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1
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ANSWERS, HINTS & SOLUTIONS

CRT–II
(Main)
Q. No. PHYSICS CHEMISTRY MATHEMATICS

ALL INDIA TEST SERIES
1. B C C
2. A B A
3. A C C
4. A C B
5. B B B
6. C B C
7. C D A
8. C B D
9. A B D
10. C A A
11. D B B
12. A C A
13. B D A
14. C A B
15. A C C
16. D C D
17. D B D
18. A C C
19. B C B
20. A B C
21. B D C
22. B C D
23. D A A
24. B C D
25. A B B
26. A D C
27. D A D
28. B A D
29. D C A
30. C B A
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2
Physics PART – I
SECTION – A
1.  Net force on the system is

F = 3 mg sin   k 3 mg cos 
3mgsin   3 k mgcos  2
 acm = = 4 m/s
3m
2. Consider an arbitrary moment when the wedge has travelled a distance x

into region II.
The area of the top surface inside the region II = ax sec 
h
Force on it = ax sec  P = ax sec  [P =1]
Component of the force opposite velocity = ax sec . sin  = ax tan . 
If it further moves by dx then the work done = ax tan dx x
b
1
 mv 02  a tan   xdx
2 0
abh
 v0 =
M
1
3. S A = v 0t  A gt 2
2
1
SB = v0t  B gt 2
2
2 L   
SA  S B = L    t =
 B  A  g

4. N/N0 = et
5. First law of motion.
6. For vertical oscillation time period

m
T1 = 2 . . . (1)
k

For the transverse oscillation period of simple pendulum T2 = 2
g
4mg
But 2T1 = T2  k =

3GMm 1
8.   mv 2  0
2R 2
 v = 3gR
9. Tension in the string T = mg  FB = 3vg  vg = 2vg

Balancing torque
kxR/2 = TR
 x = 2T/k = 4vg/k
3
10. II and IV quadrant field will be added.
1600 x 10 6
11. vP  = 4 m/s
4 x 104
1600 x 10 6
vQ  = 8 m/s
2 x 10 4
1
 A  B  A  v Q2  vP2   gh
2
h = 3.6 mm
12. mg  T  ma ----- (1)

2
mr a
Tr  x ----- (2)
2 r
2g mg
From (1) and (2), a  &T  mg
3 3
1

3
13. J1 x 0.1 = 5 x I 0.5 5 mA

J1 = 50 mA
I = 50 + 5 = 55 mA 5 mA
0.1 0.2 0.3
J1 I
I
S B C D
1
16. Let Vx and Vy be components of velocity. At contact point A Vx

and B,
the velocity along normal should be same.
ucos60o  Vy cos30o  Vx cos 60o …. (1) 60o
2u
v x  2u
30o
u
v  Vx2  Vy2 60o Vy
1
19. qEy  mv 2
2
Magnetic force will not do any work.
20. Conceptual.
21. Now downward force on the right T T

block is more.
mg mg
22. IC = I0 + M(OC)2 = I0 + M(OB2 + BC2) = IB + M(BC)2
23. Coulombic force between them remains same.
4
24. Circuit is forming a wheatstone bridge Req = 2R R R

For maximum power transfer 2R = r.
R R
R 4R
 r
3 2
25. = B
4
d 3 2 dB
=  
dt 4 dt
 32
i= 
R 4R
dx
RT 5RT x
26. C= 
M0 3M0
A B
5R   TL  T0  
dx = C. dt = T0    x  dt T0 TL
3M0   L   L
2L 3M
t
( TL  T0 ) 5R
27. Equivalent circuit is 2RT

V RT
90  V 20
  V = 500C
2R T RT
P (900C) 0
RT R (30 C)
2I P
28. Leftward Force = 
C t
29. Conceptual, torque of pseudo force.
30. Effective length = (r2 + r1)
5
Chemistry PART – II
SECTION – A
1. P1V1  P2 V2
 
P1  V2   1  7
         32  5
P2  V1   2 
7
 25  5
 27  128 .
2. 

 NH3  g  HCl
NH4 Cl 
t0 0.20 0 0
At eqm.  0.2  x  x x
2
K P  PNH3  PHCl  P  P  K P
= 0.36  0.6 atm .
PV 0.6  10
NH3 formed  
RT 0.0821 600
= 0.122 mole = moles of NH4Cl decomposed.
 Moles of NH4Cl left = 0.2 – 0.122 = 0.078.
7. Na2B 4 O7  H2 SO4  Na2 SO4  H2B 4 O7

 X
H2B4 O7  5H2O  4H3BO3

2H3BO3   B2O3  3H2O
B 2O3  6Na  2B  3Na 2O
 X
8. Go  Ho  TSo



H2 O  
 H  OH

Ho  13.7 kcal
Ho  Go 13.7  19.14
So  
T 298
-1 -1 -1
= 0.1102 kcal mol = 110.2 cal k mol
3a
9. In bcc, r 
4
Edge length = a
 Edge length not covered by atom = a – 2r
3 2 3 
a  a  a  
2  3 
2  3 
a 
2 
 percentage fraction not covered =   100  0.134  100 = 13.4%
a
6
1
10. Al3   3e  Al K
 Al3  


Al  OH3  3
 Al  3OH

pH = 14, [H+] = 1 × 10-14

(OH) = 1 M
3+ 3
Ksp = [Al ][1]
  Al3    1 10 33 M
0.0591 1
E  Eo  log
3  Al3  
0.0591 0.0591
 1.66  log1033  1.66   33
3 3
= - 2.31 V
11. Br
H 3C MgCl
 CH3Cl  CH3CH2CH3 
Cl2 Br2 /h
CH4 
h KCN 
H3 O
  C N   COOH
M1V1 MV
13.
n1
 
CO23   2 2 H
n2
 
M1  50 4  49.35
   M1  1.974
1 2
x  d  10 x  1.25  10
M  1.974 
mB 106
 x  16.7
15. H2O is weak field ligand while CN is a strong field ligand. In complex (i), the distribution is t 32g eg 2 ,
i.e. all electrons are unpaired while in (ii) complex, the distribution is t 52g eg0 , i.e. two t2g orbitals are
paired while one is unpaired.
16. O
Cl C O HO
LiAlH4
C Cl  Conc. H2 SO4
 

OH
Cl C HO
O
17. O O
H3 O

 HO 
O
OH (A) H (B)
Aldehyde and ketone can be differentiated by Fehling’s solution.
7
18. +
OH OH2
O O
H 


O


O HO
19. The rate can be compared by stability of carbocation.
C C C
H3C O NH
(I) (II) (III)
N has more tendency to donate electron than O.
21. H = E + PV  H = E + nRT
H2 = E2 + nRT2
H1 = E1 + nRT1
(H2 – H1) = (E2 – E1) + nR(T2 – T1)
 H  E  nRT  4  8.314  50
= 1660 J
22. 

H2 S  
 2H  S
2


CdS  2
 Cd  S
2

K spCdS  2
 Cd  S 
2
 8  10 27  1  10 14 S 2 

  S2    8  10 13 M
2
K H2 S  H  S2  
2
 H   8  1013  1 10 22
2
 H   1.25  1010
[H+] = 1.11 × 10-5
 pH  5 .
23. 

N2 O 4  g  
 2NO 2  g
1 0
1  x  2x
Total moles = 1 – x + 2x = 1 + x
Since PV = nRT, V  n
2x
% of NO2   100  50
1  x 
8
1
x 
3
D Theoretical VD
1  x   
d Experimental VD
4 46 46  3
  d  34.5
3 d 4
28. Species NO NO CN CN

Bond order 2 3 3 2
1
Bond order 
Bondlength
Bondlength of NO > CN+ due to greater number of antibonding electrons.
29. Tf  i  K f  m  86  0.001

 0.0054  i  1.86  0.001
0.0054
i   2.9  3
1.86  0.001
i.e. there are 3 ions in the solution of complex.
So, [Pt(NH3)4Cl2]Cl2 is the correct choice.
Mathematics PART – III
SECTION – A
2  3a  4b  c   3  4a  3b  c 
1.  10
a2  b2
18a  17b  5c
  10
a2  b2
18 17
a bc
 5 5 2
a2  b2
2. b2 = 4  2 = 8, 2ae  40
a2e2 = 10 = b2 + a2
 a2 = 2
Centre = (1, 5)
Equation of transverse axis  x – 3y + 14 = 0
Equation of conjugate axis  3x + y – 8 = 0
 3x  y  8 2  x  3y  14 2
Equation of hyperbola =   20
1 4
 25 
4 2 x 2  x 2  2  14 
x  14x  25  x 
3. f  x  =
5 5
x 2 x 2
x x
9
 2 
5
x2   x    4 
=  x  = x2  x  5  2 
 
5  x 
x 2
x
 x2 – 2x – 5 = 0
2  4  20 22 6
x = = 1 6
2 2
9
4. 6 places can be selected in C6 ways and 6 can be placed only at 5 places, except the right most
of other 6 selected. Remaining numbers i.e. 7, 8, 9 in 3! ways
Hence number of ways = 9 C6  5  3!
13     
5. z = 18 + 26i, r  10 10 , tan   ,    0,     0, 
9  2  3  6
1/ 3   
 z1/ 3  10 10  cos   isin     10  cos  isin 
 3 3 
3t  t 3 
tan   ,  t  tan 
2
1  3t  3
 1
 tan 
3 3
1/ 3
z = 3 + i, a = 3, b = 1
6. Let parabola is y2 = 4ax

 = at1t2,  = a(t1 + t2), Q = (at1t3, a(t1 + t3)), R  (at2t3, a(t2 + t3))
at t
Let T = (h, k) then h = 3  t1  t 2   3
2 2
4ah
2k = a(t1 + t2) + 2at3 =  

2
The locus id 4ax – 2y +  = 0
7. We observe that  =  Q(z2)

because of perpendicularity of two secant R(z3)
Now SOR + SOQ – SOP =  ( = )
 (arg(z3) – arg(z) + (arg(z2) – arg(z)) – (arg(z1) – arg(z)) =  P(z1)


 arg(z3) + arg(z2) =  + arg(z1) + arg(z) O(0)
= arg(z2z3) =  + arg(zz1) S(z)
 z2z3 = –zz1
 zz1 + z2z3 = 0
1
1 tan1  t 
8. Cn 
n 
n
sin1  t 
dt
n 1
1
tan1 t
L = lim n2  Cn  lim n  dt (  0)
n n 
n
sin1 t
n 1
10
1
tan1 t
n
 sin1 t
dt
n 1
L = lim (Applying Leibniz rule)
n 1
n
9. We have to find non negative integral solution of equation 2x + y + z = 21

Note that x can take a maximum value of 10 and a minimum value of 0.
We rearrange equation so that we get an integer equation with y and z as variables, x as a
constant
y + z = 21 – 2x
The number of non negative integer solution is 21 – 2x + 2 – 1C1 = 22 – 2x C1 = 22 – 2x
We now add the number of solutions so obtained for all the possible values of x.
10
The total number of solution is therefore   22  2x   132
x 0
10. As a > 0  R.H.S. > 0 hence x > 0

Applying AM  GM we get,
1
1 x
x ax  a  11
 x  
x  a x 2

2
1 1
 x  
2 x
L.H.S.  2 a
1
But x  2x>0
x
1 1
 x  
2 x
2 a  2 a  a  1  L.H.S.  2 a and equality holds if x = 1.
1 12 C2

4 51C2 11
11. The required probability is p  12 13

1 C2 C2 50
 51
 51
4 C2 C2
12.  x  2 2  3  y  13  = latus rectum = 3

 3 
 x  3 2  y  2 2
Other conic is   1 which an ellipse is
72 7
2
 
 2
2b2 2  49 7
Latus rectum =  
a 47 2
7 1
Positive difference  3 
2 2
13. B = adj (2A)  |B| = |2A|n – 1

1024 = 4n – 1 2n(n – 1)
2
210  2n n2
n=3
11
f x x
14. 2f(x) and have the same domain as f(x), f(2x) and f(x + 2), f   have the range as f(x)
2 2
m = 2, n = 3
  
Verify by f(x) = sin–1 x, d : |x|  1, R :   , 
 2 2

  2 a2
15. a1  a2  a1 a2 sin
n 2/n
    2
a1  a2  a1 a2 cos
n  2/n
2 2 a1
nsin  ncos
n n
2
   2  
tan    1   m 
 n  n 4
8
n
1  4m
Smallest possible value of n corresponds to m = 0  n = 8
17. f 1  x    x   x
5
A   x 
1/ 2
xdx
5 1 2
1  40
=
  x  dx 
 xdx  4
 xdx = 2  1 sq. unit
1/ 2 1/ 2 0
3 2
18. tan2   a, tan2 B  b

1/ 4 1/ 2
 a  12 b  12  a2 1 b2 1  a b  a2 1 b2 1  a b
       2    4       22   8
b a  b b a a b a  b b a a b a 
0 0 1
1 c 1 c2 
19. A 0 1  0  
2 b 2 ab 
c
0 1
a
If A is independent of a, b, c then C2 = ab a, c, b are G.P.
20. Using cosine rule b2 – 2bc cos A + (c2 – a2) = 0

2 2
b1 + b2 = 2c cos A b1b2 = c – a
Using b2 = 2b1
2c c 2  a2
b1 = cos A and b12 
3 2
4c 2 c 2  a2 2 2 2 2
cos2 A   9(c – a ) = 8c cos A
9 2
c
 1  8 sin2 A  3
a
3 2 2
22. x  x  x 2 = 0  (x  2) (x + x + 1) = 0  x = 2 … (1)
12
x y2 + 2 x y + 4 x  2 y2  4 y  8 = 0  (x  2) (y2 + 2 y + 4) = 0  x = 2 … (2)
Both the equation represent same line. So number of triangle formed are zero.
3 2
23. f (x) = sin x +  sin x
f (x) = 3 sin2 x cos x + 2  sin x cos x
for exactly one minimum and one maximum
 
f (x) = 0 at two points in <x<
2 2
 2
therefore f (x) = 0  cos x = 0 or, sin x (3 sin x + 2 ) = 0  sin x = or sin x = 0, cos x 
3
0
 2
1< <1
3
3 3
< but  > 0  0 <  <
2 2
24. P(x) = ax2 + bx + c

P(x) = Q1(x) + 4 = Q2(x + 1) + 3 = Q3(x – 1) + 1
P(0) = c = 4
P(–1) = a – b + 4 = 3 (b – a = 1)
P(1) = a + b + 4 = 1 (b + a = 3)
b = –1, a = –2
P(x) = 2x2 – x + 4
P(2) = –8 – 2 + 4 = –6
25. Center (–3, –5)

Radius  2
For L1 to be a chord its distance from center must be less than radius
Since P is an integer p can take value S1 = {17, 18, 31}
L2 to be chord of a circle, P can take value from the set S2 = {11, 12, ….. 25}
S1  S2 has 21 elements while
S1  S2 has 9 elements
9 3
Required probability or
21 7
1 n
26. lim n
divided N and D by 3 · n
n  x  2 1
n
3
3 n
1 1
lim to equal to  lim  0
n 3 n n
n
x2
lim    0  –1 < x < 5
n  3 
27. Let the equations of circle be y

x2 + (y – )2 = 16
= 2 6
13
28. |x + y + z| = |x| + |y| + |z|

 x2 – 2 < 0, sin x < 0
x    2, 0 
 1 1 1 
29. The normal to the plane will have direction cosine  , ,  and the distance of this plane
 3 3 3
from the origin will be OP = 3
x y z
   3  x  y  z  3
3 3 3
Intercepts lengths (3, 3, 3)
(3)2 + (3)2 + (3)2 = k2
k

3
x2  e  2 
30.  (1, e], f  x   ln  x  e    0, 1
2 2
x 1  x 1 
g    sin   cos  where   (0, 1]
cos  sin  
g'      0  
2 sin  2 cos  4

g() has an extremum point  
4
g(0) = 1  g 1  sin1  cos1
 
While g    23 / 4  g(1) > g(0) = 1
4

Since g    g  0   1
 2

g  x   1, 23/4 

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1

AITS-CRT-II-PCM (Sol)-JEE (Main)/14

ANSWERS, HINTS & SOLUTIONS

Q. No. PHYSICS CHEMISTRY MATHEMATICS

1.  Net force on the system is

2. Consider an arbitrary moment when the wedge has travelled a distance x

5. First law of motion.

6. For vertical oscillation time period

9. Tension in the string T = mg  FB = 3vg  vg = 2vg

10. II and IV quadrant field will be added.

12. mg  T  ma ----- (1)

13. J1 x 0.1 = 5 x I 0.5 5 mA

16. Let Vx and Vy be components of velocity. At contact point A Vx

21. Now downward force on the right T T

22. IC = I0 + M(OC)2 = I0 + M(OB2 + BC2) = IB + M(BC)2

23. Coulombic force between them remains same.

24. Circuit is forming a wheatstone bridge Req = 2R R R

27. Equivalent circuit is 2RT

29. Conceptual, torque of pseudo force.

30. Effective length = (r2 + r1)

7. Na2B 4 O7  H2 SO4  Na2 SO4  H2B 4 O7

8. Go  Ho  TSo

pH = 14, [H+] = 1 × 10-14

19. The rate can be compared by stability of carbocation.

 8  10 27  1  10 14 S 2 

28. Species NO NO CN CN

29. Tf  i  K f  m  86  0.001

Mathematics PART – III

6. Let parabola is y2 = 4ax

7. We observe that  =  Q(z2)

9. We have to find non negative integral solution of equation 2x + y + z = 21

10. As a > 0  R.H.S. > 0 hence x > 0

12.  x  2 2  3  y  13  = latus rectum = 3

13. B = adj (2A)  |B| = |2A|n – 1

18. tan2   a, tan2 B  b

20. Using cosine rule b2 – 2bc cos A + (c2 – a2) = 0

24. P(x) = ax2 + bx + c

25. Center (–3, –5)

27. Let the equations of circle be y

28. |x + y + z| = |x| + |y| + |z|

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