PTE 9 Electrochemistry | Chemistry | Choose the correct alternative. Only One Choice is Correct. However, questions marked ‘*” May have ‘More than One Correct option. 1 10, ML Which of the following statement is correct? (A) Ecaiand A,G of cell reaction both are extensive properties (B) —_Ecqvand A,G of cell reaction both are intensive properties Ecai is an intensive property while A,G of cell reaction is an extensive property © Eoq is an extensive property while A,G of cell reaction isan intensive property o The difference between the electrode potentials of two electrodes when no current is drawn through the cell is called, =, (A) Cellpotential (B)—Cellemt (©) Potential difference Which of the following statement is not correct about an inert electrode in a cell? () Cell voltage It does not participate in the cell reaction “ (B) __It provides surface either for oxidation or for reduction reaction (C) _Itprovides surface for conduction of electrons (D) _Itprovides surface for redox reaction An electrochemical cell can behave like an electrolytic cell when (A) Bea =0 8) Eca>Exn (©) Be >Eon Which of the statements about solutions of electrolytes is not correct? Conductivity of solution depends upon size of ions. “ (B) Conductivity depends upon viscosity of solution (C) Conductivity does not depend upon solvation of ions present in solution (D) Conductivity of solution increases with temperature Using the data given below find out the strongest reducing agent Be otras BY Eber “16¥ Expoziniet =ESIV ES, ey =-O74V @ oo (@) Cr (© Gr @) Mn”* Using the data given Q.6 and find out which of the following is the strongest oxidizing agent. a oF (By) Mn?* (©) MnOg Oo ce Using the data given in Q.6 find out in which option the order of reducing power is correct. (A) Gr < Cl Na(s); Bear -2-71V -123V Fe. =0.00V (B) —2H,0(¢) +02 (g) +4” fag) +407 ES (©) HY (ag) +e —1/2H (@) 4H" (ag) +40; By =-1.36V @) Ch —41/2Ch(g) +e: The positive value of the standard electrode potential of Cu* /Cu indicates that (A) This redox couple is a stronger reducing agent than the H* /H couple (B) This redox couple is a stronger oxidi (C) —_Cucan displace H” from acid wg agent than H* /Hy (D) —_Curcannot displace H from acid © cal for some half cell reactions are given below. On the basis of these mark the correct answer. £2.) = 0.00V H, ——-2H;0(¢)—40p(g) + 4H1* (aq) + 4e7; Been L HE (aq) +° —1/2H3(g); MM. 2803 (aq) —+8,0}" (aq) + 2c”; E2.y The correct choice is : (A) Inditute sulphuric acid solution, hydrogen will be reduced at cathode (B) _Inconcentrated sulphuric acid solution, water will be oxidized at anode (©) __Indilute sulphuric acid sotution, water will be oxidized at anode (D) _Indilute sulphuric acid solution, SO3~ ion will be oxidized to tetrathionate ion at anode 2 Ecea= I-IV for Daniel cell, Which of the following expressions are correct description of state of equilibrium in this cell? (Given n 2303RT 22 (A) 1.1=Ke (B) = ———log K,=1.1 (CC) to - _ eKe=—— @) | : OF 059 @) log K.= 1.1 Conductivity of an electrolytic solution depends on (A) Nature of electrolyte (©) Power of AC source (B) Concentration of electrolyte (D) Distance between the electrodesOS 10 is equal to _ ; 20. A) Anqen *Smiaon) Ain B® Av +N, ; a) m(ttNo3) *®n(Nasos) — (aor) (©) Anvatwoy) + Smprsony ~ favo) @) —_Atosyory *S¢ner)~ fier 21, What will happen during the electrolysis of aqueous solution of CuSO, by using platinum electrodes? (A) Copper will deposit at eathode (B) Copper will deposit at anode (C) Oxygen will be released at anode @) Copper will dissolve at anode 422, What will happen during the electrolysis of aqueous solution of CuSO, inthe presence of Cu electrodes? (A) Copper will deposit at cathode B) Copper will dissolve at anode (©) Oxygen will be released at anode ©) Copper will deposit at anode 23, Conductivity x, is equal to Le Cc Ay = Bo co : r a 0 a © Die #24, Molar conductivity of ionic solution depends on. (A) Temperature (B) Distance between electrodes Surface area of electrodes (©) Concentration of electrolytes in solution (D) |cu?*|cu For the given cell, Mg|Mg?* (B) Curis cathode (A) Mgiscathode «© ‘The cell reaction is Mg +Cu** —>Mg?* +Cu @) Cus the oxidising agent 26, Resistance of 0.2 M solution of an electrolyte is 509. The specifie conductance of the solution is 1.4Sm ' ‘The resistance of 0.5 M solution of the same electrolyte is 2809. The molar conductivity of 0.5 M solution of the electrolyte is Smol ! is : 5x10 (By) 5x10" (©) 5x10 () 5x10? The equivalent conductance of NaCl at concentration C and at infinite dilution are 2, and ha, respectively. m1. ‘The correct relationship between 2, and 2. is given as : (A) Xe= he t(B)C BY) c= he-(B)C (©) Ae= Po -(BNE D) 2 = be +(B)VE 28. ‘The metal that cannot be obtained by the electrolysis of an aqueous solution of its salts is : © cu @) cr (A) Ag @) Ca 29. Given below are half-cell reactions Mn?* +2e" —+ Mn, E*=1.18V 151V 2(Mn2* +e" —> Mn®*), B= ‘The E? for 3Mn2* —> Mn+2Mn** will be (A) -2.69V,, the reaction will not occur (B) —_~2,69V,, the reaction will occur (D) —_--0.33V,, the reaction will occur (©) -0.33V,, the reaction will not occur ae ho 5 S1SIV : Bop ge =133V 3 Boye =136V BM. Given, Eh sejq, =O78V 3 Bios att “151 + Fegot roe Fact Based on the data given above, strongest oxidising agent will be + Mn?* @) = MnO; “@ a @ a © id pend oe 2 Se ee| 31. The standard reduction potentials for Zn?*/Zn, NI“/Ni and Fe" /Fe are ~0.76, -0.23 and —O44V . respectively The reaction X + Y%* + x™ + ¥ will be spontaneous when (A) X=N,Y= @) X=N,Y=2 (© X=F,Y=Z ) X=7¥=Ni 32, The reduction potential of hydrogen half-cell will be negative if (A) p(Hp)= 1am and [H"] = 20M (8) p(Hy) = latm and [H*} = LOM (©) p(H>) = 2atm and [H*] = LOM @) — p(H2)= 20M ‘Consider the following cell reaction: 2Fe(s) + 02(g) +4H* (eq) —> 2Fe**(ag) + 2H20(0. ‘At [Fe?* ]=10-3M, P(p)=0.latm and pH =3, then cell potential at 25°C is Lazy @ LTV © 187v atm and [H* EP =1.67V @) 1s7V 34, The Gibbs energy for the decomposition of Al,O3 at 500°C is as follows +966k) mot"! Z S 21,0, —> 41+ 04,6 gAhOs—> 5 2A ‘The potential difference needed for electrolyte reduction of Al,O3 at 500°C is atleast @ 4sv ) 30V © 25v @) — 50v 35. Given, Ef... = ~0036V, Bj 2s pg = -0439V ‘The value of standard electrode potential forthe charge, Fe** (aq) + &~” —» Fe” (ag) will be () -00R2V@B) RSV © o77v ) 0270 36, Given, Bh sec, = 0.72Vs Ere =-042V ‘The potential for the cell : Cr| Cr°* (0.1 M) II Fe** (0.01 M)| Fe i 026 ®)039v © -039V @)_—-026V 37. The equivalent conductances of two strong electrolytes at infinite dilution in HO (where ions move freely through a solution) at 25°C are given below: Agy,coona = 91.0 Sem? /equiv ; Ajgc, = 426.2 Sem? /equiv What additional information/ quantity one need to calculate A of an aqueous solution of acetic acid ? (A) A°of NaCl (B) A’ of CH,COOK (©) The limiting equivalent conductance of H’ (ij...) (D) A" of chloroacetie acid (CICH,COOH) 38. The cell, Zn| Zn?*(1M) II Cu2*(IM)iCu (Bn =1 10), was allowed to be completely discharged at 298 K. 2+ The relative concentration of Zn?* to Cu2*| 281 | i, {cu*) (A) antilog (24.08) (B) 37.3 © 1075 @) 9.65 x 10% 39. Resistance of a conductivity cell filled with a solution of an electrolyte of concentration 0.1 M is 100Q ‘The conductivity of this solution is 1.29 Sm. Resistance of the same cell when filled with 0.2 M of the same solution is 5202. The molar conductivity of 0.2 M solution of the electrolyte will be : (A) 124x104Sm* mot (B) 1240 10 Sm? mot! (©) 1.24 10Sm? mo @) 124x104 Sm? mor!ERE LR 40, ‘The molar conductivities AXyone and Ajjc, at infinite dilution in water at 25°C are 91.0 and 426 spectively. To calculate Ajjoqc, the additional value required is oe pie AKal © Auow @ Auer 41, Given the data at 25°C, Agtl —> Agl+e™ ; BY = 0.152 Ag —> Ag* +e": E* = 0.8000 What is the value of log K,, for Agl ? | 2.303 = =0059v | a) 812 @) 48612 © 3783 @ 1613 42, Among the properties (A) reducing, (B) oxidising and (C) complexing, the set of properties shown by CN~ fon towards metal species is (AB ® BC © GA Ase 43, Ina hydrogen-oxygen fuel cell, combustion of hydrogen occurs to (A) Generate heat (By) Cresta wlental Sticence ber veer (ne tye erases (©) Produce high purity water (D) Remove adsorbed oxygen from electrode surfaces 44, In the cell that utilises the reaction Zn(s) + 2H* (aq) > Zn°* (aq) + Hp(2) addition of HjSO4 to cathode compartment will (A) Lower the E and shift equilibrium to the let (B) Lower the E-and shift the equilibrium to the right (©) Increase the E and shift the equilibrium to the right (D) Increase the E and shift the equilibrium tothe left 45, For the following cell with hydrogen electrodes at two different pressure py and p : Pt(Hy)IH* (aq)IPt(H5) a IM op emfis given by RT, Pt RT, PL RT, pe RT, Pp (A) Hog, PLB) tone TC) loge) loge He 2H F Ly cas 1 46. When 0.1 mol MnO}- is oxidised, the quantity of electricity required to completely oxidise MnO% to MnO, is: (A) 96500. (B) —.2x96500C (C)—-9650 ©) 96.50 47. The weight of silver (at wt. = 108) displaced by a quantity of electricity which displaces 5600 mL. of 03 at STP will be: (A) Sag B) 108¢ © 5408 @) 080g 48 At 25°Cthe molar conductance of 0.1 M aqueous solution of ammonium hydroxide is 9.45ohm 'em* mol. The degree of ionisation of ammonium hydroxide at the same concentration and temperature is (ASO nxox = 238 ohm~!cm? mol (A) 4.008 % (B) 40.800 % o ‘A hydrogen gas electrode is made by dipping platinum wire in a solution of HCI of pH = 10 and by passing hydrogen 2,080 % @) 20.800 % gas around the platinum wire at one atm pressure. The oxidation potential of electrodes would be = (A) og B)LI8V © — 0059V @) 05951, 52. 53, 58. Consider the half-cell reduction reaction Mn?* 4 2e-—)Mn; B'=-1.18V and Mn+ Mn+ 6"; BY =-1.51V The E? forthe reac 2 ° 3 the reaction 3Mn? > Mn° + 2Mn°* and possibility of the forward reaction are respectively = (A) 4.18 V and yes (B) 40.33 V and yes(C)__ +2.69'V and no (D) Standard reduction potentials of the half reaction are given below Figg) +26 > 2Ffuqy = +285 Clayg) +267 > 2Clagy ¢ Bry +2 > 2Braqy 3 B= + 1.06 lag + 2° > Magy § ‘The strongest oxidising and reducing agents respectively are () andr B)— BandCr (©) Chand Br (D) Standard electrode potential of three metals X, ¥ and Z are —1.2 V, +0.5 and ~ power of these metals will be (A) Z>Y>Xx By >X>Z (©) Z>X>¥ @) Oe forFer ire” is +077 [Asolution contains Fe, Fe and 1° ions. This solution was treated with iodine at 25 and E° for Ip/T” = 0.536V . The favorable redox reaction is: there will be no redox reaction (A) Iwill be reduced to T B® (©) will be oxidised to L (p)_Fe** will be oxidised to Fe ‘An increase in equivalent conductance of a strong elecwolyte with dilution is mainly dve f° (A) increase in ionic mobility of ions (B) 100% ionisation of electrolyte at normal dilution (©) increase in both ie., number of ions and ionic mobility of ions (D) increase in number of ions valent conductance at infinite ditution dilution of the respective | Which of the following expressions correctly represent the equi Given than A® are the equivalent conductances at infinite ae and A co3- (A) 2A a4 + 3A on B Mase + Aso © 6 (Aga + A%02-) @D) WBA 34 + 2A on On the basis of the following E* values, the strongest oxidizing agent is : [Fe(CN)g]* > [Fe(CN)g} + | SE =-035V Fe > #e%* ¢e1; EB =-0.77V @ Fe @ [FCN © [Fe(CN)s]* — D) es Jn electrolysis of NaCl when Pi electrode is taken then His liberated at cathode while with Hg catl amalgam. Which of the following is true ? Ki (A) Hg is more inert than Pt (B) More voltage is required to reduce H’ at Hg than at Pt (©) _Nais dissolved in Hg while it does not dissolve in Pt : () Cone. of H* ions is larger when Pt electrode is taken