Data Antoine

A B C
etanol ( 1 ) 16.6758 3674.49 226.45
Air (2) 16.262 3799.89 226.35
a. Bubble P
T x1 x2
318.2 0.25 0.75
b. Dew P
T y1 y2
318.2 0.25 0.75
c. Bubble T
P x1 x2
30 0.25 0.75
d. Dew T
P y1 y2
30 0.25 0.75

DATA UNIFAC
k Rk Qk vk(1) vk(2)
CH3- 1 0.9011 0.848 1 0
-CH2- 2 0.6744 0.54 1 0
-OH 15 1 1.2 1 0
H2O 17 0.92 1.4 0 1

CH3- -CH2- -OH H2O

Main grp 1 1 5 7
CH3- 1 0 0 986.5 1318
-CH2- 1 0 0 986.5 1318
-OH 5 156.4 156.4 0 353.5
H2O 7 300 300 -229.1 0

i=1 i=2
ri 2.5755 0.92
qi 2.588 1.4
e-ki 1 0.3276662 0
1 0.2086553 0
5 0.4636785 0
7 0 1
 thoumk 1 1 9 13
1 1 1 0.0450378778 0.0158902586
1 1 1 0.0450378778 0.0158902586
5 0.6116991 0.6116991082 1 0.3292504677
7 0.3895343 0.3895343341 2.0544073851 1

beta-ik i=1 i=2

1 0.8199532 0.3895343341
1 0.8199532 0.3895343341
5 0.4878333 2.0544073851
7 0.1611887 1

teta-k Sk
1 0.1249263 1
1 0.0795522 1
5 0.1767826 5
7 0.618739 7

i=1 i=2
Ji 1.9308406 0.6897198013
Li 1.5250442 0.8249852681
In gama c 0.1173365 0.0446435589
ln gama r 0.5036336 0.1156567099
ln gama 0.6209701 0.1603002688
gama i 1.8607322 1.1738632926

a. bubble P
P1sat P2sat P y1 y2
20522.6388252 10764.006 19023.387537 0.5018445684 0.4981554316

b. dew P
P1sat P2sat P x1 x2
20522.6388252 10764.006 15173.720562 0.0993379094 0.9006620906

c.bubble T
P1sat P2sat T y1 y2
35.8988667794 15.107317 54.1505 0.5566514771 0.443348136

d.dew T
P1sat P2sat T x1 x2
49.0835874226 20.882297 61.0176 0.0821185163 0.917881722
0.5536363
0.5536363
1.4571337
0.6801939