4/29/2017 CONCRETE CHEMICALS AND APPLICATIONS

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CONCRETE CHEMICALS AND APPLICATIONS
Home (https://theconstructor.org) /  Concrete Technology Guide For CIvil Engineer (https://theconstructor.org/concrete/)  /  Concrete Admixtures
(https://theconstructor.org/concrete/admixture/)  /  CONCRETE CHEMICALS AND APPLICATIONS

Concrete Chemicals (Admixtures) and Applications

Admixtures are materials other than cement, aggregate and water that are added to
concrete either before or during its mixing to alter its properties, such as workability,
curing temperature range, set time or color. Some admixtures have been in use for a
very long time in concrete construction, such as calcium chloride to provide a cold­
weather setting concrete.

Based on their functions, admixtures can be classified into the following five major
categories:

Retarding admixtures

Accelerating admixtures

Super plasticizers

Water reducing admixtures

Air­entraining admixtures

Among other important admixtures that do not fit into these categories are admixtures whose functions include
bonding, shrinkage reduction, damp proofing and coloring. The following paragraphs provides details on the
above­mentioned categories of concrete admixtures.

Retarding Admixtures

Retarding admixtures slow down the hydration of cement, lengthening set time. Retarders are beneficially used
in hot weather conditions in order to overcome accelerating effects of higher temperatures and large masses of
concrete on concrete setting time. Because most retarders also act as water reducers, they are frequently
called water­reducing retarders. As per chemical admixture classification by ASTM­ASTM C 494, type B is
simply a retarding admixture, while type D is both retarding and water reducing, resulting in concrete with
greater compressive strength because of the lower water­cement ratio.

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Retarding admixtures consists of both organic and inorganic agents. Organic retardants include unrefined
calcium, sodium, NH4, salts of lignosulfonic acids, hydrocarboxylic acids, and carbohydrates. Inorganic
retardants include oxides of lead and zinc, phosphates, magnesium salts, fluorates and borates. As an example
of a retardant’s effects on concrete properties, lignosulfate acids and hydroxylated carboxylic acids slow the
initial setting time by at least an hour and no more than three hours when used at 65 to 100 degrees
Fahrenheit. The concrete contractor, however, need not memorize these chemical­specific results. Given the
specific job requirements and goals, the concrete supplier should offer appropriate admixtures and concrete
mixes from which to choose.

Accelerating admixtures

Accelerators shorten the set time of concrete, allowing a cold­weather pour, early removal of forms, early
surface finishing, and in some cases, early load application. Proper care must be taken while choosing the type
and proportion of accelerators, as under most conditions, commonly used accelerators cause an increase in the
drying shrinkage of concrete.

Calcium chloride is a common accelerator, used to accelerate the time of set and the rate of strength gain. It
should meet the requirements of ASTM D 98. Excessive amounts of calcium chloride in concrete mix may result
in rapid stiffening, increase in drying shrinkage and corrosion of reinforcement. In colder climates, calcium
chloride should not be used as an anti­freeze. Large amount of calcium chloride is required to lower the
freezing point of the concrete, which may ruin the concrete.

Super plasticizers

Super plasticizers, also known as plasticizers, include water­reducing admixtures. Compared to what is
commonly referred to as a “water reducer” or “mid­range water reducer”, super plasticizers are “high­range
water reducers”. High range water reducers are admixtures that allow large water reduction or greater
flowability (as defined by the manufacturers, concrete suppliers and industry standards) without substantially
slowing set time or increasing air entrainment.

Each type of super plasticizer has defined ranges for the required quantities of concrete mix ingredients, along
with the corresponding effects. They can maintain a specific consistency and workability at a greatly reduced
amount of water. Dosages needed vary by the particular concrete mix and type of super plasticizer used. They
can also produce a high strength concrete. As with most types of admixtures, super plasticizers can affect
other concrete properties as well. The specific effects, however, should be found from the manufacturer or
concrete supplier.

Water reducing admixtures

Water reducing admixtures require less water to make a concrete of equal slump, or increase the slump of
concrete at the same water content. They can have the side effect of changing initial set time. Water reducers
are mostly used for hot weather concrete placing and to aid pumping. A water­reducer plasticizer, however, is a
hygroscopic powder, which can entrain air into the concrete mix via its effect on water’s surface tension,
thereby also, obtaining some of the benefits of air­entrainment (see below).

Air­entraining admixtures

Air­entraining agents entrain small air bubbles in the concrete. The major benefit of this is enhanced durability
in freeze­thaw cycles, especially relevant in cold climates. While some strength loss typically accompanies
increased air in concrete, it generally can be overcome by reducing the water­cement ratio via improved
workability (due to the air­entraining agent itself) or through the use of other appropriate admixtures. As
always, admixtures should only be combined in a concrete mix by a competent professional because some of
them can interact in undesirable ways.

Bonding admixtures

Bonding admixtures including addition of compounds and materials such as polyvinyl chlorides and acetates,
acrylics and butadiene­styrene co­polymers, can be used to assist in bonding new / fresh concrete with old /
set concrete.

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4/29/2017 CONCRETE CHEMICALS AND APPLICATIONS

Coloring agents have become more commonly used, especially for patios and walkways. Most are surface
applied and often have the additional effect of surface hardening. Such surface applied coloring admixtures
generally should not be used on air­entrained concrete. Integrally colored concrete is also available.

Waterproofing and damp proofing admixtures

Water proofing and damp proofing admixtures including soaps, butyl stearate, mineral oil and asphalt
emulsions, are used to decrease the amount of water penetration into the larger pores of concrete. “Antifreeze”
admixtures typically are accelerators used in very high doses, with a corresponding high price, to achieve a
very fast set­time, though they do not have properties to protect against freezing on their own. However, in
general, these are not used for residential work.

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