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How many protons, neutrons and electrons are present in each atom of 31P? [1 mark]
1.
What is the atomic number of a neutral atom which has 51 neutrons and 40 electrons? [1 mark]
2.
A. 40
B. 51
C. 91
D. 131
The table below shows the number of protons, neutrons and electrons present in five species. [1 mark]
3.
A. X and W
B. Y and Z
C. Z and W
D. W and Q
What is the relative atomic mass of an element with the following mass spectrum? [1 mark]
4.
A. 24
B. 25
C. 26
D. 27
5a. Strontium exists as four naturally-occurring isotopes. Calculate the relative atomic mass of strontium to two decimal places from the [2 marks]
following data.
The graph of the first ionization energy plotted against atomic number for the first twenty elements shows periodicity.
5b. Define the term first ionization energy and state what is meant by the term periodicity. [2 marks]
5c. State the electron arrangement of argon and explain why the noble gases, helium, neon and argon show the highest first ionization [3 marks]
energies for their respective periods.
5d. A graph of atomic radius plotted against atomic number shows that the atomic radius decreases across a period. Explain why [1 mark]
chlorine has a smaller atomic radius than sodium.
Explain why a sulfide ion, S2− , is larger than a chloride ion, Cl− . [1 mark]
5e.
Explain why the melting points of the Group 1 metals (Li → Cs) decrease down the group whereas the melting points of the [3 marks]
5f.
Group 7 elements (F → I) increase down the group.
6a. Define the term isotopes. [1 mark]
Describe the structure and bonding in silicon dioxide and carbon dioxide. [4 marks]
6c.
Draw the Lewis structure of NH3, state its shape and deduce and explain the H–N–H bond angle in NH3. [4 marks]
6d.
The graph below shows the boiling points of the hydrides of group 5. Discuss the variation in the boiling points. [4 marks]
6e.
Explain, using diagrams, why CO and NO2 are polar molecules but CO2 is a non-polar molecule. [5 marks]
6f.
Which statement about the species 63Cu2+ and 65Cu+ is correct? [1 mark]
7.
A. Both species have the same number of protons.
31 3−
9.
How many electrons does the ion 15P contain? [1 mark]
A. 12
B. 15
C. 16
D. 18
Iron has three main naturally occurring isotopes which can be investigated using a mass spectrometer.
Calculate the relative atomic mass of iron based on this data, giving your answer to two decimal places.
Describe the bonding in iron and explain the electrical conductivity and malleability of the metal. [4 marks]
10c.
State a balanced equation for the reaction of sodium with water. Include state symbols. [2 marks]
11c.
With reference to electronic arrangements, suggest why the reaction between rubidium and water is more vigorous than that [2 marks]
11d.
between sodium and water.
Describe and explain what you will see if chlorine gas is bubbled through a solution of [3 marks]
11e.
(i) potassium iodide.
A. 64.5
B. 65.0
C. 65.9
D. 66.4
Which quantities are the same for all atoms of chlorine? [1 mark]
13.
I. Number of protons
A. I and II only
D. I, II and III
Which statement about the numbers of protons, electrons and neutrons in an atom is always correct? [1 mark]
14.
A. The number of neutrons minus the number of electrons is zero.
B. The number of protons plus the number of neutrons equals the number of electrons.
A. 24
B. 25
C. Between 24 and 25
D. Between 25 and 26
35Cl and 37
16. Which statements about the isotopes of chlorine, 17 17Cl, are correct? [1 mark]
A. I and II only
D. I, II and III
Isotopes are atoms of the same element with different mass numbers. Two isotopes of cobalt are Co-59 and Co-60.
Deduce the missing information and complete the following table. [2 marks]
17.
18a. Explain why the relative atomic mass of argon is greater than the relative atomic mass of potassium, even though the atomic [1 mark]
number of potassium is greater than the atomic number of argon.
+
18b. Deduce the numbers of protons and electrons in the K ion. [1 mark]
19a. Explain why the relative atomic mass of cobalt is greater than the relative atomic mass of nickel, even though the atomic number of [1 mark]
nickel is greater than the atomic number of cobalt.
2+
19b. Deduce the numbers of protons and electrons in the ion Co . [1 mark]
2+
19c. Deduce the electron configuration for the ion Co . [1 mark]
Carbon and silicon belong to the same group of the periodic table.
20a. State the period numbers of both carbon and silicon. [1 mark]
20b. Describe and compare three features of the structure and bonding in the three allotropes of carbon: diamond, graphite and C 60 [6 marks]
fullerene.
20c. Draw the Lewis structure of CO2 and predict its shape and bond angle. [2 marks]
Describe the structure and bonding in SiO2. [2 marks]
20d.
Explain why silicon dioxide is a solid and carbon dioxide is a gas at room temperature. [2 marks]
20e.
20f. Describe the bonding within the carbon monoxide molecule. [2 marks]
Silicon has three stable isotopes, 28Si, 29Si and 30Si. The heaviest isotope, 30Si, has a percentage abundance of 3.1%. Calculate [2 marks]
20g.
the percentage abundance of the lightest isotope to one decimal place.
The element antimony, Sb, is usually found in nature as its sulfide ore, stibnite, Sb2S3. This ore was used two thousand years ago by
ancient Egyptian women as a cosmetic to darken their eyes and eyelashes.
Calculate the percentage by mass of antimony in a sample of pure stibnite. State your answer to four significant figures. [2 marks]
21a.
Antimony contains two stable isotopes, 121Sb and 123Sb. The relative atomic mass of antimony is given in Table 5 of the Data Booklet.
21b. Calculate the percentage of each isotope in pure antimony. State your answers to three significant figures. [2 marks]
Calculate the percentage of each isotope in pure rubidium. State your answers to three significant figures. [2 marks]
22a.
87Rb . [2 marks]
22b. State the number of electrons and the number of neutrons present in an atom of
Number of electrons:
Number of neutrons:
18O2− ? [1 mark]
23. What is the correct number of each particle in an oxygen ion,
24. Which subatomic particles are located in the nucleus of an atom? [1 mark]
Lithium and boron are elements in period 2 of the periodic table. Lithium occurs in group 1 (the alkali metals) and boron occurs in group
3. Isotopes exist for both elements.
25a. (i) Define the terms atomic number, mass number and isotopes of an element. [10 marks]
Atomic number:
Mass number:
Isotopes of an element:
(iii) Deduce the electron arrangements of the lithium ion, Li+ , and the boron atom, B.
Li+ :
B:
(iv) Naturally occurring boron exists as two isotopes with mass numbers of 10 and 11. Calculate the percentage abundance of the lighter
isotope, using this information and the relative atomic mass of boron in Table 5 of the Data Booklet.
v) Lithium exists as two isotopes with mass numbers of 6 and 7. Deduce the number of protons, electrons and neutrons for each isotope.
Every element has its own unique line emission spectrum.
iii) Deduce the chemical formulas of lithium oxide and iron(II) oxide.
Lithium oxide:
Iron(II) oxide:
+
What are the numbers of neutrons and electrons in the iodine ion, 125I+ ? [1 mark]
27.
What are the numbers of neutrons and electrons in the iodine ion, 125I+ ? [1 mark]
28.
29. Which statements about the isotopes of an element are correct? [1 mark]
A. I and II only
D. I, II and III
24Mg? [1 mark]
30. Which is an isotope of
A.
24Na
11
B. 24Mg2+
21
C. 26Mg
12
D. 22Ne
10
2-methylbutan-2-ol, (CH3)2C(OH)CH2CH3, is a liquid with a smell of camphor that was formerly used as a sedative. One way of
producing it starts with 2-methylbut-2-ene.
Explain whether you would expect 2-methylbutan-2-ol to react with acidified potassium dichromate(VI). [2 marks]
31c.
31d. Explain why 2-methylbut-2-ene is less soluble in water than 2-methylbutan-2-ol. [2 marks]
−1
2-chloro-2-methylbutane contains some molecules with a molar mass of approximately 106 g mol and some with a molar mass of
approximately 108 g mol− 1.
31e. Outline why there are molecules with different molar masses. [1 mark]
2-methylbutan-2-ol, (CH3)2C(OH)CH2CH3, is a liquid with a smell of camphor that was formerly used as a sedative. One way of
producing it starts with 2-methylbut-2-ene.
As well as 2-methylbutan-2-ol, the reaction also produces a small quantity of an optically active isomer, X.
State what optical activity indicates about the structure of the molecule. [1 mark]
32d.
32e. Optical activity can be detected using a polarimeter. Explain how this works. [3 marks]
Deduce the structural formula of X. [1 mark]
32f.
32g. Explain why 2-methylbut-2-ene is less soluble in water than 2-methylbutan-2-ol. [2 marks]
2-methylbutan-2-ol can also be produced by the hydrolysis of 2-chloro-2-methylbutane, (CH3)2CClC 2H5, with aqueous sodium
hydroxide.
Explain the mechanism of this reaction using curly arrows to represent the movement of electron pairs. [4 marks]
32h.
32i. State the rate expression for this reaction and the units of the rate constant. [2 marks]
Suggest why, for some other halogenoalkanes, this hydrolysis is much more effective in alkaline rather than in neutral conditions. [1 mark]
32j.
−1
2-chloro-2-methylbutane contains some molecules with a molar mass of approximately 106 g mol− 1 and some with a molar mass of
−
approximately 108 g mol 1.
Outline why there are molecules with different molar masses. [1 mark]
32k.
2-chloro-2-methylbutane can also be converted into compound Z by a two-stage reaction via compound Y:
32m. State the reagent and any catalyst required for both the formation of Y and the conversion of Y into Z. [3 marks]
Formation of Y:
Conversion of Y into Z:
The element boron has two naturally occurring isotopes, 10B and 11B.
33b. Calculate the percentage abundance of each isotope, given that the relative atomic mass of B is 10.81. [2 marks]
Predict and explain whether the molecules NH3 and BF3 are polar molecules. [2 marks]
33f.
Two stable isotopes of chlorine are 35Cl and 37Cl with mass numbers 35 and 37 respectively.
35 37
Calculate the number of protons, neutrons and electrons in the isotopes 35Cl and 37Cl. [2 marks]
34b.
Using the mass numbers of the two isotopes and the relative atomic mass of chlorine from Table 5 of the Data Booklet, determine [2 marks]
34c.
the percentage abundance of each isotope.
State the balanced chemical equation for the reaction of potassium bromide, KBr(aq), with chlorine, Cl 2(aq). [1 mark]
34f.
Determine the enthalpy change, ΔH, in kJ mol− 1, for stage 1 using average bond enthalpy data from Table 10 of the Data [3 marks]
34h.
Booklet.
Which ion will show the least deflection in a mass spectrometer? [1 mark]
35.
A. 35Cl+
B. 35Cl2+
C. 35Cl35Cl+
D. 35Cl37Cl+
36.
What does 52
24
X represent? [1 mark]
B. 24Mg+
C. 25Mg2+
D. 25Mg+