Aits 2013 FT Iv Jeem PDF

FIITJEE JEE (Main), 2013
From Long Term Classroom Programs and Medium / Short Classroom Program 4 in Top 10, 10 in Top 20, 43 in Top 100,
75 in Top 200, 159 in Top 500 Ranks & 3542 t o t a l s e l e c t i o n s i n I I T - J E E 2 0 1 2
FULL TEST IV
Time Allotted: 3 Hours Maximum Marks: 432

P l e a s e r e a d t h e i n s t r u c t i o n s c a r e f u l l y. Y o u a r e a l l o t t e d 5 m i n u t e s
specifically for this purpose.
Y o u a r e n o t a l l o we d t o l e a v e t h e E x a m i n a t i o n H a l l b e f o r e t h e e n d o f
ALL INDIA TEST SERIES
the test.
INSTRUCTIONS
A. General Instructions
1. Attempt ALL the questions. Answers have to be marked on the OMR sheets.
2. This question paper contains Three Parts.
3. Part-I is Physics, Part-II is Chemistry and Part-III is Mathematics.
4. Each part has only one section: Section-A.
5. Rough spaces are provided for rough work inside the question paper. No additional sheets will be
provided for rough work.
6. Blank Papers, clip boards, log tables, slide rule, calculator, cellular phones, pagers and electronic
devices, in any form, are not allowed.
B. Filling of OMR Sheet

1. Ensure matching of OMR sheet with the Question paper before you start marking your answers
on OMR sheet.
2. On the OMR sheet, darken the appropriate bubble with black pen for each character of your
Enrolment No. and write your Name, Test Centre and other details at the designated places.
3. OMR sheet contains alphabets, numerals & special characters for marking answers.
C. Marking Scheme For All Three Parts.

(i) Section-A (01 to 02 and 09 to 30) contains 24 multiple choice questions which have only one
correct answer. Each question carries +4 marks for correct answer and 1 mark for wrong
answer.
Section-A (03 to 08) contains 6 multiple choice questions which have only one correct answer.
Each question carries +8 marks for correct answer and 2 mark for wrong answer.
Name of the Candidate
Enrolment No.
FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com
AITS-FT-IV-PCM-JEE(Main)/13
2
Useful Data
PHYSICS
Acceleration due to gravity g = 10 m/s2
Planck constant h = 6.6 1034 J-s
Charge of electron e = 1.6 1019 C
Mass of electron me = 9.1 1031 kg
Permittivity of free space 0 = 8.85 1012 C2/N-m2
Density of water water = 103 kg/m3
Atmospheric pressure Pa = 105 N/m2
Gas constant R = 8.314 J K1 mol1
CHEMISTRY
Gas Constant R = 8.314 J K1 mol1

= 0.0821 Lit atm K1 mol1
= 1.987 2 Cal K1 mol1
Avogadro's Number Na = 6.023 1023
Plancks constant h = 6.625 1034 Js
= 6.625 1027 ergs
1 Faraday = 96500 coulomb
1 calorie = 4.2 joule
1 amu = 1.66 1027 kg
1 eV = 1.6 1019 J
Atomic No: H=1, He = 2, Li=3, Be=4, B=5, C=6, N=7, O=8,

N=9, Na=11, Mg=12, Si=14, Al=13, P=15, S=16,
Cl=17, Ar=18, K =19, Ca=20, Cr=24, Mn=25,
Fe=26, Co=27, Ni=28, Cu = 29, Zn=30, As=33,
Br=35, Ag=47, Sn=50, I=53, Xe=54, Ba=56,
Pb=82, U=92.
Atomic masses: H=1, He=4, Li=7, Be=9, B=11, C=12, N=14, O=16,
F=19, Na=23, Mg=24, Al = 27, Si=28, P=31, S=32,
Cl=35.5, K=39, Ca=40, Cr=52, Mn=55, Fe=56, Co=59,
Ni=58.7, Cu=63.5, Zn=65.4, As=75, Br=80, Ag=108,
Sn=118.7, I=127, Xe=131, Ba=137, Pb=207, U=238.
3 AITS-FT-IV-PCM-JEE(Main)/13
Physics PART I
SECTION A
Single Correct Choice Type
This section contains 30 multiple choice questions. Each question has four choices (A), (B), (C) and (D)
out of which ONLY ONE is correct.
1. An alternating voltage 220V and 50Hz is applied across a circuit containing pure resistance R,
inductance L and capacitance C in series. Across which of the following can the voltage be
greater than 220V ?
(A) R, L & C (B) either L or C
(C) L and C taken together (D) both (B) and (C)
2. A small ball strikes at one end of a stationary uniform frictionless rod of mass m and length l
which is free to rotate, in gravity-free space. The impact is elastic. Instantaneous axis of rotation
of the rod will pass through
(A) its center of mass.
(B) the center of mass of rod plus ball.
(C) the point of impact of the ball on the rod.
(D) the point which is at a distance 2l / 3 from the striking end.
3. The value of R for which 20 % of the main current passes R

through galvanometer of resistance 80 is
(A) 10 (B) 20
(main current)
(C) 30 (D) 40 G
I
4. A sphere of radius R is uniformly charged so that total charge on sphere is Q. Potential difference
between center of sphere and surface of sphere is
(A) Q/4 0 R (B) Q/8 0 R
(C) Q/16 0 R (D) Q/32 0 R
5. A large metallic plate is facing a charged sheet having charge

density placed parallel to plate at a distance A from the plate.
Potential at point P at a distance x from the sheet is P
x

(A) (A + x) (B) (A x)
20 20
l
(C) (A x) (D) (A + x)
0 0
Rough work
4
6. The circuit shown in the figure consists of a battery of emf E, R2

resistances R1 and R2, inductance L and a two way switch ABC.
First A is connected to B for a long time and then A is connected
to C. The total heat produced in R2 is A C
E2 E2 L B
(A) L 2 (B) L 2
R1 2R2
E2 E2 E R1
(C) L (D) L
2R12 2R1R2
7. As shown in figure, sphere of mass m is constrained to rotate about in l

a vertical plane by connecting it to O by means of a rigid light rod of o m
length A . What is the velocity of the sphere when it hits the wall of
container ? It is given that specific gravity of ball is 2 and the container
is filled with water.
(A) 2gA (B) 0.5gA
3
(C) gA (D) gA
2
1/2
E 1 RC
8. Consider three quantities x = , y= and z = . Here A is the length of a wire, C is
B 0 0 A
a capacitance and R is a resistance. All other symbols have standard meanings
(A) y, z have the same dimensions (B) z, x have the same dimensions
(C) x, y have the same dimensions (D) all of the three have the same dimensions
9. A projectile is projected in the earths gravitational with initial kinetic energy E. The horizontal of
the projectile range is R. If the mass of the projectile is 1 kg then the angle of projection of the
projectile will be equal to
gR gR
(A) sin1 (B) 2 sin1
2E 2E
gR gR
(C) 0.5 sin1 (D) 4 sin1
2E 2E
Rough work
10. Three rods of identical cross-sectional area are made from the same metal from the sides of an
isosceles right angled triangle ABC, right angled at B. The points A and B are maintained at
temperatures T and 2T respectively. In the steady state, the temperature of point C is TC. There
BD
is a point D on BA, whose temperature is same as TC. Then the ratio is
DA
(A) 1 (B) 2
1
(C) (D) 2
2
11. Neglect the effect of rotation of the earth. Suppose the earth suddenly stops attracting objects
placed near its surface. A person standing on the surface of the earth will
(A) fly up.
(B) slip along the surface.
(C) fly along a tangent to the earths surface.
(D) remain standing.
12. Variation of internal energy with density of one mole of monatomic gas is U
depicted in the adjoining figure, corresponding variation of pressure with
volume can be depicted as (Assuming the curve is rectangular hyperbola)

(A) P (B) P
v v
(C) P (D) P
v v
13. The acceleration time graph of a particle is shown in the figure. a

What is the velocity of particle at t = 8s, if initial velocity of 4
particle is 3 m/s?
(A) 4 m/s
(B) 5 m/s t
O 4 8
(C) 6 m/s 1
(D) 7 m/s
Rough work
6
14. Let B and denote induction to magnetic field and energy density at mid point of a long solenoid
carrying a current i. The graph between and B will be
(A) Y (B) Y
O X O X
B B
(C) Y (D) Y
B X O X
B
15. In the given figure, the angle of inclination of the inclined plane is 30. V0
Find the horizontal velocity V0 so that the particle hits the inclined
plane perpendicularly. 90
2gH 2gH H
(A) V0 = (B) V0 =
5 7
90 30
gH gH
(C) V0 = (D) V0 =
5 7
16. A chain of mass 10 kg and length 10 m is resting on a rough horizontal surface ( = 0.2). A
constant force of 20 newton is applied at one end. The tension in the mid point of the chain is
(A) 20 N (B) 15 N
(C) 10 N (D) 5 N
17. Find the speed of the block when it covers a horizontal F0

distance A. It is given that the block never loses contact with u=0
the smooth horizontal surface, and the force always acts at an M
angle with the horizontal. smooth
AF0 cos 2AF0 cos
(A) (B)
m m
2AF0 cos AF0 cos
(C) (D)
m m
Rough work
18. Two fixed long conducting wires cross each other perpendicularly so
that they do not actually touch but are close to each other as shown in I II
the figure. Equal current i exist in each wire in the directions indicated.
In what region(s) will there be some points with zero net magnetic
field?
III IV
(A) IV, III (B) III, II
(C) II, IV (D) I, IV
19. A sample of hydrogen gas is excited by means of a monochromatic radiation. In the subsequent
emission spectrum, 10 different wavelengths are obtained, all of which have energies greater
than or equal to the energy of the absorbed radiation. It follows that the initial quantum number of
the state (before absorbing radiation) was
(A) 5 (B) 4
(C) 3 (D) 2.
20. The ratio of the min in a Coolidge tube to deBroglie of the electrons striking the target depends on
accelerating potential V as
min min
(A) V (B) V
deBroglie deBroglie
min 1 min 1
(C) (D) .
deBroglie V deBroglie V
21. The minimum distance between an object and its real image formed by a thin convex lens of focal
length 30 cm is
(A) 45 cm (B) 50 cm
(C) 75 cm (D) 120 cm
22. A thin concave and a convex lens have the same focal length of 40 cm, and are put into contact
to form a lens combination. The combination is used to view an object of 5 mm length kept at 20
cm form the lens combination. As compared to the object, the image will be
(A) Magnified and inverted (B) Reduced and erect
(C) Of the same size as the object and erect (D) Of the same size as the object but inverted
23. A uniform plank of Youngs modulus Y is moved over a smooth horizontal surface by a constant
horizontal force F0. The area of cross-section of the plank is A. The compressive strain on the
plank in the direction of the force is
F 2F0
(A) 0 (B)
AY AY
F0 3F0
(C) (D)
2AY AY
Rough work
8
24. A solid ball of radius 0.2m and mass 1kg lying at rest on a smooth 50N-s
horizontal surface is given an instantaneous impulse of 50 N-s at point P
P as shown. The number of rotations made by the ball about its
30
diameter before hitting the ground is
625 3 2500 3
(A) (B)
2 2
3125 3 1250 3
(C) (D)
2 2
25. A thin uniform spherical shell and a uniform solid cylinder of

the same mass and radius are allowed to roll down a fixed
incline, without slipping, starting from rest. The times taken by
them to roll down the same distance are in the ratio, tsph : tcyl
14 15
(A) (B)
15 14
3 10
(C) (D) .
10 3
26. A particle A is attached to a spring and the time period for small oscillations is observed to be T;
when an additional mass dm is added on, the time period becomes T + dT. The mass of particle
A is
1 1
dT dT 2 dT dT
2
(A) dm 2 + (B) dm 2 + 2 +
T T T T
1
dT
(C) dm 2 (D) none of these
T
Rough work
27. The equation of a vibrating string, fixed at both ends, is given by

x
y = (3 mm)sin sin(400t)
15
where x is the distance (in cm) measured from one end of the string, t is the time (in seconds),
and y gives the displacement. The string vibrates in 4 loops.
The speed of transverse waves along the string equals, for the fundamental mode,
(A) 60 m/s (B) 120 m/s
(C) 30 m/s (D) 15 m/s.
28. The vibrations produced in a sitar wire are

(A) progressive transverse (B) progressive longitudinal
(C) stationary transverse (D) stationary longitudinal.
G G
29. Given F = (xy 2 )i + (x 2 y)j newton. Find the work done by F when a particle is taken along the
semicircular path OAB where the co-ordinates of B are (4, 0).
65 75
(A) J (B) J
3 2
73
(C) J (D) 0 J
4
30. A small cube of mass m slides down a circular path of radius R cut into a m
larger block of mass M, as shown in the figure. M rests on a table, and R
both blocks move without friction. The blocks are initially at rest, and m
starts from the top of the path. The velocity v of the cube as it leaves the
M
block is
2mgR
(A) (B) 2gR
M
2mgR 2MgR
(C) (D)
m+M m+M
Rough work
10
Chemistry PART II
SECTION A
1. One of the reaction coordinate energy diagrams of two nucleophilic substitution reactions are
given below:
Energy
R-X R-X
Nuc Nuc
R - Nuc
R - Nuc
X-
X-
(A) Reaction coordinates (B) Reaction coordinates
Which of the following statement(s) is/are true?
(A) (A) corresponds to SN1 and (B) corresponds to SN2.
(B) (A) corresponds to SN2 and (B) corresponds to SN1.
(C) Both (A) and (B) correspond to SN2.
(D) Both (A) and (B) correspond to SN1.
2. A liquid (A) is treated with Na2CO3 solution. A mixture of two salts (B) and (C) are produced in the
solution. The mixture on acidification with sulphuric acid produces the liquid A again (A) is
(A) H2O2 (B) Br2
(C) CS2 (D) CCl4
3. The 2NO + Br2 2NOBr follows the mechanism below

(i) NO + Br2
NOBr2 fast
(ii) NOBr2 + NO 2NOBr slow
If the concentration of both NO and Br2 are increased two times the rate of reaction would
become
(A) 4 times (B) 6 times
(C) 16 times (D) 8 times
Rough work
4. Which of the following statement is/are correct?

(i) The ligand thiosulphato S 2 O32 can give rise to linkage isomers.
(ii) In metal carbonyls the ligand CO molecule acts both as donor and acceptor.
(iii) The complex K[Cu(CN)2] has coordination number 2.
(iv) The complex ferricyanide does not follow effective atomic number (EAN) rule.
(A) (i), (ii) and (iii) (B) (i), (ii) and (iv)
(C) (i), (iii) and (iv) (D) (ii), (iii) and (iv)
5. In the following reaction sequence:

O
+ [ X]
(i) p TSA, C H Heat
6 6
(ii) CHCl , KOH

3
N (iii) H3 O+
H
What is the major product [X]?
(A) O O (B) O
Cl
OH Cl
(C) O O (D) O
Cl
H
6. The 2s-orbital of H-atom has a radial node at 2a0 because 2s is proportional to

(A) (1/2 + r/a0) (B) (2 + r/a0)
(C) (2 r/2a0) (D) (2 r/a0)
7. The standard emf E0 for the reaction

fumarate2 + lactate succinate2 + pyruvate is on the basis of the following information
fumarate2 + 2H+ + 2e succinate2 E0 = 0.031 V

pyruvate + 2H+ + 2e lactate E0 = 0.185 V
(A) 0.154 V (B) 0.216 V
(C) 0.216 V (D) 0.154 V
Rough work
12
8. OLi
(B )
RMgX
(A)
R CuLi
O
2
Hydrolysis Hydrolysis
(D ) (C)
Identify the compounds (C) and (D) respectively.
(A) O O (B) O O
R OH R R
and and
OH R OH OH
(C) O O (D) O O
R R R OH R
and and
OH
OH OH
9. Consider the following statement(s):

(i) Hypophosphorous acid shows reducing properties.
(ii) Pyrophophoric acid can show basicities from one to four because it has 4-OH groups
attached to the phosphorous.
(iii) Orthophosphoric acid is obtained during disproportionation of hypophosphorous acid.
(iv) Metaphosphoric acid on heating gives P4O10.
Which of the following is/are correct:
(A) (i), (ii) and (iii) are correct (B) (i), (ii) and (iv) are correct
(C) (i), (iii) and (iv) are correct (D) All are correct
10. What is the correct order of bond angle in the following?

(A) CH4 > NF3 > NH3 > H2O (B) CH4 > NH3 > NF3 > H2O
(C) CH4 > NH3 > H2O > NF3 (D) NF3 > CH4 > NH3 > H2O
Rough work
11. How many chiral centre(s) (excluding N centre) is/are there in morphine?
HO
O
H
N
CH3
H
HO
(A) 4 (B) 5
(C) 6 (D) more than 6
12. The products formed when a mixture of the following two amides (I and II) are treated with
bromine and aqueous KOH are
15
CONH2 CONH2
NO2
(A) NH2 NH2 (B) 15
NH2 NH2
and
and
NO2
NO2
(C) 15 (D) A mixture of all of there.
NH2 NH2
and
NO2
Rough work
14
13. Which of the following cannot be taken as unit cell of any lattice?
Q
R S
(A) P (B) Q
(C) R (D) S
14. Which of the following graphs is/are inconsistent with ideal gas behaviours?
(A) (B)
T2 > T1
T2
P
T1 PV T1
T2
V
P
(C) (D)
P2 > P1 T2 > T1
P1 T2
P2 T1
V P
T (K)
N
Rough work
15. Which statement is true if the following reaction is spontaneous?

ZZZ
X
Zn + Cu2 + YZZ 2+
Z Zn + Cu
(A) Kc is larger than 1; Go is negative, and Eo is positive.
(B) Kc is larger than 1; Go is positive, and Eo is negative.
(C) Kc is larger than 1; Go is negative, and Eo is negative.
(D) Kc is smaller than 1; Go is negative, and Eo is positive.
16. ( A ) + (B )
SnCl2 + HCl + I2
The compounds (A) and (B) are:
(A) SnI2, Cl2 (B) H2SnCl4, HI
(C) SnCl4, HI (D) HSnCl3, HI
17. In an O2 molecule how many sets of degenerate molecular orbitals are present?
(A) 1 (B) 2
(C) 3 (D) 4
18. In the following graph

0.2
Radialprobability distribution (Pn,l)
Pn3, A 3
Pn2, A 2 Pn1, A1
0.1
0
5 10 15 20
Radius (a0)
Then, what is correct set of quantum nos. for the given graphs?
(A) n1 = 3 l1 = 1, n2 = 2 l2 = 2, n3 = 2, l3 = 2
(B) n1 = 3 l1 = 0, n2 = 3 l2 = 1, n3 = 3, l3 = 2
(C) n1 = 3 l1 = 2, n2 = 3 l2 = 1, n3 = 3, l3 = 0
(D) n1 = 3 l1 = 0, n2 = 3 l2 = 1, n3 = 2, l3 = 2
Rough work
16
19. A colourless gas X forms a brown coloured gas when mixed with air. The gas X is
(A) NH3 (B) NO
(C) N2O (D) NO2
20. Among the following the optically inactive compound is

(A) N (B) P
H3C CH2 H3C
CH3
(C) (D)
H3C
C C C C
H
CH3
COOH
HO
21. Consider the ionization

H+ + H3N+ CH2COO YZZZZZX + ZZZ
X
Z H2NCH2COOH + H
Z H3N CH2COOH YZZ
+
Assuming that the following acid dissociation constants apply to the ionizations:
NH3+ YZZ
ZZZ
X + 10
Z NH2 + H ; K a = 1.6 10 M
+
ZZZ
X
COOH YZZ
Z COO + H ; K a = 4.0 103 M
Estimate a value for the equilibrium constant for the process
H3N+ CH2COO YZZ
ZZZ XZ H2NCH2COOH is
(A) 4.0 108 (B) 0.25 10+7
(C) 6.4 1013 (D) 1 108
22. The gas phase reaction between nitric oxide and oxygen is third order. The following rate
constant have been measured:
T/K : 80.0 143.0 228.0 300.0 413.0 564.0
K109/cm6mol7s1: 41.8 20.2 10.1 7.1 4.0 2.8
The behaviour is interpreted in terms of a temperature dependent pre exponential factor; the rate
constant is of the form
K = aTn eE/RT
Where a and n are constants. Assume the activation energy to be zero.
What is the value of n to the nearest half integer.
(A) 1.5 (B) 1.5
(C) 0.5 (D) 0.5
Rough work
H
23. P for an ideal gas is equal to
T
RT R
(A) V (B) TV
P P
( V )
(C) Zero (D)
T
24. In the freezing point depression experiment, it can be noted that:
(A) Vapour pressure of the solution is less than that of pure solvent.
(B) Only solute molecules solidify at freezing point.
(C) Solvent molecules solidify at a temperature above the freezing point of pure solvent.
(D) If weight of solute is much less than the weight of solvent and Hfus is heat of fusion per mole
RTf0
of solvent than the gradient (slope) of the following plot is found to be , where y = mass
Hfus
fraction of solute in the solution.
Tf

25. Calcium phosphide (Ca3P2) formed by reacting calcium orthophosphate [Ca3(PO4)2] with
magnesium was hydrolysed by water. The evolved PH3 was burnt in air to yield P2O5. How many
moles of Mg(PO3)2 would be obtained, if 384 g of Mg were used for reducing calcium phosphide.
Ca3 (PO4 )2 + Mg Ca3P2 + MgO
Ca3P2 + H2O Ca ( OH)2 + PH3

PH3 + O2 P2O5 + H2O
MgO + P2O5 Mg (PO3 )2

(A) 2 moles (B) 16 moles
(C) 8 moles (D) 4 moles
Rough work
18
26. In the following reactions:

CH3
CH3
NaOEt
(A) NaOEt
(B )
Cl Cl
H3C CH3 H3C CH3

What are the structures of (A) and (B) respectively
(A) CH3 CH3 (B) CH3 CH3
and and
H3C CH3 H3C CH3

H3C CH3 H3C CH3
(C) CH3 (D) CH3
Only Only
H3C CH3 H3C CH3
27. Ester hydrolysis in acidic condition can follow

(A) SN1 and SN2 both (B) Only SN1
(C) Only SN2 (D) SN1, SN2 and tetrahedral mechanism
Rough work
28. NO 2

NaOEt
+ NH2OH ?
(A) NO 2 (B) NO2
NH2
NH2
(C) NH2 (D) NH2
NH2
NH2
29.
CN

NaNH
( X ) major
Cl 2
OMe
What is the structure of (X)?
(A) CN (B) CN
OMe
OMe
(C) CN (D)
CN
OMe
OMe
30. Which of the following statements are in correct regarding Co2+ and Cr3+ ions?
(i) The spin magnetic moment of both the ions is same
(ii) The magnetic moment of both the ions in different
(iii) The magnetic moment of both the ions is not different
(iv) They both have same numbers of unpaired electrons
(A) (i) only (B) (iii) only
(C) (i) and (iii) both (D) All
Rough work
20
Mathematics PART III
SECTION A
1. The roots of 1 + z + z3 + z4 = 0 are represented by the vertices of

(A) a square (B) an equilateral triangle
(C) a rhombus (D) a rectangle
G G G G G G
2. The equation of plane containing the lines r = a + b and r = b + a is
GGG GGG GG
(A) [r ab] = 0 (B) [r ab] = a.b
GGG GG GGG GG
(C) [r b a] = a.b (D) [r ab] = 2a.b

3. If sin4 + cos4+ 2 = 4 sin cos , 0 , , then sin + cos is equal to
2
(A) 2 (B) 0
(C) 2 (D) 1
4. Number of points with integral coordinates lying on the circle x2 + y2 = 2008 is

(A) 0 (B) 4
(C) 8 (D) 16
5. If the equation ax2 bx + 12 = 0 where a and b are +ve integers not exceeding 10, has both roots
greater than 2 then the number of ordered pair (a, b) is
(A) 0 (B) 1
(C) 3 (D) 5
Rough work
6. The number of different ordered triplets (a, b, c), a, b, cI such that these can represent sides of
a triangle whose perimeter is 21, is
(A) 12 (B) 31
(C) 55 (D) 91
7. If the cube of a natural number ends with a prime digit then the probability of its fourth power
ending not with a prime digit, is
(A) 3/10 (B) 9/10
(C) 4/9 (D) 3/4
8. The number of different permutations of all the letters of the word 'PERMUTATION' such that any
two consecutive letters in the arrangement are neither both vowels nor both identical is
(A) 63 6! 5! (B) 57 5! 5!
(C) 33 6! 5! (D) 7 7! 5!
9. When 3233 is divided by 34, it leaves the remainder

(A) 2 (B) 4
(C) 8 (D) 32
C1 2 11C2 3 11C3
11
10. The value of 1 2 + 2 24 + ... upto 12 terms is
23 34 45
(A) 1/10 (B) 1/11
(C) 1/12 (D) 1/13
| x | 2 x 2
11. The maximum value of f(x) = , (xR), is
| x | +1
(A) 4 (B) 3
(C) 2 (D) 1
12. Maximum number of common normals of y2 = 4ax and x2 = 4by can be equal to
(A) 3 (B) 4
(C) 6 (D) 5
Rough work
22
13. The equation 2x3 15x2 + 36x + k = 0 has three real and distinct roots. The total number of
integral values of k is
(A) 0 (B) 1
(C) 2 (D) none of these
14. A cubic f(x) vanishes at x = 2 and has relative minimum/maximum at x = 1 and 1/3 such that
1 14
1
f ( x ) dx =
3
. Then f(x) is equal to
(A) x 3 + x 2 x (B) x 3 + x 2 x + 1
3 2
(C) x + x x + 2 (D) x 3 + x 2 x 2
{2 ( t 1)( t 2) ( t 2 )2 dt}
x
The function f ( x ) = + 3 ( t 1)
3 2
15. attains its maximum at x is equal to
1
(A) 1 (B) 2
(C) 3 (D) 4
x2
16. The value of lim , where [] denotes greatest integer function, is equal to
x 0 sin x tan x

(A) 0 (B) 1
(C) limit does not exist (D) none of these
17. Let A be a square Matrix all of whose entries are integers. Then the true statement is
(A) If det A = 1, then A1 exists but all its entries are not necessarily integers
(B) If det A 1, then A 1 exists and all its entries are non integers
(C) If det A = 1, then A 1 exists and all its entries are integers
(D) If det A = 1, A 1 need not exist
4 0 0
18. If A is a square Matrix such that A. ( AdjA ) = 0 4 0 then
0 0 4
(A) A = 5 (B) adjA = 18
adj ( adjA )
(C) = 16 (D) adj2A = 128
adjA
Rough work
19. sin1 cos x cos1 sin x = a has at least one solution iff a

(A) {0} (B) 0,
2
3
(C) , (D) ( 0, )
2 2
20. Area bounded by the minimum of { x 1, y 1} = 1 and the maximum of { x 1, y 1} = 4 in

square units is
(A) 16 (B) 36
(C) 25 (D) 45
x2 + 1
21. The range of function f(x) defined by f ( x ) = , x R {0} is
(
loge x 2 + 1 )
(A) ( 0,1) (B) ( 0,2 )
(C) [ e, ) (D) ( , )
22. The area bounded by the parabola x2 + 8x +12y + 4 = 0 and its latus rectum is 6k. Then the value
of k is
(A) 1 (B) 2
(C) 3 (D) 4
23. Let f ( x ) = x 3 + ax 2 + bx + c and x1, x2 be the roots of f ( x ) = 0 , if x1 < x 2 then f ( x ) = 0 will have
(A) No real root if f ( x1 ) < 0 or f ( x 2 ) > 0
(B) Only one real root if f ( x1 ) < 0 or f ( x 2 ) > 0
(C) Three real roots if f ( x1 ) < 0 or f ( x 2 ) > 0
(D) cannot say any thing
24. If a, b, c are unit vectors then | a + b |2 + | b + c |2 + | c + a |2 can not be less than

(A) 3 (B) 6
(C) 9 (D) 12
Rough work
24
2
25. If f(x) is a twice differentiable function such that f(0) = f(2) = 3;f (0) = f (2) = 1 then x f (x)dx
0
is
(A) 3 (B) 2
(C) 1 (D) 0
100x 99 sin x
26. The value of lim
x 0 sin x
+ where [.] denotes the greatest integer function is
x
(A) 197 (B) 196
(C) 198 (D) does not exist
27. General solution of (xy sin xy + cos xy)y dx + (xy sin xy cos xy) x dy = 0 is
(A) y.sin (xy) = cx (B) x.sec (x y) = cy
(C) y tan (xy) = cx (D) y cot (xy) = cx
28. The general solution of the differential equation (3x + 2y2) y dx + 2x (2x + 3y2) dy = 0, is
(A) x6y2 + x4y3 = c (B) x6y2 + x3y4 = c
2 6 4 3
(C) x y + x y = c (D) x2y6 + x3y4 = c
x + 1, x < 0 x + 1, x<0
29. Let f(x) = and g(x) = 2
then the number of points at which the
x 1, x 0 ( x 1) , x 0
function g ( f ( x ) ) is not differentiable is
(A) 0 (B) 1
(C) 2 (D) 3
cos9x + cos 6x
30. 2cos5x 1
dx = A sin 4x + B sin x + C then A + B is equal to
1 3
(A) (B)
2 4
5 7
(C) (D)
4 4
Rough work

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FIITJEE JEE (Main), 2013

Time Allotted: 3 Hours Maximum Marks: 432

B. Filling of OMR Sheet

C. Marking Scheme For All Three Parts.

Name of the Candidate

Planck constant h = 6.6 1034 J-s

Charge of electron e = 1.6 1019 C

Mass of electron me = 9.1 1031 kg

Permittivity of free space 0 = 8.85 1012 C2/N-m2

Density of water water = 103 kg/m3

Atmospheric pressure Pa = 105 N/m2

Gas constant R = 8.314 J K1 mol1

Gas Constant R = 8.314 J K1 mol1

Atomic No: H=1, He = 2, Li=3, Be=4, B=5, C=6, N=7, O=8,

3. The value of R for which 20 % of the main current passes R

5. A large metallic plate is facing a charged sheet having charge

6. The circuit shown in the figure consists of a battery of emf E, R2

7. As shown in figure, sphere of mass m is constrained to rotate about in l

13. The acceleration time graph of a particle is shown in the figure. a

17. Find the speed of the block when it covers a horizontal F0

25. A thin uniform spherical shell and a uniform solid cylinder of

27. The equation of a vibrating string, fixed at both ends, is given by

28. The vibrations produced in a sitar wire are

3. The 2NO + Br2 2NOBr follows the mechanism below

4. Which of the following statement is/are correct?

5. In the following reaction sequence:

6. The 2s-orbital of H-atom has a radial node at 2a0 because 2s is proportional to

7. The standard emf E0 for the reaction

fumarate2 + 2H+ + 2e succinate2 E0 = 0.031 V

9. Consider the following statement(s):

10. What is the correct order of bond angle in the following?

15. Which statement is true if the following reaction is spontaneous?

18. In the following graph

20. Among the following the optically inactive compound is

H3C CH2 H3C

21. Consider the ionization

Ca3P2 + H2O Ca ( OH)2 + PH3

MgO + P2O5 Mg (PO3 )2

26. In the following reactions:

H3C CH3 H3C CH3

H3C CH3 H3C CH3

H3C CH3 H3C CH3

27. Ester hydrolysis in acidic condition can follow

(A) NO 2 (B) NO2

Mathematics PART III

1. The roots of 1 + z + z3 + z4 = 0 are represented by the vertices of

4. Number of points with integral coordinates lying on the circle x2 + y2 = 2008 is

9. When 3233 is divided by 34, it leaves the remainder

20. Area bounded by the minimum of { x 1, y 1} = 1 and the maximum of { x 1, y 1} = 4 in

24. If a, b, c are unit vectors then | a + b |2 + | b + c |2 + | c + a |2 can not be less than

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