Pers.

Antoine
𝐿𝑜𝑔 𝑃�°=𝐴−𝐵/█(𝐶+𝑇@)
A B C P = mmhg
Methanol 8.08097 1582.271 239.726 T = °C
Ethanol 7.5867 1281.59 193.768
1-Propanol 8.37895 1788.02 227.438
2-Propanol 8.87829 2010.32 252.636
Water 8.07131 1730.63 233.426

Pt
Pt(mmHg) TBP(°C) TDP(°C)
760 84.1284858101 88.763806409 T
950 89.9664270931 94.5797800955
1140 94.8975014082 99.4871002793
1330 99.1862524866 103.7510537977
1520 102.975886605 107.5287726121
1710 106.396417628 110.9646100602 T
1900 109.517204208 114.0796245809
2090 112.389274055 116.9467103808 Zf
2280 115.052759016 119.6053733596 Methanol 0.1
2470 117.55915396 122.0858667299 Ethanol 0.2
1-Propanol 0.2
2-Propanol 0.3
125 Water 0.2
120

115

110

105 T
Suhu

100 Zf
Methanol 0.1
95
Ethanol 0.2
90 1-Propanol 0.2
85 2-Propanol 0.3
80
Water 0.2
500 700 900 1100 1300 1500 1700 1900 2100 2300 2500
Tekanan
TBP TDP T
Zf
Methanol 0.1
Ethanol 0.2
1-Propanol 0.2
2-Propanol 0.3
Water 0.2
 T
Zf
Methanol 0.1
Ethanol 0.2
1-Propanol 0.2
2-Propanol 0.3
Water 0.2

T
Zf
Methanol 0.1
Ethanol 0.2
1-Propanol 0.2
2-Propanol 0.3
Water 0.2

T
Zf
Methanol 0.1
Ethanol 0.2
1-Propanol 0.2
2-Propanol 0.3
Water 0.2

T
Zf
Methanol 0.1
Ethanol 0.2
1-Propanol 0.2
2-Propanol 0.3
Water 0.2

T
Zf
Methanol 0.1
Ethanol 0.2
1-Propanol 0.2
2-Propanol 0.3
Water 0.2

T
Zf
Methanol 0.1
Ethanol 0.2
1-Propanol 0.2
2-Propanol 0.3
Water 0.2

T
Zf
Methanol 0.1
Ethanol 0.2
1-Propanol 0.2
2-Propanol 0.3
Water 0.2
 1 1.25 1.5 1.75 2 2.25 2.5
760 950 1140 1330 1520 1710 1900
50 °C

84.1284858101 Pt = 760mmHg

Xi log Pi° Pi° Ki Yi

0.1 3.1952232547 1567.557 2.062574587 0.20625746
0.2 2.9749468277 943.9453 1.242033287 0.24840666
0.2 2.6401427745 436.6594 0.57455179 0.11491036
0.3 2.9087769287 810.5446 1.066506082 0.31995182
0.2 2.621442096 418.2559 0.550336736 0.11006735
Total 0.99959365

89.9664270931 Pt 950
Xi log Pi° Pi° Ki Yi
0.1 3.2817363204 1913.094 2.013783208 0.20137832
0.2 3.0698353631 1174.452 1.236265523 0.2472531
0.2 2.7456952393 556.7949 0.586099882 0.11721998
0.3 3.0104973604 1024.466 1.078384793 0.32351544
0.2 2.7198241425 524.595 0.552205258 0.11044105
Total 0.99980789

94.8975014082 Pt 1140
Xi log Pi° Pi° Ki Yi
0.1 3.3524587229 2251.431 1.974939843 0.19749398
0.2 3.1469938566 1402.794 1.230520931 0.24610419
0.2 2.8318725227 679.0043 0.595617804 0.11912356
0.3 3.0937541442 1240.95 1.088552283 0.32656568
0.2 2.8001978421 631.2448 0.553723545 0.11074471
Total 1.00003213
 99.1862524866 Pt 1330
Xi log Pi° Pi° Ki Yi
0.1 3.4122954732 2584.018 1.942870402 0.19428704
0.2 3.2119896515 1629.257 1.225005421 0.24500108
0.2 2.9047086159 802.9872 0.603749765 0.12074995
0.3 3.1642682581 1459.716 1.097530548 0.32925916
0.2 2.868164334 738.1835 0.555025188 0.11100504
Total 1.00030228

102.9758866049 Pt 1520
Xi log Pi° Pi° Ki Yi
0.1 3.4639221755 2910.196 1.91460235 0.19146023
0.2 3.2678578676 1852.925 1.21902968 0.24380594
0.2 2.967494633 927.886 0.610451331 0.12209027
0.3 3.2251606314 1679.425 1.104884913 0.33146547
0.2 2.9267788041 844.8484 0.555821339 0.11116427
Total 0.99998618

106.396417628 Pt 1710
Xi log Pi° Pi° Ki Yi
0.1 3.5095498336 3232.584 1.890400063 0.18904001
0.2 3.3170733396 2075.264 1.213604643 0.24272093
0.2 3.0229414353 1054.245 0.616517381 0.12330348
0.3 3.2790184543 1901.159 1.111788926 0.33353668
0.2 2.9785618168 951.8353 0.556628843 0.11132577
Total 0.99992686

109.5172042084 Pt 1900
Xi log Pi° Pi° Ki Yi
0.1 3.5503993806 3551.398 1.869156992 0.1869157
0.2 3.3610075422 2296.189 1.208520276 0.24170406
0.2 3.072547316 1181.809 0.62200477 0.12440095
0.3 3.3272691154 2124.561 1.118189769 0.33545693
0.2 3.024905876 1059.024 0.557381147 0.11147623
Total 0.99995387

112.3892740553 Pt 2090
Xi log Pi° Pi° Ki Yi
0.1 3.5873535153 3866.816 1.850151232 0.18501512
0.2 3.4006488799 2515.642 1.203656578 0.24073132
0.2 3.117394685 1310.372 0.626972365 0.12539447
0.3 3.3709453231 2349.337 1.124084701 0.33722541
0.2 3.0668173421 1166.319 0.558047358 0.11160947
Total 0.99997579

115.0527590158 Pt 2280
Xi log Pi° Pi° Ki Yi
 0.1 3.6210891312 4179.161 1.832965472 0.18329655
0.2 3.4367522954 2733.709 1.198995211 0.23979904
0.2 3.1583127917 1439.835 0.631506674 0.12630133
0.3 3.4108397429 2575.371 1.129548533 0.33886456
0.2 3.1050675671 1273.701 0.558640889 0.11172818
Total 0.99998966

117.5591539597 Pt 2470
Xi log Pi° Pi° Ki Yi
0.1 3.6523756896 4491.337 1.818355257 0.18183553
0.2 3.4701621918 2952.312 1.195267851 0.23905357
0.2 3.1962405791 1571.233 0.636126702 0.12722534
0.3 3.4478569473 2804.51 1.135429031 0.34062871
0.2 3.1405316452 1382.075 0.559544578 0.11190892
Total 1.00065206
 2.75 3 3.25 atm
2090 2280 2470 mmHg
 Pers. Antoine
𝐿𝑜𝑔 𝑃�°=𝐴−𝐵/█(𝐶+𝑇@)
P = mmhg
T = °C
A B C
Methanol 8.08097 1582.271 239.726
Ethanol 7.5867 1281.59 193.768
1-Propanol 8.37895 1788.02 227.438
2-Propanol 8.87829 2010.32 252.636
Water 8.07131 1730.63 233.426

Pt atm mmHg
1 760
1.25 950
1.5 1140
1.75 1330
2 1520
2.25 1710
2.5 1900
2.75 2090
3 2280
3.25 2470
 T 88.76381 P 760
Zf Yi log Pi° Pi° Ki Xi
Methanol 0.1 0.1 3.264166 1837.241 2.417422 0.041366
Ethanol 0.2 0.2 3.050609 1123.593 1.478412 0.13528
1-Propanol 0.2 0.2 2.72427 529.993 0.697359 0.286796
2-Propanol 0.3 0.3 2.989827 976.8489 1.285327 0.233404
Water 0.2 0.2 2.699849 501.0129 0.659228 0.303385
1.000232

T 94.57978 P 950
Zf Yi log Pi° Pi° Ki Xi
Methanol 0.1 0.1 3.347965 2228.254 2.345531 0.042634
Ethanol 0.2 0.2 3.142102 1387.081 1.460085 0.136978
1-Propanol 0.2 0.2 2.826399 670.501 0.705791 0.28337
2-Propanol 0.3 0.3 3.088461 1225.917 1.290439 0.232479
Water 0.2 0.2 2.795092 623.867 0.656702 0.304552
1.000014

T 99.4871 P 1140
Zf Yi log Pi° Pi° Ki Xi
Methanol 0.1 0.1 3.416436 2608.772 2.288396 0.043699
Ethanol 0.2 0.2 3.216478 1646.181 1.444019 0.138502
1-Propanol 0.2 0.2 2.909746 812.3556 0.712593 0.280665
2-Propanol 0.3 0.3 3.16915 1476.217 1.294927 0.231673
Water 0.2 0.2 2.872866 746.219 0.654578 0.30554
1.00008

T 103.7511 P 1330
Zf Yi log Pi° Pi° Ki Xi
Methanol 0.1 0.1 3.474342 2980.863 2.24125 0.044618
Ethanol 0.2 0.2 3.27911 1901.561 1.429745 0.139885
1-Propanol 0.2 0.2 2.98016 955.3455 0.718305 0.278433
2-Propanol 0.3 0.3 3.237457 1727.653 1.298987 0.230949
Water 0.2 0.2 2.938606 868.1725 0.652761 0.306391
1.000276

T 107.5288 P 1520
Zf Yi log Pi° Pi° Ki Xi
Methanol 0.1 0.1 3.524457 3345.466 2.200965 0.045435
Ethanol 0.2 0.2 3.33312 2153.375 1.416694 0.141174
1-Propanol 0.2 0.2 3.041047 1099.126 0.723109 0.276583
2-Propanol 0.3 0.3 3.296623 1979.805 1.302504 0.230326
Water 0.2 0.2 2.995475 989.636 0.651076 0.307184
 1.000701

T 110.9646 P 1710
Zf Yi log Pi° Pi° Ki Xi
Methanol 0.1 0.1 3.569098 3707.647 2.168215 0.046121
Ethanol 0.2 0.2 3.381079 2404.798 1.406314 0.142216
1-Propanol 0.2 0.2 3.095244 1245.213 0.728195 0.274652
2-Propanol 0.3 0.3 3.349366 2235.457 1.307285 0.229483
Water 0.2 0.2 3.046115 1112.026 0.650308 0.307547
1.000018

T 114.0796 P 1900
Zf Yi log Pi° Pi° Ki Xi
Methanol 0.1 0.1 3.608822 4062.771 2.1383 0.046766
Ethanol 0.2 0.2 3.423634 2652.369 1.395984 0.143268
1-Propanol 0.2 0.2 3.143437 1391.352 0.73229 0.273116
2-Propanol 0.3 0.3 3.396331 2490.755 1.310924 0.228846
Water 0.2 0.2 3.09116 1233.56 0.649242 0.308051
1.000048

T 116.9467 P 2090
Zf Yi log Pi° Pi° Ki Xi
Methanol 0.1 0.1 3.644771 4413.38 2.111665 0.047356
Ethanol 0.2 0.2 3.462048 2897.665 1.386443 0.144254
1-Propanol 0.2 0.2 3.187024 1538.239 0.735999 0.271739
2-Propanol 0.3 0.3 3.438858 2746.996 1.314352 0.228249
Water 0.2 0.2 3.131913 1354.917 0.648286 0.308506
1.000105

T 119.6054 P 2280
Zf Yi log Pi° Pi° Ki Xi
Methanol 0.1 0.1 3.677594 4759.862 2.087659 0.047901
Ethanol 0.2 0.2 3.497042 3140.811 1.377549 0.145185
1-Propanol 0.2 0.2 3.226799 1685.771 0.739373 0.270499
2-Propanol 0.3 0.3 3.477708 3004.057 1.317569 0.227692
Water 0.2 0.2 3.169111 1476.084 0.647405 0.308925
1.000203

T 122.0859 P 2470
Zf Yi log Pi° Pi° Ki Xi
Methanol 0.1 0.1 3.707783 5102.498 2.065789 0.048408
Ethanol 0.2 0.2 3.529159 3381.887 1.369185 0.146072
1-Propanol 0.2 0.2 3.263362 1833.844 0.742447 0.26938
2-Propanol 0.3 0.3 3.513458 3261.802 1.320568 0.227175
Water 0.2 0.2 3.203315 1597.037 0.646574 0.309323
1.000357
 A B C
Methanol 8.08097 1582.271 239.726
Ethanol 7.5867 1281.59 193.768
1-Propanol 8.37895 1788.02 227.438
2-Propanol 8.87829 2010.32 252.636
Water 8.07131 1730.63 233.426

T v.s V/F
88.5
88
87.5
87
86.5
86
85.5
85
84.5
84
83.5
0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9
TBP 84.12849
TDP 88.76381
V/F 0.176294
T 85 Pt
Zi log Pi° Pi°
Methanol 0.1 3.208336 1615.607
Ethanol 0.2 2.989365 975.8085
T V/F 1-Propanol 0.2 2.656151 453.0547
85 0.176294 2-Propanol 0.3 2.924186 839.8188
86 0.377172 Water 0.2 2.636358 432.8706
87 0.600215
88 0.817744

V/F 0.377172
T 86 Pt
Zi log Pi° Pi°
Methanol 0.1 3.223295 1672.227
Ethanol 0.2 3.005797 1013.438
1-Propanol 0.2 2.674409 472.5075
2-Propanol 0.3 2.941768 874.5169
Water 0.2 2.653373 450.1661

V/F 0.600215
T 87 Pt
Zi log Pi° Pi°
Methanol 0.1 3.238163 1730.465
Ethanol 0.2 3.022113 1052.235
1-Propanol 0.2 2.692551 492.6639
2-Propanol 0.3 2.959247 910.4315
Water 0.2 2.670281 468.0383

V/F 0.817744
T 88 Pt
Zi log Pi° Pi°
Methanol 0.1 3.25294 1790.358
Ethanol 0.2 3.038313 1092.226
1-Propanol 0.2 2.710578 513.5441
2-Propanol 0.3 2.976624 947.5971
Water 0.2 2.687085 486.5021
 760
Ki Xi Yi
2.125799 0.08344 0.177376
1.283959 0.190465 0.24455
0.596125 0.215332 0.128365
1.105025 0.294546 0.325481
0.569567 0.216423 0.123267
1.000206 0.999038

760
Ki Xi Yi
2.200298 0.068836 0.151461
1.333471 0.177655 0.236898
0.62172 0.233284 0.145038
1.15068 0.283867 0.32664
0.592324 0.236341 0.13999
0.999984 1.000027

760
Ki Xi Yi
2.276928 0.056611 0.1289
1.38452 0.162497 0.22498
0.648242 0.253527 0.164347
1.197936 0.268143 0.321219
0.61584 0.259936 0.160079
1.000714 0.999524

760
Ki Xi Yi
2.355734 0.047424 0.111718
1.43714 0.147333 0.211738
0.675716 0.272176 0.183914
1.246838 0.249615 0.31123
0.640134 0.283398 0.181413
0.999946 1.000012
Ethanol 7.5867 1281.59 193.768 78,37
1-Propanol 8.37895 1788.02 227.438 97

Pt 760
T Log Pa0 Log Pb0 Pa0 Pb0
97 3.1790966874 2.8678199844 1510.41638217 737.598431301
95 3.1485697363 2.8336358621 1407.8932808 681.766821224
93 3.1176169782 2.7990250223 1311.04312719 629.542453534
91 3.0862294415 2.7639794249 1219.63377176 580.736903899
89 3.0543979008 2.7284908263 1133.43834426 535.168849188
87 3.0221128676 2.6925507734 1052.23530074 492.663937409
85 2.9893645813 2.6561505966 975.808465146 453.054654572
83 2.9561429992 2.6192814027 903.947065392 416.180188651
81 2.9224377861 2.5819340681 836.445763898 381.886290836
79 2.8882383036 2.5440992308 773.104682362 350.025134243

100

90
Suhu

80

70
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
Xa , Ya

T vs Xa T vs Ya

Pt 950
T Log Pa0 Log Pb0 Pa0 Pb0
97 3.1790966874 2.8678199844 1510.41638217 737.598431301
95 3.1485697363 2.8336358621 1407.8932808 681.766821224
93 3.1176169782 2.7990250223 1311.04312719 629.542453534
91 3.0862294415 2.7639794249 1219.63377176 580.736903899
89 3.0543979008 2.7284908263 1133.43834426 535.168849188
87 3.0221128676 2.6925507734 1052.23530074 492.663937409
85 2.9893645813 2.6561505966 975.808465146 453.054654572
83 2.9561429992 2.6192814027 903.947065392 416.180188651
81 2.9224377861 2.5819340681 836.445763898 381.886290836
79 2.8882383036 2.5440992308 773.104682362 350.025134243
 100

90

80

Suhu
70

60

50
0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1 1.1 1.2 1.3 1.4 1.5
Xa, Ya

T vs Xa T vs Ya

Pt 1140
T Log Pa0 Log Pb0 Pa0 Pb0
97 3.1790966874 2.8678199844 1510.41638217 737.598431301
95 3.1485697363 2.8336358621 1407.8932808 681.766821224
93 3.1176169782 2.7990250223 1311.04312719 629.542453534
91 3.0862294415 2.7639794249 1219.63377176 580.736903899
89 3.0543979008 2.7284908263 1133.43834426 535.168849188
87 3.0221128676 2.6925507734 1052.23530074 492.663937409
85 2.9893645813 2.6561505966 975.808465146 453.054654572
83 2.9561429992 2.6192814027 903.947065392 416.180188651
81 2.9224377861 2.5819340681 836.445763898 381.886290836
79 2.8882383036 2.5440992308 773.104682362 350.025134243

100
95
90
85
Suhu

80
75
70
65
60
0.4 0.6 0.8 1 1.2 1.4 1.6 1.8 2
Xa, Ya

T vs Xa T vs Ya
 120

100

80
Suhu

60

40

20

0
0 0.2 0.4 0.6 0.8 1

Xa, Ya

T vs Xa (1) T vs Ya (1) T vs Xa (2) T vs Ya

 mmHg
Ka Kb Xa Ya
1.9873899765 0.9705242517 0.0289868638 0.0576082026
1.852491159 0.8970616069 0.1077404325 0.1995881986 TBP
1.7250567463 0.8283453336 0.1914268782 0.3302222277 Slope(M)
1.6047812786 0.7641275051 0.2805822115 0.4502730801 Intercept(B)
1.4913662424 0.7041695384 0.3758024647 0.5604591097 X
1.3845201326 0.6482420229 0.4777515079 0.661456581
1.2839585068 0.5961245455 0.5871699818 0.753901893 Y = MX + B
1.1894040334 0.5476055114 0.7048855257 0.8383936874
1.1005865314 0.5024819616 0.8318245061 0.9154948479
1.0172430031 0.4605593872 0.9690254884 0.9857343979

0.7 0.8 0.9 1

mmHg
Ka Kb Xa Ya
1.5899119812 0.7764194014 0.2748403663 0.4369719913
1.4819929272 0.7176492855 0.3694028433 0.5474524011 TBP
1.380045397 0.6626762669 0.4702233745 0.6489296035 Slope(M)
1.2838250229 0.6113020041 0.5779698018 0.7420120941 Intercept(B)
1.193092994 0.5633356307 0.6933850952 0.8272728992 X
1.107616106 0.5185936183 0.817297118 0.9052514514
1.0271668054 0.4768996364 0.9506297905 0.976455365 Y = MX + B
0.9515232267 0.4380844091 1.0944158712 1.0413621211
0.8804692252 0.4019855693 1.249811615 1.1004206643
0.8137944025 0.3684475097 1.4181136111 1.1540529188
1.1 1.2 1.3 1.4 1.5

Ka Kb Xa Ya
1.324926651 0.6470161678 0.5206938688 0.6898811838
1.234994106 0.5980410712 0.6310652542 0.7793618694 TBP
1.1500378309 0.5522302224 0.7490198707 0.8614011874 Slope(M)
1.0698541858 0.5094183368 0.8753573921 0.93650477 Intercept(B)
0.9942441616 0.4694463589 1.0109677257 1.0051487589 X
0.9230134217 0.4321613486 1.1568427282 1.0677813649
0.8559723378 0.3974163637 1.3140895992 1.1248243464 Y = MX + B
0.7929360223 0.3650703409 1.4839462167 1.1766744103
0.7337243543 0.3349879744 1.667798724 1.2237045419
0.6781620021 0.3070395914 1.8672017337 1.266265266

1.6 1.8 2
 0.8 1 1.2 1.4 1.6 1.8 2

Xa, Ya

Ya (1) T vs Xa (2) T vs Ya (2) T vs Xa (3) T vs Ya (3)

 TDP
-19.1286 Slope(M) -19.2721
96.71346 Intercept(B) 99.08751
0.5 X 0.5

87.14915 Y = MX + B 89.45145

TBP
-15.7216 Slope(M) -24.9332
100.4454 Intercept(B) 108.8944
0.5 X 0.5

92.58457 Y = MX + B 96.42786
 TBP
-13.3446 Slope(M) -31.0042
103.0487 Intercept(B) 119.412
0.5 X 0.5

96.3764 Y = MX + B 103.9099
 V/F 0.25
T 86.5788 Pt
Ethanol 7.5867 1281.59 193.768 78,37 Zi log Pi° Pi°
1-Propanol 8.37895 1788.02 227.438 97 Methanol 0.5 3.015255 1035.75
Ethanol 0.5 2.684923 484.087

V/F 0.25
T 93.2905 Pt
Zi log Pi° Pi°
Methanol 0.5 3.12214 1324.767
Ethanol 0.5 2.804079 636.9115

V/F 0.25
T 98.228 Pt
Zi log Pi° Pi°
Methanol 0.5 3.197633 1576.279
Ethanol 0.5 2.888601 773.7505
 760
Ki Xi Yi
1.362829 0.590707 0.772122
0.636957 0.409239 0.227717
0.999946 0.999839

950
Ki Xi Yi
1.394492 0.598623 0.634655
0.670433 0.417608 0.365316
1.016231 0.99997

1140
Ki Xi Yi
1.3827 0.595675 0.630981
0.678728 0.419682 0.369002
1.015357 0.999983