206-978258

@surMADzL)

Hyd ride Va por Generator

HVG.l

lnstruction Manual
Read the instruction manual thoroughly before you use the product.
Keep this instruction manual for future reference.

*******_****_"*i
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-.._**-
 lntt

This page is intentionally left blank.

 lntroduction
Read this lnstruction Manual thoroughly before using
the product.
Thank you for purchasing this product.
This manual describes the installation, operation, usage cautions, and accessories and
options for this product. Read the instruction manual thoroughly and use the product in
accordance with the described instructions.
Keep this manual for future reference.

IMPORTANT

' lf the user or usage location changes, ensure that this lnstruction Manual is always
kept together with the product.
o lf this manual or a product warning label is lost or damaged, immediately contact
your Shimadzu representative to request a replacement.

'To ensure safe operation, read all Safety lnstructions before using the product. To
ensure safe operation, read all Safety Instructions before using the product.

Notice

' lnformation in this manual is subject to change without notice and does not represent
a commitment on the part of the vendor.
'Any errors or omissions which may have occurred in this manual despite the utmost
care taken in its production will be corrected as soon as possible, although not
necessarily immediately after detection.

'All rights are reserved, including those to reproduce this manual or parts thereof in
any form without permission in writing from shimadzu corporation.

'Company names and product names mentioned in this manual are trademarks or
registered trademarks of their respective companies. The TM and @ symbols are omitted
in this manual.

Original version is approved in English.

O 2013 Shimadzu Corporation. All rights reserved

HVG-.I

I
lntroduction

lndications Used in This Manual

Dangers, Warnings,. Cautions, and Notes are indicated using the following conventions:

lndication Meaning

lndicates a potentially hazardous situation which, if not

avoided, could result in serious injury or possibly death'
a potentially hazardous situation which, if not
lnd icates
avoided, may result in minor to moderate injury or equipment
damage.
Emphasizes additional information that is provided to ensure
! Nore
the proper use of this Product.

The following symbols are used in this manual:

lndication Meaning

S
Prohibition
lndicates an action that must not be performed'

olnstruction
lndicates an action that must be performed.

"&
*
uint lndicates information provided to improve product performance.

)f Referenm lndicates the location of related reference information'

HVG.1
 Safety lnstructions

Sdety lnstrudions
-3 ensure safe product operation, read these important safety instructions carefully
:efore use and follbw allDANGER, WARNTNG and CAUTION instructions given in this
section.

t;':duct Applications

S Prohibition
Safety regulations and standards
For notifications on installation and safety controls, follow the necessary
procedures in compliance with the laws and regulations applicable in the
country where the product is used.

I nstallation Site

S
Prohibition
Do Nor install the product in locations that are exposed to flammable or
explosive gases or liquids.
This product does not feature an explosion-proof construction. This could cause
fire or an explosion.

SProhibition
Do Nor install the product in locations that are exposed to corrosive gases,
organic solvents, halogenated substances, gases containing polysiloxanes, oil
mist, or large amounts of dirt or dust.
This may make it impossible to maintain the product's performance or
shorten the life of the product.

SProhibition
Do Nor use the product in an environment where dew may condense on it.
This may prevent its normal operation.

o
lnskuction
lnstall the product in locations where the
power switch can be easily operated.
The power switch must be turned off in
case of an emergency.

Fig. I

HVG-1 llt
 lntroduction

r !nstallation

S
Prohibilion
Do NOT place heavy objects on the power cord, and keep any hot items away.
Do not modify the cord in any way. Do not bend it excessively or pull on it.
The cord may be damaged, resulting in a fire, electric shock, or malfunction.
lf the cord becomes damaged, contact your Shimadzu representative
immediately.

o
lnstruction
Take measures to prevent the instrument from falling in the event of an
earthquake or other disaster.
Strong vibrations could cause the instrument to fall over, resulting in injury.

o
lnstruction
The power supply voltage of the instrument is indicated on the label on the
rear of the instrument. Connect the instrument only to a power supply of the
voltage indicated.
Otherwise, a fire or electric shock may result. Check that the power supply
voltage is stable and that its current capacity is sufficient to operate all the
components of the system. lf not, the instrument will not operate at its rated
performance.

o
lnstruction
Ground the instrument.
Grounding is necessary to prevent electric shock in the event of an equipment
failure or short circuit, and important for ensuring stable operation.

o
lnstruction
Insert the power cord in the power outlet at an easily accessible position.
The power cord must be unplugged from the power outlet in case of an
emer9ency.

o
lnstruction
Please make sure to use only the power cord specified by Shimadzu.

Be aware of gaps around the instrument during installation-

lf your fingers get caught, it may result in an injury.

lv HVG.1
 Safety lnstructions

! l:;":: on

Aceu
orsanic sorvent on the instrument' wipe

R Ii:;t*::*y;,;r,,"",': ,,;n

SProhibition
Be careful not
instrument.
to apply liquid to office equipment such as pc as well as the

I Precautions on Handling Glass products

olnskuction
The following parts are made of glass. Handle these parts with care.
. Absorption cell
. Gas/liquid separator

S
Prohibition
Do NOT touch broken glass parts with your bare hands.
Touching broken pieces of glass may result in injury.

I Precautions on Handling Chemicals and Samples

SProhibition
Do NOT measure explosive samples.
Not only will this cause damage to the instrument or instrument failure, but
user safety cannot be guaranteed in this situation.

olnstruction
Always wear protective gloves and goggles when handling chemicals.
Eye exposure to chemicals may cause blindness.
should a chemical get into the eyes, flush immediately with large amounts of
water and seek medical attention.

olnstruction
Always wear protective gloves when handling any toxic or biologically
infectious samples.

HVG-1
 lntroduction

I lnspection and Maintenance

W
Never remove the main cover.
This may cause an injury, equipment failure, or hazardous radiation exposure.
The main cover does not need to be removed for routine maintenance,
inspection, and adjustment. Have your Shimadzu representative perform any
repairs requiring removal of the main cover.

Unplug the power cord of the instrument before inspection, maintenance, or

part replacement.
Otherwise, electrical shock or short-circuit accidents may occur.

When replacing a part, use the part described in the lnstruction Manual.
lf you use any other part, that part may be damaged, preventing normal use
of the instrument.

I Repair, Disassembly and Modification

This may result in accidents due to electric shock or short circuits. lt may also
p.Fmon result in injury or equipment failure.

o
lnstruction
When repair is necessary, request your Shimadzu representative.
Failing to do so may result in an ignition, electric shock, or injury.

vl HVG-1
 Safety lnstructions

. I ln an Emergency
Take the following action in the event of an emergency, such as when a problem occurs
with this product.
Also, when the instrument is used again, inspect the instrument and, if necessary, contact
your Shimadzu representative to request servicing.
'I turn OFF the power switch on the front of the instrument.
2 Cut off the power supply by disconnecting the power cord from the side of the
instrument.

I During a Power Outage

Take the following measures in the event of a power outage.

t Stop the supply of gas to the atomic absorption spectrophotometer and HVG-1.

7" Turn OFF power to the atomic absorption spectrophotometer and all optional
equipment including the HVG-1 hydride vapor generator.

3 Open the windows and doors of the room where the instrument is installed and
ventilate the room.

4 Check that there are no sources of ignition for acetylene gas in the room.

5 After restoring power, check the points described in "lnstallation" p.iv and
"Operation" P.v and then start the instrument normally.
lf the instrument does not start, contact your Shimadzu representative to request
inspection.

HVG-I vrl

I
 lntroduction

I Warning Labels

ln order to ensure safety, warning labels are attached in places requiring caution.
lf a warning label is lost or damaged, obtain a new label through your Shimadzu
representative and attach it in the correct position.

uescnplron Attached Position

Part No:

A
s037-72143-00
CORROSIVE
Contents are
corrisive. DO NOT
spill or touch.

Fig. 2

Part No:
s206-58757
HARMFUL GASES
During operation,
hydrogen and metal
hydride gases are

A emitted.
Ensure adequate
ventilation.
TOXIC WASTE
LIQUID
Read the instruction
manual to ensure
proper handling of
waste liquid.
Fig. 3

VIII HVG.1
 Warranty

WarranQr
Shimadzu provides the following warranty for this product.

1. Period
Please contact your Shimadzu representative for information about the period of this warranty.
2. Desciption
lf a producVpart failure occurs for reasons attributable to Shimadzu during the warranty period;
Shimadzu will repair or replace the producUpart free of charge. However, in the case of products
which are usually available on the market only for a short time, such as personal computers and
their peripherals/parts, Shimadzu may not be able to provide identical replacement products.

3. Limitation of Liability
(I) ln no event will Shimadzu be liable for any lost revenue, profit or data, or for special, indirect,
consequential, incidental or punitive damages, however caused regardless of the theory of
liability, arising out of or related to the use of or inability to use the product, even if Shimadzu
has been advised of the possibility of such damage.
(2) ln no event will Shimadzu's liability to you, whether in contract, tort (including negligence), or
otherwise, exceed the amount you paid for the product.

4. Exceptions
Failures caused by the following are excluded from the warranty, even if they occur during the
warranty period.
(1) lmproper product handling

(2) Repairs or modifications performed by parties other than Shimadzu or Shimadzu designated
companies

(3) Product use in combination with hardware or software other than that designated
by Shimadzu
(4) Computer viruses leading to device failures and damage to data and software, including the
product's basic software
(5) Power failures, including power outages and sudden voltage drops, leading
to device failures
and damage to data and software, including the product's basic software
(6) Turning OFF the product without following the proper shutdown procedure leading
to device
failures and damage to data and software, including the product's basic software
(7) Reasons unrelated to the product itself
(8) Product use in harsh environments, such as those subject to high temperatures or humidity levels,
corrosive gases, or strong vibrations

(9) Fires, earthquakes, or any other act of nature, contamination by radioactive or hazardous
substances, or any other force majeure event, including wars, riots, and crimes
(10) Product movement or transportation after installation

(1 1) Consumable items
Recording media such CD-ROMs are considered consumable items.
* lf there is a document such as a warranty provided with the product, or there is a separate contract
agreed upon that includes warranty conditions, the provisions of those documents snatt appty.

HVG-1 IX
lntroduction

After-Sales Service and Availability of Replacement Parts

r After-Sales Service

lf any problem occurs with this product, perform an inspection and take appropriate
corrective action as described in "8 Troubleshooting" P.37 of this manual.
lf the problem persists or the symptoms are not covered in the troubleshooting section,
contact your Shimadzu representative.

I Replacement Parts Availability

Replacement parts for this product will be available for a period of seven (7) years after
the product is discontinued. Thereafter, such parts may cease to be available.
Note, however, that the availability of parts not manufactured by Shimadzu shall be
determined by the relevant manufacturers.
lf Shimadzu receives notice of the discontinuation of units or parts, the necessary quantity
for the above period is immediately calculated and secured. However, such units or parts
may cease to be available within seven years after the discontinuation of the product,
depending on individual manufacturer conditions and on changes in the quantity
required.

Maintenance, lnspections, and Adjustment

This instrument has a design life of seven (7) years. ln order to maintain long-term
instrument performance and obtain accurate measurement data, daily inspections and
periodic inspections are necessary.
. For daily maintenance, inspections, and replacement parts, see "7 Maintenance and
lnspection" P.29 of this lnstruction Manual.
. Periodic inspection should be requested to your Shimadzu representative.
. Replacement cycles described for periodic replacement parts are a rough estimate.
Replacement may be required earlier than the described replacement cycles depending
on usage environment and frequency.

Disposal Precautions
Contact your Shimadzu representative before disposing of this product.
When disposing of this instrument, separate its components into industrial waste and
domestic waste and dispose of them according to the waste disposal standards stipulated
by the relevant laws and regulations.

HVG.1
 Handling of Drainage

Handling of Drainage
Drainage contains hazardous metal hydrides. Appropriately dispose of drainage according
to the laws and rei;ulations at the location of use, such as consigning disposal to an
industrial waste company. ln addition, wear protective gloves and goggles for safety
when handling drainage.

HVG.l

I
Contents
lntroduction lndications Used in This Manual
Safety lnstructions lil
Warranty tx
After-Sales Service and Availability of
Replacement Parts x
Maintenance, lnspections, and Adjustment
Disposal Precautions
Handling of Drainage ;T
0verview Product Overview 1

Details of Parts 1

1.2.1 Standard Pafts ... 1

12.2 Required Reagents 2

Part Names and 2.1 Front Panel . 3

Functions z.z Side Panel/Rear 5

2.3 Piping and Flow Paths 6

2.4 Principle of Measurement 7

I
3 | tnstallation :.t lnstallation Procedure ..

Reagent Preparation and 4.1 Reagent Preparation 15

Sample Pretreatment +.2 Sample Pretreatment 16

Measurement 5.1 Measurement Preparation 17

Operation 52 General Measurement Procedure... 19

s.s Flush Switch Operation . 20

s.+ Operations After Completing Measurement ......... 21

xil HVG-1 '

 Contents

i
o.t Linking with the 44-6200 23

il 6.2 Linking with the 44-7000/6300/6800/6650 ... 25

ix 6.3 Connecting an Autosampler (ASC-7000/6100) 27

r Eralnf,enaf
x I hspection
29
z.z Absorption Cell Maintenance ..... 30
xi
1.3 Gas/Liquid Separator Ma i ntena nce 30
74 Checking for Gas Leaks 31
7.5 Checking for Pressure Regulator (Option) Gas
1 Leaks 32
1 7.6 Periodic lnspection and Maintenance 34
1 7.6.1 Daily lnspections .. ... 34

2 7 6.2 Periodic lnspections 34

7 7 Replacement Parts 35
7 .7.1 Consumable Parts 35
1 .7 .2 Periodic Replacement Pafts .. . 35
3
7 .1 .3 Replacement Parts .. . 36
5

I I rroubleshooting Troubleshooting

9 | recnnical Data 9.1 Specif ications 38

9.2 Options 38
9.2.1 Option for Connection to the Autosampler .. 38
15

16
9.2.2 Options for Electric Heating 39
9.3 Environmental Requirements for Unit
lnstallation and Storage ... .. 39
9.4 Equipment Requirements 40
9.4.1 Power Requirements . 40
17
9.4.2 Gas Requirements .... 40
19
9.4.3 Exhaust Equipment 42
20
21

xlll
This page is intentionally left blank.
1 Overview
t-l Product Overyiew
--e HVG-1 Hydride Vapor Generator is used in combination with the Shimadzu Atomic
::sorption Spectrophotometer (AA-7000 Series and 44-6200, 44-6300, and 44-6800/6650
i:'es) to determine the quantities of elements including arsenic (As), selenium (Se),
:-:rmony (Sb) and mercury (Hg) in solution samples using the hydride generation method.

tJ Details of Palts
Standard Parts

This unit consists of the following parts.

After unpacking, please confirm that the package
includes the correct number of the following parts.

Part Name Part No.*l Q'ty Remarks

'",1AIN UNIT 206-58783-XX 1

REAGENT BOTTLE ASSY, HCI s206-58792-40 1 For HCI

REAGENT BOTTLE ASSY, NaBHo s206-58792-42 1 For NaBH4
GAS HOSE s204-05845-42 1

CORD, UC-975-NOI/CORD SET, s071-60821-08

KP-481 9D+KS-3 1 A 2.4M/CORD, s071-60814-05 1 -421-43, -44 and -581-46
KP-722+KS-31A 2.4M s07 1 -60827-05

DRAIN TUBE s206-60250-02 1

FLUORINATED RUBBER TUBE For connection to the

5206-602s0-01 1
absorption cell

GUIDE PLATE For preventing reagent bottles

s206-1 8033 1
from tipping over
CELL HOLDER s206-77510-91 1

ABSORPTION CELL s206-77607 2

HOSE CLAMP, cp16 s037-61 01 9 1 For the gas hose

PUMP TUBE, 08 s208-90038-08 4 For reagent
PUMP TUBE, 13 s208-90038-1 3 2 For sample
FRONT COVER ASSY s206-1 8069-41 1

SIDE COVER s206-17879-01 1

GAS/L|QUtD SEPARATOR s206-1 7839 1

MANIFOLD s206-17825 1

REACTION COIL s206-1 8037 1

HOSE NIPPLE s204-64601 1 Used attached to the manifold

O-RING, EPR s200-62522 1 For the hose nipple

HVG.1
1 Overview

Part Name ]it]]l]]t:]]]P;iit..No:,lilt',:.]]t]]] Q',ty Remarks

SUCTION TUBE (MARKED

s206-1 8036-01 1 For reagent (NaBH+)
YELLOW)

SUCTION TUBE (MARKED BLUE) s206-1 8036-02 1 For reagent (HCl)

SUCTION TUBE (UNMARKED) s206-1 8036-03 1 For sample
For pump tube identification
WIRE MARK (YELLOW) s072-83083-03 5
(NaBH+)

For pump tube identification

WIRE MARK (BLUE) s072-83083-02 5
(Hcr)

FLOW PATH DIAGRAM STICKER s206-1 861 6 1

NIPPLE ASSY, THREE-DIRECTION s206-58781 -41 1 For branching argon gas

For connecting the three-
HOSE CLAMP, rp14 s037-61 01 8 3
direction nipple ASSY
For'preventing disconnection
CABLE TIE, RF-1OO s072-6031 5-01 3
of the drain tube
INSTRUCTION MANUAL (this
s206-97825 1
manual)
SERIAL NUMBER LABEL 206-57770 3

*1 Parts that include "5" in the part number are sold as replacement parts or consumable parts. Parts
that do not include "S" in the part number are not sold individually.

1:2:2 Required Reagents ;*}.wl"*%€.,-@.&i*6@*6i1e*L**'4,,,,rM*#**$4*@ee-,*- *c#**

The following reagents must be prepared when using this product. Note that other
reagents may be required in pretreatment depending on the sample.

Part Name Application

Sodium hydrate
Sodium borohydride
Hydrochloric acid
Pure water (distilled)
Standard solution (containing
for measurement)
For reagent preparation (sodium hydrate
solution)
For reagent preparation (sodium borohydrate
solution)
Reagent
For preparing reagent and standard solution
the element Calibration curve creation

HVG-1
2 Part Names and Functions

Fig, 2-1 Front Panel

No. Part Name Description

o Power switch An ONiOFF switch for supplying power to the HVG-1.
Press to speed up the peristaltic pump rotor for about 20
o Flush switch seconds. This is used to perform high speed flushing of the
flow paths.
Pressure monitor llluminates if the supply gas pressure decreases below 0.2g
o lamp MPa. The rotor does not turn while this lamp is illuminated.
@ Flush pilot lamp lndicates that flushing is in progress.
o Speed control knob Sets the suction rate of sample and reagent.
Sample and reagent are fed to the reaction coil by rotating
a roller that squeezes down on these tubes. Each type can
be identified by the bridge color.

o Pump tubes I Bridge Color I Wire Mark Color

NaBHalOrangely"llo*
HCI lOrangelglue
Sample I elue
rt-'--l I

o Adjuster screw Adjusts the squeeze pressure on the pump tubes.

o Tube fitting Thisfitting presses the roller against the pump tubes in
order to draw in sample and reagent.
o Screw stopper The part for attaching the adjuster screw.
@ H inges The front cover mounts on these hinges.

HVG-I 3
2 Part Names and Functions

Description
Holds the sample pump tube.
Connects the sample suction tube and sample pump tube.
This tube is for drawing in sample. Submerge the end of
this tube in the sample solution.
Place the reagent bottles on this tray.
Attaches to the reagent tray to prevent reagent bottles from
tipping over.

HVG-1
 2.2 Side Panel/Rear

Side Panel/Rear

--rr-f--l I

_t{_=kN \_:
&
ffiT"* \-
_l\_f-f \
lr-
-*=r-
lt
t!

Side Panel/Rear

No. Part Name Description

Generates hydride as the sample and reagent move through
o Reaction coil
its interior.
o Gas/liquid separator Separates hydride and reagent residues after reaction.
Mixes NaBH4, HCl, and sample and introduces the mixture
o Manifold
to the reaction coil.
@ Carrier gas inlet Connects to the argon gas hose.
Connects to the AC power cord. A voltage
o Power connector
provided.
selector is

o Joint Connects the reagent suction tube and reagent pump tube.
o Clamp Holds the reagent pump tube.
Carrier gas tube
o (short) Connects to the manifold.
Carrier gas tube
o (long) Connects to the gas/liquid separator.
@ Drain tube Discharges sample residue into the drainage container.
Secures the connection of the drain tube to the gas/liquid
o Cable tie separator. The cable tie prevents disconnection of the drain
tube.

HVG-1

I
2 Part Names and Functions

2,3 Piping and Flow Paths

A diagram of the piping and flow paths used by the HVG-I is shown below.

Absorption cell

Burner head

Gaslliquid separator

Sample

HCI'

NsBli r

gas +
Pressure sv/ilch

Fig. 2-3 Piping and Flow Path Diagram

'
HVG-1
 I

2.4 Principle of Measurement

I"ll Principte of Measurement

- - -= : ements in aqueous solution, such as As, Se, or Sb, react with nascent hydrogen
-:
-::^e'ate gaseous hydride. lntroducing this hydride into the atomizer and performing
. -*::tion by breaking it down with heat allows high sensitivity analysis.
- - :-: other hand, inorganic mercury (Hg) in aqueous solution is vaporized as free
-=':--!' in the presence of a reducing agent. By introducing this mercury vapor into the
.-.:* zer, atomic absorption measurement can be performed without the need for
:. - u.
.'-. J and reagent (hydrochloric acid and sodium borohydride) solutions are fed into
--= -anifold by the pump, mixed, and sent to the reaction coil to generate
hydride.
--='eaction mixture that comprises hydride as well as hydrogen, water vapor and
"=.::'tt residues, which are generated at the same time, are fed into the gas/liquid
':::'ator by the carrier gas. ln the separator, the gas phase is separated from the liquid
:-:se and sent to the absorption cell by the carrier gas, while the latter is drained. The
=:,:rption cell is heated by the air acetylene flame to break down the hydride and
:::'r ze the element targeted for measurement, after which atomic absorption
-=:sr.lrement is performed. For the analysis of mercury, the same cell is used without
Y.

HVG-1 7
 lnstallation
This unit is used in conjunction with the Shimadzu Atomic Absorption Spectrophotometer.
Before installing this unit, thoroughly read the instruction manual for the main unit of
the atomic absorption spectrophotometer.

3.1 Installation Procedure

1 lnstall the HVG-1 in front of the atomic absorption spectrophotometer main unit.
Pass the AC power cord and gas hose under the atomic absorption spectrophotometer.

Alom ic a bsorption spectrophotometer

Gas hose

AC power cord

E
E
O1
o'
c.l l

ir
o-

HVG-1

340mm

Fig. 3-1 lnstallation Diagram

olnstruction
When lifting the unit, raise it slowly with both hands.
The unit body weighs approximately 9 kg. Lifting the unit with improper
posture may result in injury.
We recommend using a commercially available table with casters to move the
unit.

olnskuction
Place the HVG-1 main unit and absorption cell as close together as possible.
The length of the fluorinated rubber tube for connecting the absorption cell
is 1 m. Place the HVG-I within range of the tube.

2 Connect the provided power cord.

HVG-1
 3.1 lnstallation Procedure

l:nnect the gas hose.

ilt i,f cunt the cell holder onto the burner head of the atomic absorption
:cectrophotometer.
-,= a standard burner head (10 cm slot). Place the cell holder on the burner head and
:::-'e it in place with the provided screw.

ir
o
- s:J:tio n
Wait at least 30 minutes after extinguishing the flame before per-forming
maintenance inside the burner compartment of the atomic absorption
spectrophotometer.
Touching high temperature parts may result in burns.

Connect the fluorinated rubber tube to the absorption cel! inlet.

:=ss the other end of the tube through the hole in the center of the
cell holder.

A CEUTIoN

o
instluction
Do NOT directly touch the absorption cell with bare hands.
Wear clean gloves when handling the absorption cell.

o
lnstruction
When connecting the fluorinated rubber tube, hold the inlet pipe of the
absorption cell.
Due to the weakness of the T-shape at the center of the absorption cell,
holding any other part when pushing on the tube may cause the absorption
cell to break.

HVG-1 9
 3 lnstallation

5: lnstall the absorption cell into the cell holder.

While pushing both ends of the absorption cell onto the retaining clips in the V-grooves
of the cell holder, insert the tip of the absorption cell entrance into the cell holder hole.
Check that both bnds of the absorption cell are firmly fit into the retaining clips in the
V-grooves of the cell holder.

o
lnstruction
Make sure that the fluorinated rubber tube does not come into contact with
heated sections.
lf using an atomic muffle (sold separately), check that the tube does not enter
into the furnace.

Retaining clip Absorption cell

Fluorinated rubber tube

(connects to the HVG-1)

Fig. 3-2 Absorption Cell lnstallation (AA-7000)

10 HVG.1
 .-
3.1 lnstallation Procedure

kl! the pump tubes.

1 fit a yellow and blue wire mark onto each of the two tubes for reagent (fitted
with an orange.bridge).
Hereafter, the yellow mark identifies the NaBHa tube and the blue mark identifies
the HCI tube.

Pass the end of the NaBHa pump tube without the yellow mark to the side panel
through the bottom left hole in the front panel.

3 see "Fig. 3-3 Manifold" and connect the pump tube to the NaBHa port of the
manifold.

To lhe reaclion coil

Canier g* inlet NaBHr port

Fig. 3-3 Manifold

n
Connect the HCI pump tube to the HCI port of the manifold.

*j After passing the sample pump tube (fitted with a blue bridge) to the side panel
from the front panel, connect it to the sample port of the manifold.

Connect the reaction coil to the outlet port of the manifold and set the reaction
coil and manifold on the side panel as shown in "Fig.2-2 side panel/Rear,,

? Hook the bridges of the NaBH4 and HCI pump tubes onto the lower grooves of
the tube holder and run the tubes along the pump rotor. At the same time, hook
the bridges on the other end onto the upper grooves of the tube holder Arrange
the pump tubes from the recess to the front in the order of NaBHa, HCl, and
sample.

I Pass the NaBH4 pump tube to the side panel through the top left hole of the
front panel and connect it to the suction tube marked yellow.

I similarly, connect the HCI pump tube to the suction tube marked blue.

10 Hold the NaBH4 and HCI suction tubes with the clamp on the side panel as shown
in "Fig. 2-2 Side Panel/Rear"

11
 3 lnstallation

1 1 Hold the sample pump tube with the clamp on the side panel and connect it to
the unmarked suction tube.

o
lnstruction
lnsert the pump tubes into the joints as deeply as possible.
This prevents leaks of sample and reagent from the connections.

o
lnstruction
After connecting each tube, check that the tubes do not come off easily by
gently pulling on the connections.

S
Prohibition
Do NOT leave the pump tubes on the rotor for an extended period of time.
This will significantly shorten the service life of the tubes.

8: Connect the drain tube to the gas/liquid separator.

9: Connect the other end of the drain tube to the drainage container.

o
lnstruction

1O i Secure the connection between the gas/liquid separator and drain tube using a
' cable tie.

12 HVG-1
 3.1 lnstallation Procedure

Iount the gas/liquid separator onto the HVG-1.

1 pla." the gas/liquid separator onto the holder on the side panel and secure it in
place with a rubber ring.

Connect the end of the reaction coil to the reaction product inlet of the gas/liquid
separator.

Pass the reaction coil through the notch in the reaction coil holder and adjust the
position of the plastic tube stopper as shown in "Fig. 3-4 Tube Stopper Adjustment
Position "

Tube stopper

Tube for connecting the gas/

ltquld separator

Fig. 3-4 Tube Stopper Adjustment Position

Connect the other end of the fluorinated rubber tube that is connected to the
absorption cell to the gas outlet of the gas/liquid separator.
r
-", Prepare a suitable container for receiving drainage and insert the other end of
the drain tube into the container.

s After completing all the connections, check that both ends of the absorption cell
are are firmly fit into the retaining clips in the V-grooves of the cell holder.

/. Connect the carrier gas tube.

'l Conn"ct the short tube coming out of the top right of the side panel to the carrier
gas outlet of the manifold.

Connect the long tube coming out of the top right of the side panel to the carrier
gas inlet of the gas/liquid separator.

HVG-1 13
3 lnstallation

Attach the front Gover.

lnsert the pins'on the hinges bttached to the front cover downwards into the hinges on
the front panel.

Attach the side cover.

Attach the guide plate.

Align the leg ends of the guide plate with the pin holes on the reagent tray and then
place the guide plate on the tray.

! ruore The guide plate prevents the reagent bottles from tipping over. Always use the
guide plate.

HVG-1
4 Reagent Preparation and Sample pretreatment

{ I Beagent preparation

A cnunoN

I Always wear protective groves and goggres when handring chemicars.

Eye exposure to chemicals may cause blindness.
should a chemical get into the eyes, flush immediately with large amounts
water and seek medical attention.
of

I ..r; I -- borohydride solution (0.4o/o NaBHo solution)

I ":lve 2.5 g oI sodium hydroxide and 2.0 g of sodium borohydride in distilled water
- :ris order and then add distilled water to obtain a total volume
of 500 ml.

! rore sensitivity may decrease as sodium borohydride solution becomes old. prepare
reagent immediately before measurement.

loric acid

I rte hydrochloric acid to prepare 500 mL of 5M solution.

Prepare the standard solution to the required concentration. An

example of standard
solution concentrations is shown below.

Concentration (Units: ppb)

As 1 to 10
5e 2to20
Hg 5to50
Sb 1 to 10

! rcre The amount of element in the solution for measurement using this instrument
is very small. Because the element in the solution readily evaplrates
or is
adsorbed by the container, prepare the standard solution immediately
before
measurement.

HVG-1
 4 Reagent Preparation and 5ample Pretreatment

4,2 Sample Pretreatment

r Elementsfor measurement are restricted to samples in inorganic form. Organic form
and organic matter samples must be decomposed through wet ashing in advance.
. When measuring As, Se, and Sb, sensitivity differs depending on valences. When
measuring these elements, perform preliminary reduction treatment so that valences
match.

t Hint Methods such as the following are available for preliminary reduction treatment of As, Se,
and Sb. (These methods are only examples. Perform suitable preliminary reduction treatment
according to the condition of the sample and purpose of analysis.)

Examples of Preliminary Reduction Treatment

Add 2 mL of hydrochloric acid (35 to 37o/o) and 1.25 mL of 2oo/o

potassium iodide solution for 25 mL of standard solution or unknown
sample and let the mixture sit for about 30 minutes.
Add 20 mL of hydrochloric acid (1+'l) for 25 mL of standard solution or
unknown sample and heat for about 10 minutes at 90 to 100 "C.
Add 5 mL of hydrochloric acid (35 to 37o/o) and 3 mL of thiourea solution
Sb
(0.1 mol/l) for 25 mL of standard solution or unknown sample.

I Horr Potassium iodide will interfere with Se and Hg. Perform sufficient cleaning when
analyzing these elements using flow paths through which potassium iodide has
passed.
lf the effects ofpotassium iodide are significant even after cleaning, we
recommend preparing another set of parts that include the various tubes,
manifold, gas/liquid separator, fluorinated rubber tube, and quartz absorption
cell, and replacing all of these parts before use.

15 HVG.1
5 Measurement Operation
ffieasurement Preparation

::.:r the reagents into the reagent bottles and set the bottles onto the reagent

=":::he reagent bottle containing the sodium borohydride solution at the rear and the
='::rt bottle containing hydrochloric acid at the front.

:'epare the peristaltic pump.

iii-

'i Sufficiently loosen the adjuster screw, turn the screw stopper, and open the tube
f itting.

Hook the pump tube bridges onto the tube holder grooves and set as shown in
"Fig. 5-1 Mounting the Pump Tubes"
Arrange the tubes from the recess to the front in the order of NaBHa, HCl, and
sample.

! Nore Set the tubes perpendicular to the roller without twisting them.

For NaBHr For HCI

for sample

%
llD,l
€) tw)
Bridge (orange) Bridge (blue)

Fig. 5-1 Mounting the Pump Tubes

I
3 Close the tube fitting and turn the screw stopper so that the tubes are pressed
lightly.

t Check that the carrier gas is supplied at 0.35 MPa and then turn ON the power
switch.

17
 5 Measurement Operation

L
*-r Pour distilled water into a suitable container and insert three suction tubes intc -

s Gradually turn the adjuster screw on the sample side until solution begins to c=
drawn smoothly through the sample suction tube and then tighten further by
about half a turn.

7 Similarly, gradually turn the adjuster screw on the reagent side until solution
begins to be drawn smoothly through the two reagent suction tubes and then
tighten further by about half a turn.

Do NOT overtighten the adjuster screw. This may significantly shorten

the service life of the tubes.

I Run in the pump for about 10 minutes until the pumping rate has stabilized.

$ Xint When using new tubes, solution may not be drawn even with the adjuster
screw fully tightened. ln this case, do not forcibly tighten the screw. Run in
the pump for about 10 minutes with the screw tightened halfway and then
set the screw position again.

3:: Set the speed control knob to a suitable

speed.
The sensitivity may be affected by the suction rate of sample and reagents. Normally use
a sample suction rate of 3 to 5 mUmin.
Generally, while a higher suction rate increases sensitivity, it also increases the noise level,
which deteriorates reproducibility. We recommend setting the suction rate to a previously
determined value that ensures both appropriate sensitivity and good reproducibility.

4 Start the atomic absorption spectrophotometer.

Set the lamp current, wavelength, slit, and other parameters as specified in the
instruction manual for the atomic absorption spectrophotometer so that the
absorbance value is displayed.

Adjust the burner position so that beam passes through the center of the
absorption cell.
)) Reference For details on linking with the atomic absorption spectrophotometer, see "6
Linking with the Atomic Absorption Spectrophotometer" P.23.

lgnite the air acetylene flame. For the analysis of Hg, no flame is needed.

! Hore Set the acetylene flow rate to 2.0 Umin regardless of the element for
analysis.An acetylene flow rate higher than this may result in the
deposition of soot in the absorption cell, which will significantly
reduce the service life of the cell.

18 HVG-1

l
 5.2 General Measurement procedure

I Measurement procedure

-se.t each reagent suction tube into each reagent

bottre.
--= tubes are marked with color for identification: yellow for NaBHa and
--" -'-ction
1 . Check that the ends of each tube reach the bottom of
blue
the bottles.

&' :et the sample and insert the sample suction tube.

**,eit until the absorbance signa! stabilizes.

--":'a short delay following the start of sample suction, the absorbance signal increases
=-: stabilizes in about 30 to 70 seconds.

ineck that the absorbance signal is stable and then start measurement.

S
:'chibition
Do NoT extinguish the flame in the atomic absorption spectrophotometer
the sample is completely expelted from the ftow path.
Failure to do so will cause emission of hazardous hydride gas.
until

19
 5 Measurement Operation

5.3 Flush Switch Operation

When measuring a blank solution after measuring a high concentration sample, the signd
may take a long time to return to the zero level, as shown in "Fig. 5-2 Flush Switch
Operation" , or the noise level may increase. This type of phenomenon occurs frequend;l
with Sb.
ln this case, insert the suction tube into the blank solution and press the FLUSH switdt
when the signal begins to decline.
The pump rotor will turn at high speed and flush the flow paths in a short time. When
flushing is complete, check that the zero level signal is stable before starting
measurement of the blank solution.

No flushing

Time

Flushing

Time

HIGH T-l
Pump rotor rotation ,-O* | I

I
l

Flush switch pressed

Fig. 5-2 Flush Switch Operation

20 HVG-1
 5.4 Operations After Completing Measurement

Operations After Completing Measuremen

AceuTloN
o Yl".i T"r:u,reT:nt
rne reagent bottles.
Gas generated from
is not being performed, close the inner tid provided

the reagent may damage the instrument.

on

i'tinguish the flame in the atomic absorption spectrophotometer.

: rsh the flow paths.

-":-sfer the three suction
tubes for the sample and reagents into distilled water and
continue suction by operating the pump for about 5
to i0 minutes iin order to flush
=':: flow path.

Expel the water from the flow paths.

Expel the distilled water from each suction tube
and draw in air until no water droplets
remain in the flow paths.

{l
Stop the gas supplies.

Loosen the adjuster screw, turn the screw stopper, and release the tube fitting.

Remove the pump tubes from the rotor.

Remove the tubes connected to each part of the absorption cell and gas/liquid
separator.

E Remove the absorption cell and gas/liquid separator

and clean them with distiled
water.

HVG-1
 5 Measurement Operation

I
I
9 Dry the cleaned absorption cell and gas/liquid separator in a clean location.

o
lnskuction
The burner head is extremely hot immediately after extinguishing the flame.
Wait at least 30 minutes after extinguishing the flame before performing
maintenance inside the burner compartment.
Touching high temperature parts may result in burns.

o
lnstruction
Appropriately and promptly dispose of the sodium borohydride solution after
measurement is complete.

S
Prohibition
Do NOT dispose
drainage.
of sodium borohydride solution together with the

This may result in the emission of hydrogen and metal hydride

sample or

gases.

o
lnslruction
Final disposal of drainage must be performed appropriately.

22 HVG-1

I
 6 Linking with the Atomic Absorption Spectrophotometer

unking with the AA-6200

ronfigure the parameter settings in flame measurement (suction

mode).

{ir,
set the element for measurement and select the
IHVGI checkbox.
)B,dmdea

a.il:t'crl{ . ienptde
l

'l;nm
8GC'lr:
nr Clmd l:El
3i.t:Hi
i Ga3 7?Lhn

Fig. 5-1

Adjust the burner height to suit the HVG-I.

Loosen the chamber locking screw and set
the chamber to the middre chamber
positioning hole.

t Set the absorption cell onto the burner head.

)) Reference For detairs, refer to the 44-6200 instruction manuar.

Perform preparation for measurement, including setting

HVG-I.
the pump tubes on the
)) Reference For details, see ,,5.1 Measurement preparation " p.17.

5 lgnite the air acetylene flame (skip this step for mercury
analysis).

Start drawing in the reagents.

8 Submerge and draw blank solution (or distilled

water) into the sample suction
tube' set the hollow c-athode lamp of the element tor
measurement, and execute
[Line Search/Beam Batance].

HVG-1
 6 Linking with the Atomic Absorption Spectrophotometer

Wait about 5 minutes, draw in blank solution (or distilled water), and then
execute IAUTOZEROI.

10 Set the sample in place according to the setting order of the AA-6200 unit anc
insert the sample suction tube into the sample.

t
After the absorption signal display has mostly stabilized, ctick ISTARTI.
11 i
'*'""'''"'r' The results of absorbance are displayed when measurement is
complete.

Draw in distilled water and check that absorbance returns to the zero level.

Repeat steps 9 to 11.

24 HVG-I

I
 52 -.,. -:.,:-:-:
-

'rJ Unking with the AA-700016300/6800/6550

Set the element for measurement, select the [Flame Continuous] radio button,
:'rd select the [HVGI checkbox.
i;,t;;;;. . r-..-.. -
Lc:i!rnr -:m1 Je '

r:.1 - ._
.-. f*d
(. tnmeLrdn@ls, I
lr qo""14.*;uar"q I .{"Lllot 193 7m
I
| ?*16 :
lii:#ii:,"
I lr1 rF! o^oe+
86C-02
1:mA
l].; m

lfu=_ r=:z le3 mm

. \o-J in
:--
t-
:'ne rlre
?.S Lrffin
i' 5R Lasp !5uFPort
bas 15..] Llmin

trrl i H+ I

Fig 6-2

/ Set the absorption cell onto the burner head.

For the 4,4-6650 and AA-7000F, adjust the burner height so the beam of the hollow
cathode lamp passes through the center of the absorption cell.
For the AA-7000F/AAC, 44-6300 and 44-6800, the burner height is adjusted
automatically. Check and adjust the burner height as necessary.

<i Perform preparation for measurement, including setting the pump tubes on the
HVG-I.
)) Reference For details, see "5.1 Measurement Preparation" ?.17.

4 lgnite the air acetylene flame (skip this step in mercury analysis).

Start the suction of the reagents.

E Submerge and draw blank solution (or distilled water) into the sample suction
tube, set the hollow cathode lamp of the element for measurement, and execute
[Line Search/Beam Balancel.

Wait about 5 minutes, draw in blank solution (or distilled water), and then
execute [AUTOZERO].

8 Set the sample in place according to the setting order of the relevant AA unit
and insert the sample suction tube into the sample.

HVG-1 25
 5 linking with the Atomic Absorption Spectrophotometer

After the absorption signal display has mostly stabilized, click [START].
The results of absorbance are displayed when measurement is complete.

10 Draw in distilled water and check that absorbance returns to the zero level.

11 Repeat steps 7 to 10.

i
HVG-1

I --|:.:.]lll,M
t "
 6.3 Connecting an Autosampler (ASC_7000/6.tOO)

utosampler ;-700016100)

? -.t Automatic anarysis is possibre by connecting

the HVG-., to an autosamprer.
ln this case, the optional accessory ,lVOZzf_l ASSY,
HVG (5206_67563),,must be prepared
separately.

--, i=:tion explains the

measurement procedure when using an autosampler.

the standard sample suction tube of the HVG-I

ff" with the nozzle Assy,

A ro.nt the nozzre Assy, HVG onto the samprer arm of

the Asc-7ooo/6100.

select the [using ASC] checkbox in the

[Edit parameters] window.
firA Peihi:t ri
Lomad.qoa,l*GaSq.dcdes-6yiFE{C.ryo.r6'aCT:lils!|.*a+
t'ptE P;€ftdffi s8leie
I Etrd lkamfr.d a!*oni L*,** ,."**." ! {:M.i aRe pffiMeu ]

trebcdWtsffid 1."" -:

Lamp Sffiup rdE: f- r,t"a*

[oi-l GEr i E# |

Fig 6-3

il
Measure the time taken from the start
stabilization in advance.
of sample suction to absorbance signa!

27
 5 Linking with the Atomic Absorption Spectrophotometer

T
5 Enter the time measured in step 3 for [pre-spray Timel in the lEdit pa
window.

kmd
oFiis
i
Fffimeffi

R.petsnsque.ft
Aomnn-Cds
I s"+** I
E!* Bde ldw i y{etsk Codff FarrE I r:d3 pnrt turs ; m6.*ils.us
Fqrd Hsasffd -o-d.o.! Me:sree Paamae- C#M. Cee pffimd.E

Isusn- J
I
P-rp@ire:
E]*.,
lded.! Tme l: i*";
,.-

l-lil qlr, I !s !

Fig.6-4

! xore Set the measurement sequence so that blank solution and sample are measured
alternately.

)) Reference For details on other operations, refer to the instruction manuals for the
44-7000/6300/6800/6650/6200 an d ASC-7000/6 I 00.

28 HVG-1

I
T Maintenance and Inspection
hlmp Tube Replacement
--; section explains the replacement procedure for pump tubes that have deteriorated.

-oosen the adjuster screw.

A Turrn the screw stopper and release the tube fitting.

q Remove the pump tube bridges from the tube holder.

Remove the manifold located on the side panel and remove the used tubes from
lhe joints.

Remove the other ends of the used tubes from the joints connected to each
suction tube.

Attach new tubes according to the procedure described in "3

lnstallationlnstallation Procedure' P.8.

! Hore The pump tube suction rate gradually decreases with operation time.
Measure the suction rate with a measuring cylinder on a timely basis. When the
suction rate has reduced to about 8Oo/o of the initial rate, replace the pump
tubes.

-'i nint We recommend thinly coating the pump tubes with silicon grease.
This can extend the service life of the tubes.

HVG-1
 7 Maintenance and lnspection

7.2 Absorption Cell Maintenance

The absorption cell is made of transparent quartz glass and may rapidly deteriorate
depending on handling. Clean it after every use with distilled water.

olnshuction
Wait at least 30 minutes after extinguishing the flame before performing
maintenance on the absorption cell.
You could sustain burns.

o
lnsiruction
Do NOT directly touch the absorption cell with bare hands. Do NOT use the
absorption cell if it is dusty.
Adhered alkali metals, such as natrium and kalium, and other impurities will
accelerate devitrification and shorten the service life of the absorption cell.

o
lnstruction
Do NOT use activators or soap when cleaning the absorption cell. Do NOT let
these substances adhere to the absorption cell.

o
lnstruclion
Do NOT heat an absorption cell that is wet.

! nore Deterioration of the absorption cell cannot be avoided even by cleaning the cell
everyday.
As deterioration progresses, the surface of the absorption cell undergoes
activation and sensitivity decreases significantly. ln this case, soak the absorption
cell in about a 25o/o nitric acid solution for more than 30 minutes and then clean
it completely with distilled water.

7,3 Gas/Liquid Separator Maintenance

Clean the gas/liquid separator completely after every measurement with distilled water.

! Hore lf soiling is heavy, sensitivity will decrease and noise will increase. ln this case,
soak the gas/liquid separatorin about a 25o/o nitric acid solution for more than
30 minutes and then clean it completely with distilled water.

30 HVG-1
7 Maintenance and lnspection

7.5 checking for Pressure Regulator (option) Gas Leaks

Always set the gas supply pressure to the specified value.

Setting the pressure to any other value may cause accidents.

NEVER use a damaged pressure regulator.

This will lead to accidents.

1 : Remove any dust or grit adhered to the cylinder outlet.

2, See uFig. 7-I Pressure Regulator for Argon Gas" and connect the pressure
-*j regulator to the cylinder.

! Hore lf the mounting screw on the cylinder is close to breaking, forcibly connecting
the pressure regulator will break the screw on the pressure regulator. ln this
case, replace the cylinder.

3 I Close the stopcocks, turn the secondary pressure adjustment handle sufficiently
to the left, and then gently open the main cock.

4 Turn the secondary pressure adjustment handle to the right and set the
secondary pressure to the following value.

Secondary Pressure
Type
Value
0.35 MPa

HVG-1
 7-5 Checking for Pressure Regulator (Option) Gas Leaks

I 5 Coat each connection with gas leak detection fluid (option, part no.: 5670'115'14)
or soapy water and search for leaks.
Leaks sometimes occur at the main cock of the cylinder. ln this case, immediately close
the main cock and'contact the cylinder supplier.

Fig. 7-1 Pressure Regulator for Argon Gas

No. Part Name Description

t.,
o Secondary pressure gauge
@ Primary pressure gauge
Turn left to open and turn right to close.
o Cylinder main cock Turn the main cock nearly all the way open
during use.
@ Stopcock

o Connection nut
Turn right to increase the secondary pressure
Secondary pressure
o adjustment handle
and turn left to decrease it.
Normally, the secondary pressure is 0.35 MPa.

HVG-1
 7 Maintenance and lnspection

7.6 Periodic lnspection and Maintenance

Perform daily inspections and periodic inspections to keep the product in good condition.

;
*2. &= L &&[I'M*LW**** *. **-.*** *-* *"***- *,"* si@,-=*ru*-=.*"* * - *-,*.-o**-**

Daily inspections should always be performed before using the unit.

lnspection/Ma intenance ltem Description Remarks

No tubes are broken Check visually.

No tubes are disconnected Check visually.

Draw distilled water into the
pump and visually check that
No leaks from any tubing there are no leaks from any
tubing.
There is sufficient empty volume in the Check visually.
drainage container
The absorption cell is neither cracked nor Check visually.
broken
The gas/liquid separator is neither cracked Check visually.
nor broken
The end of the drain tube is not submerged Check visually.
in drainage

7.6.2 Periodic lnspections

Periodic inspections should be performed at least once per month even when the unit
is not being used.

lnspectionlMa intenance ltem Description Remarks

No tubes are broken Check visually.

No leaks from any tubing
The absorption cell is neither cracked nor
broken
The gas/liquid separator is neither cracked
nor broken
The rotor does not turn when argon gas
not supplied
Draw distilled water into the
pump and visually check that
there are no leaks from any
tubing.
Check visually.
Check visually.
Turn ON power to the HVG-I
is with the argon gas supPlY
stopped and visually check
that the rotor does not turn.

34 HVG.1
 :;;:;,;.;:;::;-
- : I

II Replacement ?arts

7.7.1

The following parts are considered

to be consumable parts. Make sure that your inventory
of spare consumable parts does not run out.

Part Name Part No. Remarks

PUMP TUBE, 08 s208-90038-08

Pump tube for reagent, '12
included

PUMP TUBE, 13 s208-90038-1 3

Pump tube for sample, 12
included

ABSORPTION CELL
The standard service life is
s206-77607
about 50 hours."1
*1 Service life differs depending on samples and usage conditions. Replace when measurement
sensitivity decreases.

7.7.2 Periodic rt Pa rts

Part Name Part No. Standard
Remarks
Replacement lnterval
WITHSTAND PRESSURE
RUBBER HOSE, 8x2B-BK
s01 6-02 1 01 -04 Length specification Every 3 Years

HVG-1
 7 Maintenance and lnspection

7.7.3 Replacement Parts

Part Name Part No. Remarks

GAS/LIQUID SEPARATOR s206-1 7839 F

O-ring and hose nipple sold
MANIFOLD s206-17825
separately

REACTION COIL s206-1 8037

For NaBHa suction, marked

TUBE, ASSY NABH4 s206-1 8036-01
yellow
TUBE, ASSY HCI s206-1 8036-02 For HCI suction, marked blue
TUBE, ASSY SAMPLE s206-1 8036-03 For sample suction, unmarked
For connection to the
TUBE, A55Y ASC s206-1 8036-04
autosampler
For connection to the
FLUORINATED RUBBER TUBE s206-60250-01
absorption cell
Used for connecting the carrier
HOSE NIPPLE s204-64601
gas tube to the manifold
Used together with the hose
O-RING, EPR s200-62522
nipple
JOINT s206-1 7826-01 For reagent
JOINT s206-17826-02 For sample
CABLE TIE, RF-1OO s072-603'r5-0'r For securing the drain tube

35 HVG.1
 I

Troubleshooting
8.1 Troubleshooting
This chapter explains problems that may occur during HVG-1 use and the corrective action
to take.
lf a problem occurs, first see "7 Maintenance and lnspection' P.29.
lf the problem cannot be resolved, contact your Shimadzu service representative.
Problem Probable Cause Corrective Action
Clean or replace the absorption cell.
The absorption cell has
deteriorated. )) Reference For details, see "7.2 Absorption
Cell Maintenance" P.30.
Replace the relevant pump tubes.
Sensitivity is low One or more pump tubes
have deteriorated. )) Reference For details, see "7.1 Pump Tube
Replacement" P.29.

The hollow cathode lamp

Replace the hollow cathode lamp.
has deteriorated.
Replace the relevant pump tubes.
One or more pump tubes
have deteriorated. ) Reference For details, see "7.1 Pump Tube
Sample and reagent Replacement" P.29.
are not drawn in
The rotor setting is Adjust the rotation of the rotor using
incorrect. the speed control knob.
Power does not turn Power is not being Check the connection of the power
ON supplied correctly. supply cord.
Argon gas is not being
supplied or the supply Supply argon gas at the correct pressure.
Rotor does not turn pressure is too low.
The rotor setting is Adjust the rotation of the rotor using
i ncorrect. the speed control knob.
Argon gas is not being
Pressure monitor
supplied or the supply Supply argon gas at the correct pressure.
lamp lights up
pressure is too low.
Adjust the rotation of the rotor using
Flush switch does not The rotor is at its
the speed control knob when
work maximum setting.
performing analysis.
The optical axis does not
Line search beam
pass through the center Adjust the burner position.
balance is NG
of the absorption cell.

HVG.1 37

t
i*e@*

:9
r

Technical Data
9.1 Specifications
The specifications of the HVG-1 are listed below. The HVG-1 does not comply with the
lEC6O5O1 medical electrical equipment standard.

Required power supply
Allowable Voltage Range
Short-Circuit Rating
Measurement method
Atomizer
Sample consumption rate
Reagent consumption rate
Carrier gas
Size, weight
5pecifications
1001120122012301240 VAC, 50/60 Hz, 35 VA
Within +10% (no sudden fluctuations in voltage)
Continuous flow method
Heated absorption cell
0 to 7 mUmin (variable)
0 to 2.5 mUmin (variable)
Argon, pressure: 0.35 MPa, consumption: 70 mUmin
W340xD220xH200mm,9kg

,9;,2,, 'rrr$OtionS

This section indicates the optional parts that can be added to this product.

9.2.1 Option for Connection to the Autosampler

The following parts are required when connecting this instrument to an ASC-7000/6100
autosampler in order to perform automatic analysis.

Part Name Remarks

NOZZLE ASSY, HVG

38 HVG-I
 I
9.3 Environmental Requirements for Unit lnstallation and Storage

9.2.2 9_pl!,"n,1,
for Electric He1tiry
Measurement at even higher sensitivities is possible by using an atomic muffle.
The advantages of using an atomic muffle include good temperature reproducibility,
prevention of damage to the absorption cell due to overheating, and increased
absorption cell service life.

Part Name Remarks

ATOMIC MUFFLE, SARF-I6C
MOUNTING ADAPTER SET s205-s21 3s-91 For AA-7000F/6300
MOUNTING ADAPTER SET s206-83755-91 For AA-7000G/6800/6650
MOUNTING ADAPTER SET For 44-6200

! Nore The atomic muffle does not conform to the RoHS directive. lt cannot be sold in
EU member states.

9.3 ''Environmentalrteqdremsnts for Unit lnstallation and Storage

lnstall and store the unit in a location that satisfies the following conditions:
. A location away from equipment that generates strong magnetic fields, electromagnetic
waves, or radio frequency waves.
o A location with sufficient ventilation.
. A location with little vibration.
. A location with little dust, low humidity, and no corrosive gas.
. A location where illumination is fluorescent lighting of 1300 Lx or less, indirect natural
light of 800 Lx or less, or a heat-producing light source, such as an incandescent lamp,
of 40 Lx or less.
. A location with an ambient temperature range between 35'C and ambient
10 and
humidity range between 20 and 80% (maximum 70Vo humidity when 30 'C or higher).

! Hore lnstall in an indoor location that corresponds to installation

category ll and
pollution degree 2 standards and at an altitude of 2000 m or less.

39

b
 9 Technical Data

9.4 Equipment Requirements

The following table gives the power requirements.

Specif ications

Voltage Any of 100, 120, 220, 230,240 VAC

Allowable voltage range Within +10% (no sudden fluctuations voltage)
Power capacity 30 VA
Source frequency 50160 Hz
Connections Grounded power outlet, approx. 2.4 m cord length

9.4,2 Gas Requirements

I Gas Specifications

The following table gives the gas requirements.

Max. Consurnption
Gas Type Supply Pressure (MPa) (Umin) Purity

Argon 0.35 r 0.03 0.07 99.9% pure or better

I Placement of Gas Cylinders

Select a location for the gas cylinders that satisfies the following conditions:

olnstruclion
Placethe gas cylinders outdoors.
Otherwise, fire or accidents could result.

olnstruction
Select
.
a location for the gas cylinders that satisfies the following conditions:
Not exposed to heat sources such as direct sunlight, furnaces, and heaters.
Always keep the cylinders at a temperature below 40 "C.
. Away from spark sources such as switchboards, ground wires, and high
voltage power sources.
r Away from flammable materials such as oil, gasoline, and organic solvents.
. Sufficiently ventilated
. lf outdoors, not exposed to wind and rain.

40 HVG.1
 I
9.4 Equipment Requirements

r Gas Piping

outdoors, pipile must be performed separatery

ll,l^,:.:ll::i::
the instrument. i:".:l:.:,.
tn this case, be sure io toifo* ,i"
within 5 m of
oI*"*,ronary measures listed below.
o Use stainless steel pipes
for piping.
o Ensure that the pipe diameters
are not too small to suppry gas at the pressure indicated
in "Gas Specifications.',
. A pipe diameter of at least 7 mm will
be sufficient.
' Install the stopcock and pressure regulator
at a point within 5 meters of the instrument
in the analysis room.
' Provide a hose nipple with an outer diameter
of g.4 to 9.5 mm so that the provided
gas supply hose (inner diameter 7.9
mm) can be connected to the end of the gas
piping.
' lf ,inking a shimadzu Graphite Furnace Atomizer for the
Atomic Absorption
spectrophotometer to the HVG-1, the argon gas
piping can be used branched from the
three-direction nipple provided with the
HVG-I.
ln this case' perform branching on the instrument
side from the pressure regulator in
the analysis room.

i-
Fullscale i
O.35MPa
Pressure regulatoi
Argon gas
i
I
Analysis room
I
L outdoors
Stainless steel oioino
(i.d. 7 mm or taig'ei)"
Fig 9-1 Exampre of Recommended piping for the Hydride Vapor
Generator

HVG.l 41
 9 Technical Data

o
lnstruction
Observe the following cautions when handling gas cylinders.
. Gas cylinders should be sited outdoors at a location where there is a good
passage of air and no exposure to direct sunlight, and the gas should be fed
indoors through tubing.
. Take care that gas cylinders become no hotter than 40 "C and do NOT allow
any flame within 2 meters of the gas cylinders.
. When using high pressure gas, make sure that there is sufficient ventilation.
At the start of work inspection, check for gas leakage with soapy water or
by other means.
. Secure gas cylindersin a vertical position so that they cannot drop or fall
over. Always keep liquefied gas cylinders (argon gas, etc.) in a vertical
position and do NOT allow them to fall to a horizontal position.
. Be sure to use oil-free pressure reducing valves. Also use ones that have no
oil adhering to the inside of the pipes, etc., where high-pressure gas comes
into contact.
. Use approved pressure regulators and connectors. For details, contact your
Shimadzu representative.
. When installing the pressure regulator to a cylinder, be sure to wipe the dust
off the outlet of the cylinder. This dust could cause gas leakage.

lnstall exhaust equipment with a hood above the burner compartment of the atomic
absorption spectrophotometer.
For details on exhaust equipment, refer to the manual of the atomic
absorption spectrophotometer main unit.

Be sureto provide a duct made of metal for the expulsion of high temperature
gas above the atomic absorption spectrophotometer.
A duct made of plastic will burn due to the heat of the flame.

42 HVG-1
 Shimadzu Corporation
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Phone: 61 (2)9684-4200 (2)9684-4055 3500-07150-18TD
Fax: 61
20t5, 07

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