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Introduction
1. Rheological phenomena
Newtonian flow
2. Governing equations
3. Solving Newtonian flow problems
Rheology
4. Standard flows
5. Rheometry I. Continuous shear
6. Rheometry II. Oscillatory shear
Constitutive equations
7. Generalized Newtonian Fluid
8. Generalized Linear Viscoelastic Fluid
Non-Newtonian flows
9. Solving Non-Newtonian flow problems
FJ Rubio Hernández
GNF
-NO MEMORY
-INSTANTANEOUS SHEAR RATE
()
τ (t) = η γ! γ!(t)
A single example
⎡ ⎤
()
τ (t) = −η ⎢γ! t + 0.8γ! t − t0 ⎥
⎣ ⎦ ( )
Viscoelastic Maxwell´s model
Differential form ∂τ
τ +λ = −ηγ!
∂t
λ is the relaxation time
1 tλ
e
λ
t − (t −t ´)
⎡η ⎤
τ (t ) = − ∫ ⎢ e ⎥ γ! (t´) dt´
Integral form λ
−∞ ⎣
λ ⎦
3
Morrison, Faith A.-Understanding Rheology-Oxford University Press (2001)
Generalized Viscoelastic Maxwell´s model
t − (t − t ´ )
⎡ ⎛η ⎞
N ⎤
τ (t ) = − ∫ ⎢∑ ⎜⎜ ⎟⎟e k
⎥ γ! (t´) dt´
λk
⎢
−∞ ⎣ k =1 ⎝ λ k ⎠ ⎥⎦
5
Generalized Linear Viscoelastic model
t
τ (t ) = − ∫ G (t − t´)γ! (t´) dt´
−∞