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Chapter 1
INTRODUCTION
There are many measuring tools and techniques that can be used in measuring the
density of a solid, liquid, or a gas. A material's density is defined as its mass per unit volume.
It is, essentially, a measurement of how tightly matter is crammed together. The principle of
density was discovered by the Greek scientist Archimedes. It says that the apparent weight of
an object immersed in a liquid decreases by an amount equal to the weight of the volume of
the liquid that it displaces. Density is a key concept in analyzing how materials interact in fluid
mechanics, weather, geology, material sciences, engineering, and other fields of physics.
One use of density is in how different materials interact when mixed together. Wood
floats in water because it has a lower density, while an anchor sinks because the metal has a
higher density. Helium balloons float because the density of the helium is lower than the
density of the air. The change in density can also be useful in analyzing some situations, such
as whenever a chemical conversion is taking place and energy is being released. The charge in
a storage battery, for example, is an acidic solution. As the battery discharges electricity, the
acid combines with lead in the battery to form a new chemical, which results in a decrease in
When an automotive service station tests various liquids, like transmission fluid, they
will pour some into a hydrometer. The hydrometer has several calibrated objects, some of
which float in the liquid. By observing which of the objects float, it can be determined what
the density of the liquid is. And, in the case of the transmission fluid, this reveals whether it
The hydrometer is one of the tools in measuring the density of such material but it has
a very small measuring range unlike pycnometers that has a high accuracy of measurement (to
The pycnometer (from the Greek puknos, meaning "density", and metron meaning
"measure"), also called specific gravity bottle, is a standard vessel used to measure the density
or specific gravity of a liquid or solid. It has a stopper so that air bubbles may escape from the
the liquid state, that is placed in the device and fills the pycnometer to a mark on its neck or to
the upper edge of a capillary tube, corresponding to the nominal volume of the pycnometer.
The measurement of volume is considerably simplified if the pycnometer has a scale rather
than a single mark. Pycnometers with aside capillary tube in which the stopper is usually the
determined by placing them in a pycnometer with a liquid. Pycnometer of special shape, such
The major advantages of the pycnometric method for the determination of density are
the possibility of using small quantities of material (0.5 to 100 cm3), the small area of free
surface of the liquid in the pycnometer (which virtually eliminates evaporation of the liquid
and absorption of moisture from the air), and the separation of the operations of thermostatic
Pycnometers are highly accurate but are quite expensive compared to other density
measurement methods. Unfortunately, these instruments also break easily just like
hydrometers. The method is quite slow and time consuming because the pycnometer needs to
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dried completely before using it. Besides requiring a large sample volume and a skilled
operator for this rather complicated procedure, it also requires the accurate measurement of the
temperature in the system. Thermostatting is quite a challenge and a highly precise balance is
The purpose of this experiment is to determine the density of the three liquids namely
water (the reference liquid), chloroform and methanol using the pycnometer. The chloroform
will be the densest because chlorine atoms are heavy while methanol will be the least dense of
the three.
For liquids, its exact volume can be accurately obtained by filling it with a calibration
liquid such as water. By weighing the pycnometer with water using the analytical balance, one
can calculate the exact volume as the water’s temperature-dependent density value is given.
So a thermometer is necessary for the experiment because the temperature actually affects the
density of such liquid. From the equation of density equals mass over volume, a simple
calculation provides information about the exact volume where the volume of water filling the
pycnometer is equal to the weight experimentally obtained divided by the given density of
water. When determining the unknown density of a sample afterwards, the same formula is
used in a different way where the value of density is just equal to the mass that is
experimentally obtained divided by the volume of the pycnometer obtained from the previous
Even though pycnometer is quite expensive, this apparatus is highly accurate when
measuring the density of liquids and even solids. This experiment is important because its
Chapter 2
This experiment dealt with the determination of density of three liquids, namely
water, chloroform and methanol. A pycnometer is used to determine the densities of the liquid.
The study conducted three trials for each of the reagents for accuracy and precision of the data.
Preparation of Pycnometer
The pycnometer is cleaned with enough hydrochloric acid and then washed with
distilled water. Using a dryer or an oven, completely dry the pycnometer. After drying, weigh
Fill the clean pycnometer with distilled water. Dry the sides of the pycnometer. Weigh
it accurately using the analytical balance. Determine the weight of water by subtracting the
measured weight by the weight of the empty pycnometer. Measure the temperature of water.
Search for the density of water with its corresponding temperature in the table provided in the
Fill the clean pycnometer with chloroform. Dry the sides of the pycnometer. Weigh
it accurately using the analytical balance. Determine the weight of chloroform by subtracting
the measured weight by the weight of the empty pycnometer. Measure the temperature of
chloroform. Solve for the density of chloroform using Eq. 2.2 and compute for the average
density.
(𝑚𝑙𝑖𝑞𝑢𝑖𝑑 )(𝜌𝐻2𝑂 )
𝜌𝑙𝑖𝑞𝑢𝑖𝑑 = (2.2)
𝑚𝐻2𝑂
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Fill the clean pycnometer with methanol. Dry the sides of the pycnometer. Weigh it
accurately using the analytical balance. Determine the weight of methanol by subtracting the
measured weight by the weight of the empty pycnometer. Measure the temperature of
methanol. Solve for the density of methanol using Eq. 2.2 and compute for the average density.
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Chapter 3
The volume of an object increases with increasing temperature because of the matter’s
volumetric thermal expansion. The density of a liquid depends on its temperature with higher
Density of Water
In this experiment, distilled water serves as the reference liquid. The density of water
is obtained from the table of Temperature Dependence of Distilled Water Density in the
experiment manual. In Table 3.1, water with a temperature of 300.15K has a density of 0.9966
g/cm3 . In trial 2 and trial 3, the temperature of water is 299.15K and has a density of 0.9968
g/cm3 . Temperature affects the density. A higher temperature yields a lower density.
Density of Chloroform
The density of chloroform is solved using the density and weight of water in 3.1. The
According to Perry, Chloroform has a density of 1.4810 g/cm3 and 1.4792 g/cm3 at 299.15K
and 300.15K, respectively. In Table 3.2, the recorded densities at 299.15K are 1.4660 g/cm3
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and 1.4807 g/cm3 . The experimental value from trial 3 is accurate. The experimental value
from trial 1 has a slight difference from the true value. At 300.15K, chloroform has a density
of 1.4641 g/cm3 which is a little bit less than the true value. Errors may be due to equipment
Density of Methanol
The density of methanol is solved using the density and weight of water in Table 3.1.
density. According to Perry, Methanol has a density of 0.7896 g/cm3 and 0.7910 g/cm3 at
298.15K and 296.65K, respectively. In Table 3.3, the recorded densities at 298.15K are 0.7938
g/cm3 and 0.7994 g/cm3 . The experimental value from trial 3 is very near from the true value.
The experimental values from trials 1 and 2 have a slight difference from the true value. Errors
With the information from Table 3.1-3.3, it is shown that methanol is the lightest
among the 3 liquids with a density 0.7976 g/cm3 . It is followed by water which has a density
of 0.9967 g/cm3 . Lastly, chloroform, the heaviest, has a density of 1.4702 g/cm3 .
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Chapter 4
The determination of density using pycnometer was investigated in this study. The
reference liquid, in this case, water. The method shows minimal percent error in values
of the liquid is inversely proportional to its density. A higher temperature yields a lower
density. In this study, it is found that chloroform is the heaviest and methanol is the lightest
This experiment can be more accurate with proper and careful execution of the
procedure. Accuracy and proper reading of analytical balance must also be observed. The
researchers recommend to work with various temperatures and other liquid references. It is
References
Hold, A. S. (2017, June 23). The Very Basics of Density Measurement Methods. Retrieved
August 20, 2017, from http://blog.anton-paar.com/the-very-basics-of-density-
measurement/
Jones, A. Z. (2017, August 10). Density: How Much Stuff Makes Up Different Stuff?
Retrieved August 20, 2017, from https://www.thoughtco.com/what-is-density-
definition-and-calculation-2698950
Pycnometer. (n.d.) The Great Soviet Encyclopedia, 3rd Edition. (1970-1979). Retrieved
August 20 2017 from http://encyclopedia2.thefreedictionary.com/Pycnometer
Pycnometer. (n.d.). Retrieved August 20, 2017, from https://www.merriam-
webster.com/dictionary/pycnometer
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APPENDICES
APPENDIX A
Analytical Balance – A device that measures the weight of the pycnometer accurately.
Pycnometer – It is a device used to determine the density of a liquid. This device enables a
APPENDIX B
Definition of Terms
for example, the space that a substance (solid, liquid, gas, or plasma) or shape occupies or
contains.
APPENDIX C
Computations
= 0.9967 g/cm3
mwater
Vwater = ρwater
24.82g
Trial 1: 0.99655g/cc = 24.9059 cm3
24.85g
Trial 2: 0.9968g/cc = 24.9298 cm3
24.72g
Trial 3: 0.9968g/cc = 24.7994 cm3
B. Chloroform
(mliquid)(ρwater)
ρliquid = mwater
Trial 1:
(36.51)(0.9966)
ρliquid =
24.82
= 1.4660 g/cm3
Trial 2:
(36.5)(0.9968)
ρliquid = 24.85
=1.4641 g/cm3
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Trial 3:
(36.72)(0.9968)
ρliquid = 24.72
=1.4807 g/cm3
(1.4660+1.4641+1.4807)g/cc
Average Density = 3
= 1.4702 g/cm3
C. Methanol
(mliquid)(ρwater)
ρliquid = mwater
Trial 1:
(19.77)(0.9966)
ρliquid = 24.82
= 0.7938 g/cm3
Trial 2:
(19.93)(0.9968)
ρliquid = 24.85
= 0.7994 g/cm3
Trial 3:
(19.83)(0.9968)
ρliquid = 24.72
= 0.7996 g/cm3
(0.7938+0.7994+0.7996)g/cc
Average Density = 3
= 0.7976 g/cm3