Para Gas Ideal

3⁄
2𝜋𝑚𝑘𝑇 2 𝜕 ln 𝑞𝑡𝑟𝑎𝑛𝑠 3
𝑞𝑡𝑟𝑎𝑛𝑠 (𝑉, 𝑇) = 𝑉 ( ) → ( ) =
ℎ2 𝜕𝑇 𝑉,𝑁 2𝑇
𝑙𝑒𝑣𝑒𝑙
𝜕 ln 𝑞𝑒𝑙𝑒𝑐 ∑𝑙𝑒𝑣𝑒𝑙 𝑔𝑖 𝜀𝑖 𝑒 −𝛽𝜀𝑖
𝑞𝑒𝑙𝑒𝑐 (𝑇) = ∑ 𝑔𝑖 𝑒 −𝛽𝜀𝑖 → ( ) = 𝑖=1
𝜕𝑇 𝑉,𝑁 𝑞𝑒𝑙𝑒𝑐 𝑘𝑇 2
𝑖=1

𝜋 1 ⁄2 𝑇 3 ⁄2
( )
𝜎 Θ𝑟𝑜𝑡
𝜋 1⁄2 𝑇 3⁄2 𝜕 ln 𝑞𝑟𝑜𝑡 3
𝑞𝑟𝑜𝑡 = 1⁄2 →( ) =
𝜎Θ𝑟𝑜𝑡,𝐴 Θ𝑟𝑜𝑡,𝐶 𝜕𝑇 𝑉,𝑁 2𝑇
𝜋 1 ⁄ 2 𝑇 3 ⁄2
1 ⁄2
{𝜎(Θ𝑟𝑜𝑡,𝐴 Θ𝑟𝑜𝑡,𝐵 Θ𝑟𝑜𝑡,𝐶 )
𝛼 𝛼
𝑒 −Θ𝑣𝑖𝑏,𝑗 ⁄2𝑇 𝜕 ln 𝑞𝑣𝑖𝑏 Θ𝑣𝑖𝑏,𝑗 1 1
𝑞𝑣𝑖𝑏 (𝑇) = ∏ → ( ) = ∑ 2 ( + −Θ ⁄𝑇 )
1 − 𝑒 −Θ𝑣𝑖𝑏,𝑗 ⁄𝑇 𝜕𝑇 𝑉,𝑁 𝑇 2 𝑒 𝑣𝑖𝑏,𝑗 −1
𝑗=1 𝑗=1

𝜕 ln 𝑞 𝜕 ln 𝑞𝑡𝑟𝑎𝑛𝑠 𝜕 ln 𝑞𝑒𝑙𝑒𝑐 𝜕 ln 𝑞𝑟𝑜𝑡 𝜕 ln 𝑞𝑣𝑖𝑏

𝑞 = 𝑞𝑡𝑟𝑎𝑛𝑠 𝑞𝑒𝑙𝑒𝑐 𝑞𝑟𝑜𝑡 𝑞𝑣𝑖𝑏 → ( ) = ( ) +( ) +( ) +( )
𝜕𝑇 𝑉,𝑁 𝜕𝑇 𝑉,𝑁 𝜕𝑇 𝑉,𝑁 𝜕𝑇 𝑉,𝑁 𝜕𝑇 𝑉,𝑁

𝜕 ln 𝑞
𝑆𝑎𝑏𝑖𝑒𝑛𝑑𝑜 𝑞𝑢é ( ) 𝑁 𝑘𝑇 2 = 𝑈
𝜕𝑇 𝑉,𝑁 𝑜

𝑇𝑜𝑚𝑎𝑛𝑑𝑜 𝑁𝑜 = 𝑁𝐴 → 𝑘𝑁𝐴 = 𝑅

Las propiedades molares serian

𝑙𝑒𝑣𝑒𝑙 𝛼
1 1 1
𝑈 = 𝑅 [3𝑇 + ∑ 𝑔𝑖 𝜀𝑖 𝑒 −𝛽𝜀𝑖 + ∑ Θ𝑣𝑖𝑏,𝑗 ( + Θ ⁄𝑇 )]
𝑞𝑒𝑙𝑒𝑐 𝑘 2 𝑒 𝑣𝑖𝑏,𝑗 −1
𝑖=1 𝑗=1

2
𝑙𝑒𝑣𝑒𝑙 𝑙𝑒𝑣𝑒𝑙 𝛼
𝜕𝑈 𝑔𝑖 𝜀𝑖 𝑒 −𝛽𝜀𝑖 𝑔𝑖 𝜀𝑖2 𝑒 −𝛽𝜀𝑖 Θ𝑣𝑖𝑏,𝑗 𝑒 Θ𝑣𝑖𝑏,𝑗 ⁄𝑇
( ) = 𝐶𝑣 = 𝑅 [3 − ( ∑ ) +∑ + ∑ ]
𝜕𝑇 𝑞𝑒𝑙𝑒𝑐 𝑘𝑇 𝑞𝑒𝑙𝑒𝑐 𝑘2 𝑇 2 𝑇 2 (𝑒 Θ𝑣𝑖𝑏,𝑗⁄𝑇 − 1)2
𝑖=1 𝑖=1 𝑗=1

𝑙𝑒𝑣𝑒𝑙 𝛼
1 1 1
𝐻 = 𝑅 [4𝑇 + ∑ 𝑔𝑖 𝜀𝑖 𝑒 −𝛽𝜀𝑖 + ∑ Θ𝑣𝑖𝑏,𝑗 ( + Θ ⁄𝑇 )]
𝑞𝑒𝑙𝑒𝑐 𝑘 2 𝑒 𝑣𝑖𝑏,𝑗 −1
𝑖=1 𝑗=1

2
𝑙𝑒𝑣𝑒𝑙 𝑙𝑒𝑣𝑒𝑙 𝛼
𝜕𝐻 𝑔𝑖 𝜀𝑖 𝑒 −𝛽𝜀𝑖 𝑔𝑖 𝜀𝑖2 𝑒 −𝛽𝜀𝑖 Θ𝑣𝑖𝑏,𝑗 2 𝑒 −Θ𝑣𝑖𝑏,𝑗⁄𝑇
( ) = 𝐶𝑝 = 𝑅 [4 − ( ∑ ) + ∑ + ∑ ( ) 2]
𝜕𝑇 𝑞𝑒𝑙𝑒𝑐 𝑘𝑇 𝑞𝑒𝑙𝑒𝑐 𝑘 2 𝑇 2 𝑇 (1 − 𝑒 −Θ𝑣𝑖𝑏,𝑗⁄𝑇 )
𝑖=1 𝑖=1 𝑗=1

𝑈 𝐻 𝑞
𝑆= + 𝑅 ∙ 𝑙𝑛𝑄 → 𝑆 = + 𝑅 ln
𝑇 𝑇 𝑁𝐴

𝑙𝑒𝑣𝑒𝑙 𝛼 3⁄ 𝑙𝑒𝑣𝑒𝑙 𝛼
𝑆 1 Θ𝑣𝑖𝑏,𝑗 1 1 𝑉 2𝜋𝑚𝑘𝑇 2 𝑒 −Θ𝑣𝑖𝑏,𝑗 ⁄2𝑇
= 4+ ∑ 𝑔𝑖 𝜀𝑖 𝑒 −𝛽𝜀𝑖 + ∑ ( + Θ ⁄𝑇 ) + ln ( ( ) ( ∑ 𝑔𝑖 𝑒 −𝛽𝜀𝑖
) 𝑞𝑟𝑜𝑡 (∏ ))
𝑅 𝑞𝑒𝑙𝑒𝑐 𝑘𝑇 𝑇 2 𝑒 𝑣𝑖𝑏,𝑗 − 1 𝑁𝐴 ℎ2 1 − 𝑒 −Θ𝑣𝑖𝑏,𝑗 ⁄𝑇
𝑖=1 𝑗=1 𝑖=1 𝑗=1
 Simplificando
𝜕 ln 𝑞𝑒𝑙𝑒𝑐 𝐷𝑒
𝑞𝑒𝑙𝑒𝑐 (𝑇) = 𝑔1 𝑒 −𝛽𝐷𝑒 → ( ) = 2
𝜕𝑇 𝑉,𝑁 𝑘𝑇

𝛼
𝐷𝑒 1 1
𝑈 = 𝑅 [3𝑇 + + ∑ Θ𝑣𝑖𝑏,𝑗 ( + Θ ⁄𝑇 )]
𝑘 2 𝑒 𝑣𝑖𝑏,𝑗 − 1
𝑗=1

𝛼
𝜕𝑈 Θ𝑣𝑖𝑏,𝑗 2 𝑒 −Θ𝑣𝑖𝑏,𝑗⁄𝑇
( ) = 𝐶𝑣 = 𝑅 [3 + ∑ ( ) 2]
𝜕𝑇 𝑇 (1 − 𝑒 −Θ𝑣𝑖𝑏,𝑗⁄𝑇 )
𝑗=1

𝛼
𝐷𝑒 1 1
𝐻 = 𝑅 [4𝑇 + + ∑ Θ𝑣𝑖𝑏,𝑗 ( + Θ ⁄𝑇 )]
𝑘 2 𝑒 𝑣𝑖𝑏,𝑗 − 1
𝑗=1

𝛼
𝜕𝐻 Θ𝑣𝑖𝑏,𝑗 2 𝑒 −Θ𝑣𝑖𝑏,𝑗⁄𝑇
( ) = 𝐶𝑝 = 𝑅 [4 + ∑ ( ) 2]
𝜕𝑇 𝑇 (1 − 𝑒 −Θ𝑣𝑖𝑏,𝑗⁄𝑇 )
𝑗=1

𝛼 3⁄ 𝛼
𝑆 𝐷𝑒 Θ𝑣𝑖𝑏,𝑗 1 1 2𝜋𝑚𝑘𝑇 2 𝑉𝑔 𝑒 −𝛽𝐷𝑒
1 𝑒 −Θ𝑣𝑖𝑏,𝑗⁄2𝑇
= 4+ +∑ ( + Θ ⁄𝑇 ) + ln (( ) ∙ 𝑞𝑟𝑜𝑡 ∙ ∏ )
𝑅 𝑘𝑇 𝑇 2 𝑒 𝑣𝑖𝑏,𝑗 −1 ℎ2 𝑁𝐴 1 − 𝑒 −Θ𝑣𝑖𝑏,𝑗 ⁄𝑇
𝑗=1 𝑗=1