SOAL-SOAL TERMODINAMIKA

U a
1. If dU = TdS PdV and dA = -SdT PdV, derive that 2 for a van der Waals gas
V T V
T V2 1 V 1 V
2. Derive that CP - C V if , and
V T P V P T

P V T
-1
T V P T V P
H V
3. If dH = T dS + V dP, derive that V-T
P T T P
U
4. Derive that - V T V P
P T
5. A real gas has a state equation of PV = R T + B P, determine W, U, q, S, dan H for reversibly
isothermal expansion of the gas.
6. One mol of an ideal gas is initially at 400 K and 1 atm. The gas then is expanded adiabatically at
a pressure of 5 atm to achieve an equilibrium. If CV = (18.8 + 0.021 T) J mol-1 K-1, determine U,
H and S for the process.
7. Derive that
S
a.
V T
U H
b.
S V S P
H G
c.
P S P T