Professional Documents
Culture Documents
net/publication/313148236
CITATION READS
1 31
1 author:
Shinya Inazumi
Shibaura Institute of Technology
101 PUBLICATIONS 142 CITATIONS
SEE PROFILE
All content following this page was uploaded by Shinya Inazumi on 17 December 2017.
*Shinya Inazumi1, Tomohiro Inazawa2, Suttisak Soralump3, Osamu Saiki4 and Hikaru Matsumoto5
1
National Institute of Technology, Akashi College, Japan; 2Midorishoji Co. Ltd., Japan;
3
Kasetsart University, Thailand; 4Team. S Ltd., Japan; 5Kobe University, Japan
*Corresponding Author; Received: 16 June 2016; Revised: 2 July 2016; Accepted: 11 July 2016
ABSTRACT: In recent years, surface penetration has attracted attention as a repair method for concretes
structures. Silicate based penetration materials have been used in this method. In this study, visual appearance,
water permeability, water absorption, water-vapor permeability, neutralization (carbonation) and chloride ion
penetration testing of a silicate based surface penetration material are performed. The protection and
waterproofing effects of a silicate based surface penetration material are evaluated based on the results. The
silicate based surface penetration material penetrates deeply into the concrete surface, shows self-repair
functionality, is effective to the neutralization (the carbonation) of the concrete and improves the performance of
waterproofing. The penetration depth of the silicate based surface penetration materials plays an important role
in the surface penetration method. Therefore, permeability testing of a mortar specimen, penetration depth
testing of the mortar specimens with various silicate based surface penetration materials, viscosity testing of the
materials and modelling of the one dimensional penetration into the mortar specimens are performed. The results
of viscosity testing and coefficient of permeability suggest that these silicate based surface penetration materials
will perform well surface penetration materials.
163
International Journal of GEOMATE, xxx., 201x, Vol. xxx, Issue xx, pp. xxxx-yyyy
164
International Journal of GEOMATE, Jan., 2017, Vol. 12, Issue 29, pp. 163 - 170
composition of the mortar specimen. The water- Table 4 Composition of the mortar samples
cement ratio was 50%; the sand-cement ratio was 3.
The mortar specimens used were based on those Portland
Materials Standard sand Tap water
described in “JSCE-K 571-2010 5.2”. Silicate based cement
surface penetration materials with low viscosity coat Compounded
2.5 7.5 1.25
to the top surface of the mortar specimens. Table 3 amount (kg)
shows the coating method and the amounts of
potassium silicate based surface penetration material
with low viscosity used. a
The coated mortar specimens were produced as
described by “JSCE-K571-2010 6” and the visual
appearance testing, the water permeability testing, Graduated
the water absorption testing, the water-vapor tube
permeability testing, the neutralization (carbonation)
testing and the chloride ion penetration testing were Gum Mold
conducted [8].
165
International Journal of GEOMATE, Jan., 2017, Vol. 12, Issue 29, pp. 163 - 170
Four types of silicate based surface penetration Table 5 Components of applied silicate based surface
materials were used in this testing. Each material penetration materials
was used to penetrate three mortar specimens.
Table 5 shows the main components of the Materials A B C D
silicate based surface penetration materials used. Main
K2O・SiO2 Na2O・SiO2 Na2O・SiO2 Na2O・SiO2
The main component of “A” is potassium silicate, components
while that of “B”, “C” and “D” is sodium silicate.
166
International Journal of GEOMATE, Jan., 2017, Vol. 12, Issue 29, pp. 163 - 170
The average water permeability (Wp) of the coated Table 7 Water permeability, water absorption and
specimens was 8.30 mL, while that of the uncoated vapor permeability of coated and uncoated mortar
specimens was 9.38 mL, resulting in a Wp ratio of samples
88%; the average water absorption (Wa) of the
coated specimens was 0.8%, while that of the Non-
Testing Coating
uncoated specimens was 1.7%, resulting in a Wa Measuring items coating
requirements samples
samples
ratio of 47%; the average water-vapor permeability
Water penetration
(Wv) of the coated specimens was 0.35 g, while that Water amount Wp (mL)
9.82 8.30
of the uncoated specimens was 0.30 g, resulting in a permeability Water penetration
Wv ratio of 117%. 85
ratio (%)
Coefficient of
4.3 Resistance Against Deterioration water absorption 1.7 0.8
Water
Wa (%)
absorbency
Table 8 shows the results of testing of resistance Water absorption
47
against neutralization (carbonation) and chloride ion ratio (%)
penetration. For both resistance testing, the averages Water vapor
transmission Wv 0.30 0.35
of the three coated and three uncoated specimens are Vapor (g)
recorded. The average neutralization (carbonation) permeability Vapor
depth of the coated specimens was 6.1 mm, while transmission ratio 117
that of the uncoated specimens was 7.2 mm, (%)
resulting in a ratio of 85%. The average chloride ion
penetration depth of the coated specimens was 11.7
mm, while that of the uncoated specimens was 10.8 Table 8 Resistance to neutralization and chloride ion
mm, resulting in a ratio of 92%. penetration of coating samples and non-coating
samples
4.4 Permeability Testing
Non-
Testing Measuring Coating
coating
Figure 7 shows the permeability coefficient of requirements items
samples
samples
the mortar specimens for elapsed time. The Neutralization
maximum permeability coefficient was 6.32×10-6 7.2 6.1
depth (mm)
m/s, whereas the minimum was 6.12×10-6 m/s. This Resistance to
Neutralization
neutralization
coefficient is thus essentially constant. depth ratio 85
(%)
4.5 Penetration Depth Testing Chloride ion
penetration 11.7 10.8
Table 9 shows the penetration depth of each Resistance to depth (mm)
chloride ion Chloride ions
silicate based surface penetration material into the
penetration penetration
mortar specimens. The penetration depth decreases 92
depth ratio
in order from “A” to “D”. (%)
167
International Journal of GEOMATE, Jan., 2017, Vol. 12, Issue 29, pp. 163 - 170
168
International Journal of GEOMATE, Jan., 2017, Vol. 12, Issue 29, pp. 163 - 170
surface penetration material penetrated deeply into Table 14 Comparison of hydroxide components
the concrete surface.
Sodium Potassium
Components
5.3 Waterproofing Performance hydroxide hydroxide
Chemical
structural Na-OH K-OH
Coating the specimen with the potassium silicate formula
based surface penetration material with low Color of water
viscosity decreased Wp and Wa by 15% and 53%, Clear
solution
respectively, thus implying the effect of the silicate Absorptivity of Sodium hydroxide < Potassium
based surface penetration material mentioned above. CO2 hydroxide
In other words, calcium silicate was formed by a Sodium hydroxide < Potassium
Alkali level
reaction of potassium silicate with calcium hydrate hydroxide
and caused densification of the mortar specimens, Solubility with
Sodium hydroxide < Potassium
water and
suppressing water penetration. hydroxide
alcohol
Voids formed due to entrapped air when mixing
ingredients may provide passages for water
migration within concrete, thereby advancing
Table 15 Comparison of carbonate components
deterioration. It is assumed that coating concrete
with a silicate based surface penetration material can Components Sodium carbonate Potassium carbonate
eliminate or reduce the size of these voids, leading Color of dry
White
components
to the densification of concrete. Absorptivity of CO2 Sodium carbonate < Potassium carbonate
Coating with the potassium silicate based surface Solubility with water Sodium carbonate < Potassium carbonate
penetration material with low viscosity caused Wv to Alkali level Sodium carbonate < Potassium carbonate
increase by 17% because existing moisture
decreased as the voids were filled.
169
International Journal of GEOMATE, Jan., 2017, Vol. 12, Issue 29, pp. 163 - 170
6. CONCLUSIONS
This study found results concerning the Part1. Effect of Types of Surface Improvement”,
performance of silicate based surface penetration Research Report of the Architectural Institute of
materials including low viscosity one. They are Japan, Kyusyu Branch, Vol.44, pp.105-108,
listed as follows:
2005.
(1) Because it is low viscosity, the potassium silicate
[3] Miyagawa T, Okamoto T, “Illustration
solution penetrates deeply into the surface of
understand materials make civil engineering”,
concrete.
Environment and Social Foundation Facilities,
(2) Potassium silicate reacts stably because the
pp.60-72, 2009.
properties of potassium silicate change less with
[4] Someya N, Kato Y, “Basic study for penetration
temperature and concentration compared with
mechanism and modification effects of silicate
those of sodium silicate.
based surface penetration materials”, Collection
(3) Because the ionization tendency of potassium
of Papers of Concrete, Vol.25, pp.181-189,
silicate is large, it can effectively repair itself
2014.
when small quantities of water are added.
[5] Iwama H, Kobayashi M, “Long life measures of
(4) Potassium hydroxide and potassium carbonate
existing bridge by silicate based surface
form from chemical reactions with concrete and
penetration methods of reaction type”, Journal
absorbed CO2, allowing the silicate based surface
of Waterproofing, No.507, pp.58-60, 2014.
penetration material to effectively resist
[6] Misono M, Imamoto K, Nagai K, Kiyohara T,
neutralization (carbonation). Although these
“Evaluation of moisture migration of surface
substances are white in color, no bleaching of the
treated concrete member under accelerated
concrete was observed because they penetrated
weathering condition”, Japan Society for
deeply.
Finishings Technology, pp.24-27, 2013.
(5) Penetration of the potassium silicate based
[7] Japan Society of Civil Engineers, “Guide for
surface penetration material with low viscosity
Design and Construction Silicate Surface
improved the performance of waterproofing and
penetration Method (Idea), Japan Society of
the deterioration control performance of concrete
Civil Engineers, p.137, 2012.
structures.
[8] Japan Society of Civil Engineers: “Standard
(6) Evaluating the viscosity of silicate based surface
Specification for Concretee Structures -2010
penetration materials enables the evaluation of
(Standard) Testing Methods and Specifications”,
penetration depth and performance of silicate
Japan Society of Civil Engineers, 2010.
based surface penetration materials.
[9] Osawa T, Oki M, TanakaM, Chihara H,
“Unabridged Dictionary of Chemistry”,
7. REFERENCES
Tokyokagakudojin, 1989.
[10] Sawa K, “Geotechnical Engineering”, Morikita
[1] Takewaka K, “Current trends and issues of
Publishing Co., Ltd., Vol.2, pp.48-50, 2011.
surface protection method”, Journal of concrete
technology, Vol.32, No.2, pp.84-88, 2013.
[2] Miura O, Hadachi M, Hamanaga Y, Ueda K, Copyright © Int. J. of GEOMATE. All rights
Sato Y, Kiyohara C, Otani T, “Study on reserved, including the making of copies unless
Inhibitory Action of Surface Improvement permission is obtained from the copyright
Agent on Shrinkage Cracking of Concrete : proprietors.
170