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ABSTRACT
The mechanical properties of Nitinol 60, 60 w/o Ni, 40 from corrosion attack if not protected and though
w/oTi (55 a/o Ni, 45 a/o Ti) are sufficiently attractive to electrically conductive they are also highly magnetic. In
warrant its consideration as a lubricated spacecraft addition, when used as bearing rolling elements, their
triboelement. The ability to lubricate Nitinol 60 by the high density leads to high centrifugal forces and limited
oils usually used on spacecraft mechanisms—Pennzane fatigue life. These considerations have driven the search
2001A, Krytox 143AC and Castrol 815Z - was and development of alternate bearing and mechanical
experimentally determined. These oils were run in the component alloys, namely stainless steels and ceramics.
boundary lubrication regime for Nitinol 60 balls running Stainless steels such as 440C are widely used in the
against a 440C steel counterface in the vacuum spiral bearing and gear industry where corrosion resistance and
orbit tribometer. Test results consisting of the coefficient high hardness are required. These martensitic stainless
of friction versus time (friction traces) and relative steels are reasonably low cost, easy to machine prior to
degradation rates are presented. Contrary to the inability heat treatment and are dimensionally stable. When
to successfully lubricate other metal alloys with high prepared through vacuum melting processes, they
titanium content, it was found that Nitinol 60 is able to achieve very uniform, fully dense microstructures which
be lubricated by these oils. Overall, the results presented lead to fine surface finishes and good fatigue behavior.
here indicate that Nitinol 60 is a credible candidate Despite being referred to as stainless, however, the 400
material for spacecraft bearing applications. series martensitic steels are prone to corrosion and are
more accurately referred to as corrosion-resistant alloys
1. INTRODUCTION rather than stainless. They are also highly magnetic
which can be problematic in certain applications.
Binary nickel-titanium (NiTi) alloys are in widespread
use in the medical and dental industries in applications Silicon nitride ceramics, on the other hand, are
where their biocompatibility and unique superelastic or essentially corrosion proof. They can be polished to very
Shape Memory Effect (SME) characteristics are readily fine surface roughness and are quite wear resistant.
exploited [1,2]. In the present paper, we present evidence Silicon nitride’s low density compared to steels also
that NiTi alloys can be tailored to avoid shape memory makes it ideal for ultra high-speed applications because
or superelastic behavior and that such alloys display lower centrifugal stresses result. These attributes make
excellent tribological properties under oil-lubricated silicon nitride the material of choice for high stiffness,
contact conditions. high load, high-speed bearings and for applications that
include corrosive conditions and aggressive sliding
Materials for high performance bearings, gears and other environments. Such applications include bearings for gas
mechanical components require a number of specific turbine hot sections, cryogenic oxidizer turbopumps and
properties and characteristics. Among these key components for diesel engine fuel injection systems.
attributes are high strength and hardness, high thermal Though nonmagnetic, silicon nitride is an electrical
conductivity, and the ability to be manufactured to very insulator. It is also more expensive to manufacture than
high levels of precision with regards to final dimensions steels owing to the complexity and cost of the high
and surface finish. In addition, excellent corrosion temperature, high pressure powder metallurgy
resistance and good tribological properties are often of processing required. Silicon nitride’s low thermal
importance especially for applications in extreme expansion coefficient can present challenges in
environments. applications involving wide temperature variations.
Traditional tool steel based bearing materials, such as This paper assesses the feasibility of using NITINOL 60
M50 and 52100 enjoy widespread application due to (60 w/o Ni, 40 w/o Ti (55 a/o Ni, 45 a/o Ti)) for bearings
their high hardness, ease of manufacture and good and mechanical components. NITINOL 60, when
tribological properties. However, these alloys suffer appropriately heat-treated, does not exhibit SME
__________________________________________________________________________________________
Proc. ‘13th European Space Mechanisms and Tribology Symposium – ESMATS 2009’, Vienna, Austria
23–25 September 2009 (ESA SP-670, July 2009)
properties at normal ambient and anticipated use
temperatures and is dimensionally stable. It has high
hardness when properly heat-treated and yet can be
readily machined prior to final heat treatment. Like
silicon nitride, NITINOL 60 is nonmagnetic and is
intrinsically highly resistant to corrosion. Unlike
ceramics, NITINOL 60 is electrically conductive.