56
    g. ALB (1:10, 60 menit, T=60oC)
    0.4 x 0.5 x 256
    %ALB6=
    x 100 =1.7
    3 x 1000
    %ALBo %ALB 6
    2.561.7
    X6=
    x 100 =
    x 100 =33.6
    ALB o
    2.56
    h. ALB (1:10, 30 menit, T=65oC)
    0.57 x 0.5 x 256
    %ALB7=
    x 100 =2.43
    3 x 1000

    %ALBo %ALB 7
    2.562.43
    x 100 =
    x 100 =5
    ALB o
    2.56
    i. ALB (1:10, 45 menit, T=65oC)
    0.56 x 0.5 x 256
    %ALB8=
    x 100 =2.39
    3 x 1000
    %ALBo %ALB 8
    2.562.39
    X8=
    x 100 =
    x 100 =6.6
    ALB o
    2.56
    j. ALB (1:10, 60 menit, T=65oC)
    0.55 x 0.5 x 256
    %ALB9=
    x 100 =2.34
    3 x 1000
    %ALBo %ALB 9
    2.562.34
    X9=
    x 100 =
    x 100 =8.6
    ALB o
    2.56
    X7=

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