Mock Test 5 Paper 2 Q. Paper

FIITJEE MOCK TEST-5
IIT – JEE, 2019

Paper Code
PAPER-II 100393.1
Time: 3 Hours Maximum Marks: 216
A. Question Paper Format:

1. The question paper consists of 3 Parts (Chemistry-Part-I, Mathematics-Part-II and Physics-Part-III).
2. Section A(i) contains 8 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) for its answer,
out of which only one is correct.
3. Section A(ii) contains 6 groups of questions. Each group has 2 questions based on a paragraph. Each question has
4 choices (A), (B), (C) and (D) for its answer, out of which only one is correct.
4. Section A(iii) contains 6 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) for its
answer, out of which one or more is/are correct.
B. Marking Scheme:
5. For each question in Section A(i) you will be awarded 3 marks if you darken the bubble corresponding to the
correct answer and zero mark if no bubble is darkened. In case of bubbling of incorrect answer, minus one (-1)
mark will be awarded.
6. For each question in Section A(ii), you will be awarded 4 marks if you darken the bubble(s) corresponding to the
correct answer and zero mark if no bubble is darkened. In all other cases, minus one (-1) mark will be awarded.
7. For each question in Section A(iii), you will be awarded 4 marks if you darken the bubble(s) corresponding to the
correct choice(s) for the answer, and zero mark if no bubble is darkened. In all other cases, Minus one (-1) mark
will be awarded.
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Mock Test-5–Paper-2 (100393.1)-CMP-IITJEE-4
Chemistry PART – I
SECTION – A
Single Correct Answer Type
This section contain 8 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out of
which ONLY ONE is correct.
–
1. Reduction potential of a calomel electrode with [Cl ] = 1 M; is + 0.28 V. The potential of a cell made
up of an electrode of unknown potential and same standard calomel electrode is 1.04 V, with the
calomel electrode positive (cathode). What is the potential of the unknown electrode referred to the
hydrogen electrode?
(A) - 1. 06 V (B) - 1.32 V
(C) + 0.76 V (D) - 0.76 V
2. What is the product of the following reaction?


OH/H2 S
 ?
Cl Cl
CH3
(A) (B) O
H3C O CH3 H3C O
CH3
(C) (D)
S
H3C S H3C S CH3
3. Which of the following is correct?

(A) All sulphides are insoluble in water (B) All sulphates are soluble in water
(C) NH4ClO3 leaves no residue on heating (D) Si  HNO3  dil. 
 SiO 2  N2  H2 O
4. The osmotic pressure of 1 molar CH3 COOH  aq solution is recorded as 27.1 atm at 300K. What is
the pH of the solution?
(A) 1 (B) 2
(C) 1.1 (D) 1.5
Rough work
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website: www.fiitjee.com
5. Which of the following can show linkage as well as ionization isomerism?

(A) Co NH3 5 NO 2  Cl2 (B) Co H2O 5 Cl SO4
(C) Co  H2 O 4  NO NH3   SO 4 2 (D) Co H2 O 6  Cl3
6. An endothermic reaction X  Y has an activation energy of 175 KJ/mol and the heat of reaction
is 85 KJ. Find the activation energy of backward reaction?
(A) 70 (B) 80
(C) 90 (D) 100
7. What are the final products of the following process?

Br H H
H alc.KOH(excess) O3 /Zn/H2O
   ?
H H
CH3
Br
(A) CH3COOH, COOH (B) CH 3CHO, CHO

|
COOH CHO
(C) HCHO, CHO  CH2  CH2  CHO (D) CH3CHO, HCHO, OCHCH2 CHO
8. F
Cl
H
C a b
3
C H
1 H 2
H c
H H
H
H
Which of the following is correct about the above?
(A) a > b> c (B) b > c > a
(C) 3 > 2 > 1 (D) 3 > 1 > 2
Rough work
Paragraph Type
This section contains 6 multiple choice questions relating to three paragraphs with two questions on each
paragraph. Each question has four choices (A), (B), (C) and (D) out of which ONLY ONE is correct.
Paragraph for Question Nos. 9 to 10

Pinacols (1, 2 diols) on treatment with acids undergo a rearrangement to Ketones (Pinacolones, the
rearranged interemediate is a carbocation. A further observation is that with unsymmetrical glycols the
product formation depends mainly by which OH is lost to leave behind the more stable of the two
carbocations, and thereafter by which is the better migrating groups (order of migratory aptitude is
Ar > H > Alkyl).
OH OH

H
9. C CH3  Major product is
Ph
Ph O CH3 O
(A) C (B) C
CH3 Ph
O O
CH3 Ph
(C) Ph (D)
CH3
OMe Me
10.
14 H 
Ph C C Ph  Pr oduct is
OH OH
OMe OMe
OMe Me OMe Me
14 14
(A) Ph C C Ph (B) (C) Ph C C Ph (D)
O O 14
Ph C C O C C Ph
Ph O Ph
Me Me
Rough work
Paragraph for Questions 11 and 12
Read the paragraph and answer the questions given below:
Proteins are the building blocks of amino acids. Except glycine, all amino acids extracted from proteins are
optically active and exists dominantly in L-form. Any -amino acid exists in the following equilibrium
depending on the conditions of pH.
O O O
K in basic medium
H3 N CH C 
a1

OH  H2N CH C 
OH H2N CH C O
in acidic medium K a2
R R R
(C) (A)
H3 N CH C O
R
Zwitter ion
(N)
In strongly acidic conditions, amino acid exists mainly as cationic form (C) and in strongly basic conditions,
amino acid exist mainly as anionic form (A). There is a certain pH for each amino acid at which Zwitter ion or
neutral form (N) becomes maximum. This pH is called isoelectric point of the amino acid.
11. At isoelectric point, for an amino acid, which of the following relation is correct?
(A)  C   A  and N is minimum (B)  C   A  and N is maximum
(C)  C   A  and N is cons tan t (D)  C   A  and N is maximum
12. Acetic acid : glycine : ethane amine

(I) (II) (III)
The correct order of the boiling point of the above three compounds is
(A) I < II > III (B) III < II < I
(C) III < I < II (D) III = 1 < II
Rough work
At 1090 K, Kp for the reaction

CO2(g) + C(s)  
 2CO(g) is 10 atm,
At the constant temperature, Equilibrium position will shift, when pressure change occurs.
13. In the above Equilibrium reaction, partial pressure of CO2 of equilibrium if total pressure at equilibrium
is 4 atm
(A) 10 atm (B) 0.938 atm
(C) 0.23 atm (D) 0.77 atm
14. In the above reaction, if we use catalyst. Equilibrium constant value:

(A) Increase (B) decrease
(C) does not change (D) change is rapid
Rough work
Multiple Correct Answer(s) Type
The section contains 6 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out
of which ONE or MORE are correct.
15. Which of the following is/are correct?

(A) Lewis acid character: SiF4 > SiCl4 > SiBr4 > SiI4
(B) Lewis acid character: AlCl3 > BI3 > BF3
(C) Dimerisation tendency: AlCl3 > Al(CH3)3 > AlI3  AlF3
(D) Acidic strength : CaO < CuO < H2O < CO2 < Tl2O
16. Which is the correct order of relative acidic strength of the following?
Br Br
(A) OH (B) OH
H2O > > C2H2 > NH3 > H2O > C2H2 > NH3
Br Br
(C) OH (D) OH
HCOOH > > H2O > NH3 > H2O > NH3 > C2H2
17. Which of the following statements(s) is /are correct?

(A) Higher the gold number, more is the protective power of lyophilic colloid
(B) Lower the gold number, more is the protective power of lyophilic colloid
(C) Higher the flocculating power, more is the precipitating power of an electrolyte
(D) Lower the flocculating power, higher the precipitation power of an electrolyte
Rough work
18. A compound is composed of three elements A, B and C in cubic geometry as fcc, in which corners
are occupied by A and face centers by C. B occupy central octahedral void in each cubic unit cell.
Then which of the following is/are correct?
(A) Coordination number of A is 12
(B) Formula of the compound is ABC3
(C) If all the atoms along one face diagonal of each unit cell are removed then the formula of the
compound becomes A3B4C10
(D) If all the atoms along one of the body diagonal are removed, the compound would lose its identity
19. Which of the following carbonates do not evolve CO2 on heating?

(A) Na2CO3 (B) Li2CO3
(C) MgCO3 (D) K2CO3
20. A Graph A represents 2 Zn + O2  2 ZnO

-200
B Graph B represents 4Cu + O2  2Cu2O
G in KJ / mole 
C Graph C represents 2CO + O2  CO2

Graph D represents C + O2  CO2
D Graph E represents 2C + O2  2CO
-1200 E
1000 K
Temperature in K 
According to above Ellingham diagram, which of the following reaction is/are feasible above 1000K
(A) Cu2O + C  2Cu + CO (B) ZnO + C  Zn + CO
(C) Cu2O + CO  2Cu + CO2 (D) ZnO + CO  Zn + CO2
Rough work
Mathematics PART – II
SECTION – A
1. If z1, z2 be two complex numbers where none of these of z1 and z2 is r. If |z1| = r, |z2| = r,
|z1 + z2 – r| = r where r > 0. Then z1 + z2 equals
(A) 0 (B) r
r
(C) (D) 2r
2
2 2 2 2 6 6
2. Let a, b be two non–zero real numbers if a b (a b + 4) = 2(a + b ) then
(A) a and b are both rational number (B) a and b are both irrational numbers
(C) one of a or b is irrational (D) nothing can be said in general
3. The complex number which is equidistant from roots of the equation (z + 2)4 + 16z4 = 0
1 2 2 i
(A)  i (B) 
3 3 3 3
1 2
(C) (D)
3 3
Rough work
  

4. Let O be an interior point of ABC such that OA  2OB  3OC  0 . Then the ratio of the area of ABC
to the area of AOC is
3
(A) 2 (B)
2
5
(C) 3 (D)
3
5. Let A, B, C be three square matrices of same order with real entries BA + BC + AC = I and
det(A + B) = 0 then det(A + B + C – ABC) equals
(A) 0 (B) 1
(C) –1 (D) cannot be found
2
6. Two focal chords AB and CD of parabola y = 4ax are perpendicular to each other. Then
1 1
 equals (where l(AB) and l(CD) represent lengths of AB and CD respectively)
  AB    CD 
2 1
(A) (B)
latus rectum latus rectum
2 1
(C) (D)
semi  latus rectum semi  latus rectum
7. Let f be thrice differentiable function on [0.2]. If f(0) = 0; f(1) = 2 and f(2) = 4 then
(A) f(x0) = 0 for all x  [0, 2] (B) f(x0) = 0 for all x  [1, 2]
(C) f(x0) = 0 for some x  (1, 2) (D) f(x0) = 0 for some x  (0, 2)
8. Let M  (–1, 2) and N  (1, 4) be two points. P is a moving point on the x–axis. When MPN takes its
maximum value then x–coordinate of P is
(A) 0 (B) –1
(C) 1 (D) –7
Rough work
Paragraph Type
Read the following write up carefully and answer the following questions:
The rule of an “obstacle course” specifies that at the nth obstacle a person has to toss a die n times. If the
sum of numbers obtained on these tosses is bigger than 2n, the person is said to have crossed the obstacle.
9. The maximum number of obstacles a person can cross is

(A) 3 (B) 4
(C) 5 (D) 6
10. The probability that a person crosses the first three obstacles is
117 10
(A) (B)
243 729
100 2
(C) (D)
243 9
There are n black balls and 2 red balls in bag. One by one ball is drawn from the bag, x wins as soon as 2
black balls are drawn and y wins as soon as 2 red balls are drawn. The game continuous until one of 2 wins.
Let x(n) and y(n) denotes the probability that x and y wins respectively
11. lim  y 1  y  2   .....  y  n   is

n
(A) 1 (B) 2
(C) 3 (D) 4
12. lim x  2  x  3  .....x  n  is

n
1 1
(A) (B)
2 5
1 2
(C) (D)
10 3
Rough work
 4
In a plane rectangular coordinate system, there are three points A  0,  , B(–1, 0) and C(1, 0). The distance
 3
from point P to line BC is geometric mean of the distances from this point to lines AB and AC
13. Locus of point P is

(A) 2x2 + 2y2 + 3y – 2 = 0 (B) 8x2 – 17y2 + 12y – 8 = 0
(C) both A and B (D) only A or B
14. If line L passes through the incentre (D) of ABC, and has exactly 3 common points with locus of
point P number of values of slope of line L is
(A) 1 (B) 3
(C) 5 (D) 7
15. The vertices of a triangle are A(x 1, x1 tan 1); B(x2, x2 tan 2); C(x3, x3 tan 3). If circumcentre of ABC
sin 1  sin 2  sin 3
is origin then represent ratio of y coordinate and x coordinate of
cos 1  cos 2  cos 3
(A) centroid of ABC (B) incentre of ABC
(C) orthocenter of ABC (D) ex–center of ABC
16. If a, b, c are positive and a = 2b + 3c then roots of the equation ax 2 + bx + c = 0 are real for
a c
(A)  11  4 7 (B)  11  4 7
c a
b c
(C)  4  2 7 (D)  4  2 7
c b
Rough work
1
17. If f  x   , then the points of discontinuity of the composite function y = f(f(f(x))) are
1 x
(A) 0 (B) 1
(C) 2 (D) –1
 1
sin  n   x

 2  dx , n  N is
18. The value of
0
 x
sin  
2
(A) independent of n (B) 2n
n
(C)  (D)
2
19. If n is the number of positive integral solutions of x 1 x2 x3 x4 = 210. Then,

(A) n must be divisible by 3 distinct primes (B) n must be a perfect square
(C) n must be a perfect 4th power (D) n must be a perfect 8th power
 1  1  1 
20. ,  and  are the angles given by   2 tan1  2  1 ,   3 sin1    sin   2  and
 2
1
 
  cos1   , then
3
(A)  >  (B)  > 
(C)  >  (D) none of these
Rough work
Physics PART – III
SECTION – A
1. A particle is projected from a point O in a horizontal surface OA with

speed u and angle of projection . It is just grazes the plane BC which
make an angle  with the horizontal as shown in figure. The time taken
by the projectile to reach P from the instant of projection is :
2usin  u sin 
(A) (B)
gcos  gcos 
usin |  –  | ucos |  –  | 
(C) (D)
gcos  gcos 
2. A point charge ‘q’ is placed at distance ‘a’ from the

centre of an uncharged thin spherical conducting shell
of radius R = 2a. A point ‘P’ is located at a distance R = 2a
‘4a’ from the centre of the conducting shell as shown.
The electric potential due to induced charge on the P O a q
inner surface of the conducting shell at point ‘P’ is
4a
kq kq
(A) (B) 
5a 5a
kq kq
(C) (D) 
4a 4a
Rough work
3. A particle of mass m is given initial speed u as shown in the figure. It

moves to the fixed inclined plane without a jump, that is, its trajectory
changes sharply from the horizontal line to the inclined line. All the
surfaces are smooth and 90   > 0. Then the height to which the u
particle shall rise on the inclined plane (assume the length of the
inclined plane to be very large)
(A) Increases with increase in 
(B) decreases with increase in 
(C) is independent of 
(D) data insufficient
4. Two point electric dipoles with dipole moments ‘P1’ and ‘P2’ are P1
separated by a distance ‘r’ with their dipole axes mutually
perpendicular as shown. The force of interaction between the r P2
 1 
dipoles is  where, k  
 40 
2kP1P2 3kP1P2
(A) 4
(B)
r r4
4kP1P2 6kP1P2
(C) (D)
r4 r4
5. A uniform thin rod of mass m and length R is placed normally on M

surface of earth as shown. The mass of earth is M and its radius is R.
Then the magnitude of gravitational force exerted by earth on the rod m
is: R
GMm GMm
(A) 2
(B) R
2R 4R 2
4GMm GMm
(C) (D)
9R2 8R2
Rough work
6. Two blocks A and B connected by spring (spring is in its natural

length) are kept on smooth inclined plane and released. If acceleration
of block B is 6 m/s2 then that of block A at that instant (g = 10 m/s2) :
(A) must be greater than 6 m/s2
(B) may be less than 6 m/s2
(C) must be 6 m/s2
(D) any thing possible depending on masses of blocks A & B
7. In a cylindrical magnetic field B is changing as B = B 0 + t. Find 

     
the value of E.d  for the path of BOA, as shown in the figure.
  O  
 
  
Line AOB is semicircular. ( E is the induced electric field in the A B
region).  2a 

a2   
(A) (B) a2    1
2 2 
(C) a2 (D) a2
8. A uniform thin, rod AB of length L and mass m is undergoing m, L

fixed axis rotation about end A, such that end A remains A P B
stationary as shown. The kinetic energy of section AP of rod is
equal to kinetic energy of section BP of rod at an instant. Then
AP
the ratio of length AP and length AB, that is,
AB
1 1
(A) (B) 1/3
2 2
1 1
(C) (D)
2 2 2
Rough work
Paragraph Type
A particle of mass 'm' is moving in horizontal circle inside a smooth inverted

vertical cone above height 'h' from apex. Half angle of cone is '' then give
the answer of following questions.
9. Normal force by surface of cone is :

(A) mg cos  (B) mg sec 
(C) mg sin  (D) mg cosec 
10. Speed of particle to move in horizontal circle, if h increases keeping  constant:

(A) will remain same (B) will decrease
(C) will increase (D) first increase then decrease
Rough work
A small fish touching the surface of a spherical air bubble is observed from =4/3
opposite surface from point P. The diameter of bubble is 12 cm. (Refractive
index of water is 4/3). Answer following questions on basis of above said P
B
situation. A 12cm
11. Find the location of image of fish, assuming B as origin.

(A) +9.6 cm (B) 9.6 cm
(C) 48 cm (D) 96 cm
12. The fish will appear

(A) touch to the surface of bubble
(B) Inside the bubble
(C) At some distance behind the surface of bubble
(D) none of the above

Consider two parallel, conducting frictionless tracks are kept in gravity P
A 
free space as shown in the figure. A movable conductor PQ, initially B
X Y
kept at OA, given a velocity 10 m/s towards right. If space contains a v
R=1
magnetic field which depends upon the distance moved by conductor
PQ from OA line and given by O
X

 
B  cx kˆ [c = constant = 1 S.I-unit] O
x
Q
The mass of conductor PQ is 1 kg and length of PQ is 1m. Answer the
following questions based on above passage.
13. The distance travelled by conductor when its speed is 5 m/s is

1/ 3 1/ 3
 15   10 
(A)   (B)  
 2   3 
1/ 3
(C) 10  (D) None of the above
14. The heat loss during the time interval t = 0 to time t sec, when the speed of conductor is 5 m/s is
(A) 50 J (B) 30 J
(C) 10 J (D) none of the above
Rough work
15. A semicircular wedge of mass M is placed on horizontal floor. A man of B

mass m starts moving on the wedge from position A with constant speed m
M
v relative to wedge. Initially, both man and wedge were at rest. Neglect A C
friction between wedge and horizontal floor and man doesn’t slip on
wedge. While man moves from position A to C relative to wedge,
(A) speed of wedge will first increase and then decrease
(B) net work done by contact force between man and wedge on system containing man and wedge
during the walking of man is zero.
2mR
(C) wedge will get displaced by towards left after man reaches C.
Mm
(D) speed of wedge will be maximum when man reaches B.
16. A rigid rod of mass M slides along a fixed semicircular track (in vertical r
A O
plane) followed by a flat track. At the given instant velocity of end B is v
along horizontal plane. Then at the given instant r
C
(A) angular speed of rod is v/r B v
(B) velocity of centre of mass is v/2
(C) angular momentum of rod about O is 2/3 mvr
(D) the ratio of rotational to translational kinetic energy is 1:2
17. When the temperature of a copper coin is raised by 80°C, its diameter increases by 0.2%
(A) Percentage rise in the area of a face is 0.4%
(B) Percentage rise in the thickness is 0.4%
(C) Percentage rise in the volume is 0.6%
(D) Coefficient of linear expansion of copper is 0.25 × 10–4 C°–1
Rough work
18. Three capacitor C1 = 6F, C2 = 3F and C3 = 4F are C2 = 3F

separately charged with battery such that charge on  +
each capacitor are 36 C, 24 C and 40 C respectively
and then disconnected with the battery. After that they + +
are connected in a circuit along with an uncharged C1 = 6F C3 = 4F
 
capacitor C4 = 4F and a battery of emf = 4 volts as S
shown in figure. Now the switch S is closed. Choose
the correct option(s).  +
(A) Final charge on capacitor C4 = 4C. 4V C4 = 4F
(B) Final charge on capacitor C2 = 24C.
(C) Final charge on capacitor C3 = 36C.
(D) Amount of charge flow in circuit is zero.
19. A particle has a rectilinear motion and the figure gives its
displacement as a function of time. Which of the following statements
are true with respect to the motion
(A) in the motion between O and A the velocity is positive and
acceleration is negative
(B) between A and B the velocity and acceleration are positive
(C) between B and C the velocity is negative and acceleration is
positive
(D) between C and D the acceleration is positive
20. The wires A and B shown in the figure, are made of the same material and have radii
of cross-section rA and rB. When a constant force F is applied as shown, one of the
wires breaks. (Assume the masses of the wire to be negligible)
(A) A will break before B if rA > rB
(B) B will break before A if rA < rB
(C) Either A or B will break if rA = rB
(D) The lengths of A and B must be known to decide which wire will break
Rough work

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FIITJEE MOCK TEST-5

IIT – JEE, 2019

A. Question Paper Format:

2. What is the product of the following reaction?

3. Which of the following is correct?

5. Which of the following can show linkage as well as ionization isomerism?

7. What are the final products of the following process?

(A) CH3COOH, COOH (B) CH 3CHO, CHO

Paragraph for Question Nos. 9 to 10

Paragraph for Questions 11 and 12

Read the paragraph and answer the questions given below:

12. Acetic acid : glycine : ethane amine

Paragraph for Questions 13 and 14

At 1090 K, Kp for the reaction

14. In the above reaction, if we use catalyst. Equilibrium constant value:

Multiple Correct Answer(s) Type

15. Which of the following is/are correct?

17. Which of the following statements(s) is /are correct?

19. Which of the following carbonates do not evolve CO2 on heating?

20. A Graph A represents 2 Zn + O2  2 ZnO

C Graph C represents 2CO + O2  CO2

  

Paragraph for Questions 9 and 10

9. The maximum number of obstacles a person can cross is

Paragraph for Questions 11 and 12

11. lim  y 1  y  2   .....  y  n   is

12. lim x  2  x  3  .....x  n  is

Paragraph for Questions 13 and 14

13. Locus of point P is

Multiple Correct Answer(s) Type

19. If n is the number of positive integral solutions of x 1 x2 x3 x4 = 210. Then,

Physics PART – III

1. A particle is projected from a point O in a horizontal surface OA with

2. A point charge ‘q’ is placed at distance ‘a’ from the

3. A particle of mass m is given initial speed u as shown in the figure. It

5. A uniform thin rod of mass m and length R is placed normally on M

6. Two blocks A and B connected by spring (spring is in its natural

7. In a cylindrical magnetic field B is changing as B = B 0 + t. Find 

8. A uniform thin, rod AB of length L and mass m is undergoing m, L

Paragraph for Questions 9 and 10

A particle of mass 'm' is moving in horizontal circle inside a smooth inverted

9. Normal force by surface of cone is :

10. Speed of particle to move in horizontal circle, if h increases keeping  constant:

Paragraph for Questions 11 and 12

11. Find the location of image of fish, assuming B as origin.

12. The fish will appear

Paragraph for Questions 13 and 14

13. The distance travelled by conductor when its speed is 5 m/s is

Multiple Correct Answer(s) Type

15. A semicircular wedge of mass M is placed on horizontal floor. A man of B

18. Three capacitor C1 = 6F, C2 = 3F and C3 = 4F are C2 = 3F

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