Adva PII Sol PDF

1 AITS-CRT-II-(Paper-2)-PCM(S)-JEE(Advanced)/14
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ANSWERS, HINTS & SOLUTIONS
CRT –II
(Paper-2)
Q.
ALL INDIA TEST SERIES
PHYSICS CHEMISTRY MATHEMATICS

No.
1. A B D
2. B D B
3. C A B
4. C A B
5. D D B
6. A D B
7. A A B
8. A C C
9. A D B
10. A D A
11. D A B
12. A B A
13. B D A
14. A B C
15. B, D B, C, D A, C
16. B, C A, B A, D
17. A, C A, B A, B, C
18. B, C, D A, B, D B, D
19. B, D A, D A, D
20. A, B, C, D A, C, D A, C, D
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AITS-CRT-II-(Paper-2)-PCM(S)-JEE(Advanced)/14
2
Physics PART – I
1 2 u (, )
2.  =  tan   g 2
2 u cos2  
2g

u
1 2 
 =  tan   g
2 2g
1 tan2 
 4 
tan2  4 tan  +  1  =0
  
If particle will not hit the target.

(b2  4ac) < 0
 4 
16  4  1  <0
  
4 > 3
Smooth A
mv B2 N
3. At B, mg sin  = . . . (1) B
r 
vB

Using energy considerations
1
mv B2 = mgr(cos   sin ) . . . (2)
2
From (1) and (2)
mg sin  = 2mg(cos  sin )
2cos = 3 sin 
7. i = 5A
qm2 q2 1 2
  Li  qmax = 6 C
2C 2C 2
8. Time period does not depend on amplitude SHM and both particle will exchange velocity at every
collision.
15. The slope of curve at such a point will be  1

dy  x  y
  2cos    1
dx  L 
L 2L
 x= or 135
3 3
x
45
16. P1  m  16  2m  0  16m
Pf  mv 'A  2mv B'
1
  2mvB2  2mgh
2
 vB  10 m/s
16 m = mv 'A  2m  10
 v 'A  4m / s
v B'  v 'A 10  ( 4) 14 7
e =  
v A  vB 16  0 16 8
1 1 1
17. If v be the velocity at mean position in two cars then mv 2  KA 12  KA 22
2 2 2
m
and T1  T2  2
K
A1 = A 2
18. Initially potential and kinetic both energies zero and from conservation of mechanical energy total
energy of the two object zero
Further, decrease in P.E. = increase in K.E.
G(m)(4m) 1 2
 v r
r 2
10Gm
vr 
r
G(m)(4m) 4Gm2
Total K.E.  
r r
4
Chemistry PART – II
SECTION – A
1. XeO46  (perxenate ion) because oxidation state of Xe is +8 and it is highly unstable compound.
2. Br
Due to formation of resonance stabilized carbocation.

 293.4
3.   CRT,So,C    0.1 mol / L
RT 8.31 293
If 100 ml contains 6.33 g of haematin.
 1 L will contain 63.3 g of haematin.
Molecular mass of haematin = 633 u
Estimating the empirical formula of compound
64.6 5.2 8.8 12.6 8.8
C:H:N:O:F= : : : :
12 1 14 16 56
 34 : 33 : 4 : 5 : 1
So, empirical formula is C34H33N4O5Fe, whose mass corresponds to the molecular mass.
0.059
4. EoZn2 /ZnY2 / Y4   EZn
o
2
/ Zn 
 logK
2
 ZnY 2   1
Kf  4
K 
 Y  Kf
0.059 1
EoZn2 / ZnY2 / Y 4  0.76  log10
2 3.2  1016
= - 1.25 V
5. Tf  0.5K  iK f m
Tf 0.5
i    1.022
K f m 1.86  0.263
HA  H  A
1 0 0
1   
i  1      0.022
Ka = C2 = 0.2 × (0.022)2 = 9.6 × 10-5
 pKa = 4.0177
On adding 0.25 M NaA, buffer is formed.
 pH  pK a  log10
Salt   4.0177  0.0969
 Acid
= 4.1146
6. Na2B4 O7  7H2 O  2NaOH  4H3BO3

Strong base Weak acid

Alkaline

Na2B 4 O7  2NaBO2  B 2 O3
  
Glassy bead
Na2B4 O7  H2SO 4  5H2 O  Na2 SO 4  4H3BO3

 White crystals
7.
OH H  OH Ring O H
 expansion  H3C

H3C CH CH2 H3C CH CH3
H3 C
H
H3C O
H3 C
8. O O
O O
||
+ KCl
N K  Cl  CH2  C OC2H5  N CH2 C OC2H5
 X O
Y
O O
OH H /H2 O
 H2N  CH2  COOH 
 C2 H5 OH

OH Glycine
 Z O
Burning
9. 3M N2   M3N2
A  B 
M3N2  6H2 O  3M  OH 2  2NH3
B  C D
All statement with respect to NH3 are correct.
10. Ba and Ca quite readily liberate hydrogen.
In cold water Mg decomposes water only on heating. So, element (A) may be Ca and Ba not Mg.
Ca  OH2 & Ba  OH2 , both givess milkiness with CO2.
Lime water  Baryta water 
P2 H  1 1 
11. 2.303log    
P1 R  T1 T2 
H  11.99 kJmol1
6
2
RT 2M 8.314   353   100
12 Kb    8.64 K kgmol1
1000 H 1000  11.99  103
Tb  K b 1    m
1 1000
1  8.64  1    
100 100
 = 0.158
13. Two structural isomers of (A) are:
Me
Me Me Me
& Me OH
Me OH
There are four geometrical isomers for each strucutre, i.e. total number of stereoiosmers = 8.
14. Convert aldehyde and ketone to alcohol
(1)
OH (5C )
(2) OH (6C )
OH
(3) HO
OH (2C )
15. CH2OH CH2OH

H O OH
OH O
H H
H O H
OH OH
H H
H
H OH H OH
16. (A)
N N
H F
H F
H F
NH3  NF3
(B) (I) is 3o allylic with extended conjugation.
o o
(II) is 3 allylic, (III) is 3 free radical.
(C) Correct order is: RS  CH3 O  OH Basic strength 
(D) Correct order is: I  Br   Cl  F  Ba sic strength 
17. (A) NH4NO3  NaOH 
 NH3  NaNO3  H2 O
7NaOH  NaNO3  4Zn  4Na2 ZnO2  NH3  2H2 O
(B) NH4NO2  NaOH 
 NaNO2  NH3  H2 O
3Zn  5NaOH  NaNO3 
 3Na2 ZnO2  NH3  H2 O
3RT 3P3PV
18. v rms   
M dM
19. 

In metal carbonyls, M  
 CO , the C – O bond length increases compared to that in CO

molecules due to synergic bonding between metal and carbonyl ligand.
n
Facial and meridenal isomers Ma 3b 3  contains plane of symmetry.


CH3 COO  H2 O 
 CH3 COOH  OH

20.
0.11  h  0.1h 0.1 h
Kh 
 0.1h  0.1h   0.1 h2  h  7.48  105
0.11  h 
  OH   Ch  7.48  10 5  10 1  7.48  10 6
KW 10 14
 H     1.33  109
OH  7.48  10 5

And pH = 8.8 approx.
8
Mathematics PART – III
1. We express x in terms of a new variable y

1 y 1
x 1   x 
y y
5 3
6  y  1 5  y  1
4  y  1  y  12
a b c d e
 5
 3
 1 = 5  4  3  2   f
2

y y y y y y y y y
Multiplying both side by y we get 6y(y + 1) + 5y (y + 1) + y (y + 1) + 4y5(y + 1) – y6
6 5 3 3 4 2
= ay + by2 + cy3 + dy4 + ey5 + fy6

Differentiating both side and then satisfying y = 1
Gives the value a + 2b + 3c + 4d + 5e + 6f = 910
50
n 51 n
2. f  x    x  n
n 1
50
ln  f  x     n  51  nln  x  n 
n 1
Differentiating both side w.r.t. x
50
f 'x n  51  n 

f x 
  x n
n 1
f '  51
  1275
f  51
3. a2 = b2 + c2 – 2bc cos A = (b – c)2 + 2bc(1 – cos A)

1 4
 = bc sin A  2bc 
2 sin A
2 4 A
 a2   b  c   1  cos A  = (b – c)2 + 4 tan
sin A 2
Since A and  are fixed hence a is minimum when b = c
4
Hence 2bc = 2b2 =
sin A
f  3x  3y  f  3x  3y 
4.   x, y  R
sin  2x  3y  sin  2x  2y 
 2x 
 f  x   k sin  
 3 
2 3
 f ' 0   k  1  k 
3 2
3  2x   3 3
 f x  sin    f '   
2  3   2 4
3 3 1 
Equation of tangent is y   x  
4 2 2
 2 
m m
1  
5.  aia j =   ai    ai2 
1 i jm
2  i 1

 i1 
 2 
1  a1 1  r m   a12 1  r 2m  
=   
2  1  r  1  r 2 
2
a12  1  r m  
1  r 2m 
= 
2 1  r   1  r 1  r 
r  a1 1  r m1    a1 1  rm  
=   
1 r  1 r   1 r 
r
= Sm1Sm
1 r
6. Use L’Hospital’s Rule twice
f  x  dx A B C D E 
7. g(x) = x 2  x  1 3
=   x  x 2
 
x  1  x  1 2
  dx
 x  13 
B D E
= A ln x   c ln 1  x   
x 1  x 2  x  12
Since g(x) is a rational function, hence logarithmic function must be absent
A=C=0
B D E
g x   2
 2
 dx
x  x  1  x  13
 f(x) = (B + D)x3 + (3B + D + E)x2 + 3Bx + B
 B + D = 0, f(0) = 1 gives B = 1  D = –1
f(x) = (2 + E)x 2 + 3x + 1
f(x) = 2(2 + E)x + 3
f(0) = 3
8. Denoting the two curve by S1 and S2 the equation of curve S passing through intersection of S1
and S2 can be S = S1 + S2 = 0. Since S is circle
 Coefficient of x2 = Coefficient of y2, Coefficient of xy = 0 we get  = 1
S = (a + a)(x2 + y2) – 2(g + g)x – 2(f + f)y + 2c = 0
 g' g f ' f 
The centre is  ,  which is P
 a ' a a ' a 
PA2 + PB2 + PC2 = 3(Radius)2 = 3(PD)2
 x   x   x 
9. sin x  sin  sin x  sin     or sin  2  
180  180   180 
x x
x   , x  2 
180 180
180 360
x , x
180   180  
On comparing, m = 360, n = 180, p = 180, q = 180
 (m + n + p + q) = 900
 A  C2  x2  Bx
10. lim 2
x   B 
x A   C
 x 
For existence of limit A = C2
10
B
Hence, C  A , 2
A C
B
 4
C
For C   A limit does not exist
11. The visible are of P(2, –6) is the area of ABP ABP has base AB of length 4 and its height is the
distance from AB to point P. Which is 10, since AB is parallel to x–axis.
1
Thus area =  b  h  20
2
1 1
12. Similarly area = QBC = bh   4 4  8
2 2
  sinh tanh cosh 1 

 
2h2  ln(2  h)  tanh 
13. LHD = lim  
h 0  h 
sinh tanh 1  cosh
  2
h
h h h
= lim 0
h 0 2h2  ln  2  h   tanh
2 2
eh  1  0 eh  1
RHD = lim  h 0
h0 h h
 L1  y = 0, L2  x = 0
1    
14.   2   cot     cot  1
2  4 2 2 

2sin
= 1 4
     
2  sin     sin
  4 2  2
2
= 1
  
cos      cos
 4 4
2
min  1   1  2  2  1   3  2 2
1
1
2
  
15. Four point A, B, C, D are coplanar if three vector AB , AC , AD are coplanar or STP of there
vectors is 0
  
AB   AC  AD   0
1 0 0
 3 f t 1  0  t  R
2 f ' t 2
 f(t) = 2f(t)
 f(t) = ce2t

Similarly for B  ˆi  ˆj  differential equation will be f(t) –2 f(t) = –4
On solving f(x) = 2 + ce2x, c  R
16. First use integrating by parts to show that

/2
n 1
un   cos
0
x sin x sinnx dx
/2 / 2
n 1 n
=
 cos
0
x cos(n  1)x   cos
0
x cosnx dx (Use sin nx sin x = cos(n – 1)x – cos nx cos x)
= un – 1 – un
u 1
 n 
un1 2
 1  
We have, u1  , un  n1   n1
4 2 4 2
17. If three planes pass through the same line, their normal vector will be coplanar
1 sin  sin 
 sin  1 sin   0
sin  sin  1
 sin2  + sin2  + sin2  + 2 sin  sin  sin  = 1 ..... (1)
Now the cross product r̂ of normals of P1, and P2 will parallel to line
ˆi ˆj kˆ
2
Direction ratio of r̂ = 1 sin  sin  = {(sin  sin  + sin ), (sin  sin  + sin ), (1– sin )}
sin  1 sin 
r̂ is parallel to given line
sin  sin   sin  sin  sin   sin  1  sin2 
    ..... (2)
cos  cos  cos 
Using (1) and (2) we get
  
 cos  =  sin ( + )  sin ( + ) = sin     =  +  +  = 2n  (n  z)
2  2
18. Let the circle be x2 + y2 = r2, and the five points be Pi = (r cos i, r sin i), i = 1, 2, 3, 4, 5
Let (hi, ki) represent the centre of that rectangular hyperbola which passes through the four points
Pj( j  i) let (h1, k1) is centre of hyperbola which passes through P2, P3, P4, P5.
h r k r
Now 1   cos 2  cos 3  cos 4  cos 5  , 1   sin 2  sin 3  sin 4  sin 5 
2 4 2 4
(As we know if a circle and rectangular hyperbola intersect at four point then their means is mid–
point of centre of two curves)
5
2h1  r  cos   r cos 
i1
i 1
5
 2k1  r  sin   r sin 
i1
i 1
 5   5 
However, r,   

 i 1



cos i  and   


 sin   are fixed
i1
i
 2h1 =  – r cos 1, 2k1 =  – r sin 

2 2 2
    r
  h1     k1     
 2  2  2
This equation is satisfied by all (hi, ki), i = 1, 2, 3, 4, 5
12
y
19. Divided the given equation by ax4, and let m
x
b 3 c 2 d
Equation become m4  m  m  m 1 0 ..... (1)
a a a
Assuming that four slopes m 1, m2, m3, m4  m1·m2·m3·m4 = 1
Now it is given pair of these lines, bisect the angle between the other pair. So let, m 1m2 = –1
m3m4 = –1 which means other two lines are also perpendicular
Equation (1) can be written as
 1  1
(m – m1)(m – m2)(m – m3)(m – m4) = (m – m1)  m   m  m3   m  
 m1   m3 
2 2
= (m + m – 1)(m + m – 1) ..... (2)
1  m12 1  m23
Where    
m1 m3
Comparing the coefficient (1) and (2)
b c d
    ,   2  ,      ..... (3)
a a a
b d
Thus,    b + d = 0
a a
Also, we have to use angle bisector fact
1
m3 
m1  m3 m1
  (m1 – m3)2 = (1 + m1m3)2 ..... (4)
1  m1m3 m3
1
m1
c  1  m12   1  m23  c
From (3),   2        2  ..... (5)
a  m1   m3  a
Using (4) and (5) we obtain (c + 6a) = 0
 2k  
20. Since Pk  eik , k 
n
Let Ak = xk + iyk = a cos k + ib sin k
x y x2 y2
 k  cos k , k  sin k , which implies that k2  2k  1, Ak lies on ellipse
a b a b
n n n
  A S    a  ex
k 1
k
k 1
k   na  e xk
k 1
 na
n n n n
   A k S 2
k 1
   a  exk 2
k 1
 na2  2ae 
k 1
xk  e2 x
k 1
2
k
n 2 2 n
na e 1
= na2  a2 e2  cos 2
k = na2   a2 e2 cos 2k 
k 1
2 2 k 1
na2  b2  n
= na2   1  2  =  3a  b 
2 2
2  a  2
n
(  cos 2 k  0 sum of roots of zn / 2  1  1 )
k 1

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1 AITS-CRT-II-(Paper-2)-PCM(S)-JEE(Advanced)/14

PHYSICS CHEMISTRY MATHEMATICS

If particle will not hit the target.

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Due to formation of resonance stabilized carbocation.

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Na2B4 O7  H2SO 4  5H2 O  Na2 SO 4  4H3BO3

15. CH2OH CH2OH

molecules due to synergic bonding between metal and carbonyl ligand.

And pH = 8.8 approx.

Mathematics PART – III

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6. Use L’Hospital’s Rule twice

  sinh tanh cosh 1 

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