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9 T h e Multipole Expansion 83
We set
y1 = 21 + 2 2 , y2 = 21 -22,
so that
1 1
21 = -(Y1
2
+ Y d , 2 2 = -(Y1
2
- YZ),
For the difference with Eo, i.e. with no dipole-dipole interacion, we obtain for the ground state of
the system (N1 = 0, N2 = 0 )
= ; h o ( / G + / - - 2 )
N -1h o (
2
- $) K -.1
R6
This is an energy similar to that of a van der Waals force. One can look at this calculation as a
rough physical model of the Casimir effect in producing the potential K l / R 6 , at least this was
suggested in the 1iterature.q Actually the Casimir effect is a boundary effect, as we shall see in
Chapter 20.
qSee D. Kleppner, Physics Today (Oct. 1990) 9; cf. also the Casimir effect in Chapter 20.