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ULVA SEPRIZAL Question

1607116198 1. For the system methanol (1)/methyl acetate (2), the f


TEKNIK KIMIA S1 C correlation for the activity coefficients:
TUGAS TERMODINAMIKA II ln 𝛾_1=A 〖� _2 〗 ^2
Where
�=2.771−0.00532 �
Antoine equation:
ln 〖〖� _1 〗 ^𝑠𝑎𝑡 (𝑘�𝑎)=16.59158−3643.31/(� (𝐾𝑒𝑙𝑣
ln 〖〖� _2 〗 ^𝑠𝑎𝑡 (𝑘�𝑎)=14.25326−2
Find: a). � 𝑎𝑛𝑑 𝑦𝑖, 𝑓𝑜𝑟 �𝑖=0.4 𝑎𝑛𝑑 �=330 𝐾 (𝐵𝑈𝐿𝐵 �
b). � 𝑎𝑛𝑑 �𝑖, 𝑓𝑜𝑟 𝑦𝑖=0.5 𝑎𝑛𝑑 �=330 𝐾 (𝐷𝐸𝑊 �
c). � 𝑎𝑛𝑑 𝑦𝑖, 𝑓𝑜𝑟 �𝑖=0.6 𝑎𝑛𝑑 �=90 𝑘�𝑎 (𝐵𝑈𝐿𝐵
d). T 𝑎𝑛𝑑 �𝑖, 𝑓𝑜𝑟 𝑦𝑖=0.45 𝑎𝑛𝑑 �=90𝑘�𝑎 𝐾 (𝐵𝑈
)/methyl acetate (2), the following equationsbprovide a reasonable
efficients:
ln 𝛾_1=A 〖� _2 〗 ^2 ln 𝛾_2=A 〖� _1 〗 ^2

9158−3643.31/(� (𝐾𝑒𝑙𝑣𝑖𝑛)−33.424) 〗
𝑠𝑎𝑡 (𝑘�𝑎)=14.25326−2665.54/(� (𝐾𝑒𝑙𝑣𝑖𝑛)−53.424) 〗
4 𝑎𝑛𝑑 �=330 𝐾 (𝐵𝑈𝐿𝐵 �)
5 𝑎𝑛𝑑 �=330 𝐾 (𝐷𝐸𝑊 �)
6 𝑎𝑛𝑑 �=90 𝑘�𝑎 (𝐵𝑈𝐿𝐵 �)
45 𝑎𝑛𝑑 �=90𝑘�𝑎 𝐾 (𝐵𝑈𝐿𝐵 �)

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