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001L- (AQ) - شيت 1
001L- (AQ) - شيت 1
Sheet 1
Using group molar attraction constants , calculate the solubility parameter for the following
compounds :-
( = )
G = (CH)+(CH=)
G =(2133)+(2111)=488
M.Wt=(412)+(61)=54
.
= . = = . ()/
( )
G = (CH)
G =(2133)=266
M.Wt=(212)+(41)=28
.
= . = = . ( )/
HTI
Page |2
Ahmed Abd El-Nasser Ahmed
20120084
Polymer (2)
Dr:Shaheer
Eng:Asmaa
G = (2214)+(-93)+(133)+(310)=778
M.Wt=(512)+(216)+(81)=100
.
= . = = . ( )/
G = (133)+(28)+(310)+(90)=561
M.Wt=(312)+(216)+(41)=72
.
= . = = . ()/
HTI
Page |3
Ahmed Abd El-Nasser Ahmed
20120084
Polymer (2)
Dr:Shaheer
Eng:Asmaa
G = (2214)+(-93)+(133)=468
M.Wt=(412)+(81)=56
.
= . = = . ( )/
G = (2150)+(2-93)=114
M.Wt=(212)+(418)=96
.
= . = = . ()/
HTI
Page |4
Ahmed Abd El-Nasser Ahmed
20120084
Polymer (2)
Dr:Shaheer
Eng:Asmaa
G = (28)+(133)+(735)=896
M.Wt=(812)+(91)=105
.
= . = = . ( )/
G = (133)+(28)+(310)+(214)=685
M.Wt=(412)+(61)+(216)=86
.
= . = = . ()/
HTI
Page |5
Ahmed Abd El-Nasser Ahmed
20120084
Polymer (2)
Dr:Shaheer
Eng:Asmaa
G = (133)+(28)+(214)=375
M.wt=(312)+(61)=42
.
= . = = . ( )/
G = (2133)+(111)+(214)+(19)=610
M.Wt=(512)+(81)=68
.
= . = = . ( )/
HTI
Page |6
Ahmed Abd El-Nasser Ahmed
20120084
Polymer (2)
Dr:Shaheer
Eng:Asmaa
G = (2133)+(111)+(270)=647
M.Wt=(412)+(51)+(35.5)=88.5
.
= . = = . ()/
.
G = (150)+(150)+(270)+(2-93)=384
M.Wt=(318)+(212)+(35.5)=113.5
= . = . = . ( )/
HTI
Page |7
Ahmed Abd El-Nasser Ahmed
20120084
Polymer (2)
Dr:Shaheer
Eng:Asmaa
G = (133)+(28)+(210)=571
M.Wt=(312)+(31)+(14)=53
.
= . = = . ()/
HTI
Page |8
Ahmed Abd El-Nasser Ahmed
20120084
Polymer (2)
Dr:Shaheer
Eng:Asmaa
Sheet 2
1-Determine the number average , weight average , z-average molecular weight and poly
dispersity index for the following :
Solution
.
Mn =
= = . /
Mw = = . = . /
Mz= = = . /
.
= = . = .
HTI
Page |9
Ahmed Abd El-Nasser Ahmed
20120084
Polymer (2)
Dr:Shaheer
Eng:Asmaa
Mass % 30 60 10
Mi (Kg/Mol) 1.00 1.60 1.80
Solution
Mass % 30 60 10
Mass (kg)
= . = . = .
Mi 1.00 1.60 1.80
Ni = . . .
= . = . =.
/(. ) . .
.
Mn =
= . = . /
.
Mw = = = . /
.
.
Mz= = = . /
.
.
= = . = .
HTI
P a g e | 10
Ahmed Abd El-Nasser Ahmed
20120084
Polymer (2)
Dr:Shaheer
Eng:Asmaa
3- Apolymer solution contains 250 molecules of molar mass 75000gm/mol , 500 molecules of
molar mass 100000 gm/mol , and 250 molecules of molar mass 125000 gm/mol. Calculate
Mn,Mw,Mz and poldispersity index.
Solution
Ni= .
Ni=. = 4.11
Ni=. = 8.3
Ni=. = 4.1
.
Mn = = = /
.
.
Mw = = . = . /
.
Mz= = = . /
.
.
= = = .
HTI
P a g e | 11
Ahmed Abd El-Nasser Ahmed
20120084
Polymer (2)
Dr:Shaheer
Eng:Asmaa
Sheet 3
Solution
T=K.m
m= ,, Number of moles = .
m=. T=K.
.
M.wt = = = 25000 kg/mol
.
C (g/l) 2 4 6 8
(cm xylene) 2.585 5.965 9.66 13.935
Solution
(cm xylene) atms =
HTI
P a g e | 12
Ahmed Abd El-Nasser Ahmed
20120084
Polymer (2)
Dr:Shaheer
Eng:Asmaa
C (g/l) 2 4 6 8
atms 2 4.6 7.49 0.0108
By numerical method :
_ (. __()(. )
a= _ = = .
_
a=slope=ART
.
A= = (.)()=2.3
(.)()
b (intersection) = Mn= = =35970.99 gm/mol = 35.590
.
kg/mol
HTI
P a g e | 13
Ahmed Abd El-Nasser Ahmed
20120084
Polymer (2)
Dr:Shaheer
Eng:Asmaa
Solution
C(mg/cm) C(g/l)
/C (N ) /C( ) 1.013
/
_ (. __()(. )
a= _ = = .
._
HTI
P a g e | 14
Ahmed Abd El-Nasser Ahmed
20120084
Polymer (2)
Dr:Shaheer
Eng:Asmaa
a=slope=ART
.
A= = (.)()=7.9570
(.)()
b (intersection) = Mn= = . =137194.9199 gm/mol =
137.1949 kg/mol
HTI
P a g e | 15
Ahmed Abd El-Nasser Ahmed
20120084
Polymer (2)
Dr:Shaheer
Eng:Asmaa
4-The following osmotic pressures were observed for solutions of poly isobutylene in
cyclohexane at 25 c :-
C(g/l) 20 15 10 5
(atms) 16.09 9.92 5.29 2.03
Determine the number average molecular weight and second virial coefficient .
Solution
_ (. )__((.)( )
a= _ = = .
..
a=slope=ART
.
A= = (.)()=1.0869
(.)()
b (intersection) = Mn= = =91589 gm/mol = 91.589
.
kg/mol
HTI
P a g e | 16
Ahmed Abd El-Nasser Ahmed
20120084
Polymer (2)
Dr:Shaheer
Eng:Asmaa
Sheet 4
1- Calculate the average molecular weight using the following light scattering data:-
=546nm = 549
=. /
n=1.4
Solution
K= ( )=( )(. . ) = 0.0516
( ) (.
C(gm/l) R
=30 =60 =90 =120
0.1 6.63 3.64 2.94
0.2 10 . .
0.3 . . .
0.4 . . . .
C(gm/l)
=30 =60 =90 =120
0.1 150.8 200 274.7 340
0.2 200 250 320 380.2
0.3 240 300 351.69 424.9
0.4 279.7 340.1 410.2 485.4
C(gm/l)
=30 =60 =90 =120
0.1 7.781 10.32 14.17 17.544
0.2 10.32 12.9 16.512 19.618
0.3 12.384 15.48 18.14 21.9
0.4 14.43 17.549 21.16 25
HTI
P a g e | 17
Ahmed Abd El-Nasser Ahmed
20120084
Polymer (2)
Dr:Shaheer
Eng:Asmaa
Polyethylene tristearin
C(gm/l) r C(gm/l) r
12.4 0.61 4.41 3.41
20.36 1.44 10.27 7.83
30.54 2.89 15.29 11.84
40.17 4.9 19.88 14.87
Solution
For Solvent
b=.
. . (.)(.)_(.)(.)
b= = =0.723
_ ..
K=b . = . = .
HTI
P a g e | 18
Ahmed Abd El-Nasser Ahmed
20120084
Polymer (2)
Dr:Shaheer
Eng:Asmaa
For Polymer :
. . (.)(.)(.)(.)
b= = =9.2
..
.
M.Wt= = . = . /
HTI
P a g e | 19
Ahmed Abd El-Nasser Ahmed
20120084
Polymer (2)
Dr:Shaheer
Eng:Asmaa
Sheet 9
1- Apolymer consist of 700 segments , each 0.9 nm long. If the chain was idealy flexible ,
what is the contour length , soot mean square length and radius of gyration .
Solution
Flexible = Random
= ()() = (. )() = .
= ()() = (. )() = .
= () ( ) = (. ) ( ) = .
2- The radius of gyration of a long molecule is found to be 7.3 nm . The chain consists of a
tetrahedral C-C links of lingth 154 pm . Assume that it is a constrained chain , estimate
the number of links in the chain.
Solution
= () ( ) . = ( ) ( ) =
HTI
P a g e | 20
Ahmed Abd El-Nasser Ahmed
20120084
Polymer (2)
Dr:Shaheer
Eng:Asmaa
3- Calculate the contour length and the root mean square seperation (the end-to-end
distance) for poly ethylene with molar mass of 280 kg/mol , use R(C-C) = 154 pm
Solution
( )
M.Wt=(212)+(41)=28
.
= = =
.
Solution
= ( ) = (. )( . ) = .
( ) = = =
.
When = ,
= = . = %
HTI
P a g e | 21
Ahmed Abd El-Nasser Ahmed
20120084
Polymer (2)
Dr:Shaheer
Eng:Asmaa
5- The polymerization process described in problem (4) , determine the total number of
molecules . And the total number of polymers containing 25 monomers when the
reaction is 75% completely . Assume a 1-mole sample of monomers was used.
Solution
.
= . =
.
= .
= ( )
= (. )( . ) . = .
Solution
= ( )
= ( )
Frist :
= . ( . ) . = .
= . ( . ) . = .
= . ( . ) . = .
HTI
P a g e | 22
Ahmed Abd El-Nasser Ahmed
20120084
Polymer (2)
Dr:Shaheer
Eng:Asmaa
= . ( . ) . =
Second :
= ( . ) . =0.0157
= ( . ) . = 0.01886
= ( . ) . = 0.01694
= ( . ) . = 0.01352
HTI