Adivis H-023

Adivis H-023 is recently developed acrylic emulsions for high viscosity alkali swellable
associative thickener of the water base paints and inks.
Neutralized viscosity of these products are higher than former thickeners, therefore
dosages to get the same viscosity are lower than former thickeners and it is possible to
select the thickener to get the required paint Rheological properties.
Main advantages of these thickener emulsion are as following.

◇ Paint chemist select the preferred Adivis H-023 to get the required Rheological
properties of paint. Rheological properties of High Viscosity grade Adivis H-023 are as
following.
Properties Adivis H-023180 Adivis H-023201 Adivis H-023203 Adivis H-023206
Associative viscosity in Medium High High High
paints
Paint Flow Thixotropic(High Moderate Moderate Good
(Acrylic binder) M.W.HEC like)
Paint flow Fair Moderate Moderate Good

◇ Paints thickened with Adivis H-023 thickener are highly resistant to attack by
microbes and their enzymes. thereby eliminating viscosity loss. Therefore it can be
possible to design the more biologically stable paints.

◇ Paints thickened with Adivis H-023 thickener is less costly to achieve the same
viscosity than that thickened with HEC.

◇ Paints thickened with Adivis H-023 thickener exhibits no remarkable viscosity change
in long term storage(Especially paints based on styrene/Acrylic copolymer emulsion).
It is stable under tropical and freeze-thaw condition.

◇ Because low dosage is enough to achieve the required viscosity. It is possible to

improve the water sensitivity of paint.
 PHYSICAL PROPERTIES
Properties Adivis H-018 Adivis H-021 Adivis H-023 Adivis H-026 Remarks
Solid contents(%) 29-31 29-31 29-31 29-31
Viscosity(cps at 25oC) 70 Max 70 Max 70 Max 70 Max Brookfield viscometer
PH 2 - 3.5 2 - 3.5 2 - 3.5 2 - 3.5
Density(At 25oC) CA1.05 CA 1.05 CA1.05 CA1.05
Ionic charge Anionic Anionic Anionic Anionic

SELECTION GUIDE
For well understanding of Adivis H-023 associative thickeners, following Diagram will
be helpful compared to the former medium and low viscosity range Adivis H-023
grades.
Former product Adivis H-02365, H-85 and H-15 have many advantages and special
properties for water based paints until now. But paint chemists can have chance to
select the thickener among the more grades of Adivis H-023. One of advantages is
tropical stability of the paint based on high viscosity grade Adivis H-023 in
Styrene/Acrylic binder emulsion.
After tropical stability test, viscosity difference is small compared to former thickener.

High
Viscosity H-021 H-023
H-026

H-018 High Viscosity grade

Associative viscosity

H-015 Medium viscosity grade

H-58
Low
Viscosity Low viscosity grade H-56

High shear viscosity

Thixotropic Good Flow
Adivis H-023 have different Rheological properties in water based paint. If paint
chemist want to design the paints having special rheological properties, paint chemist
could select and combine among the above 4 kinds of Adivis H-023. Because of Adivis
H-023 make the very high viscosity paints, paint chemist could design the paint have
wanted viscosity and rhoelogical properties as using small dosages of HISOL

D. according to following Diagram of selection guide,

Adivis H-018 Adivis H-012 Adivis H- 026

Adivis H-023

High in can viscosity Medium in can viscosity Good paint flow

Thixotropic flow Medium flow High high shear viscosity
Anti-sagging properties Little roller spatter One coat coverage

Adivis H-023 is very similar to Adivis H-021 our former product, but paint flow based on
Adivis H-023 is better than based on Adivis H-021. According to the selection diagram,
paint chemist select and combine the Adivis H-023 to get the required rheological
properties.

MANUFACTURING OF THE PAINTS

When Adivis H-023 thickener emulsions meet the any base, Adivis H-023 thickener
emulsions make gel. To save the dispersing time of Adivis H-023 thickener emulsion, it
is prefer to dilute the Adivis H-023 thickeners with water before adding to the paint and
to add slowly with reasonably good agitation in the tank .
After adding the Adivis H-023 thickener, appropriate amount(CA 10% based on
thickener weight) of base(ammonia or AMP95) should be added to get the PH(Up to
8).
If PH is low, paint viscosity is very high and paint exhibits different rheological
properties.
Adivis H-023 thickener emulsions can be added not only to the grinding stage in order
to raise the viscosity during the grinding but also to the let-down stage in order to get
the final viscosity. But When addition in grinding stage it is prefer to add the AMP 95
than ammonia to maintain the viscosity, because of high temperature of grinding
media, evaporation of neutralizer reduce the viscosity.
SAFETY AND HANDLING
Adivis H-023 thickener emulsions would be slightly irritating the mild skin and eyes.
Avoid contact with skin and eyes. When handling, wear impervious gloves and
goggles. For operation where contact can occur, a safety shower and eyes wash facility
should be available. Handling should be available in well ventilated place.
Use stainless steel or plastic vessel when handling. Store in closed container at 5℃ -
40℃. Further information will be fined in MSDS.
WHITE EXTERIOR PAINT BASED ON Adivis H-023
(Vinyl acetate-acrylic copolymer binder : HISOL VA200)
Control 201 HA726 HA105 HA731
Grind:
Deionized Water 33.5 60 60 60
Propylene glycol 14 14 14 14
SN Dispersant 44S 3 3 3 3
Triton CF10 3 3 3 3
Nopco NXZ 2 2 2 2
Natrosol 250HBR 3% 20 20 20 20
Troysan198 1.5 1.5 1.5 1.5
Tronox CR828 170 170 170 170
Talc#400 60 60 60 60
CaCO3#325 190 190 190 190
Let down :
Nopco NXZ 2 2 2 2
HISOL AC111 350 350 350 350
Deionised Water 30 54.3 54.8 54.8
Natrosol 250HBR 3% 54 - - -
Adivis H-023180 - 3.2 - -
Adivis H-023203 - - 2.8 -
Adivis H-023206 - - - 2.8
Ammonia 2 2 2 2
Coasol 10 10 10 10
HIQUE 821 55 55 55 55
Total 1,000.0 1,000.0 1,000.0 1000.0

PVC(%) 50.3 50.3 50.3 50.3

Viscosity(After over Night)(KU) 89 91 94 94
Tropical Stability
(60oC 5days)(KU) 87 108 113 110
High shear viscosity 0.39 0.45 0.52 0.54
(ICI cone & plate) (Poises)
WHITE INTERIOR PAINT BASED ON Adivis H-023
(Acrylic binder : HISOL AC111)

Control 615 HV721 HV101 HV731

Grind:
Deionized Water 120 120 120 120
SN-Dispersant 44S 2 2 2 2
Triton CF10 1 1 1 1
Nopco NXZ 2 2 2 2
Natrosol 250HBR 3% 50 50 50 50
Troysan198 1.5 1.5 1.5 1.5
Tronox CR828 50 50 50 50
Talc#400 60 60 60 60
CaCO3#325 320 320 320 320
Let down :
Ethylene Glycol 10 10 10 10
Nopco NXZ 2 2 2 2
HISOL VC200(50% NV) 130 130 130 130
Deionised Water 59.5 161.7 162.1 161.9
Natrosol 250HBR 3% 106 - -
Adivis H-018 - 3.8 -
Adivis H-023 - - 3.4
Adivis H-026 - - 3.6
Ammonia 4 4 4 4
Coasol 12 12 12 12
HIQUE 821 70 70 70 70
Total 1,000.0 1,000.0 1,000.0 1000.0

PVC(%) 73 73 73 73
Viscosity(After over Night)(KU) 89 91 91 93
Tropical stability(60oC 5 days) 86 86 87 88
High shear Viscosity(Poises)
(ICI cone & plate viscometer) 0.8 0.88 0.94 0.94
 White exterior paint based on Adivis H-023 thickener

Control 818 D8818 D8821 D8823 D 8826

Grind:
Deionized Water 120 120 120 120 120
SN-Dispersant 44S 1.5 1.5 1.5 1.5 1.5
Triton CF10 0.5 0.5 0.5 0.5 0.5
Nopco NXZ 2 2 2 2 2
Natrosol 250HBR 3% 30 30 30 30 30
Tronox CR828 80 80 80 80 80
Talc#400 80 80 80 80 80
CaCO3#325 260 260 260 260 260
Let down :
Ethylene Glycol 10 10 10 10 10
Deionized Water 51.0 146.6 147.6 147.8 147.2
Natrosol 250HBR 3% 100 - - - -
Adivis H-023180 - 4.4 - - -
Adivis H-023201 - - 3.4 - -
Adivis H-023203 - - - 3.2 -
Adivis H-023206 - - - - 3.8
HISOL AC111 190 190 190 190 190
Troysan 198 3 3 3 3 3
Ammonia 4 4 4 4 4
Coasol 5 5 5 5 5
HIQUE 821 60 60 60 60 60
Total 1,000.0 1,000.0 1,000.0 1000.0 1,000.0

PVC(%) 67.6 68 68 68 68
Viscosity(After over Night)(KU) 99.4 102.3 101.2 100.3 101.4

Tropical stability(60oC 5 days) 108.7 111.9 114.1 113.4 112.2

High shear Viscosity(Poises)
(ICI cone & plate viscometer) 0.52 0.38 0.48 0.48 0.67
 Rheological properties (Exterior paints based on Acrylic binder)

Viscosity vs. Shear rate

100.0

Control 818

10.0 D8818(HISOL D180)

D8821(HISOL D201)
Viscoty(P)

1.0
5 30 1000 10000 12000 27000

0.1 Shear rate(sec-1)

Viscosity vs. Shear rate

100.0

Control 818
10.0
D8823(HISOL D203)

D8826(HISOL D206)
Viscoty(P)

1.0
5 30 1000 10000 12000 27000

0.1 Shear rate(sec-1)

 White interior paint based on Adivis H-023 thickener

Control 806 D8618 D8621 D8623 D 8626

Grind:
Deionized Water 120 120 120 120 120
SN-Dispersant 44S 1.5 1.5 1.5 1.5 1.5
Triton CF10 0.5 0.5 0.5 0.5 0.5
Nopco NXZ 2 2 2 2 2
Natrosol 250HBR 3% 30 30 30 30 30
Tronox CR828 80 80 80 80 80
Talc#400 80 80 80 80 80
CaCO3#325 260 260 260 260 260
Let down :
Ethylene Glycol 10 10 10 10 10
Deionized Water 71.0 144.2 146.4 146.4 145.4
Natrosol 250HBR 3% 80 - - - -
Adivis H-023180 - 6.8 - - -
Adivis H-023201 - - 4.6 - -
Adivis H-023203 - - - 4.6 -
Adivis H-023206 - - - - 5.6
V-200 190 190 190 190 190
Troysan 198 3 3 3 3 3
Ammonia 4 4 4 4 4
Coasol 5 5 5 5 5
HIQUE 821 60 60 60 60 60
Total 1,000.0 1,000.0 1,000.0 1000.0 1,000.0

PVC(%) 66 68.1 66.2 66.3 66.2

Viscosity(After over Night)(KU) 98.9 98.1 101.2 100.3 101.4

Tropical stability(60oC 5 days) 88.2 100.3 114.1 113.4 112.2

High shear Viscosity(Poises)

(ICI cone & plate viscometer) 1.27 1.03 1.04 1.07 1.34
Rheological properties : Interior paints based on Vinylacete-Acrylic binder

Object 3

Object 4
 Comparison with Urethane thickener(S* co) Comparison with Urethane thickener(S* co)
(Exterior paint) (Interior paint)
E7601 E7602 E7603 H5701 H5702 H5703
Grind Grind
Deionized Water: 120 120 120 Deionized Water: 120 120 120
SN-Dispersant 44S 1.5 1.5 1.5 SN-Dispersant 44S 1.5 1.5 1.5
Triton CF10 0.5 0.5 0.5 Triton CF10 0.5 0.5 0.5
Nopco NXZ 2 2 2 Nopco NXZ 2 2 2
Natrosol 250HBR 3% 65 65 65 Natrosol 250HBR 3% 65 65 65
Tronox CR828 70 70 70 Tronox CR828 50 50 50
Talc#400 80 80 80 Talc#400 60 60 60
CaCO3#325 210 210 210 CaCO3#325 320 320 320
Alsilate W 60 60 60 Alsilate W
Let down : Let down :
Ethylene Glycol 10 10 10 Ethylene Glycol 10 10 10
Deionized Water 108.4 101.8 112.4 Deionized Water 142 129 152
H-600(P) 7.6 - - H-600(P) 15 - -
L-150(P) - 14.2 - L-150(P) - 28 5
Adivis H-023206 - - 3.6 Adivis H-023206 - - 5
AC111 190 190 190 AC111 130 130 130
Troysan198 3 3 3 Troysan198 3 3 3
Nopco NXZ 3 3 3 Nopco NXZ 3 3 3
Ammonia 4 4 4 Ammonia 4 4 4
Coasol 5 5 5 Coasol 4 4 4
HIQUE 821 60 60 60 HIQUE 821 70 70 70
Total 1,000.0 1,000.0 1,000.0 Total 1,000.0 1,000.0 1,000.0

PVC(%) 63 63 63 PVC(%) 74 74 74
Viscosity 94.4 91.4 92.8 Viscosity 106.1 109.3 107.3
(After over Night) (KU) (After over Night) (KU)

Tropycal Stability 88.1 85.8 85.4 Tropycal Stability 불가 99.5 111.8

(60°C 5days)(KU) (60°C 5days)(KU)

High shear viscosity 1.91 1.63 1.21 High shear viscosity 0.60 0.83 0.67
(ICI cone & plate) (Poises) (ICI cone & plate) (Poises)
Comparison with Urethane thickener (S* co)
(Exterior paint)

Object 5

Comparison with Urethane thickener (S* co)

(Interior paint)

Object 6
 Comparison with Urethane thickener(R* co) Comparison with Urethane thickener(R* co)
(Medium PVC paint) (Semi gloss paint)
N1751 N1752 N1753 H5701 H5702 H5703
Grind Grind
Deionized Water: 60 60 60 Deionized Water: 164 164 164
Propylene glycol 14 14 14 Propylene glycol 20 20 20
SN-Dispersant 44S 3 3 3 SN-Dispersant 44S 4 4 4
Triton CF10 3 3 3 Triton CF10 1 1 1
Nopco NXZ 2 2 2 Nopco 8034L 0.5 0.5 0.5
Natrosol 250HBR 3% 20 20 20 AMP95 1 1 1
Troysan198 1.5 1.5 1.5 Troysan198 1 1 1
Tronox CR828 170 170 170 Tronox CR828 160 160 160
Talc#400 60 60 60
CaCO3#325 190 190 190
Let down : Let down :
Nopco NXZ 2 2 2 Triton CF10 3 3 3
Deionized Water 54.5 44.5 54.3 Nopco 8034L 0.6 0.6 0.6
RM825 2 - - HISOL AC111 446 446 446
RM2020 - 12 - Deionized Water: 121.3 84.9 123.1
TT615 1 1 - RM825 - - 5.8
Adivis H-023206 - - 3.2 RM2020 - 44 -
HISOL AC111 350 350 350 TT615 - 2 2
Ammonia 2 2 2 Adivis H-023206 9.6 9.6 9.6
Coasol 10 10 10 Ammonia 2 2 2
HIQUE 821 55 55 55 Texanol 8 8 8
Propylene glycol 8 8 8
HIQUE 280S 50 50 50
Total 1,000.0 1,000.0 1,000.0 Total 1,000.0 1,000.0 1,000.0

PVC(%) 52.1 51.9 52.1 PVC(%) 25.4 24.5 25.6

Viscosity 103.8 106.5 106.4 Viscosity 99.1 96.5 98.9
(After over Night) (KU) (After over Night) (KU)

Tropycal Stability 104.2 108.1 108.3 Tropycal Stability 100.6 97.2 99.4
(60°C 5days)(KU) (60°C 5days)(KU)
High shear viscosity 0.51 1.48 0.82 High shear viscosity 0.52 1.52 0.25
(ICI cone & plate) (Poises) (ICI cone & plate) (Poises)
Comparison with Urethane thickener (R*)
(Medium PVC paint)

Object 7

Comparison with Urethane thickener (R*)

(Semi gloss paint)

Object 8