1 Direct laser lithography for energy BTech/MTech/MSc TA
harvesting applications
Description: Strategic patterning of material is
reported to lead enhanced performance in photodevices. In this project, various simple and complex structures will be conceived and fabricated for specific applications in solar cells. 2 Plasmonic metamaterials for sensing BTech/MTech/MSc TA applications Description: (Metamaterials is an upcoming research field with many exciting applications. Arranging micro and 1 nanostructures in predefined manner may (Shobha alter the interaction of electromagnetic field Shukla) with the materials. Here, we will make these plasmonic nanostructures, characterize and use for sensing applications.
3 Water purification using graphene BTech/MTech/MSc TA
composite materials Description: Nanoporous graphene has emerged as wonder materials for water purification. Synthesis of graphene based composite materials will be followed by extensive characterization. Finally, water treatment will be performed using this material system.
4 All oxide superconducting devices M. Sc. In Physics, TA
M.Tech in Materials Superconductor (S) / Half Metal (HM) films Science (where both S and HM are oxides) in various multilayered stacked forms will be fabricated into either planar junctions or pillar type trilayer junctions in order to study the S/HM proximity effect. The possibility of developing an all oxide spin valves will also be investigated. 5 Novel routes towards Graphene M. Sc. In Physics, TA Spintronics M.Tech in Materials Science or Electrical The traditional approach to Graphene engineering. spintronics has been by spin injection through 1 ferromagnetic contacts. However, last year (Avradee exfoliable 2D ferromagnets have been p Pal) discovered, and Graphene devices coupled to ferromagnetic insulators have not been studied in detail. Detailed hall bar characterizations of Graphene either stacked with a 2D ferromagnet or with ferromagnetic insulators grown over them will be studied to ascertain the possibility of spintronics in graphene through these routes.
6 Preparation of vertically aligned carbon BE/Btech/M.Tech in TA
nanostructures for energy and sensor Metallurgy, materials applications science and nanotechnology. Description: Using atmospheric plasma M.Sc/M.Tech. in growth method, vertically aligned carbon nanostructures will be prepared on large area physics/applied flexible substrates for energy and coating physics/electronics. applications. The study involves preparation of devices for the energy applications (supercapacitors, J. Electroanal. Chem. Volume 803, 2017, Pages 30-39) and miniature sensors for the detection of the impurities (RSC Adv., 2016, 6, 100383). Device preparation for supercapacitors and sensors will be based on methods already established in the lab. 7 Corrosion sensor based on the interdigital BE/Btech/M.Tech in TA 1 Metallurgy, materials (Smrutir patterns science and anjan Description: Objective is to design a nanotechnology. Parida) corrosion sensor using interdigital electrode M.Sc/M.Tech. in (IDE) system. The wrok is require to use the physics/applied thin film processing such as PVD and CVD. physics/electronics A new electrochemical patterning will also be used for the the sensor design. After the preparation of the IDE, electrochemical testing of sensor will be done to measure the paraterer of the merits such as potential, impedance and capacitance. 8 Electrochemical additive manufacturing BE/Btech/M.Tech in TA Metallurgy, materials Description: Objective is to design a system science and for the electrochemical additive manufacturing system. Electrochemical nanotechnology. additive manufacturing will be a miniature M.Sc/M.Tech. in mobile electrochemical cell with drive control physics/applied position and height. The understanding of the physics/electronics/chem established mechanisms of the istry. electrochemical processes (deposition/dissolution) at the micro- and millimeter electrode will be used to create varios 3D form and patterns on the surface. The forms will be used for various applications such as sensors and supercapacitors. 9 Pressure sensitive patterns from the nano- BE/BTech/M.Tech in TA carbon and conductive polymers Materials science, polymer science and Description: The project aims to prepare engineering, chemical smart pressure responsive patterns using engineering, polymer carbon nanomaterials and conductive engineering and polymers. The patterns will be created using nanotechnology hydrogels and hollow spheres prepared using (polymer specialization). carbon nanomaterials and conductive M.Sc/M.Tech. in polymers. The responsiveness of these Chemistry/applied surfaces to the pressure will be tested using a chemistry/polymer/rubb dynamic pressure system. er and plastic engineering.
10 Layered hybrid materials for B.Tech./ BE or M.Tech. TA
supercapacitors and membranes in any relevant Engineering discipline, Three-dimensional (3D) hybrid carbon or M.Sc. in Chemistry or nanomaterials are of considerable interest due Physics. Candidate to their potential of combining merits of both should have good one-dimensional (1D) and two-dimensional analytical and (2D) nanostructures. 3D hierarchical quantitative skills structures comprised of graphene and carbon nanotubes provide a large accessible surface area, which can enable high energy storage and better catalytic activity making them ideal for high-performance supercapacitors and membranes. The organization of constituent graphene and carbon nanotubes in hybrid materials depends on the interplay of various molecular level interactions, and determines the properties and performance of hybrid materials. This project will involve the use of self-assembly based methods for fabrication of hybrid nanostructures and molecular-level computer simulations for predicting interactions in hybrids. 11 Design and analysis of bio-inspired B.Tech./ BE or M.Tech. TA 1 (Ajay membranes for ultra-pure separations in any relevant Panwar) Engineering discipline, There exist several examples in biology of or M.Sc. in Chemistry or ultra-fine pores in membranes which can Physics. Candidate purify or separate analytes with extreme precision. Synthetic membranes composed of should have good nanomaterials such as carbon nanotubes or analytical and graphene, and functional polymers can be quantitative skills. fabricated which mimic the essential properties of biological membranes to achieve analyte separation for industrial and technological applications. This project will involve the use of molecular-level computer simulations to design and simulate analyte separation through ultra-fine pore structures. Simulation and analysis would help in estimating transport coefficients and optimizing device design for ultra-fast and ultra-pure separations. 12 Polymer Nanocomposites for Piezoelectric M.Tech/M.Sc with TA Applications Polymer Science & Engineering/Chemical It is observed that few polymeric materials, Engineering/ Mechanical viz. polyvinylydene fluoride (PVDF), polyvinyl alcohol (PVA) exhibit piezoelectric Engineering/Physics/Ch behaviour. This is due to the development of a emistry background is specific crystal structure associated with desirable. piezoelectric behaviour. Moreover, various nano-fillers (carbon nano tubes, graphene oxide) also induce that specific crystal structure, which shows piezoelectric behaviour. Further, orientation during processing also leads to the metastable beta phase for PVDF, which is responsible for the piezoelectric behaviour. The scope of the research project is to develop PVDF and PVA based nanocomposites, which show enhanced piezoelectric properties. In this context, processing-structure-property relationship studies will be investigated 13 Films and Fibers of Graphene and Carbon M.Tech/M.Sc with TA 1 (Arup nanotubes incorporated Polymer Polymer Science & Bhattach Nanocomposites Engineering/Chemical arya) Engineering/ Mechanical It is known that orientation during processing Engineering/Physics/Ch leads to the alignment of the nano-materials emistry background is along with polymer chains. Moreover, a desirable higher extent of orientation can be achieved if the interfacial interaction between the polymer phase and the nano-material can be judiciously tailored. The scope of the project is to develop hybrid nano-filler based polymer composite fiber or film for various industrial applications. In this context, processing- dispersion-interfacial interaction- crystallization behaviour-property relationship studies will be investigated.
14 Localized thermomechanical properties in Candidate with M.Sc./ TA
confined polymer nanocomposites: M.Tech with Physics/ Chemical Engineering/ Understanding of mechano-rheological Chemistry/ Polymer properties of polymer nanocomposite is Science & Engineering/ expected to advance designing of Materials Science & mechanically improved polymer Engineering/ Mechanical nanocomposites (PNC) with optimum particle Engineering background loading and desired functionalities. On the is suitable. question of confinement and glass transitions, PNC is comparable to a polymer thin film, where the interparticle distance in the nanocomposite could be comparable to the film thickness dictating the extent of confinement and reportedly shown variation in glass transition temperature (Tg). Beyond this simplistic picture it has been found that confinement (from film thickness) in polymer thin film enhances nanoparticle dispersion in polymer matrix. The enhanced dispersion takes place without altering the polymer– particle interactions, whereas, nanoparticles in a bulk polymer matrix are known to alter the entanglement and stress relaxation in polymers. How and why the viscous/ viscoelastic properties in PNC films distinct 1 compare to polymer film are is an interesting (Mithun area to explore and signify further questions Chowdh in PNC films should be addressed in a way ury) that exploits nanoparticle-polymer interaction in a localized and controllable manner. In the proposed work by spatially incorporating polymers, nanoparticles and PNC films in a multilayer geometry, viscous flow at the suitable polymer-nanoparticle or polymer- PNC interface will be probed. In-situ hot- stage optical and atomic force microscopy will be employed to primarily probe topographical features and their relaxation in PNC films, whereas, at the advanced stage X- ray reflectivity and/ or dielectric spectroscopy could be used. For X-Ray studies appropriate Synchrotron sources (around the world) will be used upon requirement and advancement of the project.
15 Fundamental studies on controlling Candidate with M.Sc./ TA
orientation and crystallinity in semi- M.Tech with Physics/ crystalline functional polymers: Chemical Engineering/ Chemistry/ Polymer The central idea to enhance the performance Science & Engineering of organic electronic devices is to tune the background is suitable. way excitons and electrons (holes) travel within the active conjugated material by controlling its morphology, crystallinity, aggregation, and domain purity. Many studies aimed to enhance the long-range ordering (crystallinity) in semi-crystalline conjugated polymers, whereas, role of short-range ordering primarily by pi-stacking induced aggregation also remain beneficial for exciton diffusion and carrier mobility. Especially the interlamellar region and their role on structure-property relationship is yet to be fully understood. The proposed research project will particularly probe mostly- amorphous (less-crystalline) yet high performance conjugated polymeric materials and exploit its ability to reorganize into relatively ordered domains via controlled inclusion of its small-molecule (or short chain) analogues utilizing controlled blending and annealing. The process will be extended with acceptor molecules and small molecules having complexation abilities by charge transfer. Beyond conjugated polymers, at the advanced level the project will also investigate controlling orientation and crystallinity in ferroelectric/ piezoelectric polymers, such as PVDF. Upon satisfactory progress and understanding of structural properties, experiments could be extended towards characterizing optoelectronic and transport properties, if needed, seeking appropriate collaborations within the institute. Microscopic (optical and atomic force), Spectroscopic (UV-VIS and Fluorescence) and X-ray diffraction studies will be primarily used. Processing of semi-crystalline polymers will be performed through precision hot-stage and custom-built solvent annealing stage. For X-Ray studies appropriate Synchrotron sources (around the world) will be used upon requirement and advancement of the project.
16 Physico-chemical phenomena during Metallurgical TA/RA 1 (N N
induration of single hematite pellet engineering or chemical Viswanat engineering. Should han) Proportion of pellets in lieu of iron ore have interest in sinter is being is thermodynamics, increasing in iron making processes as more chemical reaction spherical uniform size kinetics and transport pellets gives better permeability. On the phenomena other hand, with decreasing grade of iron ore, liberation and benefeciation calls for finer size, which again favour pelletization process. Though there are numerous studies to understand induration of hematite pellets mixed with carbon, these studies primary empirical in nature without seriously going in the processes occuring with in the pellets. Recently such work has been carried out for magnetite pellets using optical dilatometer. Along the same lines, this project proposes to look at the physico-chemical phenomena, which includes, reaction of carbon particles in the hematite pellet, sintering hematite mixed with fluxes and associated heat and mass transfer. The work will be a combination of experiments and modeling.
17 Analysing the role of defects and dopants MSc/ MTech TA 1
in modulating the magnetic and electronic (Amrita properties of Heusler compounds Bhattach arya) 18 Encapsulants for Photovoltaic modules M.Tech or M.Sc. TA/RA Background in polymers The aim of the project is to evaluate the and Hands on experience various types of encapsulants and back sheets in chemical synthesis/ use for protecting the solar cells in a PV characterization is module. The evaluation will require detailed desired. mechanical, optical and chemical characterization of the polymeric encapsulants and back sheets. 1 (Sudhans hu Mallick) 19 Perovskite based solar cells :M.Tech or M.Sc. TA/RA Hands on experience in The aim of the project is to develop large area chemical synthesis/ perovskite based solar cells and detailed characterization is characterization to improve the cell lifetime desired and efficiency.
20 Thermo-physical properties of molten Metallurgical engg. / TA
oxides and halides - modelling at the nano Ceramics / Chemistry and sub-nano scale (M.Sc.) - preferably with specialisation in physical Understanding the high temperature or inorganic chemistry / properties (like viscosity and interfacial Chemical engg.. (in tension) of oxide and halide melts, in terms of decreasing order of ordering and ionic arrangements. Suitable preference) modelling approach would have to be developed to simulate the physical properties, followed by validation with experimentally measured values. 1 (Somnat h Basu) 21 Fusion and flow characteristics of FeO-rich Metallurgical / Ceramics TA oxide melts / Chemical / Mechanical engineering. This project would focus primarily on incipient melts encountered during metal Applicants with M.Sc. oxide reduction, typical examples being iron Chemistry background oxide reduction in a BF or COREX. The work are also welcome, would involve estimation of intermediate provided they have done compositions, experimental determination of M.Tech. in liquidus and viscosity measurement of the ME&MS/equivalent, incipient oxide melts over relevant preferably with temperature range(s). The results would then specialisation in Process be used to develop a mathematical model to predict the sequence of melt formation, the Metallurgy (in local compositions (as opposed to the gross decreasing order of reported composition) and the flow preference): characteristics of the different liquid streams. It is expected that this would eventually provide an insight into the effect of these liquid steams on the kinetics of the gas-solid reactions that occur during pyrometallurgical extraction of several metals. 22 Role of thermal vibrations on phase BTech/MTech/MSc TA 1 (T R S stability/transitions Prasanna ) Predicting the stability of any material is an area of current research in materials science. This topic involves the first principles (ab initio)calculations of the free energy of different phases at different temperatures and pressures to determine the phase stability. In particular, the role of thermal vibrations on phase stability will be carefully studied. This is expected to lead to better understanding of phase stability and phase transitions. The phase transition temperatures and pressures will be compared with experimental data.
23 Fabrication of flexible and stretchable TA
electronic devices 1 (Dipti Gupta) 24 Fabrication of flexible pressure and strain TA sensors for biomedical applications TAP 1 Mopping oil with graphene based BTech/MTech/MSc TAP composite sponge RD/0118 Description: Superhydrophobic graphene- - framework is expected to be an excellent 1 (Shobha DST0000 Shukla) candidate for oil adsorbent. Oxidized -010 graphene frame-work is hydrophilic in nature and can be used directly for removing organic contaminants from water. Here we plan to reduce and convert the framework from hydrophilic to superhydrophobic for applications in organic materials removal. The ultimate aim of this project will be to focus on development of processes and devices that can be implemented in coastal areas after extensive characterization and studies.
2 Silver Pastes for solar PV and other M.Tech. Materials TAP
industrial applications science or Nanotechnology, M.Sc. The fellowship will be 1.5 times the regular chemistry (organic). 1 (Parag TA but there is lack of clarity on whether Candidates with Bhargava) tuition fee would have to be paid by the background/experience student or not. The candidate will be in materials required to do three courses in Tata Centre characterization and in addition to prescribed regular courses. interested in industrial research or product development would be preferred.
3 Superconducting proximity effect studies M.Tech Materials TAP
with ferromagnetic insulators. Science, M. Sc. In (seed Physics, some grant) The project involves ultra-high vacuum 1 experience in vacuum (UHV) sputter growth of thin films of (Avradeep systems preferable. superconducting Nb, Al and NbN and Pal) ferromagnetic insulating GdN, and subsequently multi-layers of these materials in various combinations depending on the physics to be probed. Standard thin films characterization techniques like AFM, Low Angle XRD, TEM will be employed to study quality of films and multilayers. Low temperature (4K) Current in plane measurements will be then used to study the proximity effect. The initial part of the project will involve participation in setting up an UHV sputter deposition system. 4 Development of Passive daytime BE/BTech/M.Tech in TAP radiative cooling (PDRC) coatings Materials science, polymer science and Description: The project aims to prepare engineering, chemical 1 smart responsive nanomaterials using engineering, polymer (Smrutira emulsion polymerization methods already engineering and njan Parida) established in the lab (Polymer 118, 2017, nanotechnology 116-126). These materials and method will (polymer specialization). be used to create Passive daytime radiative M.Sc/M.Tech. in cooling (PDRC) coatings. The Chemistry/applied responsiveness of these smart materials in chemistry/polymer/rubb the coating to temperature will be tested. er and plastic The temperature sensitivity will be tested engineering by exposing the coating to the sun and measuring solar reflectance index (SRI) using the instrument available in the lab. 5 Development of high performance M Tech/B.Tech/MSc in TAP hybrid supercapacitors based on Materials The nanostructure carbon and core/shell Si Science/Engineering project is nanowires (and associated areas) sponsored and/or physics/chemistry by the Description: The project will focus on Departme 1 development of the nanostructure carbon nt of (Smrutira and core/shell Si nanowires (NW) by CVD Science njan method, which involve optimization of the and Parida) process parameters to tune the structure Technolog (length, thickness of core/shell) of the y (DST), nanowires. The surface of the NWs will be Govt. of modified by conformal deposition of metal India, and oxide and conducting polymer coatings, to the prepare hybrid device. These electrodes scholarshi will be used to assemble supercapacitors of p will be various symmetric and asymmetric as per the regular configurations (RSC Adv., 2016, 6, SRF or 100467). After studying the individual JRF DST devices, the supercapattery stacks will be norms (as designed based on the output voltage and applicable power requirements. . ). The IITB project code is: RD/0117- DST0000- 029.
6 Identifying materials with improved MSc/ MTech TAP
properties by combining advance (Seed machine learning approaches with first 1 (Amrita principles based methods grant) Bhattacha rya)
7 Role of processing conditions of Candidate with M.Sc./ TAP
polymers on the mechano-rheological M.Tech with Physics/ (Seed properties of confined glassy thin films: Chemical Engineering/ Grant) Chemistry/ Polymer 1 (Mithun In a simple picture, compared to bulk Chowdhu Science & Engineering/ polymers, sufficiently thin polymer films ry) Materials Science & are expected to have a lower-density due to Engineering/ Mechanical poor packing, since chains do not Engineering background significantly interpenetrate each other due is suitable. to high entropy losses. This may correspond to a reduction of the glass transition temperature (Tg) of the polymer film, which in turn, can be related to the lower density of a polymer film deposited on solid substrate. On the other hand, extent of adsorption of polymer chains at the substrate interface during annealing above the Tg of polymer dictates the Tg deviation of thin polymer films, where a poorly packed, high free volume, less dense adsorbed layer of restricted mobility is expected at the substrate. At this point it is not clear how the Tg of entire film including the surface is perturbed by the interfacial adsorbed layer, and how the extent of non-equilibrium properties of polymer chains is contributing to the material properties (density, modulus) of the entire film. Primarily, using techniques like atomic force microscopy, optical microscopy, ellipsometry and/or X-ray reflectivity the adsorbed layer of polystyrene will be characterized. To probe the non-equilibrium properties related to viscoelasticity and density in the entire film, hole growth and adsorption approach will be applied, those will be further characterized by atomic force and optical microscopy. At the advanced stage of the project relaxation dynamics can be followed using dielectric spectroscopy. 8 Flux-assisted inclusion engineering Metallurgical / TAP 1 Mechanical / (Somnath DST Basu) This project would focus on the influence Chemical engineering(i (approve of welding flux composition on the n decreasing order of d) chemistry and morphology of inclusions preference): generated in the melt pool during high heat input (and deep pool) welding process (e.g. SAW of thick plates). It would further investigate the effect the inclusions on the morphology and orientation of the grains formed in the weld metal during cooling, and explore if specific inclusions can be used to "engineer" the microstructure of the welded joint.
The work would be part of a BRICS STI
framework project, proposed in collaboration with Northeastern University (China) and University of Pretoria (South Africa), which has just been approved by DST. One JRF position would be supported for a period of three years. Portions of the work would be carried out at the partner universities and DST would support the travel expenses of the research scholar (within the terms of the grant). The prime focus of the work at IITB will be to investigate the flow behaviour and interfacial properties of molten fluxes, and their interaction(s) with inclusions as well as the molten steel. The experimental results (from all three partner institutions) would then be collated and used for developing a model to explain the formation and growth of the inclusions, as well as it influence on evolution of the weld metal microstructure. 9. Omni-Directional Micro-TIG Cladding Metallurgical / TAP 1 (K for Hybrid Layered Manufacturing Mechanical Engineering Narasimh (16DSTI an) (HLM) MP001 (MHRD Metal Inert Gas (MIG) and Tungsten IMPRIN Inert Gas (TIG) are the two types of arc T project cladding processes. Omni-directionality on refers to the invariance of the geometry and quality of the bead with the path of the Multi- cladding torch. This is an essential Station requirement in HLM. Both energy and Multi- mass flow from the same source in MIG Axis whereas they are from two different sources in TIG. Therefore, MIG inherently HLM) has omni-directionality but suffers poor bead quality due to the lack of independent control of these flows and vice-versa in TIG. As the quality of bead is better in TIG, we wish to develop a special mechanismfor varyingthe orientation of wire feeding to achieve omni- directionality.
Traditional arc cladding
usefillersstarting from 1.2mm and hence produce very large beads and involve extensive heat. Therefore, we propose to develop a micro-TIG which will use wires as thin as 0.2mm.
After the development of omni-
directional micro-TIG cladding system, a systematic set of experiments will be carried out to study the effect of various parameters on the bead quality, microstructure and mechanical properties, which in turn will be used to arrive at optimum process parameters. Finally, a few case studies of complex geometries and exotic materials will be carried out using the developed omni-directional micro-TIG HLM system.
10 Development of Low Corrosion Rate B.Tech metallurgy / TAP 1
Completion Fluid Formulation for High corrosion engg / (Smrutira Pressure High Temperature Oil and Gas chemical engg. MTech njan Parida) Wells in metallurgy / corrosion engg / chemical engg / *Description:* The project will focus on Materials Science / development of a low corrosion completion Materials engg. M.Sc in fluid for the high pressure and high chemistry / chemical temperature gal well. Drilling is carried out technology / applied using drilling fluids or drilling muds to chemistry remove the rock cuttings and keep the hole stabilized. Once target depth is attained, the well completion process starts to get oil and gas production from the well. Completion fluids are specially designed to aid in completion operations. The most commonly used completion fluids are clear brines. These brines can be composed of one type of dissolved salt (single salt), or mixture of two more inorganic/organic salts that are compatible with one another and do not contain any suspended solid mass. Oil wells have temperature beyond 150°C and may reach as high as 250°C. In this condition corrosion happens in the brine used. So the objective is to design a non-corrosive, clear and environmental friendly aqueous completion fluid and test its corrosiveness and stability in high temperature and pressure.