1.

The displacement of a particle moving in a straight line is D

described by the relation, s  6  12t  2t 2 . Here s is in metre
and t in second. The distance covered by the particle in first
5 s is
20 m
32 m
24 m
26 m
2. A ball is projected upwards from the foot of a tower. The B
ball crosses the top of the tower twice after an interval of 6s
m
and the ball reaches the ground after 12s. The height of the
tower is (g = 10 m/s2)
ntu

120 m
135 m
175 m
me

None of these
3. A ball is dropped from the top of a building. At the same B
instant ball B is thrown vertically upwards from the ground.
Mo

When the balls collide, they are moving in opposite

directions and the speed of A is twice the speed of B. At
what fraction of the height of the building did the collision
occur?
1/3
2/3
1/ 4
None of these
4. Velocity of a particle varies with time as v  atiˆ  2bt 2ˆj . If B
the particle starts from point (0, c), the trajectory of the
particle is
bx 3/2
y c
a
3/2
4 2b  x 
y   c
3 a
3/2
4 2b  x 
y   c
3 a
 None of these
5. Velocity-time graph of a particle undergoing rectilinear C
motion is plotted upto t = t4 as shown in the figure. Average
acceleration of the particle is zero in the time interval
between

m
ntu
0 and t1
t1 and t 2
t1 and t 3
me

t 2 and t 4
6. A ball is hit by a batsman at an angle of 37o as shown in B
figure. The man standing at P should run at what minimum
Mo

velocity so that he catches the ball before it strikes the

ground. Assume that height of man is negligible in
comparison to maximum height of projectile.

3ms 1
5ms1
9ms1
None of these
7. A projectile is given an initial velocity of ˆi  2ˆj . The A
Cartesian equation of its path is (g = 10 m/s2)
(Here, î is unit vector along horizontal and ĵ is unit vector
vertically upwards)
 y  2x  5x 2
y  x  5x 2
4y  2x  5x 2
y  2x  25x 2
8. The horizontal range and maximum height attained by a D
projectile are R and H respectively. If a constant horizontal
acceleration a = g/4 is imparted to the projectile due to wind,
then its horizontal range and maximum height will be
H
(R  H),
2
m
 H
 R   , 2H
ntu
 2
 R  2H  ,H
 R  H  ,H
me

9. The speed of a projectile when it is at its greatest height is B

2 / 5 times its speed at half the maximum height. The
angle of projection is
Mo

30o
60o
45o
tan 1 (3 / 4)
10. The acceleration of a particle which moves along the B
positive x-axis varies with its position as shown. If the
velocity of the particle is 0.8 m/s at x = 0, the velocity of the
particle at x = 1.4 is (in m/s)

1.6
1.2
1.4
 None of these
11. An object is cooled from 75o C to 65o C in 2 min in a room C
at 30o C. The time taken to cool the same object from 55o C
to 45o C in the same room is
5 min
3 min
4 min
None of these
12. A gas is expanded to double its volume by two different A
processes. One is isobaric and the other is isothermal. Let
W1 and W2 be the respective work done, then
m
W2  W1 ln (2)
ntu
W1
W2 
ln (2)
W
W2  1
me

2
Data is insufficient
13. In a certain gas, the ratio of the speed of sound and root D
Mo

5
mean square speed is . The molar heat capacity of the
9
gas in a process given by PT = constant is
R
2
3R
2
5R
2
7R
2
14. One mole of an ideal gas undergoes a process in which A
T  T0  aV 3 , where T0 and 'a ' are positive constants and V
is volume. The volume for which pressure will be minimum
is
1/3
 T0 
 
 2a 
 1/3
 T0 
 
 3a 
2/3
 a 
 
 2T0 
2/3
 a 
 
 3T0 
15. Pressure versus temperature graph of an ideal gas is as B
shown in figure. Density of the gas at point A is 0 . Density
at B will be
m
ntu
me

3
Mo


4 0
3

2 0
4

3 0
None of these
16. How much heat energy should be added to a mixture of 10g B
of hydrogen and 40 g of He to change the temperature by
50o C kept in a closed vessel?
2500 cal
2750 cal
2000 cal
None of theses
17. An ideal gas mixture filled inside a balloon expands A
according to the relation pV 2/3  constant. The temperature
inside the balloon is
Increasing
Decreasing
 Constant
Cannot be defined
18. Heat is supplied to a diatomic gas at constant pressure. The C
ratio of Q : U : W is
5:3:2
5:2:3
7:5:2
7:2:5
19. Six identical conducting rods are joined as shown in figure. C
Points A and D are maintained at temperatures 200o C and
20o C respectively. The temperature of junction B will be
m
ntu
me

120o C
Mo

100o C
140o C
None of these
20. A composite rod made of three rods of equal length and A
cross-section is shown in the figure. The thermal
conductivities of the materials of the rods are K/2, 5K and K
respectively. The end A and end B are at constant
temperatures. All heat entering the face A goes out of the
end B. The effective thermal conductivity of the bar is

15K/16
6K/13
5K/16
2K/13
21. The 1/v versus position graph of a particle is shown in the 6
figure, where v is the velocity of the particle. The particle is
 moving in a straight line along positive x-axis. Find the time
taken by the particle to reach from the point A to B in
second.

m
ntu

22. Figure shows the velocity-time graph for a particle travelling 1

along a straight line. The magnitude of average velocity (in
m/s) of particle during the time interval from t = 0 to t = 6s
me

is 10  . Find the value of  .

Mo

23. An object is projected with a velocity of 20 m/s making an 4

angle of 45o with horizontal. The equation for trajectory is
h  Ax  Bx 2 where h is height, x is horizontal distance. A
x
and B are constants. The ratio A : B is . Find value of x.
0.1
(g = 10 m/s2)
24. Two moles of an ideal diatomic gas is taken through the 4
process PT  constant. Its temperature is increased from
T0 K to 2T0K . If the work done by the gas is nRT0 , then find
the value of n.
25. In steady state, rate of heat flow through rod of variable 5
thermal conductivity shown in the figure is Q = 6000 W.
Area of cross section of rod in m2 varies with x according as
 A (x)  (1  x), while temperature in Kelvin of rod is
T (x)  300 (1  4x  x 3 ). Find thermal conductivity (in
watt/m-k) of rod at x = 0. (Thermal conductivity depends
only on x).

m
ntu

26. For the decomposition of NH3(g) in sealed tubed : A

me


2NH3 (g)   N 2 (g)  3H 2 (g)
Kp does not change with pressure
Concentration of H2(g) is less than that of nitrogen
Mo

Concentration of ammonia does not change with pressure

Kp changes significantly with pressure
27. At a certain temperature the equilibrium constant KC is 0.25 for the reaction: C

A(g)  B(g)   C(g)  D(g)
If we take 1 mole of each of four gases in a 10 litre container, what would be
the equilibrium concentration of A (g)?
0.331 M
0.033 M
0.133 M
1.33 M
28. Consider the reactions, whose KC = 33, B

SO2 (g)  NO2 (g)   SO3 (g)  NO(g)
If 0.1 mol each of SO2 and NO2 are placed in 1 L container, what is the
concetration of SO2 at equilibrium?
0.003 M
0.015 M
0.085 M
 0.097 M
29. Le Chatelier’s principle is not applicable to : A

Fe(s) + S(s)   FeS(s)

H2(g) + I2(g)   2HI (g)

N2(g) + 3H2(g)  2NH3(g)

N2(g) + O2(g)  2NO(g)
30. The equilibrium constant for the following reaction B
2
 [NO ]
N 2O 4 (g)  2NO 2 (g) is K  2
m  N 2O4 
Which of the following graphs is correct?
ntu
me
Mo

31. 
For the reaction : R P C
Variation of cencentration is plotted against time :

Which of the following regions show (s) equilibrium?

 III
II
I
II and III both
32. Which is a possible set of quantum number for the unpaired electrons in the B
orbital box diagram below?

1
n = 1, l = 1, ml = – 1, ms = 
2
m 1
n = 4, l = 1, ml = – 1, ms = 
2
1
ntu
n = 4, l = 2, ml = – 2, ms = 
2
1
n = 4, l = 0, ml = 0, ms = 
2
me

33. Which type of orbital is designated by n = 2, l = 3, ml = – 2? D

4p
4d
Mo

4f
None of these
34. Which of the following statement regarding subshell filling order for a neutral C
atom is/are correct?
(P) Electrons are assigned to the 4s subshell before they are assigned to the 3d
subshell
(R) Electrons are assigned to the 4d subshell before they are assigned to the
5p subshell
P only
Q only
P and R
P, Q and R
35. The highest probability of finding the electron in an orbital having values of C
quantum numbers n = 3, l = 1 and m = – 1.
In between any two axis out of three
On any two axis simultaneously, perpendicular to each other
On any one axis out of the three at a time
On all the three axis simultaneously at a time
36. For a 6s electron the values of n, l, m, s respectively could be : D
 1
6, 4 ,4, 
2
1
1, 0, 0, 
2
1
6, 1, 0, 
2
1
6, 0, 0, 
2
37. Which of the following statements in relation to the hydrogen atom is A
correct?
3s, 3p and 3d orbitals all have the same energy
m
3s and 3p orbitals are of lower energy than 3d orbitals
3p orbital is lower in energy than 3d orbital
ntu

3s orbital is lower in energy than 3p orbital

38. In case of d x 2  y2 orbital : C
me

Probability of finding the electron along x – axis is zero

Probability of finding the electron along y – axis is zero
Probability of finding the electron is maximum along x and y axis
Probability of finding the electron in zero in xy plane
Mo

39. Read carefully four statements : D

(P) s–subshell consists of one orbital
(Q) p-orbital consits of three subshell
(R) d–subshell can accommodate maximum of ten electrons
(S) f–orbtial can accommodate maximum of two electrons
Choose the correct statements :
P, Q, R and S
P and R
Q and S
P, R and S
40. Which electronic distributaion in d–subshell is not observed in any neutral D
element of 3d series?

41. Which element has the following ground state electronic configuration? A
 Se
As
S
Ge
42. Hund’s rule states that the most stable arrangement of electrons : (for a C
ground state electrons configuration)
has three electrons per orbital, each with identical spins
has ml values greater than or equal to + 1
has the maximum number of unpaired electrons, all with the same spin in
m
degenerate orbitals
has two electrons per orbital, each with opposing spins
ntu

43. Which of the following is wrong outer electronic configuration? D

21 1 2
Sc = 3d 4s
Ti22 = 3d2 4s2
me

Cr24 = 3d5 4s1

V23 = 3d2 4d2
44. The diagram shows the energy levels for an electron in certain atom. Which D
Mo

transition shown represents the emission of a photon with the most energy

II
I
IV
III
45. The wave function of atomic orbital of H–like species is given as : B
1
 2s  Z3/2 (2  Zr)e Zr/2
4 2
The radius for nodal surface for He+ ion in Å is :
1.5 Å (B) (C) (D)
1Å
2Å
4Å
46. For the reaction, 4
A(g)  B(g)    C(g)  D(g),
The initial concentrations of A and B are equal. The equilibrium concentration
of C is two times the eequilibrium concentration of A. The value of the
equilibrium constant is _____.
47. Calculate the total number of electrons for Mn having n + l + m = 2. 4
48. How many unpaired electrons are there in Ni2+ ion if the atomic number of Ni 2
is 28.
49. The maximum number of electrons that can be accommodated in all the 6
orbitals for which l = 1 is ............. .
50. The number of species which are diamagnetic amongst the following :
m 3
Fe2+, Fe4+, Mn2+, Cr3+, Ni2+, Cr+6, Mn+7, V3+, Sc3+
51. The value of (1  i)(1  i 2 )(1  i3 )(1  i 4 ) is B
ntu

2
0
1
me

i
52. 3  2isin  A
If is a real number and 0  2, then  
1  2isin 
Mo


/2
/3
/6
53. If a  i b  x  i y, then possible value of a  i b is D

x 2  y2
x 2  y2
x iy
x iy
54. The principal value of the amplitude of (1  i) is A
/4
 / 12
3 / 4

55. 1 i  4 A
If z    , then z equals
1 i 
 1
-1
0
None of these
56. 1  7i D
If z  2
, then
(2  i)
| z | 2
1
| z |
2

amp (z)  m
4
3
amp (z) 
ntu
4
57. iz B
The complex number z which satisfies the condition  1 lies on
iz
me

circle x 2  y2  1
the x-axis
the y-axis
Mo

the line x + y = 1
58. Two vertices of a triangle are (3, -5) and (-7, 4). If its centroid is A
(2, -1), find the third vertex.
(10, -2)
(10, 2)
(-10, 2)
None of these
59. If the two vertices of an equilateral triangle be (0, 0), (3, 3), find B
the third vertex.
(3,  3)
(0, 2 3)
(3, 3)
None of these
60. Let the opposite angular points of a square be (3, 4) and (1, -1). Find A
the coordinates of the remaining angular points.
9 1  1 5
 ,  and   , 
2 2  2 2
  9 1 1 5
  ,   and  , 
 2 2 2 2
9  1 
 , 0  and  , 0 
2  2 
None
61. If three points A (h, 0), P (a, b) and B (0, k) lie on a line, then : C
a b
 ?
h k
2
4 m
1
3
ntu
62. The distance between the orthocentre and circumcentre of the A
 3 3 3 3 
triangle with vertices (1, 2) . (2, 1) and  ,  is
 2 2 
me

0
2
3 3
Mo

None of these
63. The point which divides the join of (1, 2) and (3, 4) externally in the D
ratio 1 : 1.
lies in the III quadrant
lies in the II quadrant
lies in the I quadrant
cannot be found
64. The equation of the straight line which passes through the point A
(-4, 3) such that the portion of the line between the axes is divided
internally by the point in the ratio 5 : 3 is
9x  20y  96  0
9x  20y  24
20x  9y  53  0
None of these
65. The line segment joining the points (-3, -4) and (1, -2) is ivided by C
y-axis in the ratio
1:3
2:3
 3:1
3:2
66. The area of a triangle with vertices at (-4, -1), (1, 2) and (4, -3) is A
17
16
15
None of these
67. The centroid of a triangle is (2, 7) and two of its vertices are (4, 8) B
and (-2, 6). The third vertex is
(0, 0)
(4, 7) m
(7, 4)
(7, 7)
ntu
68. The equation of the line with slope 3 / 2 and which is concurrent B
with the lines 4x + 3y – 7 = 0 and 8x + 5y – 1 = 0 is
3x  2y  63  0
me

3x  2y  2  0
2y  3x  2  0
None of these
Mo

69. The coordinates of the foot of the perpendicular from the point (2, 3) B
on the line x + y – 11 = 0 are
(-6, 5)
(5, 6)
(-5, 6)
(6, 5)
70. Three vertices of a parallelogram taken in order are (-1, -6), (2, -5) B
and (7, 2). The fourth vertex is
(1, 4)
(4, 1)
(1, 1)
(4, 4)
71. Find the real value of a for which 3i3  2ai2  (1  a)i  5 is real. 2
72. Write the area of the triangle formed by the coordinate axes and the 2
line (sec   tan )x  (sec   tan )y  2.
73. If (, ) be the coordinates of incentre of the triangle whose vertices 3
  
are (4, -2), (-2, 4) and (5, 5), then the value of ?
5
74. If G be the centroid and I be the incentre of the triangle with vertices 1
25
A(-36, 7), B(20, 7) and C(0, -8) and GI  (205) , then the value
3
1
of is
25
75. The point P is equidistant from A(1, 3), B(-3, 5) and C(5, -1), then 5
 PA 
  is
 10 

m
ntu
me
Mo