Faculty of Chemical Engineering CPE553 Chemical Engineering Thermodynamics

TUTORIAL 6

1. Determine good estimates of the fugacity for SO2 at 600K and 300 bar by using eqn. (11.67).

2. Estimate the fugacity of isobutylene as a gas at 280oC (553.15 K) and 20 bar by using eqn.
(11.68).

3. Determine the fugacity and fugacity coefficient for isobutane at 40oC (313.15 K) and pressure
of 2 bar, 5.28 bar and 8 bar. The saturation pressure of isobutane at 40oC (313.15 K) is 5.28
bar.
Given the fugacity coefficient for vapor phase, fugacity for liquid phase and molar volume of
saturated liquid are:

 Pr 
  exp  B 0
 B1  
 Tr 
V sat  P  Pi sat 
fi   P exp
i
sat sat
i
RT
1Tr 2/7
V sat  Vc Z c

4. For the system ethylene(1)/propylene(2) as a gas, estimate fˆ1 , fˆ2 , ˆ1 , and ˆ2 at t/T = 150oC
/423.15 K, P = 30 bar and y1 = 0.35
(a) Through application of eq. (11.63)
(b) Assuming that the mixture is an ideal solution