FULL ORGANIC – Guess Questions – JEE 2020

Choose the correct alternate:-

1. HBr reacts at fastest rate with; c) both of a & b d) none of these
a) 2-Methyl-2-propanol b) propanol 16. Gabriel phhalimide synthesis can be used to
c) 2-propanol d) all at ame rate synthesize - - - - - - - - amines;
2. The compound which on reaction with aq.HNO2 a) prim.aliphatic b) prim. Aromatic
at low temperature produces an oily nitrosoamine c) secondary d) both a & b
is; 17. In the reaction sequence;
a) methyl amine b) ethyl amine Ph-NH2 + NaNO2 → X + CuCN → Y + H2O → Z.(Z) is;
c) diethyl amine d) triethyl amine
a) benzyl amine b) N-methylaniline
3. Carbyl amine test is performed in alc.KOH by
c) benzoic acid d) phenylacetic acid
heating a mixture of;
18. Which of the following doesnot react with acetyl
a) CHCL3 + Ag b) CHX3 + RNH2
chloride ?
c) RX + RNH2 d) RCN + RNH2
a) prim.amine b) sec.amine
4. Chlorobenzene can be separated by reacting
c) tert.amine d) all will react
aniline with;
19. Silver chloride is soluble in;
a) HCl b) CuCl
a) methyl amine b) ammonia
c) Cl2 + anhy.AlCl3 d) HNO2 + CuCl
c) aniline d) all of these
5. Among the following most basic compound is;
20. An unknown amine absorbs 3 mole of iodoform to
a) C6H5-CH2NH2 b) C6H5-NH2
form quat.ammonium salt.The amine is;
c) C6H5-CONH2 d) p-nitroaniline
a) aniline b) ethyl amine
6. Reaction of RCONH2 with mixture of Br2 and
c) benzyl amine d) all of these
KOH gives RNH2 as the main product.The
21. Which of the following nitro compound doesnot show
intermediate involved in reaction is;
tautomerism ?
a) R-CO-NHBr b) R-NHBr
a) nitromethane b) nitrobenzene
c) R-N=C=O d) R-CO-NBr2
c) nitroethane d) all will show
7. Which of the following is strongest base ?
22. Nitrobenzene on electrolytic reduction in weak acidic
a) p-methoxyaniline b) aniline
medium gives;
c) p-nitroaniline d) p-hydroxyaniline
a) aniline b) p-aminophenol
8. Which of the following alkyl halide will be
c) nitrobenzene d) nitrosobenzene
hydrolysed at fastest rate by SN2 mechanism ?
a) (CH3)3Br b) CH2 = CH-CH2Br
23. Which of the following doesnot undergo Friedel-
c) CH3Br d) all at same rate
Craft’s acylation ?
9. Which of the following compound will dissolve in
a) aniline b) N,N-dimethylaniline
an alkali solution after it has undergone reaction
c) nitrobenzene d) all will not show
with Hinsberg reagent ?
24. Which of the following can be used with conc.nitric
a) R2NH b) R-NH2
acid as nitrating mixture for generating NO2+ as
c) R3N d) all of these
electrophile ?
10. To promote electrophilic substitution reaction at
a) H2SO4 b) HCLO4
the nucleus of aniline, aniline is to be reacted first
c) HCl d) HI
with;
25. The amine that can exhibit enetiomerism is;
a) dil.CL b) ethyl alcohol
a) benzenamine b) i-butylamine
c) acetic acid d) acetic anhydride
c) i-propylamine d) none of these
11. Aldehydes having no  hydrogen undergoes;
26. Acetaldoxime on heating with P2O5 forms;
a) Tischenko’s reaction b) Aldol’s rxn
a) ethanenitrile b) methanitrile
c) Reimer Tiemann rxn. d) Cannizaro’s rxn.
c) ethyl carbylamine d) methyl carbylamine
12. C6H6 + A + anhy.AlCl3 → C6H5-CH3 + CL2 + light
27. The reagent with which both aldehydes and ketones
→ (B) + KCN → C6H5-CH2CN + H3O+ → (C).
react easily is/are;
The product (B) in the sequence is;
a) Schiff’s reagent b) Ag+
a) benzoic acid b) aniline
c) Rochelle’s salt d) R-Mg-Br
c) benzal chloride d) none of these
28. The compound that gives positive iodoform test is;
13. C6H5COOC6H5 + mononitra (X). (X) is;
a) pentanol b) pentan-2-one
a) m-C6H4(NO2)COOC6H5
c) pentan-3-one d) pentanal
b) p-C6H4(NO2)COOC6H5
29. When acetaldehyde is heated with fehling’s solution ,it
c) m-C6H5COOC6H4(NO2) d) none of these
gives ppt.of ;
14. C6H5-NO2 + Na3AsO3 / glucose + NaOH → Y.
a) Cu b) CuO
(Y) is
c) Cu2O d) Cu + CuO
a) azobenzene b) azoxybenzene
c) hydrazobenzene d) p-aminophenol
15. RR’C = NOH + H2SO4 → ?. The unknown
product is;
a) RCONHR’ b) R’CONHR

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30. Which of the following will react with aq ,KOH ? 42. Which of the following compound on ozonolysis will
yield acetone?
a) ethyl alcohol b) chlorobenzene
a) 2,3-dimethylbut-2-ene b) but-2-ene
c) benzaldehyde d) all of these
c) isobutylene d) none of these
31. Benzaldehyde can be from oxidation of toluene
by using; 43. Cinnamic acid is produced when benzaldehyde is
condensed with ethanoic anhydride in presence of;
a) acid.KMnO4 b) Cr2O7-2
a) (CH3COO)2Mg b) alc.KOH
c) CrO2Cl2 d) all of these
c) CH3COONa d) none of these
32. A compound (X) of formula C3H8O yields a
compound C3H6O on oxidation.To which of the 44. Which of the following contains sodium citrate ?
following class a compound (X) belongs to; a) Tollen’s reagent b) Fehling’s A
a) aldehyde b) secondary alcohol c) Fehling’s B d) none of these
c) alkene d) tert.alcohol 45. Paraformaldehyde is;
33. Which among the following can be most easily a) (HCHO)n b) (CH3CHO)3
oxidised ?
c) (HCHO)3 d) (CH3CHO)n
a) HCHO b) acetaldehydye
46. Which of the following is most stable towards
c) propionaldehyde d) acetone nucleophilic additions?
34. Which of the following will be obtained when a) benzophenone b) acetaldehyde
crotonaldehyde ( But-2-enal ) is reduced in
presence of Raney Ni ? c) aetophenone d) benzaldehyde
a) butyl alcohol b) butanal 47. Acetamide is treated separately with following
reagents, which one of these would yield methyl
c) but-2-en -1-ol d) butane amine?
35. Phenol doesnot react with; a) PCl5 b) NaOH / CaO
a) sodium bicarbonate b) NaOH c) NaOH / Br2 d) conc.H2SO4
c) KOH d) ferric chloride 48. Which of the following will undergo cannizaro’s
36. Which of the following is/are reducing agent / reaction?

a) formic acid b) acetic acid a) acetaldehyde b) acetone

c) oxalic acid d) both a) & c) c) iso-butyraldehyde d) none of these

37. Acidic strength is more for; 49. Treatment of acetone with Mg followed by acidification
yields;
a) oxalic acid b) malonic acid
a) iso-propyl alcohol b)3,3-dimethylbutanone
c) succinic acid d) butyric acid
c) 2,3-dimethylbut-2-ene d) none of these
38. Electrophile generated by using conc. sulphuric
acid is; 50. When calcium benzoate is distilled, product obtained
is;
a) SO3 b) SO3H+
a) benzoic acid b) benzaldehyde
c) SO2 d) both a) & b)
c) acetophenone d) none of these
39. Which of the following will undergo elimination at
fastest rate ?
a) allyl Iodide b) crotonyl chloride
c) i-propyl chloride d) n-propyl chloride
40. Acetone will form ketal in presence of
dil.HCLwith;
a) ethyl alcohol b) ethylene glycol
c) propyl alcohol d) all of these
41. meta aldehyde is a/an;
a) trimer b) tetramer
c) monomer d) polymer

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ANSWER
FULL ORGANIC

1. A 2. C 3. B 4. D 5. A 6. C 7. A 8. C 9. B 10. D

11. D 12. D 13. D 14. B 15. C 16. A 17. C 18. C 19. D 20. D

21. B 22. A 23. C 24. A 25. D 26. A 27. D 28. B 29. C 30. C

31. C 32. B 33. A 34. B 35. A 36. D 37. A 38. D 39. C 40. B

41. B,D 42. A 43. C 44. D 45. A 46. A 47. C 48. D 49. B 50. D

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