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Par*cle Size reduc*on
CH
2040
–
Mechanical
Opera*ons
Basavaraj
M.
Gurappa
Department
of
chemical
engineering
IIT‐Madras
Par*cle
Size
reduc*on
Size
reduc*on
or
comminu*on
is
an
unit
opera*on
used
to
create
par*cles
of
a
certain
size
and
shape,
to
increase
the
surface
area
available
for
chemical
reac*on
or
to
liberate
valuable
minerals
held
within
the
par*cles
Solids
may
be
broken
in
many
different
ways
–
commonly
used
methods
are
‐
1. Compression
2. Impact
3. ARri*on
or
rubbing
4. CuSng
1
3/26/12
Par*cle
Size
reduc*on
Size
reduc*on
or
comminu*on
is
an
unit
opera*on
used
to
create
par*cles
of
a
certain
size
and
shape,
to
increase
the
surface
area
available
for
chemical
reac*on
or
to
liberate
valuable
minerals
held
within
the
par*cles
Solids
may
be
broken
in
many
different
ways
–
commonly
used
methods
are
‐
1. Compression
2. Impact
3. ARri*on
or
rubbing
4. CuSng
1. Compression
–
common
example
‐
Nutcracker
2. Impact
–
common
example
‐
Hammer
3. ARri*on
or
rubbing
–
common
example
‐
File
4. CuSng
–
common
example
–
A
pair
of
scissors
Stressing Mechanism
1.
Stress
applied
between
two
surfaces
–
at
low
veloci7es
–
0.01
to
10
m/s
(Crushing
+
AAri7on)
2.
Stress
applied
at
a
single
solid
surfaces
–
at
high
veloci7es
–
10
to
200
m/s
(Impact
fracture
+
AAri7on)
2
3/26/12
Energy
and
Power
requirements
in
comminu*on
Cost
of
power
is
a
major
expense
crushing
and
grinding
STAGES
DURING
SIZE
REDUCTION:
The
feed
material
is
distorted
and
strained
The
work
necessary
to
strain
the
material
is
stored
temporarily
in
the
solids
as
mechanical
stresses
When
addi*onal
force
is
applied
to
the
stressed
par*cles,
they
are
distorted
beyond
their
ul*mate
strength
and
suddenly
ruptures
into
fragments
and
new
surface
is
generated
Ul7mate
strength
is
the
maximum
stress
that
a
material
can
withstand
(without
necking
–
when
stretched
or
pulled)
or
rapture
Unit
area
of
a
solid
has
a
definite
amount
of
surface
energy
and
crea*on
of
new
surface
requires
work,
which
is
supplied
by
the
released
stresses
when
the
par*cle
break
Energy
and
Power
requirements
in
comminu*on
Crushing
Efficiency:
The
ra*o
of
the
surface
energy
created
by
crushing
ηe
to
the
energy
absorbed
by
the
solid
is
the
crushing
efficiency,
If
es
is
the
surface
energy
per
unit
area
(feet
*mes
pounds
force
per
square
foot)
and
Awb
and
Awa
are
the
areas
per
unit
mass
of
the
product
and
feed,
respec*vely,
the
energy
absorbed
by
a
unit
mass
of
the
material
Wn
is
es (Awb − Awa )
Wn =
ηe
SIZE
REDUCTION
is
the
least
energy
efficient
of
all
unit
opera*ons
–
that
is
–
the
surface
energy
created
by
fracture
is
small
in
comparison
with
the
total
mechanical
energy
stored
in
the
material
at
the
*me
of
rupture.
Less
than
1%
of
the
energy
delivered
to
the
solids
is
used
to
create
new
(obtained
from
theory)
3
3/26/12
Energy
and
Power
requirements
in
comminu*on
The
energy
absorbed
by
the
solid
Wn
is
less
than
that
fed
to
the
machine.
Part
of
the
total
energy
W
is
used
to
overcome
fric*on
in
bearings
and
other
moving
parts,
and
rest
is
available
for
crushing.
The
ra*o
of
energy
absorbed
to
the
energy
input
is
the
mechanical
efficiency:
W
ηm = n
W
W e (A − Awa )
W = n = s wb
ηm ηmηe
m
If
is
the
feed
rate,
the
power
required
by
the
machine
is
s (Awb − Awa )
me
P = Wm =
ηmηe
Energy and Power requirements in comminu*on
s (Awb − Awa )
me
P = Wm =
ηmηe
sp 6
By
defini*on
=
vp Φs Dp
s ⎛ 1
6 me 1 ⎞
P= −
ηmηe ρ p ⎜⎝ Φb Dsb Φ a Dsa ⎟⎠
Volume surface mean diameter
4
3/26/12
Empirical
Rela*onships:
RiSnger’s
law
and
Kick’s
law
RiSnger’s
law
(1867):
Work
required
in
crushing
is
propor*onal
to
the
new
surface
created.
This
hypothesis
is
equivalent
to
the
statement
that
the
crushing
efficiency
is
constant
for
a
given
machine
and
feed
material.
6es
P ⎛ 1 1 ⎞ Kr =
= Kr ⎜ − Φηmηe ρ p
m ⎝ Dsb Dsa ⎟⎠ Spherici*es
of
feed
and
product
is
same
Generalized rela*on for RiSnger’s law and Kick’s law
⎛ P⎞ dD
d ⎜ ⎟ = −K ns
⎝ m ⎠ D s
Where n= 1, 2 leads to Kick's law and RiSnger's law, respec*vely.
Both
Kick's
law
and
RiSnger's
law
have
been
shown
to
apply
over
limited
ranges
of
par*cle
size,
provided
Kk
and
Kr,
are
determined
experimentally
by
tests
in
a
machine
of
the
type
to
be
used
and
with
the
material
to
be
crushed.
They
thus
have
limited
u*lity.
5
3/26/12
Bond’slaw
and
work
index
Work
required
to
form
par*cles
of
size
Dp
from
very
large
feed
is
propor*onal
to
the
square
root
of
the
surface‐volume
ra*o
of
the
product
sp/vp.
sp 6
P K =
= b By
defini*on
vp Φs Dp
m Dp
Kb is
a
constant
that
depends
on
the
type
of
machine
and
the
materials
being
crushed.
Kb is related to work index
Wi is
defined
as
the
gross
energy
requirement
in
kilowaRhours
per
ton
(2000
lb)
of
feed
needed
to
reduce
a
very
large
feed
to
such
a
size
that
80%
of
the
product
passes
through
a
100
–
micron
mesh.
If
Dp
m
is
in
millimeters,
P
is
kilowaRs
and
in
tons
per
hour
K b = 100 × 10 −3Wi
Bond’s law and work index
If
80%
of
the
feed
passes
a
mesh
size
of
Dpa
mm
and
80
%
of
the
product
passes
through
a
mesh
of
Dpb
mm,
then
P K
= b
m Dp
can
be
modified
to
P ⎛ 1 1 ⎞
= 0.3162Wi ⎜ − ⎟
m ⎝ D pb D pa ⎠
6
3/26/12
Bond’s law and work index
Popula*on
Balance
Equa*ons
Popula*on
Balance
Modeling
is
a
general
engineering
framework
used
to
predict
par*cle
size
distribu*on
in
par*culate
processes
such
as
crystalliza*on,
granula*on,
pollutant
forma*on,
aggrega*on,
growth
of
microbial
popula*ons,
etc.
When
a
process
involves
a
large
number
par*cles,
solu*on
of
the
PBE
is
necessary
to
determine
the
proper*es
of
the
resul*ng
product
and
its
dependence
on
processes
that
alter
par*cle
size
distribu*on
–
for
example
–
coalescence,
breakage
and
surface
growth
hAp://www.nonequilibrium.com/PatrickSpicerPhD1997.pdf
Coagula*on Breakup
7
3/26/12
Simula*on of Milling Or Size reduc*on Opera*ons by PBE
The
material
in
a
mill
or
crusher
at
any
*me
is
made
up
of
par*cles
of
many
different
sizes.
The
size
distribu*on
of
the
products
from
various
types
of
size
reduc*on
can
be
predicted
by
the
computer
simula*on
of
milling
opera*ons
using
PBM
approach.
Computer
simula*on
of
Milling
Or
Size
reduc*on
Opera*ons
For
simultaneous
coagula*on
and
fragmenta*on:
The
forma*on
of
par*cles
comprised
The
loss
of
par*cles
of
size
of
i
primary
par*cles
by
collisions
of
i
by
fragmenta*on
smaller
j‐
and
k‐
sized
par*cles.
For
milling
opera7ons:
n −1
dxn
= −Sn xn + ∑ xu Su ΔBn,u
dt u =1
Grinding‐rate
func*on
Breakage
func*on
8
3/26/12
Computer simula*on of Milling Or Size reduc*on Opera*ons
Grinding‐rate
func7on
Stack
of
nT
standard
screens
the subscript u (u<n)
The
grinding‐rate
func7on
Su
is
the
frac*on
of
Screen
n
the
material
of
a
given
size,
coarser
than
that
on
screen
n,
which
is
broken
in
a
given
*me.
If
xu
is
the
mass
frac*on
retained
on
one
of
the
upper
screens,
its
rate
of
change
by
breakage
to
smaller
sizes
is
given
by
dxu
= −Su xu
dt
Computer simula*on of Milling Or Size reduc*on Opera*ons
Grinding‐rate
func7on
The
grinding‐rate
func7on
Su
is
the
frac*on
of
the
material
of
a
given
size,
coarser
than
that
on
screen
n,
which
is
broken
in
a
given
*me.
If
xu
is
the
mass
frac*on
retained
on
one
of
the
Coarsest
to
finest
upper
screens,
its
rate
of
change
by
breakage
to
smaller
sizes
is
given
by
Screen
n
dxu
= −Su xu
dt
Suppose,
for
example,
that
the
coarsest
material
in
the
charge
to
a
grinding
mill
is
4/6‐
mesh,
that
the
mass
frac*on
of
this
material
xi,
is
0.05,
and
that
one‐hundredth
of
this
material
is
broken
every
second.
Then
Su
would
be
0.01
s‐1
and
xi
would
diminish
at
the
rate
of
0.01
x
0.05
=
0.0005
s‐1
9
3/26/12
Computer simula*on of Milling Or Size reduc*on Opera*ons
Breakage
func7on
The
breakage
func*on
ΔBn,u
gives
the
size
distribu*on
resul*ng
from
the
breakage
of
the
upper
material.
Some
of
the
4/6‐mesh
material,
aqer
breaking,
would
be
fairly
coarse,
some
very
small,
and
some
in
between.
Probably
very
liRle
would
be
as
large
as
6/8‐mesh,
and
only
a
small
amount
as
small
as
200‐mesh.
One
would
expect
sizes
in
the
intermediate
range
to
be
favored.
Consequently ΔBn,u varies with both u and n.
Furthermore
it
varies
with
the
composi*on
of
the
material
in
the
mill,
since
coarse
par*cles
may
break
differently
in
the
presence
of
large
amounts
of
fines
than
they
do
in
the
absence
of
fines.
In
a
batch
mill,
therefore,
ΔBn,u
(and
Su
also)
would
be
expected
to
vary
with
*me
as
well
as
with
all
the
other
milling
variables.
Computer simula*on of Milling Or Size reduc*on Opera*ons
If
ΔBn,u
and
Su
are
known
or
can
be
assumed,
the
rate
of
change
of
any
given
frac*on
can
be
found
using
PBE.
For
any
frac*on
except
the
coarsest,
the
ini*al
amount
is
diminished
by
breakage
to
smaller
sizes
and
simultaneously
augmented
by
the
crea*on
of
new
par*cles
from
breakage
of
all
coarser
frac*ons.
If
the
input
and
output
from
a
given
screen
are
at
equal
rates,
the
frac*on
retained
on
that
screen
remains
constant.
Usually,
however,
this
is
not
the
case,
and
the
mass
frac*on
retained
on
screen
n
changes
according
to
the
equa*on:
n −1
dxn
= −Sn xn + ∑ xu Su ΔBn,u
dt u =1
10
3/26/12
Computer simula*on of Milling Or Size reduc*on Opera*ons
n −1
dxn
= −Sn xn + ∑ xu Su ΔBn,u
dt u =1
In
crushing
coal,
for
par*cles
larger
than
about
28‐mesh,
Su
has
been
found
to
vary
with
the
cube
of
the
par*cle
size
and
the
breakage
func*on
to
depend
on
Dn
the
reduc*on
ra*o
according
to
the
equa*on
Du
β
⎛D ⎞
Bn,u =⎜ n⎟
⎝D ⎠ u
where the exponent β may be constant or may vary with the value of B.
Computer
simula*on
of
Milling
Or
Size
reduc*on
Opera*ons
β
⎛D ⎞
Bn,u =⎜ n⎟
⎝D ⎠ u
where the exponent β may be constant or may vary with the value of B.
β
in
above
Eq.
is
constant,
implies
‐
that
the
par*cle‐size
distribu*on
of
the
crushed
material
is
the
same
for
all
sizes
of
the
ini*al
material.
The
value
of
ΔBn,u
in
crushing
4/6‐mesh
material
to
8/10‐mesh
will
be
the
same
as
in
crushing
6/8‐mesh
par*cles
to
10/14‐mesh,
since
the
size‐reduc*on
ra*o
is
the
same.
11
3/26/12
Size Distribu*on by PBE ‐ Problem
A
batch
grinding
mill
is
charged
with
material
of
the
composi*on
shown
in
Table.
Size
Distribu*on
by
PBE
‐
Problem
The
grinding‐rate
func*on
Su
is
assumed
to
be
0.001
s‐1
for
the
4/6‐
mesh
par*cles.
Breakage
func*on
Bn,u
is
given
by
β
⎛D ⎞
Bn,u =⎜ n⎟
⎝D ⎠
u
with
β
=
1.3..
Both
Su
and
Bn,u
are
assumed
to
be
independent
of
*me.
(a)
How
long
will
it
take
for
the
frac*on
of
4/6‐mesh
material
to
diminish
by
10
percent?
(b)
Tabulate
the
individual
breakage
func*ons
ΔBn,u
for
the
28/35‐mesh
frac*on
and
for
all
coarser
frac*ons.
(c)
How
will
the
values
of
xn
vary
with
the
*me
during
the
first
6
h
of
opera*on?
Use
a
*me
interval
Δt
of
30
s
in
the
calcula*ons.
12
3/26/12
Size Distribu*on by PBE ‐ Problem
(a)
How
long
will
it
take
for
the
frac*on
of
4/6‐mesh
material
to
diminish
by
10
percent?
For
the
4/6‐mesh
material
there
is
no
input
from
coarser
material
dxu
= −Su xu
dt (Mass
frac*on
of
material
on
4/6‐mesh
xu,initial = 0.0251
Su = 0.001s −1 (given)
xu, final = 0.0251 × 0.9 = 0.02259
Size Distribu*on by PBE ‐ Problem
(b)
Tabulate
the
individual
breakage
func*ons
ΔBn,u
for
the
28/35‐mesh
frac*on
and
for
all
coarser
frac*ons.
Calcula*on
of
breakage
func*on
Bn,u:
When
n
and
u
are
equal,
or
whenever
n
<
u,
ΔBn,u=
O.
The
total
mass
frac*on
smaller
than
6/8‐mesh
resul*ng
from
breakage
of
4/6‐mesh
par*cles,
B2,1
is
from
the
following
equa*on
β
⎛ Dn ⎞
Bn,u = ⎜ ⎟
Coarsest
to
finest
Screen
n
⎝D ⎠ u
1.3
⎛ 2.362 ⎞
B2,1 = ⎜ = 0.6407
⎝ 3.327 ⎟⎠
ΔB2,1
is
the
frac*on
of
the
broken
material
retained
on
8
mesh
=
1‐0.6407
=
0.3593
13
3/26/12
Size Distribu*on by PBE ‐ Problem
The
total
mass
frac*on
smaller
than
8/10‐mesh
resul*ng
from
breakage
of
4/6‐mesh
material,
1.3
⎛ 1.651 ⎞
B3,1 = ⎜ = 0.4021
⎝ 3.327 ⎟⎠
In general, the individual breakage func*ons are found from the rela*on
Thus
the
mass
frac*on
of
the
broken
4/6‐mesh
material
retained
on
the
10‐mesh
screen
=
0.6407‐0.4021=0.2386
Breakage
Func*ons
When
n
=
u,
Bn,uis
unity
When
u=1,
0.6407
of
the
broken
par*cles
from
the
4/6‐mesh
material
is
smaller
than
8‐mesh,
0.4021
smaller
than
10‐mesh,
0.2564
smaller
than
14‐mesh,
and
only
0.0672
smaller
than
35‐mesh.
14
3/26/12
Mass Frac*ons Calcula*ons
(c)
How
will
the
values
of
xn
vary
with
the
*me
during
the
first
6
h
of
opera*on?
Use
a
*me
interval
Δt
of
30
s
in
the
calcula*ons.
Let
xn,t
be
the
mass
frac*ons
retained
on
the
various
screens
at
the
end
of
t
*me
increments
Δt.
Then
x1,0,
x2,0,
etc.,
are
the
ini*al
mass
frac*ons
dxn n −1
Δxn n −1
= −Sn xn + ∑ xu Su ΔBn,u = −Sn xn + ∑ xu Su ΔBn,u
dt u =1 Δt u =1
n −1
xn,t +1 = xn,t − Sn xn,t + ∑ xu,t Su ΔBn,u
u =1
n −1
xn,t +1 = xn,t (1 − ΔtSn xn,t + Δt ∑ xu,t Su ΔBn,u
u =1
Mass Frac*ons Calcula*ons
15
3/26/12
Mass Frac*ons Calcula*ons
Ball Mills
16
3/26/12
Ball Mills – How does grinding/size reduc*on happen?
o When
the
mill
is
rotated,
the
balls
are
picked
up
by
the
mill
wall
and
carried
nearly
to
the
top,
where
they
break
contact
with
the
wall
and
fall
to
the
boRom
to
be
picked
up
again.
o Centrifugal
force
keeps
the
balls
in
contact
with
the
wall
and
with
each
other
during
the
upward
movement.
While
in
contact
with
the
wall,
the
balls
do
some
grinding
by
slipping
and
roIling
over
each
other,
but
most
of
the
grinding
occurs
at
the
zone
of
impact,
where
the
free
faIling
balls
strike
the
boRom
of
the
mill.
o The
faster
the
mill
is
rotated,
the
farther
the
balls
are
carried
up
inside
the
mill
and
the
greater
the
power
consump*on.
The
added
power
is
profitably
used
because
the
higher
the
balls
are
when
they
are
released,
the
greater
the
impact
at
the
boRom
and
the
larger
the
produc*ve
capacity
of
the
mill.
o If
the
speed
is
too
high,
however,
the
balls
are
carried
over
and
the
mill
is
said
to
be
centrifuging.
The
speed
at
which
centrifuging
occurs
is
called
the
cri*cal
speed.
LiRle
or
no
grinding
is
done
when
a
mill
is
centrifuging,
and
opera*ng
speeds
must
be
less
than
the
cri*cal.
FORCES
in
a
BALL
in
BALL
MILL
The
posi*on
or
height
at
which
the
outermost
balls
lose
contact
with
the
wall
of
the
mill
depends
on
the
balance
between
gravita*onal
and
centrifugal
forces.
Two forces act on the ball –
Gravita*onal
force
Centrifugal
force
17
3/26/12
FORCES in a BALL in BALL MILL
Centrifugal
force
‐
m(R
‐
r)
ω2/gc
where
ω
=
2πn
and
n
is
the
rota7onal
speed.
As
long
as
the
centrifugal
force
exceeds
the
centripetal
force,
the
par*cle
will
not
break
contact
with
the
wall.
As
the
angle
a
decreases,
however,
the
centripetal
force
increases,
and
unless
the
speed
exceeds
the
cri*cal,
a
point
is
reached
where
the
opposing
forces
are
equal
and
the
par*cle
is
ready
to
fall
away.
The
angle
at
which
this
occurs
is
found
by
equa*ng
the
two
forces
FORCES in a BALL in BALL MILL
g m ⎡⎣ 4π 2 n 2 (R − r) ⎤⎦
m cos(α ) =
gc gc
4π 2 n 2 (R − r)
cos(α ) =
g
At
the
cri*cal
speed,
α=
0,
cos(α)
=
1,
and
n
becomes
the
cri*cal
speed
nc
1 g
nc =
2π R−r
Tumbling
mills
run
at
65
to
80
percent
of
the
cri*cal
speed,
with
the
lower
values
for
wet
grinding
in
viscous
suspensions.
18
3/26/12
FORCES in a BALL in BALL MILL
g m ⎡⎣ 4π 2 n 2 (R − r) ⎤⎦
m cos(α ) =
gc gc
4π 2 n 2 (R − r)
cos(α ) =
g
At
the
cri*cal
speed,
α=
0,
cos(α)
=
1,
and
n
becomes
the
cri*cal
speed
nc
1 g
nc =
2π R−r
Tumbling
mills
run
at
65
to
80
percent
of
the
cri*cal
speed,
with
the
lower
values
for
wet
grinding
in
viscous
suspensions.
Factors that affect choice of size reduc*on equipment
Stressing mechanics
Size of feed and product
Material proper*es
Carrier medium
Mode of Opera*on
Capacity
19
3/26/12
Factors affec*ng choice of size reduc*on equipment
Stressing mechanics
Size of feed and product
Material proper*es
Carrier medium
Mode of Opera*on
Capacity
Factors affec*ng choice of size reduc*on equipment
Stressing mechanics
Size
of
feed
and
product
Hardness/Toughness,
cohesivity/
Material
proper*es
adhesivity,
Abrasiveness,
Fibrous
nature
Carrier
medium
Air
or
Liquid
20
3/26/12
Type of milling circuits
Closed
circuit
milling
–
the
material
leaving
the
mill
is
subjected
to
some
form
of
classifica*on
with
oversize
being
returned
to
the
mill
with
the
feed
material.
Such
system
is
more
flexible
–
product
mean
size
and
size
distribu*on
may
be
controlled.
Type
of
milling
circuits
Closed
circuit
dry
milling
Closed circuit wet milling
21