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Ritwik Das*, Ritesh Kant Gupta, Tapapriya Gupta, Chiranjit Maji, Hirok Chaudhuri
ABSTRACT
It is well recognized by different geophysical & geochemical techniques such as Audio
Magnetuteluric survey, Magnetuteluric survey, geochemical survey that Bakreswar-Tantloi area
is a potential geothermal province located in eastern part of India. We have estimated that
reservoir temperature lies in the range of 126 0C-139 0C. In this paper we mostly discussed about
different aspects on geothermal power plant technologies. Here we propose pilot scale Kalina
cycle based binary power plant utilizing geothermal fluids (hot water) as hot fluid. A steam and
gas separator will be used to separate the water and gas phase. Organic fluid of lower boiling
temperature may be used as working fluid for the proposed binary cycle power plant. Our study
shows that the Kalina cycle will be appropriate for power production from this low enthalpy
geothermal system at Bakreswar. Here we have discussed in detailed about the Kalina cycle and
proposed operational aspect of the power plant.
Keywords: Bakreswar Geothermal area, Geothermometry, Binary cycle power plant, Kalina
cycle
1. INTRODUCTION
Eco-friendly power generation techniques stand as a challenge in front of the scientific
community of the world. In today’s world the main focus is on the issue of climate change
resulted out of the deliberating pollution caused by conventional fossil fuels based power plants.
Therefore, the developed countries and developing countries are giving attention towards
reduction of production of electricity by coal, gas etc. as much as possible and to produce
electricity by renewable and green energy resources. A quick switch over to the non-
conventional methods of producing power such as geothermal, solar, wind etc. is very much
required in the current scenario. It is to be noted that geothermal energy is an excellent example
of renewable energy and can be a promising source of electricity generation. Geothermal power
is independent of weather condition and it is grid interactive also. Geothermal energy is a clean
and green energy technology. Many countries throughout the globe already developed
geothermal power plant, however the electricity production using geothermal heat is still ignored
in India [1].
Geothermal energy is the natural heat of the earth’s interior. This energy is produced from decay
of radioactive elements such as uranium, thorium, potassium etc. which are stored in the rock
structure of the earth’s crust. This is radiogenic heat. The other source, namely primordial heat
source, is supplying heat from the inception of the earth’s about 4.5 billion years ago [2]. Based
on the surface manifestation of geothermal resources in terms of hot springs, geothermal systems
are divided into three categories (i) high (> 200 0C), (ii) medium (100-200 0C) and (iii) low (<
100 0C) enthalpy geothermal systems based on the temperature of the hot water at surface [3].
India’s geothermal zones are mostly medium to low enthalpy systems. These are manifested as
hot springs and scattered throughout the country. In comparison with the other geothermal zones
in India, Bakreswar [23.87 0N, 87.37 0E] and Tantloi [24.03 0N, 87.28 0E] seem to be promising
and these are located at Birbhum district of West Bengal and Dumka district of Jharkhand
respectively [4]. In fact several hot springs are found in cluster in the Bakreswar-Tantloi
geothermal area. The geothermal gradient (90 0C/km) of this area is almost three times higher
than the average global geothermal gradient (30 0C/km) [5]. Since the maximum hot spring water
temperature at Bakreswar is 67 0C, therefore it can be treated as a low enthalpy geothermal
system.
There are different techniques such as Audio Magnetotelluric survey, Magnetotelluric survey and
geochemical survey which are already performed to explore the potential of Bakreswar
geothermal area [6]. Recently we have estimated the reservoir temperature which lies in the
range of 126-129 0C. In this paper we have discussed about some well-known geothermal power
generation techniques and focused on the Kalina cycle based binary power plant for production
of power from the aforesaid geothermal system. Moreover the paper describes our research
activities through different geochemical and geophysical techniques to explore the potential of
the Bakreswar-Tantloi geothermal area.
Figure 3: Schematic flow diagram of single flash steam (Modified after [11])
Figure 4: Schematic flow diagram of double flash steam (Modified after [11])
3.4. PROPOSED BINARY TYPE KALINA CYCLE BASED POWER PLANTS
Hot fluid coming out from the production well will pass through separator, heat exchanger,
preheater and then again send back to the reservoir through injection well. If the geothermal
fluid temperature is less than 150 0C it becomes difficult to harness power using a flash-
steam plant which can efficiently and economically deliver power. If the geothermal system
is of kind of low enthalpy system, it is always better to use Kalina cycle based binary power
plant to harness power. Organic fluid, ammonia-water mixture is used as working fluid in
binary type Kalina cycle.
In binary cycle power plant different cycles are used to generate power from hot fluid. One of
them is Rankine cycle which is classified into many categories such as water Rankine, organic
Rankine, and other multi-fluids cycles. The working fluids for the Rankine cycle are composed
of water, organic fluids of different kinds, or mixture of multi-fluids or binary fluids. The
Organic Rankine Cycle (ORC) which uses refrigerants or other organic working fluids with
lower boiling points as working fluid is widely used in power production technique from a wide
range of low and medium temperature heat sources including geothermal, solar thermal, ocean
thermal and industrial waste heat. The selection of working fluid is based on the temperature of
the heat sources. Based on the temperature of the reservoir at Bakreswar we are proposing Kalina
cycle for power generation. The Kalina cycle is a thermodynamic cycle that works on the same
Rankine cycle but uses a mixture of ammonia and water as the working fluid. Because of the
particular thermodynamic properties of the working fluid, the shape of the Kalina cycle diagram
is different from the ORC diagram. A typical Kalina cycle diagram for power generation is
shown below in Fig. 6.
Table I: Geochemical and geophysical characteristics of hot spring waters and gases at
Bakreswar geothermal area as measured by Chaudhuri et al. [14]
222Rn 222Rn He
Sl. Spring Temp. pH (spring (spring (spring
No. (0C) water) gas) gas)
kBq/m3 kBq/m3 vol%
1 Agnikunda 69.0 9.2 38.9±3 830±48 1.46
(230 52/ 50.0// N; 870 22/ 41.9// E)
2 Kharkunda 66.0 9.3 46.9±5 850±42 1.42
(230 52/ 50.4// N; 870 22/ 42.0// E)
3 Bhairabkunda 62.2 9.3 34.7±4 377±32 1.12
(230 52/ 49.4// N; 870 22/ 41.1// E)
Table III: Chemical characteristics of hot spring waters at Bakreswar and Tantloi
HCO3 (ppm)
Measurement
(ppm)
NO32- (ppm)
SO42- (ppm)
Spec. Cond.
EC at 25°C
SiO2 (ppm)
Ca2+ (ppm)
TDS (mg/l)
B- (ppm)
Na+ (ppm)
Cl- (ppm)
Li+ (ppm)
K+ (ppm)
Hardness
F- (ppm)
(μS/cm)
(ppm)
Total
No.
pH
-
2-
CO 3
124.8
315.0
<0.2
10.7
26.0
70.0
92.0
26.0
10.0
2.29
87.0
2.0
5.0
2.0
<1
1
105.6
255.0
<0.2
10.7
36.0
46.0
55.0
38.0
12.5
0.26
1.45
81.0
2.0
5.0
<1
2
106.2
260.0
<0.2
43.0
31.0
56.0
12.5
0.28
1.34
81.0
NA
NA
9.6
5.0
<1
3
5.2. GEOTHERMOMETRY
Moreover we have performed geothermometry study of the Bakreswar-Tantloi geothermal area.
Geothermometers helps to estimate the temperature of under earth fluid reservoir. This
geothermometer are classified in different categories such as silica (quartz and chalcedony),
Na/K, Na-K-Ca, Na/Li, Li/Mg, K/Mg ratios and many more. Here investigation was made
through (A) silica geothermometer and (B) Na-K-Ca geothermometer since temperature of the
hot spring water is restricted to 67 0C (surface manifestation only), whereas the other
geothermometers are applicable for high temperature hydrothermal waters. Details of the
estimation related to geothermometer applied in case of Bakreswar and Tantloi is described in
Table IV.
Table IV: Different types of geothermometers applied during investigation
0
Quartz , (applying θ ( C) =[1309/5.19-log SiO2 ]-273.15 as described by
no steam loss
Fournier [15]
Silica criteria)
geo-
0
thermometer Quartz , (applying θ ( C) =[1522/5.75-log SiO2 ]-273.15 as described by
max. steam loss
Fournier [15]
criteria)
0 1/2
Na-K-Ca θ ( C) =[1647/log (Na/K) + β {log(Ca /Na) + 2.06}+2.47 ]- 273.15
geo- 0
β =4/3 for t <100 C
thermometer 0
=1/3 for t >100 C as described by Fournier and Truesdell [16]
Table I & Table II are showing values of temperature, pH and chemical compositions which
were measured at Bakreswar-Tantloi area. Temperature varies in the range of 37 0C - 69 0C and
48 0C-69 0C reported in Table I & Table II. The hydrothermal waters are alkaline in nature with
pH values 7.5-9.3 and 10.4-10.7 reported in Table I & Table II. The TDS of the samples are in
the range of 255-315 mg/l. Electrical conductance (EC) ranges from 451-552 μS/cm. SiO2
content is moderate to high i.e. 81-87 ppm. The spring waters are low in K+ (1.34-2.29 ppm), low
in Ca2+ content (0.26-2.00 ppm), low in (31-70 ppm), low in (26-38 ppm) and
moderate to high , (56-99 ppm) and the waters contain high , (10-12.5 ppm).
The estimated reservoir temperature at Bakreswar spring and Tantloi spring 1 and Tantloi spring
2 are in the range of 126-129 0C, 123-125 0C and 123-125 0C respectively using silica
geothermometer. On the other hand these values are 104 0C, 139 0C and 133 0C in case of
Bakreswar spring and Tantloi spring 1 and Tantloi spring 2 respectively using Na-K-Ca
geothermometer.
6. CONCLUSION
Our experimental and analytical observations clearly say that the Bakreswar-Tantloi geothermal
area has a sustainable heat reservoir. Before installation of a power plant the primary concern is
the source of heat. From this point of view the heat source is reliable and that can be exploited
for long time. Since our study area is one of the low temperature geothermal systems, the binary
type Kalina cycle power plant will be suitable for the power production instead of having lower
efficiency. Binary-cycle technology is the most efficient solution to produce electricity from
such low temperature resources.
7. ACKNOWLADGEMENT
The authors acknowledge the financial support and institutional support from National
Institute of Technology Durgapur. Authors are grateful to Geothermal Division, GSI, Lucknow
for their assistance in analyzing silica content of the water samples.
REFERENCES