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NON-NEWTONIAN FLOWS AND RHEOLOGY

Introduction
1. Rheological phenomena

Newtonian flow
2. Governing equations
3. Solving Newtonian flow problems

Rheology
4. Standard flows
5. Rheometry I. Continuous shear
6. Rheometry II. Oscillatory shear

Constitutive equations
7. Generalized Newtonian Fluid
8. Generalized Linear Viscoelastic Fluid

Non-Newtonian flows
9. Solving Non-Newtonian flow problems

FJ Rubio Hernández
Shear rheometers and usual geometries

Parallel disks Cone and plate

Concentric cylinders 2
Oscillatory Shear

γ! γ γ = γ 0senωt
t γ! = γ 0ω cos ωt
τ
γ! γ
Hookean Solid γ = γ 0senωt
t τ = Gγ 0senωt

γ
γ!
τ Newtonian Liquid γ! = γ 0ω cos ωt
t τ = ηγ 0ω cos ωt
Oscillatory Shear
Viscoelastic

γ
γ!
τ

τ 21 (t ) = τ 0 sen(ωt + δ )
τ 21 (t ) = τ 0 sen(ωt + δ ) = τ 0 [senωt cos δ + cos ωt senδ ] = (τ 0 cos δ )senωt + (τ 0 senδ )cos ωt

τ0
G´(ω ) = cos δ Storage modulus
γ0

τ0
G´´(ω ) = senδ Loss modulus
γ0
Oscillatory Shear

Test I: Amplitude sweep

logG´

log G´´

log γ
LVEL
Oscillatory Shear

Test II: Frequency sweep

logG´

log G´´

log ω

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