Answers & Solutions Chemistry Part - A: T A A T

Answers & Solutions
Chemistry
Part A
1. B
+
1. The electron configuration of Cu is :
2 2 6 2 6 10
1s 2s 2p 3s 3p 3d
Number of electrons with l = 0 is 6
Number of electrons with l = 2 is 10
Total number of electrons = 16
2. C
3 3
2. Phosphorus undergoes sp d hybridization instead of dsp .
3. C
t 1
2 2 a
2
1n
t
3.
1
a1
2 1
1n 3 1n
1 1 1 1
8 2 or,
2 2
or, 1 n = 3 or n = 2
4. B
4. At equilibrium, pX + pY + pZ = 6
Since the concentration of the reacting species are same, p x = py = pz = 2atm
22
Kp 2 atm
2
5. B
n n 1
5. 6n 4
2
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2
Six-different transitions takes place.
n = 4 n = 3, n = 4 n = 2, n = 4 n = 1
n = 3 n = 2, n = 3 n = 1
n=2n=1
The visible region (Balmer series) involves the transitions n = 3 n = 2 and n = 4 n = 2.
6. A
6. Since carbon is more electronegative than hydrogen, the bp - bp repulsion is highest for the two CH
bonds.
7. C
7. It is a zero order reaction for which the half-life is given as :
a
t1 t1/2 a (initial concentration of reactant)
2 2k
8. A
8.

SO3 (g) CO(g)
SO2 (g) CO2 (g)
Initial 1 1 1 1
At Equilibrium 1 0.5 1 0.5 1 + 0.5 1 + 0.5
1.5 1.5
Kc 9
0.5 0.5
34
Q 6 Q KC,
1 2
The reaction will proceed towards forward direction
9. C
nRT 4 0.0821 400

9. P 13.136 atm
V 10
10. C
3
2
10. Rate = k[X] [Y]
4 108 = k [0.1] [0.1]

2
4 108
k 4 105 mol2L2 sec 1
102 101
11. B
11. The reaction is second order with respect to X.
1 1
t1/2 t1/2
Ka a
12. AB
12. Spin-multiplicity = 2S + 1
1 1
= 2n 1 2 3 1 4
2 2
It contains 8 electrons with l = 0 ( 1s2 2s2 3s2 4s2 )
It contains 3 unpaired electrons.

Its magnetic moment = n(n 2) 3(3 2) B.M.
Its tripositive ion contains 30 electrons which is not the atomic number of any inert gas.
13. ABC
13. The corrects structure is:
F
Cl
Cl
Cl
14. AB
Sol. The reaction moves towards forward direction by increasing temperature as it is an endothermic reaction.
Decreasing pressure favours the reaction towards more number of moles.
4
15. ABD
Sol. The concentration of a reactant can be increased to such a label where the change in concentration is
minimum ~ negligible. The order due to this reactant will be zero. Catalyst can change the mechanism
as well as order. Due to similarity in concentration and gas pressure, pressure change can also affect the
order.
Part C
1. 1
Sol. Cl 1s22s22p63s23p5
=1
2. 7
N 1s 2s 2p (3 unpaired electron)
2 2 3
Sol.
N2 No unpaired e

O 2 unpaired electrons
O2 2 unpaired electrons
3. 8
Sol. 3X Y
a 0
a 3x x
At t *X+ = *Y+
a 3x = x a = 4x x = a/4
a t1/ 2 a
a
t1/ 2

2 4
t = 2 t1/2 = 2 4 = 8 sec
4. 8
5
Sol. KP pNH3 pHCl 16
pNH3 pHCl ,pNH3 pHCl pequm = 4 + 4 = 8 atm
5. 5
Sol. The orbitals that hold electrons are 4s, 4px, 4pz, 4dz2 and 4dxz
Since s = - , the five orbitals will contain one electron each.
Mathematics
Single Correct Choice (01 07)
1. B M120322
2
4x 3 4x 3
1. f x 2 sin2 2cos
6 3
2 2

2
4x 3 4x 3
1 cos 2cos
3 3
2 2

4x 3
1 cos2
3
2
1 8x 6
2 1 cos
3
2
2
3 1 8x 6
cos
3
2
2 2
2 63 33
Period of f x
8 8 4
3 2
2. A M120317
2
1 3 3
2. 9x 3x 1 3 x
2 4 4
3 28
For x ,1 , 9x 3x 1 .
4 4
6
3. B M120315
3. 2 x2 3 x x
2 2
x2 x2 2
Also, 2x 3
1 1 1
or
3 x 2
1 1

x x
1
Hence, x2 2
x
or x3 2x 1 0
or x 1 x2 x 1 0
1 5
x x 0
2
4. A M120316
1 e
1/ x 1
0 e
1/ x 1
4. 1
1 x 1
1 0 0 + +
x x
O 1
x ,0 1,
5. B M110603
5. For x 0 , sin x x
sin x
1
x
For x 0 , sin x x
sin x
1
x
100x 99 sin x
Hence, lim x
100 98 198
x 0
sin x
7
6. D M120306
6. Clearly, R is reflexive and symmetric.
Let z1Rz2 and z2Rz3
z1 z2
is real, say k
z1 z2
z 2 z3
and is real, say l
z 2 z3
z1 z2 z 1 k
Now, k 1
z1 z2 z2 1 k
z 2 z3 z 1 l
and l 2
z 2 z3 z3 1 l
z1 1 k 1 l
Thus,
z3 1 k 1 l
z1 z3 1 k 1 l 1 k 1 l

z1 z3 1 k 1 l 1 k 1 l
which is real.
7. C M120412
7. f x x2 3x 2 cos x x 1 x 2 cosx
x 2 3x 2 cos x, x 0
2
x 3x 2 cos x,0 x 1
2
x 3x 2 cos x,1 x 2
x 2 3x 2 cos x, x 2
2x 3 sin x, x 0
2x 3 sin x,0 x 1

f ' x
2x 3 sin x,1 x 2

2x 3 sin x, x 2
It is clear that f(x) is not differentiable at x = 1, since

f ' 1 1 sin1
8
and
f ' 1 1 sin1
Comprehension Type (08 11)
8. A M120324
8. Only one positive root

2
y= g(x)
1
y= h(x)
2 2
9. A M120325
9. a 0, 1/ 2 y
1/2
x
2 1 0 1 2
10. D M110606
x
10. In triangle OPR, PR tan QR
2
1 1 x
T x .PR.QR.sin PRQ tan2 sin x
2 2 2
1 x x 1
sec 2 1 sin x tan sin x
2 2 2 2
1 2 1 2 x sin x
S x 1 x 1 sin x
2 2 2
x
T x 2
tan2
sin x
Now, lim lim
x 0 S x x 0 x sin x
9
2
x
tan 2 sin x
x
x
lim 2
1
.
x 0 x sin x 4
x3
x sin x 1
1
2
.1 3 lim
x 0 x 3
6
1 2
4. by L 'Hospital' srule
6
11. C M120504
x sin x
11. S x
2
1 cos x
S' x
2
Multi Correct Type (12 15)
12. ABCD M120308, M120309, M120317
gof x 2x sin x
1/3
12.
Range of (gof) (x) is R.
13. ABCD M120322
13. Option (a) : Periods of sin x and sin x are 2 and respectively.
Period of f(x) = LCM of 2, 2
Option (b) : Period of g x
Option (c) : Period of h x LCM of 2,2 2
1 2
Option (d) : p x x x x
3 3
1 2
x x x 11
3 3
10
1 2
11 x x x
3 3
Period of p(x) is 1.
14. BC M110609, M110603,M110605,M110607
14. lim x
x
x 1 x
x 1 1
lim lim
x
x 1 x x
1 2
1 1
x
x2 x3
x ... x
ln 1 x x
lim
2 3 1
Option (a) : lim 2 2

x 0 x x 0 x 2
x
2 sin2
1 cos x 2 1
Option (b) : lim lim
x 0 x2 x 0
x
2
2
4
2
1 x 1
1/2 1/2
1 x 1 1
Option (c) : lim lim
x 0 x x 0 1 x 1 2
x 1 1
Option (d) : lim lim
x 0 x 0
x x 2 2x 2 2
1 1
x
15. AD M120410
f x 1 1 t dt, x 2
x
15.
0
1 2
2 t dt t dt
1 x
x 1
0 1 2
1 2
x 1, x 2
We have, f x 2
5x 1, x 2
lim f x 3 and lim f x 11

x 2 x 2
Hence, f(x) is not continuous at x = 2.
11
f 2 h f 2
Rf ' 2 lim
h0 h
1
2 h 1 11
2
lim 2
h 0 h
2 h
2
20
lim
h 0 2h
Part C
Integer Type (01 05)
1. 2 M120411
1. LHL = VF = RHL

lim f x f lim f x

x
2
2 x 2

lim f h a lim f h
h0
2 h0
2
1 cos3 h b 1 cosh
lim 2
a lim
h0 3 sin h h0 4h2
1 cosh 1 cosh cos2 h b 1 cosh

lim a lim s
h 0 3 1 cosh 1 cosh h0 4h2
3 b b
a or 8
3 2 8 a
2. 5 M120414
xy
2. Given, f x f y f
1 xy
Putting x = 0, y = 0, we get f (0) = 0 ..(i)
and putting y = x, we get
f x f x f 0 0
f x f x .(ii)
f x h f x
Now, f ' x lim
h0 h
12
f x h f x
lim [from Eq. (ii)]
h0 h
xhx
f
1 x h x
lim
h 0 h
h
f
1 x xh
2
lim
h 0
h

1 x 2 xh . 1 x xh

2

2 f x
f ' x lim 2
1 x2
x 0 x
2 2
f ' 2
1 4 5
and f x 2 tan1 x c
f 0 0 c 0
c=0
f x 2 tan1 x
f 3 2 tan 1
3
2
3
3. 9 M110601
3. lim f x lim f 0 h
x 0 h0
sin1 1 0 h .cos1 1 0 h
lim
h0
2 0 h. 1 0 h
sin1 1 1 h .cos1 1 1 h
lim
h0
2 1 h . 1 1 h
sin1 h.cos1 h
lim
h 0
2 1 h .h 2 2
4. 4 M120322
13
x
4. The period of sin is 24

12
x 24 x 24 x x
as sin
sin sin 2 sin
12 12 12 12
x x 2
Similarly, the period of tan
3
is 3 and the period of cos is 8 .
4
4
Hence, the period of the given function LCM of (24, 8, 3) = 24.
5. 1 M120324
x
5. sin 1 x 2 2x 2
2
x
sin 1 x
2
LHS 0 and RHS 0 .
Then solution is obtained if LHS = RHS = 0 and x satisfies both.
Physics
HINTS AND SOLUTIONS
Part-A
1. C (Concept code: P110216)
Q
Sol. cos = R Q
R
2. A (Concept code: P110321)
14

Sol. v r should be same in both the situations.
45

vr
vm
vr vm
Thus, v r 3 2 km/hr. 3

vm = 3km/hr. 6km/hr = v m
3 3
Sol. Let u be the initial speed of the particle

2 2
Then v = u 2gh
2 2
or u = v + 2gh
or u2x u2y = v 2x v 2y 2gh (vx = ux)
or u2y = v 2y 2gh
or u2y = (2)2 + (2) (10) (0.4) = 12
uy = 12 or 2 3 m / s
and ux = vy = 6 m/s
uy 2 3 1
tan = =
ux 6 3
or = 30
4. B (Concept code: P110420)
Sol. n1 = k(l1 l)
where l is its natural length
n2 = k(l2 l)
n1 (l l)
= 1
n2 (l2 l)
n1l2 n2l1
On solving, l=
(n1 n2 )
Now, n1 = k[(l1 l)]
(n1l2 n2l1 )
= k l1
(n1 n2 )
15
(n1 n2 )
k=
(l1 l2 )
Sol. Since, mg cos > mg sin
Force of friction is f = mg sin
= 2 9.8 sin 30
1
= 2 9.8 = 9.8 N
2
K
Sol. Power P = F .v = .v K cons tan t
v
W = P. t = Kt
Sol. W = Kf Ki =
1
2

m v 2f vi2
1 1
2 2
1
= m a2 t 2 a1t1
2 2 2

1 t 24 2 t ma12 4 4
= m 2 a1 a12 t12 Since, a2 2 a1 = (t 2 t1 )
8 t1 t1 8t12
8. D (Concept code: P110314)

Sol. Question number 8, 9: Take components of V and a along X and Y axis. If at time t, velocity is V t .

Then, if V t is to V i . We have V t Vi = 0.
16
Sol. For just slipping f = 3N
F cos = smg F sin )
Fcos 1
s =
mg Fsin 3
Sol. Just after t = 4 sec.
Fcos k (mg Fsin )

a
m
2 1
a k
3 4
After t = 4 sec.
Fcos k (mg Fsin )

a
m
F(cos k sin )
a k g
m
19 2 5
v (t 16) (t 4)
48 2
At t = 20 sec, v = 112 m/s
12. BCD (Concept code: P110503)
Sol. Apply conservation of mechanical energy to obtain x.
13. BC (Concept code: P110413)

Sol. PQ = 2R
a = g cos
u = 2(g cos ) (2R)

2
u = 2 gRcos
u 2 gR cos R
t= 2
a gcos gcos
In reaching upto centre.
17
u = 2 (g cos ). R =
2
2gRcos .
14. AC (Concept code: P110512)

Sol. Umin = 20 5 = 15 J
Kmax = E Umin = 20 15 = 5J
Umin is at sin (4x) = 1
3 7
4 = ,
2 2
3 7
x= , ,.....
8 8
15. CD (Concept code: P110303)

Sol. As going up, speed of the particle is decreasing and hence time taken
in crossing the windows
(if S1 = S2 = S3) will be t1 < t2 < t3.

Since, u = ua t
u t (as acceleration is same)
So, u1 < u2 < u3
(as for equal windows t1 < t2 < t3)
For unequal windows,
t1 = t2 = t3 if S3 < S2 < S1.
Part-C
1. 6 (Concept code: P110412)
Sol. For equilibrium of block rod
m = 0.5
Mg sin = (N)
= (Mg cos + mg cos ) M
0
37
18
21 6 21
Sol. a= , TB = 6a = = 9 N.
14 14
d2U
Sol. As stable equilibrium, U is minimum. Thus > 0.
dx 2
dv
And = 0.
dx
1 x3 ax 2
= 20x = 0.
dx 3 2
x 9x + 20 = 0. (x 5) (x 4) = 0.
2
x = 5 and x = 4 are points of equilibrium.
d2U
And U minimum when > 0. i.e. at x = 5.
dx 2
Sol. Draw FBD of rod and apply condition of equilibrium.
dv 3t
2
Sol. P = F V = mv
dt 2
v t
3t 2
m v dv dt
0 0
2

1
V = 2 ms

Answers & Solutions Chemistry Part - A: T A A T

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Answers & Solutions

Number of electrons with l = 0 is 6

Number of electrons with l = 2 is 10

Total number of electrons = 16

Since the concentration of the reacting species are same, p x = py = pz = 2atm

Six-different transitions takes place.

The visible region (Balmer series) involves the transitions n = 3 n = 2 and n = 4 n = 2.

7. It is a zero order reaction for which the half-life is given as :

At Equilibrium 1 0.5 1 0.5 1 + 0.5 1 + 0.5

The reaction will proceed towards forward direction

nRT 4 0.0821 400

4 108 = k [0.1] [0.1]

11. The reaction is second order with respect to X.

It contains 8 electrons with l = 0 ( 1s2 2s2 3s2 4s2 )

It contains 3 unpaired electrons.

13. The corrects structure is:

Sol. KP pNH3 pHCl 16

pNH3 pHCl ,pNH3 pHCl pequm = 4 + 4 = 8 atm

Since s = - , the five orbitals will contain one electron each.

Single Correct Choice (01 07)

6. Clearly, R is reflexive and symmetric.

Let z1Rz2 and z2Rz3

It is clear that f(x) is not differentiable at x = 1, since

Comprehension Type (08 11)

8. Only one positive root

Multi Correct Type (12 15)

12. ABCD M120308, M120309, M120317

Range of (gof) (x) is R.

13. ABCD M120322

Period of f(x) = LCM of 2, 2

Option (b) : Period of g x

Option (c) : Period of h x LCM of 2,2 2

14. BC M110609, M110603,M110605,M110607

lim f x 3 and lim f x 11

Hence, f(x) is not continuous at x = 2.

Integer Type (01 05)

1 cosh 1 cosh cos2 h b 1 cosh

Putting x = 0, y = 0, we get f (0) = 0 ..(i)

and putting y = x, we get

Hence, the period of the given function LCM of (24, 8, 3) = 24.

LHS 0 and RHS 0 .

Then solution is obtained if LHS = RHS = 0 and x satisfies both.

HINTS AND SOLUTIONS

1. C (Concept code: P110216)

2. A (Concept code: P110321)

3. C (Concept code: P110313)

Sol. Let u be the initial speed of the particle

or u2x u2y = v 2x v 2y 2gh (vx = ux)

or u2y = (2)2 + (2) (10) (0.4) = 12

4. B (Concept code: P110420)

where l is its natural length

Now, n1 = k[(l1 l)]

5. A (Concept code: P110410)

Sol. Since, mg cos > mg sin

Force of friction is f = mg sin

6. C (Concept code: P110504)

7. B (Concept code: P110502)

8. D (Concept code: P110314)

9. A (Concept code: P110314)

10. B (Concept code: P110411)

Sol. For just slipping f = 3N

F cos = smg F sin )

11. C (Concept code: P110412)