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Our Objective
Qualitative Analysis
Our objective is to determine ofpresent
the anion Anions
in the given salt.
The Theory
What is Qualitative Inorganic Analysis?
The qualitative inorganic analysis is a method of analytical chemistry that seeks to find
out the elemental composition of inorganic compounds through various reagents. It is
mainly focused on detection of ions in an aqueous solution, so the substances in other
states need to be converted into an aqueous solution before starting the experiment.
The procedure for detecting ions (cations and anions) in aqueous solutions are called
Cation Analysis and Anion Analysis.
CO32-, S2-, NO2- and SO32- react with dil. H2SO4 to give out CO2, H2S, NO2 and SO2 gases
respectively. These gases on identification indicate the nature of the anion present in
the salt.
Cl-,Br-,I-,NO3- and C2O42- and CH3COO- react with conc. H2SO4 but not with dil. H2SO4 to
produce characteristic gases.
SO42- and PO43- react neither with dil H2SO4 nor with conc. H2SO4. These are, therefore,
identified by individual tests.
Thus, these anions may be identified by performing the following tests below:
1) Dil. H2SO4 Tests
Treat a pinch of the salt with dil. H2SO4 and identify the gas evolved.
Chemical Reactions Involved in Dil.H2SO4 Test:
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11/20/2019 Qualitative Analysis of Anions (Theory) : Class 11 : Chemistry : Amrita Online Lab
Dilute H2SO4 decomposes carbonates, sulphides, sulphites and nitrites in cold to give
gases. These gases on identification indicate the nature of the anion present in the salt.
(a) Carbonate: On treating the solid carbonate, CO2 is given off in the cold with brisk
effervescence.
(b) Sulphide: Sulphides when treated with dil. H2SO4 give H2S gas.
(c) Sulphite: On heating solid sulphite with dil.H2SO4, SO2 gas is evolved
(d) Nitrite: On treating solid nitrite with dil. H2SO4, nitric oxide (NO) gas is evolved which
readly gives brown fumes of NO2 with the oxygen of the air.
(b) Bromides: Bromide salts react with conc. H2SO4 to evolve bromine gas.
(c) Iodides: Iodide salts react with conc. H2SO4 to evolve vapours of iodine.
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11/20/2019 Qualitative Analysis of Anions (Theory) : Class 11 : Chemistry : Amrita Online Lab
(d) Nitrates: Upon reaction with conc.H2SO4 nitrates evolve NO2 gas.
(e) Acetates: Acetates react with conc. H2SO4 to produce vapours of acetic acid.
(f) Oxalates: Oxalates salts react with conc. H2SO4 to evolve a mixture of carbon dioxide
and carbon monoxide.
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11/20/2019 Qualitative Analysis of Anions (Theory) : Class 11 : Chemistry : Amrita Online Lab
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11/20/2019 Qualitative Analysis of Anions (Theory) : Class 11 : Chemistry : Amrita Online Lab
The overall reaction is the reduction of nitrate ion by iron (II) which reduced to iron (I)
and formation of a nitrosonium complex where nitric oxide is oxidised to NO+.
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11/20/2019 Qualitative Analysis of Anions (Theory) : Class 11 : Chemistry : Amrita Online Lab
When bromide salts react with manganese dioxide and concentrated sulphuric acid,
bromine gas is liberated.
Note: Carbon tetrachloride, cyclohexane, chloroform etc can be used instead of carbon
disulphide.
Confirmation of Iodide (I-)
(a) Silver nitrate test
Iodides on reaction with silver nitrate solution forms an yellow precipitate of silver iodide
which is insoluble in ammonium hydroxide.
Note: Carbon tetrachloride, cyclohexane, chloroform etc can be used instead of carbon
disulphide.
Confirmation of Acetate (CH3COO-)
(a) Oxalic acid test
Oxalic acid reacts with acetate salt to form acetic acid which has a characteristic vinegar
like smell.
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11/20/2019 Qualitative Analysis of Anions (Theory) : Class 11 : Chemistry : Amrita Online Lab
Note: To prepare magnesia mixture, add solid NH4Cl to magnesium chloride solution.
Boil, cool and add NH4OH till a strong smell of ammonia ia obtained.
Learning Outcomes:
Students understand different types of anions.
Students understand various tests to identify the anion present in a given salt.
Students understand the chemical reactions and their balanced equations that takes
place during each test.
Students acquire the skill to perform the experiment in the real lab once they
understand different steps in the procedure.
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Nedungadi P., Raman R. & McGregor M. (2013, October). Enhanced STEM learning with
Online Labs: Empirical study comparing physical labs, tablets and desktops. In Frontiers
in Education Conference, 2013 IEEE (pp. 1585-1590). IEEE.
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