Eq.

(4-37) in order to obtain kd and Y

q S0 S X (S0-S)/X
11.2 1037 47 409 2.420538 Looki
2.45
9 1010 58 401 2.374065
6 987 80 388 2.337629

(S⁰-S)/X
2.4 f(x) = 0.0160556031x
3.75 986 162 358 2.301676 R² = 0.9889596658
3.4 1040 220 359 2.284123
2.8 1043 303 324 2.283951 2.35

Slope 0.0161 2.3

Intercept 2.2369
Y 0.447047 2.25

kd 0.007197
2.2
2 3 4 5

Eq.(4-35) in order to obtain k0 and Km

qX/(S0-S) 1/S
4.627071 0.021277 Lookin
3.790966 0.017241 5

2.566703 0.0125 4.5

θX/(S⁰-S)
f(x) = 186.820627
1.629248 0.006173 4 R² = 0.986764447
1.488537 0.004545 3.5
1.225946 0.0033 3
2.5
Slope 186.82 2
Intercept 0.5297 1.5
k0 0.843963 1

Km 0.5
352.6902
0
0 0.005
 Looking for kd and Y
5

4 f(x) = 0.0160556031x + 2.2369284509

R² = 0.9889596658

2
2 3 4 5 6 7 8 9 10 11 12
θ

Looking for k0 and Km

f(x) = 186.8206273989x + 0.5297153934

R² = 0.9867644476

0 0.005 0.01 0.015 0.02 0.025

1/S
33 44 0.030303 0.022727
50 91 0.02 0.010989
80 400 0.0125 0.0025
83 1000 0.012048 0.001
81 1500 0.012346 0.000667
86 3000 0.011628 0.000333
77 6000 0.012987 0.000167
65 11000 0.015385 9.091E-05

Chart Title
12000

10000

8000

6000

4000
f(x) = - 156704.739698084x + 5370.9105773436
R² = 0.069145182
2000

0
0.01 0.015 0.02 0.025 0.03 0.035
 X
0.025

f(x) = 1.2254553097x - 0.0146749613

0.02 R² = 0.9474881512

0.015

0.01

0.005

0
0.01 0.015 0.02 0.025 0.03 0.035

Eq.(4-35) in order to obtain k0 and Km

Slope -156705
Intercept 5370.9
k0 -0.012666
Km -29.17667
Eq.(4-37) in order to obtain kd and Y

slope 1.2255
intercept -0.0147
Y -68.02721
kd -83.36735
values of Km (mg acid/liter) for several temperatures

Acetic
T (°C) Km (mg acid/liter) 1/T ln Km
25 869 0.04 6.767343
30 333 0.033333 5.808142
35 154 0.028571 5.036953

ln Km vs 1/T (Acetic)
8

7 slope =
f(x) = 150.9256521422x + 0.7441318569 R =
6 R² = 0.9988927572
slope =
5
E =
ln Km

0
0.025 0.027 0.029 0.031 0.033 0.035 0.037 0.039 0.041
1/T

Propionic
T (°C) Km (mg acid/liter) 1/T ln Km
25 613 0.04 6.418365
35 32 0.028571 3.465736

ln Km vs 1/T (Propionic)
7

6 f(x) = 258.3550403994x - 3.91583668 slope =

R² = 1 R =
5 slope =
4 E =
ln Km

0
0.025 0.027 0.029 0.031 0.033 0.035 0.037 0.039 0.041
1/T
 150.93
1.987 cal/gmol°K
E/R
299.8979 cal/gmol

258.36
1.987 cal/gmol°K
E/R
513.3613 cal/gmol