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E(element)
particle charge mass Atomic No Atomic number Proton number
Proton +1 1 Mass number Proton number plus the number of neutrons in the
Electron -1 negligible nucleus of its atom
Neutron 0 1
Hydration Chemical combination of water and another substance
Solvent Substance in which other substances are dissolved
Solute Substance dissolved in another substance(solvent)to form a solution
Empirical formula Ratio of atoms of different elements present in a molecule of a compound, in their lowest terms as whole numbers
(C4H4 has CH empirical formula)
Molecular formula Actual number of atoms of each element in a molecule of a compound
Dibasic acid One which has 2 replaceable H atoms per molecule
Isotopes Atoms having the same atomic number but different mass numbers
- As the number of protons increases, the number of neutrons increases relatively faster, so small atoms have proton and neutron
numbers which are comparable whereas large atoms have more neutrons than protons
- Neutrons reduce repulsive forces between positive protons
- Departure from optimum range of ratio of protons to neutrons will lead to nuclear instability(radioactivity)
- No of electrons in outer(valence)shell(and sometimes the shell next to the outer shell)and the IEs & EAs for an atom will determine
the chemistry of the element
- Outer shell electrons determine the chemistry of an element as they can get close to the outer shell electrons of other atoms, so can
be transferred or shared. The inner shell electrons are tightly held and shielded from the electrons in other atoms/molecules
- Isotopes dont affect the electron number or structure so dont affect the chemistry of the element, but have varying rates of reaction
- 12C is the only atom with relative atomic mass which is an exact whole number because 12C is chosen as a standard and given a
relative atomic mass of exactly 12
Nuclide A nuclear species of given mass number and atomic number Radionuclide Radioactive nuclide
Relative atomic mass Average mass of an atom of an element compared with 1/12 of the mass of an atom of carbon-12 isotope
Relative isotopic mass Mass of an atom of an isotope of an element compared with 1/12 of the mass of an atom of carbon-12 isotope
Relative molecular mass Sum of relative atomic masses
1 Electrons are emitted from the filament, accelerated and used to bombard the
gaseous sample which is at very low pressure
2 Sample molecules have electrons knocked off them by bombarding electrons
forming positive ions. The molecules can also fragment or rearrange giving different
positive ions
3 Positive ions accelerated by an electric field
4 Positive ions deflected by a magnetic field in a circular path whose radius depends
on mass/charge ratio and strength of the field. The machine sweeps over the chosen
mass range by altering the magnetic field and hence ions reaching the detector are
separated according to their mass
5 Positive ions(Species: radical cation/molecular ion/fragment ion) detected and
relative amounts calculated by the machine
- Chamber vacuumed to prevent air molecules obstructing the passage of particles through the mass spectrometer
- Likelihood of 2+ ions being produced in the mass spectrometer is small, because the chance of a molecule being ionised by electron
impact is already quite small. When it has been ionised it is pulled away by the potential gradient leading to the magnet which also helps
to reduce the possibility of a second impact
- Important to use minimum possible energy to ionise a sample in a mass spectrometer to prevent formation of double positive ions rather
than single positive ions(or to prevent fragmentation of molecular substances)
(%Abundance x Mass) + (%Abundance x Mass) +..
Total % composition = Relative atomic mass RAM
Molecular ion peak (The molecular ion peak is not always the most intense and maybe absent)
Highest significant peak where the molecule has lost 1 electron but has not broken up
Base peak Highest peak in the mass spectrum
- If the sample is an element each line represents an isotope of the element
- Molecules broken up into fragments make fragmentation patterns on the mass spectrum(used to identify molecules and structure)
- Relative masses are just numbers, no units
- No element in the periodic table has a relative atomic mass that is a whole number because relative atomic mass is an average so its not
usually a whole number
- Mass spectrometer with gas-liquid chromatography used in forensic work for analysis of complex mixtures, samples introduced to gas
liquid chromatograph and various constituents separated, output gases then led to mass spectrometer, fragmentation patterns compared
with large database of patterns from known substances
- Once the electron has passed the final anode, it doesnt decelerate and go back to the anode because it has either collided with a gaseous
molecule or passed on to earth(ground)at the other end of the chamber
- It is a good approx to consider that relative atomic mass of 6Li+ determined in a mass spectrometer is the same as that of 6Li because
mass of the electron lost from 6Li to form 6Li+ is negligible
(1) Calculate RAM from these isotopes and their % compositions 54Fe 5.8%, 56Fe 91.6%, 57Fe 2.2%, 58Fe 0.33%
(1) (54x5.8) + (56x91.6) + (57x2.2) + (58x0.33)
5.8 + 91.6 + 2.2 + 0.33 = 55.91(2dp)
1st Ionisation energy M(g) M+(g) + e
Energy/enthalpy change per mole to remove an electron from each atom in the gas phase to form a singly positive ion
2nd Ionisation energy Energy/enthalpy change per mole for the process, M+(g) M2+(g) + e
1st Electron affinity X(g) + e X(g)
Energy/enthalpy change per mole for each atom in the gas phase to gain an electron to form a singly negative ion
- Negative(exothermic), since the electron is attracted by the positive charge on the atoms nucleus
2nd Electron affinity Energy/enthalpy change per mole for the process, X(g) + e X2(g)
- Positive(endothermic), since energy needed to overcome repulsion between the electron and negative ions
Energy level Electrons in atoms can only have certain amounts of energy, groups of electrons can exist with roughly the same amount of
energy, these positions of roughly similar amounts of energy are called energy levels
Size of IE depends on Nuclear charge Atomic radius Electron shielding, energy level
Successive IEs increase because electrons are being removed from increasingly positive ions and so the attractive forces are greater
- Large jumps in IEs arise from a large increase in attraction, corresponding to an electron being removed from a new energy level
significantly closer to the nucleus(proving that electrons are arranged in shells)
IEs increase across periods(left to right)
Number of protons increasing, meaning stronger nuclear attraction
Extra electrons are at roughly the same energy level, even if the outer electrons are in different orbital types
Little extra shielding effect, little extra distance to lessen the attraction from the nucleus
IEs decrease down groups Each element down a group has an extra electron shell
Extra inner shells means extra distance of outer electrons from the nucleus, and greater shielding from the attraction of the nucleus,
overall reducing nuclear attraction
Atomic radius decreases across period 3(left to right) Nuclear charge increases, electrons pulled closer to the nucleus, electrons are all
added to the same outer shell
n Subshell Number of electrons Subshell 1s 2s 2p 3s 3p 3d 4s 4p 4d 4f
Max number of electrons 2 2 6 2 6 10 2 6 10 14
Principal quantum number(n) shell numbers Subshell 1st shell has no subshell Orbital s subshell has 1 orbital, p has 3, d has 5
Aufbau build up principle
Electrons are added to the lowest energy orbital available
One at a time With no more than 2 electrons occupying one orbital
If there are several orbitals of the same energy available then electrons enter
these orbitals singly so as to be as far apart as possible
Halogens have high IEs so they dont form positive ions but negative ions
because they have one electron less than a full shell
Anomalously low EA for F due to repulsion of the incoming electron from a
concentrated electric field of a small atom
Quantum mechanics The electron in an atom behaves as a wave which is a mathematical construction, not a particle
Atomic orbital IS the electron/pair of electrons, the volume in which the electron has a 95% probability of being found(no such thing as
an empty orbital)
Spin is a property of an electron. The 2 electrons in an orbital have opposite spins, helping to counteract the repulsion between their
negative charges(spin pairing)
Z Group II Be 1s22s2 1st IE = 900 kJmol1
Sy 1s 2s 2p 3s 3p 3d 4s 4p Group III B 1s22s22px1 1st IE = 799 kJmol1
m
Group V N 1s22s22px12py12pz1 1st IE = 1400 kJmol1
bo
l Group VI O 1s22s22px22py12pz1 1st IE = 1310 kJmol1
1 H 1 N 2s 2p O 2s 2p
2 He 2
3 Li 2 1
4 Be 2 2 In B the 2p electron easier to remove than the 2s electron from
Be because subshells that are full are more stable
5 B 2 2 1
In B the 2p orbital is further from the nucleus
6 C 2 2 2
The 2p orbital is screened not only by the 1s2 electrons but also
7 N 2 2 3
partially by the 2s2 electrons
8 O 2 2 4 - These factors are strong enough to override the effect of the
9 F 2 2 5 increased nuclear charge resulting in the IE to drop slightly
10 Ne 2 2 6 Screening identical and electron being removed is from an
11 Na 2 2 6 1 identical orbital
12 Mg 2 2 6 2 N structure is symmetrical and more stable than that in O
13 Al 2 2 6 2 1 Repulsion between 2 electrons in the same orbital means an
14 Si 2 2 6 2 2 electron in the 2px2 pair is easier to remove
15 P 2 2 6 2 3
16 S 2 2 6 2 4 (q) An atom contains 5 protons and 5 neutrons, give the symbol for
17 Cl 2 2 6 2 5 this atom including the mass number (a) B
18 Ar 2 2 6 2 6 (q) Formula of the compound formed between this element and
19 K 2 2 6 2 6 1 chlorine (a) BCl3
20 Ca 2 2 6 2 6 2
21 Sc 2 2 6 2 6 1 2
22 Ti 2 2 6 2 6 2 2
23 V 2 2 6 2 6 3 2
24 Cr 2 2 6 2 6 5 1
25 Mn 2 2 6 2 6 5 2
26 Fe 2 2 6 2 6 6 2
27 Co 2 2 6 2 6 7 2
28 Ni 2 2 6 2 6 8 2
29 Cu 2 2 6 2 6 10 1
30 Zn 2 2 6 2 6 10 2
31 Ga 2 2 6 2 6 10 2 1
32 Ge 2 2 6 2 6 10 2 2
33 As 2 2 6 2 6 10 2 3
34 E 2 2 6 2 6 10 2 4
35 Br 2 2 6 2 6 10 2 5
36 Kr 2 2 6 2 6 10 2 6
(1)(i)Mass spectrum of HCl, peak at mass 36 is molecular ion (H 35Cl)+ Chlorine has only 2
isotopes 35Cl, 37Cl What particle is responsible for peak mass 38? (1)(i) (H 37Cl)+
(ii)How do you explain the fact that the height of the peaks at mass 36 is 3 times as high than the
peak at mass 38
(ii)There is 3 times as much 35Cl to 37Cl and therefore 3 times as much H35Cl to H37Cl
(2)(a)Mass spectrum of methane, peak at mass 16 is molecular ion(CH)+
Explain peaks of relative mass 1, 2, 12, 13, 14, 15, 17
Relative mass 1 2 12 13 14 15 17
(1H)+ (2H)+ (12C)+ (12C1H)+ (12C1H2)+ (12C1H3)+ (12C1H32H)+
(2)(a)Bromine consists of 2 isotopes, mass numbers 79 and 81. A sample of Br 2(g) was examined in a mass spectrometer. Identify
the species responsible for the peak at m/e = 160 (2)( 79Br81Br)+
(2)(b)For a particular sample of copper two peaks were obtained in the mass spectrum
Peak at m/e Relative abundance
63 69.1 (i)Give the formula of the species responsible for the peak at m/e = 65 (i)65Cu+
65 30.9 (ii)State why two peaks, at m/e values of 63 and 65, were obtained in the mass spectrum
(ii)2 different isotopes
(3)How would accelerating field and magnetic field differ in its affect on X+ and X2+ ?
(3)The accelerating force and deflecting field on X+ will be twice that on X+
(4)2 reasons why particles must be ionised before being analysed in a mass spectrometer? (4)Have to be accelerated, then deflected
(5)Boron, relative atomic mass 10.8 gives 2 peak mass spectrum, m/z=10 and m/z=11 Calculate the ratio of the heights of the 2 peaks
(5)10x + 11(1 x) = 10.8, x = 0.2, y =1 x = 0.8 ratio of heights = 1:4
(7)Explain why K has lower 1st IE than Na
(7) Electron being removed is further from the nucleus More shielding Reduces attraction of the nucleus
(8)What force causes the scattering of particles by nuclei? 6
L o g io n is a tio n e n e r g y /k J m o l 1
(8) particles and nuclei both positively charged thus electrostatic forces of repulsion
(9)Explain why all isotopes of Mg have the same chemical properties 5
(9) Same number of electrons in all Mg isotopes Outer electron structure 4
determines chemical properties
(10)Using subshell notation, give electronic configuration of K atom and K+ ion 3
(10)K 1s22s22p63s23p64s1 K+ 1s22s22p63s23p6
(11)State why 2 peaks at m/e values of 63 and 65 were obtained in a mass spectrum 2
of an element (11)2 different isotopes
1
(12)Write equation for 5th ionisation of Na (12)Na4+(g) Na5+ (g) + e
(14)The logarithm of successive IEs for Mg across the page 0
Explain what this graph tells you about the electron arrangement in the Mg atom 0 1 2 3 4 5 6 7 8 9 10 11 12
(14)Two/big jumps show 3 different shells present, shows 2.8.2 N u m b e r o f e le c tro n re m o v e d
Find the empirical formula of the compound containing C 22.02% H 4.59% Br 73.39% by mass
Atomic ratio Simplified atomic ratio
C 22.02/12= 1.835 1.835/0.917 = 2
H 4.59/1= 4.59 1.835:4.59:0.917 4.59/0.917 = 5
Br 73.39/80= 0.917 0.917/0.917 = 1 Empirical formula is thus C2H5Br
(1)Compound X contains only B and H, % by mass of B in X is 81.2% In mass spectrum of X the largest value peak of m/z is at 54
Calculate empirical and molecular formula
(1)B:H = 81.2/10.8 : 18.8/1, 7.51:18.8, 1:2.5, 2:5 Empirical formula is B2H5 Mr(B2H5) = 26.6 Molecular formula = B4H10
(2)Hydrazine(empirical formula NH2)mass spectrum of this compound shows a molecular ion peak at m/e 32,
show the molecular formula of hydrazine is N2H4
(2)Relative Molar Mass = 32 n(N + 2H)= 32 n(14 + 2)= 32 n= 2 Molecular formula = 2 NH2 = N2H4
Equations are: Internationally understood Quantitative Shorter than the same information given in words
Equations balance for mass and total charge LHS & RHS have the same number of each type of atom, if there are 2 positives on LHS
there must be 2 on RHS
Ionic equations: 1 Write soluble ionic compounds with the ions separated 2 Write insoluble ionic and covalent compounds as usual
3 Cross out spectator ions(ions which appear on both sides of the equation)
NaCl(aq) + AgNO3(aq) NaNO3(aq) + AgCl(s)
Silver nitrate silver chloride(white ppt)
Ions: Na+(aq) + Cl(aq) + Ag+(aq) + NO3(aq) Na+(aq) + NO3(aq) + AgCl(s)
Deleting spectator ions: Ag+(aq) + Cl(aq) AgCl(s)
2KMnO4(aq) + 8H2SO4(aq) + 10FeSO4(aq) 2MnSO4(aq) + 5Fe2(SO4)3(aq) + K2SO4(aq) + 8H2O(l)
potassium manganate(VII) iron(II)sulphate
Ions: 2K+(aq) + 2MnO4(aq) + 16H+(aq) + 18SO42(aq) + 10Fe2+(aq) 2Mn2+(aq) + 10Fe3+(aq) + 18SO42(aq) + 2K+(aq) + 8H2O(l)
Deleting spectator ions: MnO4(aq) + 8H+(aq) + 5Fe2+(aq) Mn2+(aq) + 5Fe3+(aq) + 4H2O(l)
(4)Back-titration(concerning substances which are insoluble)used to find purity of sample of chalk which is insoluble in water
A solution cant be used so its reacted with a known amount of excess acid, acid remaining then titrated with standard alkali
1.5g of chalk reacted with (excess)50cm3 of 1moldm3 HCl
When reaction ceased, solution transferred to a 250cm3 graduated flask and made to the mark with pure water
25cm3 of the solution titrated with 0.1moldm3 NaOH(aq) 24.5cm3 required, % purity of the chalk?
(4)CaCO3(s) + 2HCl(aq) CaCl2(aq) + H2O(l) + CO2(g) HCl(aq) + NaOH(aq) NaCl(aq) + H2O(l) CaCO3 = 100gmol1
Amount of NaOH = amount of HCl unreacted = 0.0245dm x 0.1moldm3 = 2.45 x103mol in 25cm3
3
Hydration of metal ions In solution metal ions attract water molecules forming complex ions([M(H 2O)6]x+)
The metal ion is joined to 6 water ligands by dative covalent bonds.
The water molecules donate a lone pair of electrons to empty orbitals on the metal ion and an octahedral complex forms
( [Cu(H2O)6]2+(pale blue) Ions formed by transition metals are usually coloured)
Simple anions Non metals (Cl, O2) Complex anions Where groups around the central metal ion are negative([Fe(CN) 6]4)
Polyatomic cations Several atoms bonded covalently, the whole structure having a positive charge (NH4+)
Polyatomic anions Several atoms bonded covalently, the whole structure having a negative charge(SO42, NO3, CHCOO, MnO4)
derived from acids by the loss of one or more hydrogen ions
Cation increases in size Group (II) Cation Hlatt kJmol 1
Charge density decreases Chlorides Radius Experimental Calculated Difference
Less polarising MgCl2 72 2526 2326 200
Covalence decreases CaCl2 100 2258 2223 35
SrCl2 113 2156 2127 29
BaCl2 136 2056 2033 23
Anion increases in size Magnesium Anion Hlatt kJmol 1
More polarisable Halides Radius Experimental Calculated Difference
(outer electrons further from the nucleus, less tightly held, MgF2 133 2957 2913 44
more prone to distortion) MgCl2 180 2526 2326 200
Covalence increases MgBr2 195 2440 2097 343
MgI2 215 2329 1944 385
Bonds in solids vibrate about a mean position in the crystal lattice which arise because the crystal isnt at absolute zero, amplitude of
vibrations increase with temperature
Forces between molecules in liquids are no different in type from those in solids, difference is that the particles in liquids are more
energetic than those in solids so bonds arent particularly directional and liquids have no particular shape
At Tm vibrations in solid become sufficient to overcome forces holding the crystal together
At Tb vapour pressure of the liquid is the same as the external pressure and bubbles of vapour produced throughout the liquid, heat
being put into the liquid is being used by particles to overcome the interparticle forces to separate from each other and escape the
liquid(evaporation) so temp remains constant
Bt of liquids depends on Magnitude of interparticle forces Masses of particles
2bp linear shape 3bp trigonal planar shape (molecule is flat) 4bp tetrahedral shape
P
H H
H
Electron lone pairs Electron pairs not involved in bonding
1 Electron pairs in the valence shell(bp or lp)are as far apart as possible to minimise
repulsion/reach lowest energy state
2 Order of repulsion between electron pairs is: bpbp less than bplp less than lplp
3 Multiple bonds behave as single bonds(no difference between dative and single bonds)
- A molecule will not be polar if its symmetrical and dipoles of molecule cancel
Hybrid orbital A type of atomic orbital that results when 2 or more atomic orbitals of an isolated atom mix, describes orbitals in
covalently bonded atoms(hybrid orbitals dont exist in isolated atoms), in a set are equivalent, and form identical bonds
Hybridisation A model that describes the changes in the atomic orbitals of an atom when it forms a covalent compound
(Excited C atoms, 4 orbitals rearranged into 4 identical hybrid orbitals(sp 3 hybrid orbitals)4 bonds arent identical unless you start
from 4 identical orbitals)
sp hybrid orbital One of the 2 hybrid orbitals formed by hybridisation of an s orbital and p orbital
sp2 hybrid orbital One of the 3 hybrid orbitals formed by hybridisation of an s orbital and 2p orbitals,
same shape as sp3 but lies in one plane at 120
sp3 hybrid orbital One of the 4 hybrid orbitals formed by hybridisation of an s orbital and 3p orbital
- Ethene, only 3 orbitals hybridised rather than all 4, one 2s electron, two 2p electrons, other 2p electron unchanged(sp 2 hybrid
orbitals)
- All double bonds will consist of a pi bond and a bond
- In 3rd diagram bonds shown using lines, each line representing one pair of shared electrons
- 2 C atoms linked by overlap of sp2 hybrid orbitals, making a bond and a pi bond formed by sideways overlap of the non-hybridised
p atomic orbitals.
- Pi bond sideways overlap of two p-orbitals to give a two part orbit above and below a bond (likely to be attacked by
electrophiles, they are weaker than bonds)
Pi bond formed by sideways overlap of the non hybridised p
atomic orbitals
Hydrogen bond Electrostatic attraction between a strongly + H atom attached covalently to a highly electronegative element
F/N/O and a strongly F/N/O atom on another molecule, H bonds are longer than covalent bonds
- As water cools, (long)H bonds form in greater quantity, the open & ordered structure of ice gives it a lower density than liquid water
- Compounds which can H bond with water are very soluble (glucose, has OH groups that H bond with water)
- Extensive H bonds with F/N/O
cause higher Bts
Dipole-Dipole forces(permanently polar molecules) + and parts of the molecules attract electrostatically giving Bts higher than
those of non polar molecules of similar size. For large molecules dispersion forces can exceed dipole-dipole attraction
Dispersion/Van der waals forces(non polar molecules)Temporary dipoles form between molecules because of mobile electron density
within the molecule. + on one molecule will induce a on a nearby one and so on, tho theres a net attraction between molecules
Higher forces: More electrons Larger area of contact(larger molecules/atoms) Linear instead of branched chains
- Descending noble gases or hydrides, bigger van der waals forces as Atomic/molecular size increases More shells of electrons
Giant molecular substances Diamond,
High Mt, hard, stiff as have to break strong covalent bonding throughout
whole structure
Good thermal conductor as it readily transmits vibration
Poor electrical conductor as no ions or free electrons as they are held
tightly between atoms
Insoluble in water, organic solvents as attractions between solvent
molecules and carbon atoms will never be strong enough to overcome the
strong covalent bonds
Silica Lower Mt as has longer(therefore weaker)bonds across whole structure
Graphite Lower density than diamond because of space between the sheets
High Mt as have to break strong covalent bonding throughout whole
layered structures
Electrical conductivity along layers, but not at right angles Graphite
Electrons arent localised between carbon atoms and are free to move along
but not between layers, van der waals forces attract the layers together
Insoluble in water, organic solvents as attractions between solvent
molecules and carbon atoms will never be strong enough to overcome the
strong covalent bonds Diamond Mt4000C SiO2 Mt1700C
Soft, slippery as layers of giant molecules can slide over one another
- Used in pencils
Ionic substances High Mt as have to break strong electrostatic bonds
throughout lattice of oppositely charged ions
Hard, brittle as layers of crystal may slide so ions of same charge come
next to one another and repel
Solid doesnt conduct electricity as no charge carriers available to move
Molten does conduct electricity as mobile ions can move
Soluble in water
Ice
Molecular covalent substances Bonded strongly within the molecule but weakly between molecules
Properties depend on intermolecular forces Non-conductors of electricity (no free electrons, all used in bonding)
Metallic bonding Malleability from non-directional nature of bonds
Electrical conductivity(outer electrons in metals arent localised in bonds but free to move around whole lattice formed from + ions)
Polymers All long chains which maybe cross-linked by covalent bonds or held by H bonds or dispersion forces(or in silicates forces of
ionic attraction between the negatively charged chains of silicate and positive metal ions)
- Mechanical properties of the polymer depend on extent of cross-linking whether crystallites can form
- Pure substances have sharp Mts but polymers dont(usually impure substances), melting over a range of temperatures instead as
varying chain lengths of molecules means that they will have a melting range
Synthetic organic polymers Made from alkenes by addition reactions or from reactions between organic molecules which have 2
functional groups which can undergo condensation reactions They are mixtures since chain lengths vary(no sharp Mt)
Polymers formed by radical polymerisation LDPE is branched, cross-linked Few crystallites, flexible, translucent
Polymers formed by highly controlled type of polymerisation HDPE, ziegler natta catalyst More crystallites, stiffer, opaque
Natural polymers(organic)polysaccharides(cellulose, glycogen), nucleic acids, proteins, all produced by condensation reactions
Inorganic polymers Silicates, phosphoric acid on heating
(1)Why & which elements lose electrons?
(1)Metals because Usually they have 1, 2, 3 electrons By losing these electrons they achieve full outer shells and become more stable
In energy terms, its easier to lose these electrons than gain more electrons
(2)Why & which elements gain electrons?
(2)Non metals because Usually they have 5, 6, 7 electrons By gaining electrons they achieve full outer shells and become more stable
In energy terms, its easier to gain these electrons than lose the outer electrons
(3)Suggest reasons why NaCl vapour is regarded as a collection of ion pairs rather than as NaCl molecules
(3)If ion pairs collide theres nothing to stop them changing partners whereas if covalent molecules collide, its improbable
(4)What happens to an electrostatically charged rod next to a polar liquid like water?
(4)Itll move towards the rod, because polar liquids contain molecules with permanent dipoles. Doesnt matter if the rod is positively or
negatively charged. Polar molecules in the liquid can turn around so the oppositely charged end is attracted towards the rod
(5)Why does water have a partial charge? (5)Oxygen has a higher electronegativity than hydrogen
(6)(a)State the difference in density between solid ice and liquid water and describe how the presence of H bonds accounts for this
(a) Water is more dense than solid ice The H bonds in solid ice which holds the molecules together are in fixed positions and lead to
an open structure In water the H bonds are constantly being broken and made
(b)Explain the structure of ice, include a diagram
(b) Covalent in water molecules H bonds between molecules each water with four waters around tetrahedral
(7)Describe in terms of the position and motion of particles, what happens when some MgCl 2(s) is heated from RT to just above Mt
(7) At RT the ions are in a fixed positions in a lattice As heat is applied the ions vibrate more Eventually ions have enough energy
to overcome electrostatic attraction Ions break free and are able to move as solid melts
(9)Sketch a graph of temp vs time as a (1)(a)What part of the NH3 molecule enables it to form a dative covalent bond?
substance is heated from (a)Lone pair on the nitrogen
just below Mt to just above Bt (b)List intermolecular forces between molecules of ammonia
(b)H bonds and dispersion forces
(2)Name 2 elements in [Mg(H2O)6]2+ which are joined by a covalent bond (2)H and O
(3)Name 2 elements in [Mg(H2O)6]2+ which are joined by a dative covalent bond
(3)O and Mg
(1)Why is MgI2 more covalent than MgCl2?
(1)Because I ion is larger than Cl ion so more easily polarised leading to covalency
(2)Metal/Non-metal compounds usually ionic yet solid aluminium chloride has many
covalent characteristics because?
(2)Small radius, large + charge of Al3+, means high polarising ability giving covalent
character pulling electron density away from Cl creating a mostly covalent bond
m e ltin g t e m p e r a tu r e / K
(3)(i)2 factors which affect the polarising power of cations? (i)ionic radius, charge 1400
(1)(a)2 bottles are clearly labeled sulphate. The solid in bottle A dissolves easily in 1200
water but none of the solid in bottle B appears to dissolve when added to water 1000
Which of these two bottles contains barium sulphate? (a)B 800
(b)Bottle C, labeled magnesium carbonate When a sample is heated a colourless gas 600
is produced that turns limewater cloudy. State whether this label is correct and explain 400
(b)Limewatermilky CO2 MgCO3 decomposes on heating to CO2 label correct 200
0
Na Mg Al Si P S Cl Ar
e le m e n t