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Prof. N. Venkataramani1, Abeen Bhattacharya2



1 Professor,Department of Metallurgical Engineering & Materials Science, IIT Bombay

2 Student, Department of Metallurgical Engineering & Materials Science, IIT Bombay

Spintronics and its Real-World Applications


Abstract — Spintronics, or spin electronics, is an emerging II. SPINTRONICS
field of basic and applied research in physics and
A. Introduction
engineering that aims to exploit the role played by electron
spin in solid-state materials. Spintronic devices make use Spintronics (a portmanteau meaning spin transport
of spin properties instead of or in addition to electron electronics), also known as spin electronics, is the study of the
charge to carry information thereby offering opportunities intrinsic spin of the electron and its associated magnetic
moment, in addition to its fundamental electronic charge, in
for novel micro-electronic and nano-electronic devices.
solid-state devices. The field of spintronics concerns spin-
This paper reviews the background and current status of
charge coupling in metallic systems; the analogous effects in
this subject, and also some of the applications of
insulators fall into the field of multi-ferroics.
Spintronics
Spintronics fundamentally differs from traditional
electronics in that, in addition to charge state, electron spins
I. INTRODUCTION
are exploited as a further degree of freedom, with implications
The word spintronics—short for spin electronics—was in the efficiency of data storage and transfer. Spintronic
coined in the 1990s to describe devices that take advantage of systems are most often realised in dilute magnetic
“spin,” a quantum-mechanical property of an electron that semiconductors (DMS) and Heusler alloys and are of
takes only two values: spin-up and spin-down. Spintronics particular interest in the field of quantum computing and
research flowered following the discovery of the giant neuromorphic computing.
magnetoresistance (GMR) effect in the late 1980s.

The fundamental underlying spintronics phenomena that B. History


made the spin-valve a reality was discovered while Spintronics emerged from discoveries in the 1980s
researching novel properties of superlattices formed from concerning spin-dependent electron transport phenomena in
combinations of various magnetic and non-magnetic materials solid-state devices. This includes the observation of spin-
based on flowing charge currents through these superlattices. polarised electron injection from a ferromagnetic metal to a
By working at the atomic scale, it was discovered that by normal metal by Johnson and Silsbee (1985) and the discovery
sandwiching a non-magnetic layer of material between two of giant magnetoresistance independently by Albert Fert et al.
magnetic layers, where each of the layers was just a few atoms and Peter Grünberg et al. (1988). The origin of spintronics can
thick, and by applying small magnetic fields, the current be traced to the ferromagnet/superconductor tunnelling
flowing through the sandwich could significantly be changed. experiments pioneered by Meservey and Tedrow and initial
The reason was that within the magnetic layers, the electrical experiments on magnetic tunnel junctions by Julliere in the
current, which was composed of negatively charged electrons, 1970s. The use of semiconductors for spintronics began with
became “spin-polarised”: all the electrons’ spins became the theoretical proposal of a spin field-effect-transistor by
oriented either “up” or “down,” depending on the magnetic Datta and Das in 1990 and of the electric dipole spin
orientation of these layers—just like nanoscopic compass resonance by Rashba in 1960.
needles, which point to either the North or the South Pole.
Small magnetic fields reorient these compass needles. This
C. Theory
effectively created the ability to turn the “spin-polarised”
current on or off—just like a valve. The spin of the electron is an intrinsic angular momentum that
is separate from the angular momentum due to its orbital
The spin valve also created the ability to detect more minute motion. The magnitude of the projection of the electron's spin
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magnetic impulses when flown over a magnetic hard drive. along an arbitrary axis is ℏ, implying that the electron acts as
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This ability allowed for vastly more data to be written to and a fermion by the spin-statistics theorem. Like orbital angular
stored on a hard drive than was possible before the discovery momentum, the spin has an associated magnetic moment, the
of GMR. magnitude of which is expressed as
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3 q does not conserve spin, and can therefore switch an incoming


μ= ℏ spin up state into an outgoing spin down state. Spin de-
2 me phasing is the process wherein a population of electrons with a
common spin state becomes less polarised over time due to
different rates of electron spin precession. In confined
In a solid, the spins of many electrons can act together to structures, spin de-phasing can be suppressed, leading to spin
affect the magnetic and electronic properties of a material, for lifetimes of milliseconds in semiconductor quantum dots at
example endowing it with a permanent magnetic moment as in low temperatures.
a ferromagnet.
Superconductors can enhance central effects in spintronics
In many materials, electron spins are equally present in both such as magnetoresistance effects, spin lifetimes and
the up and the down state, and no transport properties are dissipation less spin-currents
dependent on spin. A spintronic device requires generation or
manipulation of a spin-polarised population of electrons,
resulting in an excess of spin up or spin down electrons. The D. Metal-based Spintronics
polarisation of any spin dependent property X can be written The simplest method of generating a spin-polarised current in
as a metal is to pass the current through a ferromagnetic material.
X↑ − X↓ The most common applications of this effect involve giant
PX = magnetoresistance (GMR) devices. A typical GMR device
X↑ + X↓
consists of at least two layers of ferromagnetic materials
A net spin polarisation can be achieved either through creating separated by a spacer layer. When the two magnetisation
an equilibrium energy split between spin up and spin down. vectors of the ferromagnetic layers are aligned, the electrical
Methods include putting a material in a large magnetic field resistance will be lower (so a higher current flows at constant
(Zeeman effect), the exchange energy present in a ferromagnet voltage) than if the ferromagnetic layers are anti-aligned. This
or forcing the system out of equilibrium. The period of time constitutes a magnetic field sensor.
that such a non-equilibrium population can be maintained is
known as the spin lifetime, τ. Two variants of GMR have been applied in devices: (1)
current-in-plane (CIP), where the electric current flows
In a diffusive conductor, a spin diffusion length λ can be parallel to the layers and (2) current-perpendicular-to-plane
defined as the distance over which a non-equilibrium spin (CPP), where the electric current flows in a direction
population can propagate. Spin lifetimes of conduction perpendicular to the layers.
electrons in metals are relatively short (typically less than 1
nanosecond). An important research area is devoted to Other metal-based spintronics devices:
extending this lifetime to technologically relevant timescales. • Tunnel magnetoresistance (TMR), where CPP transport is
achieved by using quantum-mechanical tunnelling of
electrons through a thin insulator separating ferromagnetic
layers.
• Spin-transfer torque, where a current of spin-polarised
electrons is used to control the magnetisation direction of
ferromagnetic electrodes in the device.
• Spin-wave logic devices carry information in the phase.
Interference and spin-wave scattering can perform logic
operations.

E. Semi-Conductor Based Spintronics

Doped semiconductor materials display dilute


ferromagnetism. In recent years, dilute magnetic oxides
(DMOs) including ZnO based DMOs and TiO2-based DMOs
have been the subject of numerous experimental and
computational investigations. Non-oxide ferromagnetic
A plot showing a spin up, spin down, and the resulting spin
semiconductor sources (like manganese-doped gallium
polarised population of electrons. Inside a spin injector, the
arsenide GaMnAs), increase the interface resistance with a
polarisation is constant, while outside the injector, the
tunnel barrier, or using hot-electron injection.

populations go to equilibrium.
Spin detection in semiconductors has been addressed with
The mechanisms of decay for a spin polarised population can
multiple techniques:
be broadly classified as spin-flip scattering and spin de-
• Faraday/Kerr rotation of transmitted/reflected photons
phasing. Spin-flip scattering is a process inside a solid that
• Circular polarisation analysis of electroluminescence
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• Nonlocal spin valve (adapted from Johnson and Silsbee's IV. APPLICATIONS
work with metals)
A. Spin Transistor
• Ballistic spin filtering
The basic idea of spin transistor, as proposed by Suprio Datt
Because external magnetic fields (and stray fields from and Biswajit Das, is to control the spin the spin orientation by
magnetic contacts) can cause large Hall effects and applying a gate voltage, as shown in fig.3. A spin –FET, as
magnetoresistance in semiconductors (which mimic spin- depicted below, consists of ferromagnetic electrodes and
valve effects), the only conclusive evidence of spin transport semiconductor channels that contain a layer of electrons and a
in semiconductors is demonstration of spin precession and de- gate electrode attached to the semiconductor. The source and
phasing in a magnetic field non-collinear to the injected spin drain electrodes are ferromagnetic (FM) metals. The spin-
orientation, called the Hanle effect polarised electrons are injected from the FM source electrode
(FMs), and after entering the semiconductor channels they
begin to rotate. The rotation can be controlled by an applied
III. MATERIAL SELECTION FOR SPINTRONICS electric field through the gate electrode. If the spin orientation
of the electron channels is aligned to FM drain (FMd)
There are two major criteria for selecting the most electrode, electrons are able to flow into the FM drain
promising materials for semiconductor spintronics. First, the electrode. However, if the spin orientation is flipped in the
ferromagnetism should be retained to practical temperatures electron layer electrons cannot enter the drain electrode. In
(i.e. >300 K). Second, it would be a major advantage if there this way, with the gate electrode the orientation of the electron
were already an existing technology base for the material in spin can be controlled.
other applications. Most of the work in the past has focused on
(Ga, Mn)As and (In, Mn)As. There are indeed major markets
for their host materials in infra-red light-emitting diodes and B. Spin (Magnetic) BJT
lasers and high speed digital electronics (GaAs) and magnetic In a magnetic transistor, magnetised ferromagnetic layers
sensors (InAs). In samples carefully grown single phase by replace the role of n and p type semiconductors. Much like in
molecular beam epitaxy (MBE), the highest Curie a spin-valve, substantial current can flow through parallel
temperatures reported are 110 K for (Ga, Mn)As and 35 K for magnetised ferromagnetic layers. However if say, in a three
(In, Mn)As. For ternary alloys such as (In0.5Ga0.5)0.93Mn layer structure, the middle layer is antiparallel to the two side
0.07As, the Curie temperature is also as low as 110 K. layers; the current flow would be quite restricted, resulting in a
high overall resistance. If two outside layers are pinned and
A tremendous amount of research on these materials the middle layer allowed to be switched by an external
systems has led to some surprising results, such as the very magnetic field, a magnetic transistor could be made, with on
long spin lifetimes and coherence times in GaAs and the and off configurations depending on the orientation of the
ability to achieve spin transfer through a hetero-interface, middle magnetised layer. Magnetic (spin) transistors are good
either of semiconductor–semiconductor or metal- candidates for logic (spin logic).
semiconductor. One of the most effective methods for
investigating spin-polarised transport is by monitoring the
C. Spin Valve with Giant Magneto Resistance
polarised electroluminescence output from a quantum well
light-emitting diode into which the spin current is injected. Spintronic device that currently has wide commercial
Quantum selection rules relating the initial carrier spin application is the spin valve. Most modern hard disk drives
polarisation and the subsequent polarised optical output can employ spin- valves to read each magnetic bit connected on
provide a quantitative measure of the injection efficiency. the spinning platters inside A spin-valve is essentially a spin
“switch” that can be turned on and off by external magnetic
There are a number of essential requirements for achieving fields. Basically it is composed of two ferromagnetic layers
practical spintronic devices in addition to the efficient separated by a very thin non-ferromagnetic layer. When these
electrical injection of spin-polarised carriers. These include the two layers are parallel, electrons can pass through both easily,
ability to transport the carriers with high transmission and when they are anti-parallel, few electrons will penetrate
efficiency within the host semiconductor or conducting oxide, both layers. The principles governing spin-valve operation are
the ability to detect or collect the spin-polarised carriers and to purely quantum mechanical.
be able to control the transport through external means such as
biasing of a gate contact on a transistor structure. The D. Spin LEDs
observation of spin current induced switching in magnetic
Recently, efficient spin injection has been successfully
hetero-structures is an important step in realising practical
demonstrated in all semiconductor tunnel diode structures by
devices. Similarly, spin orbit interaction in a semiconductor
using a spin- polarised DMS as the injector in one case, and
quantum well could be controlled by applying a gate voltage.
using a paramagnetic semiconductor under high magnetic field
Combined with the expected low power capability of
as a spin filter in the other. In such a case, spin-polarised holes
spintronic devices, this should lead to extremely high packing
and unpolarised electronics are injected from either side and
densities for memory elements.
recombine in a quantum well. The polarisation of the injected
holes can be left-circularly polarises light in the
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electroluminescence spectra. Among such devices the simplest but by magnetic storage elements.
seems to be the concept of a light emitting diode (LED) with
one of the contact layers made ferromagnetic by incorporation The elements are formed from two ferromagnetic plates,
of transition metal impurities, a so called spin LED. each of which can hold a magnetic field, separated by a thin
insulating layer. One of the two plates is a permanent magnet
set to a particular polarity; the other's field will change to
E. Magnetic Random Access Memory [MRAM]
match that of an external field. A memory device is built from
You hit the power button on your television and it instantly a grid of such "cells". Reading is accomplished by measuring
comes to life. But do the same thing with your computer and the electrical resistance of the cell. A particular cell is
you have to wait a few minutes while it goes through its boot (typically) selected by powering an associated transistor which
up sequence. Why can't we have a computer that turns on as switches current from a supply line through the cell to ground.
instantly as a television or radio? IBM, in cooperation with Due to the magnetic tunnel effect, the electrical resistance of
Everspin, has launched a Solid State Drive adopting a new the cell changes due to the orientation of the fields in the two
architecture with magnetoresistive RAM (MRAM) write plates. By measuring the resulting current, the resistance
caches instead of capacitor-backed DRAM, that will inside any particular cell can be determined, and from this the
potentially eliminate the boot-up process. Magnetic random polarity of the writable plate. Typically if the two plates have
access memory (MRAM) has the potential to store more data, the same polarity this is considered to mean "0", while if the
access that data faster and use less power than current memory two plates are of opposite polarity the resistance will be higher
technologies. The key to MRAM is that, as its name suggests, and this means "1". On comparison with existing memory
it uses magnetism rather than electrical power to store data. technologies, MRAM is faster than SRAM, have a higher
This is a major leap from dynamic RAM (DRAM), the most storage density than DRAM, the power requirement is less
common type of memory in use today, which requires a than that of DRAM and it is faster than FLASH. MRAM is the
continuous supply of electricity and is terribly inefficient. Memory of the future. If the researches turn up, it will replace
Twenty-five years ago, DRAM overtook ferrite core memory both Volatile and Non Volatile Primary memories.
in the race to rule the PC memory market. Now it looks like
ferromagnetic technology could be making a comeback, with MRAM (Magnetoresistive Random Access Memory) uses
IBM Corp. and Infineon Technologies charging a joint team of electron spin to store data. Memory cells are integrated on an
80 engineers and scientists with the task of making magnetic integrated circuit chip, and the function of the resulting device
RAM (MRAM). is like a semiconductor static RAM (SRAM) chip, with
potentially higher density and the added feature that the data
All modern hard disks are equipped with two different are nonvolatile, that is data are retained with power off.
heads, one for writing and the other for reading. The principle Typical “classic” or “conventional” MRAM uses spin-
of the writing head is quite simple, i.e., generation of a dependent tunnel junction memory cells and magnetic row and
magnetic field as electricity passes through the head. The head column write lines as illustrated.
focuses this magnetic field generated to the area on the disk
surface where the bit is to be written. Conceptually the The spin-dependent tunnel junction produces a large change
technique for reading is the reverse of that of writing, i.e., in resistance depending on the predominant electron spin in a
using electromagnetic induction and it was the technique used storage layer. The tunnel barrier is as thin as a few atomic
in earlier hard disks. But as the storage density increased, it layers--so thin that electrons can “tunnel” through the
became very difficult to read a bit from the disk surface as normally insulating material, causing a resistance change.
there was the interference of magnetic fields from the Row and column magnetic write lines allow data to be written
neighbouring bits. to a selected cell in a two-dimensional array:

A small electrical current is kept flowing through the Data are written by small electrical currents in the write
reading head. When a bit passes 21 under the head, due to the lines that create a magnetic fields, which flip electron spins in
presence of the magnetic field associated with the bit, the the spin-dependent tunnel junction storage layer, thus
electrical resistance of head changes which alters the current changing the junction’s resistance. Data is read by the
flowing through it. This change in the current flow is so tunnelling current or resistance through the tunnel junction.
significant that it can be easily detected. Next generation MRAM could reduce cell size and power
consumption. Potential next-generation designs include
Magnetoresistive Random Access Memory (MRAM) is a SpinMomentum Transfer, Magneto-Thermal MRAM, and
non-volatile computer memory (NVRAM) technology, which Vertical Transport MRAM. Spin-Momentum Transfer (also
has been under development since the 1990s. Continued “Spin-Transfer,” “Spin Injection,” or “Spin Torque Transfer”)
increases in density of existing memory technologies -- MRAM is based on changing the spin of storage electrons
notably Flash RAM and DRAM -- kept MRAM in a niche role directly with an electrical current rather than an induced
in the market, but its proponents believe that the advantages magnetic field. This method has the potential to significantly
are so overwhelming that MRAM will eventually become reduce MRAM write currents, especially with lithographic
dominant. Unlike conventional RAM chip technologies, in feature sizes less than 100 nanometers. M-T MRAM uses a
MRAM data is not stored as electric charge or current flows, combination of magnetic fields and ultra-fast heating from
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ACKNOWLEDGEMENT Phys. 40 2001.
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