You are on page 1of 78

Safety Manual

Operational Information and Safety


Precautions for General Equipment

Issue B Rev 1

Date of Issue: July 2016

Sonardyne International Limited T. +44 (0) 1252 872288


Blackbushe Business Park F. +44 (0) 1252 876100
Yateley, Hampshire E. support@sonardyne.com
GU46 6GD, United Kingdom www.sonardyne.com
Operational Information and Safety Safety Manual
Precautions for General Equipment Issue B1

© 2012–2016 Sonardyne International Limited. All rights reserved.


This Safety Manual is the copyright and intellectual property right of Sonardyne International Limited
(“Sonardyne”) and is provided solely for the customer’s use of the Sonardyne equipment as described
in this user manual and in accordance with Sonardyne’s then prevailing terms and conditions of sale.
This user manual has been compiled to the best of Sonardyne’s knowledge and belief, but no
representation, warranty (whether express or implied) or guarantee is made to any persons or legal
entities as to the accuracy, reliability or completeness of the information contained in this user manual.
This user manual contains the proprietary, confidential information of Sonardyne and other third parties
and as such may not be used, disclosed or placed in the public domain (by whatever means) by the
customer except expressly in accordance with and subject to the above referenced terms and
conditions of sale.
The copyright and any and all intellectual property rights of any and all third parties which may be
referenced in this user manual or which may have provided proprietary products and/or software
and/or documentation (in whatever format) to Sonardyne in respect of the Sonardyne equipment as
described in this user manual are hereby duly acknowledged. The provision of any and all such
products and/or software and/or documentation by Sonardyne shall be subject to and in accordance
with the relevant third parties’ terms and conditions or the Sonardyne then prevailing conditions of sale,
as appropriate.
The Sonardyne equipment described in this user manual is protected by various UK and US Patents
and other patents internationally and registered trademarks of Sonardyne International Limited.

2
Operational Information and Safety Safety Manual
Precautions for General Equipment Issue B1

Contacting the Sonardyne Support Team


24-hour Emergency Telephone Helpline: +44 (0) 1252 877600

The Sonardyne 24-hour helpline is answered at the UK Headquarters during normal office hours
(08:00 to 17:00). Outside these hours, your call is automatically transferred to an agency, which logs
the details of your emergency and alerts the appropriate Sonardyne personnel.
Our aim is to make sure emergency requests are dealt with immediately during office hours, and are
responded to within 30 minutes at all other times.
Please note the helpline is for emergency use only.
If you require non-emergency product support, please contact your nearest Sonardyne office.
Alternatively, contact the Sonardyne Head Office:
Sonardyne International Ltd
Blackbushe Business Park
Yateley
Hampshire
GU46 6GD
United Kingdom
Telephone: +44 (0) 1252 872288
Fax: +44 (0) 1252 876100
Email: support@sonardyne.com
Note
Email and telephone support is available during normal UK office hours (08:00 to 17:00).

3
Operational Information and Safety Safety Manual
Precautions for General Equipment Issue B1

Contents
Contacting the Sonardyne Support Team 3
Amendment History 7
Section 1 – Introduction 8
1.1 General Operational Safety Precautions 8
1.2 General Safety Precautions 8
1.2.1 Hazard Appreciation 8
1.3 General Handling of Equipment 9
Section 2 – Pressure Housings 10
2.1 Introduction 10
2.2 Instruments fitted with a Pressure Relief Vent Valve 10
2.3 Instruments not fitted with a Pressure Relief Vent Valve 11
2.4 Dismantling Precautions (Instrument fully functioning) 11
2.5 Dismantling Precautions (instrument known or suspected to be pressurised) 11
Section 3 – Electronic Hazards 13
3.1 High Voltages 13
3.1.1 High Voltage Awareness 13
3.1.2 Storage Capacitors 13
3.1.3 Handling of Electronic Components 13
Section 4 – Batteries 14
4.1 Use of Appropriate Battery Types 14
4.2 Primary Lithium (Li) Batteries 15
4.2.1 Lithium Battery Types 15
4.2.2 Safety Precautions for Primary Lithium (Li) Batteries 15
4.2.3 Fault Procedures 15
4.2.4 Primary Lithium Batteries Storage Instructions 16
4.2.5 Transporting Primary Lithium Batteries 16
4.2.6 Disposal of Primary Lithium Batteries 17
4.3 Lithium Ion (Li+) Batteries 17
4.3.1 Safety Precautions for Lithium Ion (Li+) Batteries 17
4.3.2 Fault Procedures 17
4.3.3 Lithium Ion Batteries Storage Instructions 17
4.3.4 Transporting Lithium Ion Batteries 18
4.3.5 Disposal of Lithium Ion Batteries 18
4.4 Alkaline and Nickel Metal Hydride (NiMH) Batteries 18
4.4.1 Alkaline Batteries 18
4.4.2 Nickel Metal Hydride (NiMH) Batteries 18
4.5 Charging Batteries in Sealed Containers 18
4.6 Reconnecting a Partially Used Battery 19
4.7 Batteries – End of Life 19
4.8 Fitting a New Battery 19
4.9 Battery Pack Fuses 19
4.10 WEEE Directive 19

4
Operational Information and Safety Safety Manual
Precautions for General Equipment Issue B1

4.11 Additional Battery Manufacturer Information 20


Section 5 – Equipment Environmental Limitations 21
5.1 Storage Temperature Limits 21
5.2 Instrument Load Bearing Capability 21
5.3 Floatation Equipment 21
5.3.1 Introduction 21
5.3.2 Float Inspection 21
5.3.3 Minimum Nett Buoyancy of Floats 21
5.3.4 Float Inserts 22
Appendix A – Safety Datasheets/Battery Information Sheets 23
A.1 Lithium Cells and Batteries 23
Saft Lithium Safety Information 24
A.2 Lithium-ion Cells and Batteries 31
Saft Lithium-ion Safety Information 32
Appendix B – Cell Datasheets 38
B.1 Lithium Cells 38
Saft LS33600 39
Saft LS26500 41
Saft LSH20 43
Saft LSH14 45
Saft LSH14 Light 47
Saft LS14500 49
B.2 Lithium-ion Cells 51
allbatteries - Enix Energy 292393 52
Molicel ICR18650H 53
Saft MP144350 55
VARTA LLP50379DL 57
Inspired Energy NL2024 58
Appendix C – Cell Transportation Certificates 59
C.1 Lithium Cell and Battery Transportation Certificates 59
Saft LS33600 60
Saft LS26500 61
Saft LSH20 62
Saft LSH14 63
Saft LSH14 Light 64
Saft LS14500 65
C.2 Lithium-ion Cell and Battery Transportation Certificates 66
Saft MP 144350 67
allbatteries - Enix Energy 292393 68
allbatteries - Enix Energy 292661 69
allbatteries - Enix Energy 700006 70
Inspired Energy Li-ion 71
VARTA 72

5
Operational Information and Safety Safety Manual
Precautions for General Equipment Issue B1

Definitions 74

Figures
Figure 4–1 Example of a Lithium Battery Identification Label 14
Figure 4–2 Example of a Lithium-ion (Li-ion) Battery Identification Label 14
Figure 4–3 Example of an Alkaline Battery Identification Label 14

Tables
Table 4–1 WEEE Directive 2002/96/EC Logo Definitions 19

6
Operational Information and Safety Safety Manual
Precautions for General Equipment Issue B1

Amendment History
The amendment history records all amendments and additions made to this manual.
Issue Revision Date Comments Section Page
A 0 11/04/2012 Initial Issue All All
B 0 21/05/2012 Complete review of manual; datasheets and All All
MCDS certificates Appendices added
B 1 5/07/2016 Battery datasheets updated and general update All All

7
Operational Information and Safety Safety Manual
Precautions for General Equipment Issue B1

Section 1 – Introduction
1.1 General Operational Safety Precautions
This Safety Manual provides information and safety precautions for operating and servicing
Sonardyne products. Sonardyne products can contain hazardous energy and must only be opened by
qualified service personnel.
Operators and Service personnel must be familiar with the information detailed in this manual before
using or servicing Sonardyne equipment.
Additional information including warnings and cautions (if applicable) is included in the relevant
product user, operating or maintenance manual for the specific equipment and must be read and fully
understood before operating the equipment.

Documentation must be consulted whenever the warning symbol is found on the equipment, in
order to find out the nature of the potential hazard and any precautions which have to be taken.
Sonardyne equipment should not be used outside of the manufacturer’s specifications as the
equipment could be damaged or its operation impaired.
The safety of any system incorporating any Sonardyne equipment is the responsibility of the
assembler of the system.
It is the operator’s responsibility to conduct Hazard Identification and Risk Analysis for all conditions.

1.2 General Safety Precautions


The general safety precautions that follow are not equipment or installation specific.
Before the installation or use of equipment the facilities local Health and Safety legislation, regulations,
Safe Working Procedures and Practices must be understood and followed.
All procedures and practices contained in this Safety Manual must be read and fully understood.
It is the RESPONSIBILITY OF ALL PERSONS working on or near an installation to make sure they:
l Work with and obey all persons that have responsibilities for the safe operation of the
applicable installation.
l Report any defect of any equipment that can cause danger to the health, safety or welfare of
persons that work on or may be affected by the installation or equipment.
l Use equipment only for the purpose for which it is intended.
l Do not act in a way on or near the installation, that could cause a danger to you or other
persons that work on or near the installation.
l Do not cause any equipment used on or near an installation to be unsafe.
l Do not remove any WARNING signs without permissions.
l Do not remove or alter any safety equipment without permissions.
l Do not disconnect or connect any power source without permissions.

1.2.1 Hazard Appreciation


Subsea equipment remains safe in use when operated and handled within standard operating
procedures and written guidelines, therefore in normal operation little threat is posed to the safety of
personnel or instruments. However, all subsea units are capable of posing a threat to personal safety,
particularly when pressure housings become internally pressurised. Great care must be taken when

Section 1 – Introduction 8
Operational Information and Safety Safety Manual
Precautions for General Equipment Issue B1

this happens, or is suspected to have happened, since the pressures present within the instrument are
likely to be extremely high. Internal pressure problems may also be aggravated by unknown chemical
hazards if battery breakdown has occurred.
l The following non-exhaustive list gives examples of typical hazardous situations:
l All deteriorated/failed batteries (not just lithium batteries)
l High voltages being present when the equipment is transmitting, particularly on the transmitter
PCB and transducer.
l A pressure housing becoming internally pressurised by water pressure due to a leak
l A pressure housing becoming internally pressurised due to battery failure
l Charging of non-rechargeable battery packs/cells
l Using equipment or instrumentation outside the design parameters
l Using equipment or instrumentation beyond the load bearing limits
l Failing to maintain equipment reducing its load bearing capability
l Using unauthorised components or inferior parts in critical assemblies, e.g. release systems,
battery packs etc.

1.3 General Handling of Equipment


Do not allow instruments to be dropped or exposed to shock damage which can cause sensitive
internal components to fail. Note that minor damage to metal finishes often creates burrs which can
present a hazard to unprotected hands, other parts of the body and to components such as O-rings.
Control the local working environment with good house-keeping practices to prevent slips, trips or
falls, and make sure ropes or cables which are attached to equipment are positioned safely to prevent
entanglement.
Do not allow any tools or equipment to block any access routes or impede normal traffic flows in a
gangway or on a stairway.
Water tightness of instruments depends on fine surface finishes, accurate dimensional tolerances and
cleanliness of components. When dismantling equipment care should always be taken to protect
surface finishes. The disassembly process should be carried out in a well-ventilated area with as few
personnel in the vicinity as possible.
Servicing must always be carried out by suitably qualified and experienced personnel.
.

Section 1 – Introduction 9
Operational Information and Safety Safety Manual
Precautions for General Equipment Issue B1

Section 2 – Pressure Housings


2.1 Introduction
Subsea equipment fitted with a pressure housing is subject to a vast range of externally applied
pressures and is susceptible to internal pressure build up, for example, if a leak occurs or the
instrument’s battery malfunctions/fails, resulting in venting. Internal pressure presents a potentially
dangerous situation and all appropriate safety measures must be enforced.
WARNINGS

Fumes given off by malfunctioning/failed batteries, particularly lithium based, pose a health
hazard. Make sure the area is well ventilated and the appropriate personal protective equipment, such
as gloves, aprons and goggles, are worn.

When an instrument has leaked it often behaves like a valve, i.e. water pressure causes a rise in
internal pressure which cannot then escape because the point of leakage becomes sealed. When this
happens the instrument is potentially dangerous and all precautions described in this section must be
followed.

Any instrument recovered that is not operable should be suspected of leaking and being flooded.
There may be no prior indication of the presence of a build-up of internal pressure. First indications
may be the endcap(s) of the instrument being forced out of the housing under pressure during the
dismantling process.
Complete removal of an endcap’s retaining mechanism means it becomes unconstrained and
therefore free to be discharged from its housing under high internal pressure; an uncontrolled and
potentially dangerous situation.
Symptoms that indicate a higher risk of internal pressure include:
l Equipment that failed when deployed, in transit or storage.
l Equipment stored for a long time with batteries connected.
l Equipment having suffered physical damage.

WARNING

Do not transport equipment that is internally pressurised.

2.2 Instruments fitted with a Pressure Relief Vent Valve


Pressure relief vent valves are fitted into all subsea equipment housings containing batteries. They
comprise a valve with dual O-rings and a vent hole behind the second O-ring. The pressure relief vent
valve is designed so it can operate automatically to release any internal pressure, or it can be manually
withdrawn, using a screw, to the point where the relief hole becomes open to the atmosphere and
allows internal pressure to dissipate. The valve is normally retained to the instrument by means of a
retaining spring preventing it from being completely extracted.
A normal functioning instrument may emit a short audible rush of air when the pressure relief vent
valve is operated. A longer rush of air/gas indicates a pressurised instrument, in which case the work
area must be ventilated while the air/gas is discharged. Internal pressure dissipates to atmosphere in
a very short time and may be accompanied by water, debris, fumes, noise etc.

Section 2 – Pressure Housings 10


Operational Information and Safety Safety Manual
Precautions for General Equipment Issue B1

WARNING

Risk of Toxic Gases. When operating the pressure release vent valve, ensure the work
environment is well ventilated and only necessary authorised personnel are present as toxic gases
may be released. Ensure personal protective equipment, such as gloves and eye protection are worn.

2.3 Instruments not fitted with a Pressure Relief Vent Valve


Some older Sonardyne instruments are not fitted with a pressure relief vent valve.
If an instrument indicates, or is suspected being pressurised and does not have a pressure relief vent
valve fitted, contact the Sonardyne Emergency Support Line (+44 (0) 1252 877600) in the first
instance for advice on the correct course of action to follow.

2.4 Dismantling Precautions (Instrument fully functioning)


The techniques for retaining endcaps in the pressure housings differ for instrument types; refer to the
instrument's user manual for the dismantling procedure.
The normal procedure before opening any underwater instrument is to wash the instrument in clean
fresh water to remove any salt, sand/silt and marine growth and then dry it with a lint free cloth. The
instrument should only be opened in a clean, well-ventilated, dry area.
To ease dismantling and release any slight internal pressure that may have built up during normal
operation, the pressure relief vent valve should be operated as described in Section 2.2 and in the
intrument’s user manual.
WARNING

Do not stand directly in front of the end cap during removal. There is potential for the endcap to
be ejected forcibly without notice due to internal pressure.

2.5 Dismantling Precautions (instrument known or suspected to be


pressurised)
The techniques for retaining endcaps in the pressure housings differ for instrument types; refer to the
instrument's user manual for the dismantling procedure.
The normal procedure before opening any underwater instrument is to wash the instrument in clean
fresh water to remove any salt, sand/silt and marine growth and then dry it with a lint free cloth. The
instrument should only be opened in a clean, well-ventilated, dry area.
If an instrument is known, or suspected to be internally pressurised through water ingress or battery
failure, additional precautions must be taken.
Remove the instrument to a well-ventilated location away from other working personnel.
WARNING

Do not attempt to dismantle or perform any maintenance activity on an instrument that has a hot
housing. The instrument must be cooled before proceeding.

If the instrument housing is hot, this indicates recent or current active internal chemical action and it
must not be dismantled. Wear the appropriate personal protective equipment such as gloves and
lower the instrument overboard into the water for several hours or until it has cooled. Refer to the
battery manufacturer’s SDS/BIS (see Appendix A).

Section 2 – Pressure Housings 11


Operational Information and Safety Safety Manual
Precautions for General Equipment Issue B1

To release internal pressure operate the pressure relief vent valve as described in Section 2.2. If there
is no significant pressure dissipation and no fumes indicating a battery failure, the instrument can be
dismantled; refer to the instrument's user manual for the dismantling procedure. If a pressure relief
vent valve is not fitted follow the precautions described in Section 2.3.
If chemical fumes are present when the pressure relief vent valve is released, or there are deposits
around the vent exterior, these are signs that the battery has vented due to water ingress or battery
failure. In these circumstances the battery pack and internal electronics may have been severely
damaged.
Take extreme care when removing the endcap. There may be a possibility of some internal pressure
remaining, due to the pressure relief vent valve being blocked with products of the internal chemical
reaction.
If a removed battery is found to be leaking, it must be placed in a sealable plastic bag and covered with
a mixture of neutralizing agent (soda ash or baking soda) and absorbent material (vermiculite) and
then placed in a secondary bag for additional containment. The battery should be classified as
hazardous waste and disposed of in accordance with local health and safety, and environmental
regulations.
Any spilled electrolyte must be absorbed/neutralized using absorbent material and neutralizing agent.
The contaminated absorbent must be placed into a sealable bag and then placed in a secondary bag
for additional containment, and disposed as hazardous waste. The contaminated area can be cleaned
with water or an ammonia-based cleaner.
The electronics, end caps and pressure housings should be thoroughly cleaned with fresh water.

Section 2 – Pressure Housings 12


Operational Information and Safety Safety Manual
Precautions for General Equipment Issue B1

Section 3 – Electronic Hazards


3.1 High Voltages
3.1.1 High Voltage Awareness
Operation of Sonardyne equipment does not present any danger to users in normal use. Where
permitted, if the internal electronics chassis is removed from its housing for maintenance, high
voltages are present when transmitting, particularly on the transmitter PCB and transducer. The
following warning symbol , when found on the equipment, indicates high voltage awareness is
required.

3.1.2 Storage Capacitors


Subsea equipment incorporates capacitors which are capable of storing large quantities of electrical
energy. Avoid contact or inadvertent discharge during dismantling.

3.1.3 Handling of Electronic Components


Most of the circuits in subsea equipment use CMOS logic, which is easily damaged by static discharge
or excessive supply voltage. The best action for electronics is no handling.
CAUTION

Electrostatic Discharge (ESD) precautions (grounded wrist strap) must be taken before handling
circuit boards or modules.

Field servicing cannot compare in efficiency and accuracy with the original factory calibration and
therefore field servicing should be limited to checking correct calibration/operation (within the limits of
the test gear available) and repair by exchange of PCBs or modules.

Section 3 – Electronic Hazards 13


Operational Information and Safety Safety Manual
Precautions for General Equipment Issue B1

Section 4 – Batteries
4.1 Use of Appropriate Battery Types
WARNING

Do not fit unauthorised battery pack types into equipment.

Battery packs must not be reconfigured from one type to another, e.g. NiMH to alkaline or lithium
as this may lead to alkaline or lithium cells being inadvertently charged.

Sonardyne equipment uses a variety of battery types including: rechargeable, alkaline and lithium
based packs. Instruments must not be fitted with alternative battery pack types unless they are
specifically designed to use them.
Note
Damage caused by using unauthorised battery packs will invalidate any warranty.

To identify the type of battery installed, a label is attached on the outside of the equipment. Examples
of the labels used are shown below:
Figure 4–1 Example of a Lithium Battery Identification Label

Figure 4–2 Example of a Lithium-ion (Li-ion) Battery Identification Label

Figure 4–3 Example of an Alkaline Battery Identification Label

Section 4 – Batteries 14
Operational Information and Safety Safety Manual
Precautions for General Equipment Issue B1

4.2 Primary Lithium (Li) Batteries


4.2.1 Lithium Battery Types
Primary (non-rechargeable) lithium batteries are often referred to as lithium metal batteries.
Two types of primary lithium cells (LS and LSH) are used throughout Sonardyne products depending
on the application requirements. The LS cell types used are: LS26500 (Size C), LS33600 (Size D)
and LS14500 (Size AA).
The LSH cells are designed for applications requiring higher continuous currents. The LSH cell types
used are: LSH14 (Size C) and LSH20 (Size D).

4.2.2 Safety Precautions for Primary Lithium (Li) Batteries


WARNINGS

Fire, explosion and burn hazard. Do not recharge, short circuit, crush, disassemble, heat above
100°C, incinerate or expose battery contents to water.

Lithium based batteries become hazardous (fire and corrosion) if exposed to air and water and if
damaged may emit fumes. Consult the battery manufacturer's Safety Datasheet/Battery Information
Sheet prior to operating lithium based battery products.

Special precautions and regulations apply to the transport, handling and disposal of primary Lithium
products; see Section 4.2.5.
Lithium batteries are powerful sources of electrical energy and should be handled with care to avoid
short-circuiting.
When a battery powered underwater instrument is suspected of flooding, extreme caution must be
exercised when opening the instrument in case it is internally pressurised; see Section 2.4 and Section
2.5.
Safety Datasheets/Battery Information Sheets for primary lithium cells and batteries are shown in
Appendix A.1.
Primary lithium cell datasheets are shown in Appendix B.1.

4.2.3 Fault Procedures


WARNINGS

If a cell is ruptured, potentially flammable materials may be exposed.

For primary lithium battery packs, CO2 extinguishers or, even preferably, copious quantities of
water or water based foam, can be used to cool down burning LI-SOCI2 cells and batteries, as long as
the extent of the fire has not progressed to the point that the lithium metal they contain is exposed
(marked by deep red flames). Do not use for this purpose sand, dry powder or soda ash, graphite
powder or fire blankets. Use only metal (Class D) extinguishers on raw lithium.

There is a risk of burns and injury when handling hot batteries; suitable personal protective
equipment, such as gloves, aprons and goggles, must be worn.

If a cell or battery is shorted or starts to heat up, it should be disconnected from the transponder
immediately and removed to the outdoors or to a well-ventilated area to cool down. Tongs, or a shovel,
are recommended for this purpose. Should the battery overheat significantly or catch fire, use the fire-
fighting media as described in in the above Warning, or the cell manufacturer’s safety datasheet. Once

Section 4 – Batteries 15
Operational Information and Safety Safety Manual
Precautions for General Equipment Issue B1

the temperature has dropped and it is deemed safe to do so, the cell or battery can be disposed of as
described in Section 4.2.6.
Charging of Non-Rechargeable Battery Packs
WARNING

Do not attempt to charge non-rechargeable batteries or battery packs.

Non-rechargeable cells exhibit a range of unpredictable characteristics if any attempt is made to


charge them. Very high pressures and temperatures can occur in an instrument often some-time after
the attempt to charge them has terminated.
Attempts to charge a primary battery may lead to an imbalance within the cell potentially leading to gas
generation and in extreme cases explosion.

4.2.4 Primary Lithium Batteries Storage Instructions


Primary Lithium batteries should be stored in their original containers, in a clean, dry, cool, ventilated
area, where the temperature should be as cool as possible to maximise shelf life and not exceed 30°C.
CAUTION

Battery life may be reduced if exposed to temperatures in excess of 30°C.

Instruments with batteries installed should not be left on deck in strong sunlight such that they become
hot to the touch.
Observe the manufacturers minimum and maximum storage temperatures.
Store all primary lithium battery packs in an isolated area, away from combustible materials. Store
depleted cells in an area separate from fresh cells. Allow space for complete encapsulation with Lith-X
in the event of a fire.
Any primary lithium battery storage area should have immediate access to both a class D and an ABC
fire extinguisher. Refer to the battery manufacturer’s specifications for extinguishing fires containing
this battery type.
Instruments should be cooled to normal room temperature or lower before being opened for battery
replacement.

4.2.5 Transporting Primary Lithium Batteries


The current regulations and the information below is provided for guidance only. Note that datasheets
concerning quantities of lithium per cell are available from cell manufacturers and these may change
without prior notice, therefore the quantities of lithium per battery pack cannot be verified by
Sonardyne Ltd.
When transporting lithium based products it is the operator’s responsibility to comply with local,
national and international regulations in force at the time of transport.
l By Road: ADR European Agreement concerning the International Carriage of Dangerous
Goods by Road Regulations (http://www.unece.org)
l By Sea: International Maritime Dangerous Goods Code (http://www.imo.org)
l By Air: IATA Dangerous Goods Regulations (http://www.iata.org)
Transportation Certificates for cells are shown in Appendix C. The certificates detail nominal voltage,
capacity, energy and the equivalent Lithium Metal content. Transportation certificates for battery
packs used in Sonardyne equipment are available on request from Sonardyne Support.

Section 4 – Batteries 16
Operational Information and Safety Safety Manual
Precautions for General Equipment Issue B1

The IATA Dangerous Goods Regulations Section II, Packing Instructions 967, Note A154 states that
lithium batteries identified by the manufacturer as being defective for safety reasons, or that have been
damaged, that have the potential of producing a dangerous evolution of heat, fire or short circuit are
forbidden for transport.

4.2.6 Disposal of Primary Lithium Batteries


WARNING

Do not dispose of primary Lithium batteries in a fire as there is a potential risk of battery
explosion.

Cells and batteries must be disposed of in accordance with local health and safety, and environmental
regulations regarding hazardous substances. Packaging suitable for the storage and transport of
Lithium cells/batteries must be used at all times when not installed in an instrument.
Suitable personal protective equipment, such as gloves, apron and goggles, should be worn when
handling suspect cells/batteries. If the skin has come into contact with the electrolyte, it should be
washed thoroughly with clean water.

4.3 Lithium Ion (Li+) Batteries


In a lithium ion (li-ion) cell, the negative electrode (anode) is graphite and the positive electrode
(cathode) is a lithium-bearing metal compound. Li-ion cells have an exceptional cycling aptitude owing
to the stable electrode structure. Charging and discharging involves exchange of lithium ions between
the electrodes via the electrolyte. Because of the high output voltage (up to 4.2 V), a non-aqueous
electrolyte is used, mainly comprising a mixture of organic carbonates.
Safety Datasheets/Battery Information Sheets for li-ion cells and batteries are shown in Appendix A.2.
Li-ion cell datasheets are shown in Appendix B.2.

4.3.1 Safety Precautions for Lithium Ion (Li+) Batteries


Refer to Section 4.2.2 "Safety Precautions for Primary Lithium (Li) Batteries"
WARNINGS

Only charge li-ion batteries using the charging equipment supplied; do not attempt to charge
li-ion batteries using any other type of charging equipment.

4.3.2 Fault Procedures


Refer to Section 4.2.3 "Fault Procedures".
WARNING

Dry chemical type or CO2 extinguishers, Halon, or copious quantities of water or water-based
foam can be used to cool down burning li-ion cells and batteries. During water application, caution
should be exercised as burning pieces of flammable particles may be ejected from the fire. In case of
fire, it is recommended to wear self-contained breathing apparatus to avoid contact with irritant
fumes. Evacuate all persons from immediate area of fire. Do not re-enter the area until it has been
adequately purged of the fire vapour and extinguishing agent.

4.3.3 Lithium Ion Batteries Storage Instructions


Refer to Section 4.2.4 "Primary Lithium Batteries Storage Instructions".

Section 4 – Batteries 17
Operational Information and Safety Safety Manual
Precautions for General Equipment Issue B1

When charging li-ion batteries for the first time after long-term storage, deactivation of reactants may
lead to increased battery voltage and decreased battery capacity. It is possible to restore batteries to
their original performance by repeating several cycles of charging and discharging.
For long-term storage of more than one year, li-ion batteries should be charged at least once a year to
prevent leakage and deterioration in performance due to self-discharging. Batteries stored whilst
connected to equipment and batteries containing sophisticated battery management electronics may
need to be monitored and charged several times a year to avoid technical and performance difficulties.

4.3.4 Transporting Lithium Ion Batteries


Section 4.2.5 "Transporting Primary Lithium Batteries".
The IATA Dangerous Goods Regulations Section II, Packing Instructions 967, Note A164 states that
li-ion batteries and cells contained in equipment, must have the battery electrically disconnected and
exposed terminals protected before transportation.

4.3.5 Disposal of Lithium Ion Batteries


Refer to Section 4.2.6 "Disposal of Primary Lithium Batteries".

4.4 Alkaline and Nickel Metal Hydride (NiMH) Batteries


Other battery types installed in Sonardyne equipment are Alkaline and Nickel Metal Hydride (NiMH).

4.4.1 Alkaline Batteries


WARNING

Do not attempt to charge alkaline batteries.

Alkaline batteries are non-rechargeable. They must be disposed of as hazardous waste, in


accordance with local health and safety, and environmental regulations.

4.4.2 Nickel Metal Hydride (NiMH) Batteries


WARNING

Only charge NiMH batteries using the charging equipment supplied; do not attempt to charge
NiMH batteries using any other type of charging equipment.

Nickel Metal Hydride (NiMH) batteries are rechargeable. Sonardyne supplies the correct charging
equipment with any euipment containing NiMH batteries.
NiMH batteries should be replaced when they fail to hold their charge. They must be disposed of as
hazardous waste, in accordance with local health and safety, and environmental regulations.

4.5 Charging Batteries in Sealed Containers


Batteries may give off gases when charged. As a general rule, sealed containers must be allowed to
vent to atmosphere during the charging process.
Some equipment may be fitted with safety features which prevent the possibility of problems caused
by gases vented by batteries. Refer to the equipment user manual for the correct charging procedure.
Equipment fitted with a pressure relief vent valve must be checked to make sure the vent valve is
seated properly following recharging of the batteries.

Section 4 – Batteries 18
Operational Information and Safety Safety Manual
Precautions for General Equipment Issue B1

4.6 Reconnecting a Partially Used Battery


When reconnecting a partially used battery, calculate if the remaining battery life will allow the next
mission to be safely accomplished. If so, note the date of reconnection, both on the battery label and in
written records, against the serial number of the instrument.

4.7 Batteries – End of Life


Discharging batteries below their end point voltage can lead to internal corrosion and leakage of
electrolyte in certain types of cells. Although there is very little gas to cause a pressure rise under these
conditions, the electrolyte leakage will cause severe corrosion.
After recovering an instrument, the battery voltage(s) should be checked while still connected to see if
it is above the end point voltage for that type of cell. Disconnect and mark as usable or not with date of
disconnection noted both on the pack and in written records. Check the instrument, including solder
joints for signs of corrosion.
The remaining life of a battery depends on both time and, for a transponder, the number of times it has
been interrogated. Some transponders keep their own record of battery usage, but a separate record
should be maintained consisting of time elapsed whilst battery is installed and connected, plus
estimates of the number of interrogations .

4.8 Fitting a New Battery


Refer to the equipment user manual for the instructions on how to fit a new battery.
Make a note of the date when a new battery is connected. Write this date on the battery label and also
in your written records.

4.9 Battery Pack Fuses


A number of Sonardyne battery packs have carefully selected, highly-reliabile fuses soldered onto the
diode-board of the pack. The fuses can be either resettable “Polyfuse” devices, or "Littlefuse" devices.
If a fuse has blown due to mishandling, it may be replaced by an identicaly specified fuse type; the
rating must not on any account be increased.

4.10 WEEE Directive


A number of Sonardyne battery packs may have the WEEE (Waste from Electrical and Electronic
Equipment Directive 2002/96/EC) ‘crossed out wheelie bin logo’ marked on them.
This logo indicates that the batteries must not be disposed of in a landfill. If the logo has a black solid
line under it, this indicates that the equipment was manufactured after 13 August 2005, after the
directive came into force and that the equipment must not be disposed of in a landfill.
Table 4–1 WEEE Directive 2002/96/EC Logo Definitions

Symbol Definition
The WEEE Directive (Waste from Electrical and Electronic Equipment Directive)
2002/96/EC used on equipment to show the product must not be disposed of in landfill. The
logo is defined in detail in the European Standard EN50419

Section 4 – Batteries 19
Operational Information and Safety Safety Manual
Precautions for General Equipment Issue B1

Table 4–1 WEEE Directive 2002/96/EC Logo Definitions (continued)

Symbol Definition
The same as the WEEE Directive (detailed above) but the bottom bar is added to indicate
equipment that has been manufactured after 13 August 2005, after the Directive came into
force. This must not be disposed of in landfill.

4.11 Additional Battery Manufacturer Information


Additional information applicable to lithium and lithium-ion cells is available from:
Saft Headquarters
12, rue Sadi Carnot
93170 Bagnolet
France
Tel: +33 (0)1 49 93 19 18
Fax: +33 (0)1 49 93 19 50
http://www.saftbatteries.com

Panasonic Batteries
Panasonic Industrial Company
A Division of Panasonic Corporation of North America
5201 TollView Drive, 1F-3
Rolling Meadows, IL-60008
Toll Free: 877-726-2228
Fax: 847-468-5750
e-mail: oembatteries@us.panasonic.com
http://www.panasonic.com/batteries

E-One Moli Energy Corp.


10 Dali 2nd Rd., Shan-Hwa
Tainan County
Taiwan, R.O.C,
Tel: 886-6-505-0666
Fax: 886-6-505-0777
http://www.molicel.com/

allbatteries/Enix Energies
Unit 20, Monkspath Business Park
Highlands Road
West Midlands
B90 4NZ
Tel: +44 121 5068619
http://www.allbatteries.com

Section 4 – Batteries 20
Operational Information and Safety Safety Manual
Precautions for General Equipment Issue B1

Section 5 – Equipment Environmental Limitations


5.1 Storage Temperature Limits
Equipment must be stored according to the specifications quoted in the equipment manual/datasheet.
It should be noted however that lines connecting pressure transducers to a transponder may become
partly filled with seawater during service. This cannot easily be expelled and may therefore freeze if
transponders are stored at sub-zero temperatures after recovery from the sea.
Batteries should be stored in their original containers, in a clean, dry, cool, ventilated area, where the
temperature should be as cool as possible to maximise shelf life and not exceed 30°C. Refer to the
battery manufacturers specifications for battery storage.

5.2 Instrument Load Bearing Capability


Navigational Transponders are not normally designed to take in-line loads greater than the maximum
upthrust applied by the floatation equipment. The carrying straps, if fitted, are for ease of manual
handling and the range of transducer guards selected for their acoustic properties.
WARNING

Do not exceed the Working Load Limit capabilities of release mechanisms, or additional lifting
equipment.

The Working Load Limit (WLL) capability of the release mechanism built into many instruments, can
only be used for in-line lifting operations if a suitably-rated, approved, lifting strap, transducer guard,
buoyancy collar eyes or other safe method is selected.
It is the responsibility of the Responsible Body at the worksite to make sure the condition of the
equipment is acceptable and that a safe lifting method has been devised for any particular operation.
Sonardyne’s range of Oceanographic Release Transponders have been designed specifically for in-
line lifting operations.
Appropriate shackles must be used in release systems to ensure freedom from corrosion. It is
important to note that instruments, their release mechanisms and shackles form part of an integrated
and complete system.

5.3 Floatation Equipment


5.3.1 Introduction
Floatation equipment is fitted to subsea transponders in order to aid their recovery once a deployment
is complete. A nett up-thrust requirement is given in manuals and technical data for any particular
instrument. The following guidelines are given to assist operators in their understanding of the general
requirements.

5.3.2 Float Inspection


The float lifting eyes and attachment bolts can be susceptible to corrosion. To guarantee safe
operation, the float lifting eyes and attachment bolts must be inspected prior to use, any indication of
corrosion and the lifting eyes and bolts must be replaced.

5.3.3 Minimum Nett Buoyancy of Floats


Floats are described as having a minimum nett buoyancy in seawater and this is the figure quoted in
Sonardyne float technical data and by the float manufacturer. Total up-thrust can be calculated by

Section 5 – Equipment Environmental Limitations 21


Operational Information and Safety Safety Manual
Precautions for General Equipment Issue B1

knowing this figure, e.g., a float with 30 kilogram nett buoyancy in sea water supporting a load with
weight in sea water of 30 kilogram would result in neutral buoyancy, i.e. no nett up-thrust.

5.3.4 Float Inserts


Float collar Inserts are used to allow floats of larger internal bore to be used with housings of nominal
six inches diameter. The weight in water of an insert is usually slightly positive and this will be
additional to the weight of the instrument being supported by the float. Two inserts will result in
approximately 0.5 kilogram reduction in nett up-thrust.
Nett Upthrust
The difference between the nett buoyancy of the float and the total weight of an object, or objects, in
water that it is supporting, e.g.
Nett Upthrust = (minimum nett buoyancy of the float) - (the weight of the instrument + the float inserts
in water)
e.g. 30 kg - (11.2+ 0.5) kg = 17.3 kg nett upthrust
Float Storage Conditions
Floats should be stored within the temperature range -6 to +65°C. Floats are not hygroscopic and
should not therefore be affected by moisture in air.
CAUTION

Do not stack the floats on top of each other or store in direct sunlight.

Float Over-Pressure
The maximum water depth quoted for a float must not be exceeded. Over-pressured floats are forced
to absorb water and their weight in air thus increases. All floats should be weighed prior to use to
check that they are maintaining their original manufactured weight.

Section 5 – Equipment Environmental Limitations 22


Operational Information and Safety Safety Manual
Precautions for General Equipment Issue B1

Appendix A – Safety Datasheets/Battery Information Sheets

A.1 Lithium Cells and Batteries

Saft Lithium Safety Information 24

Appendix A – Safety Datasheets/Battery Information Sheets 23


Battery Information Sheet
Primary Li-SOCl2 single cells and multi-cell battery packs

According to REACH regulation (EC 1907/2006, Art 31) and to OSHA regulation (29 CFR 1910.1200),
batteries are ARTICLES with no intended release. As such, they are not covered by legal requirements
to generate and supply an SDS or an MSDS.

This Battery Information Sheet is provided solely as information


document for the purpose of assisting our customers.

1. IDENTIFICATION
1.1 Product
Lithium-thionyl dichloride primary unit cells and multi-cell battery systems composed of these cells

1.2 Supplier
Headquarters Saft S.A.S.
Address 12 rue Sadi Carnot, 93170 BAGNOLET – France
Phone/Fax +33 (0)1 49 93 19 18 /+33 (0)1 49 93 19 50
Factory Saft Poitiers
Address Rue Georges Leclanché, BP 1039, 86060 POITIERS Cedex 9 – France
Phone/Fax +33 (0)5 49 55 48 48 /+33 (0)5 49 55 48 50
Factory Saft Ltd.
Address River Drive, Tyne & Wear, SOUTH SHIELDS, NE33 2TR – United Kingdom
Phone/Fax +1 44 191 456 1451/+1 44 191 456 6383
Factory Saft America Inc.
Address 313 Crescent Street, VALDESE, NC 28690 – USA
Phone/Fax +1 828 874 4111/+1 828 874 2431
Factory Saft Batteries Co., Ltd.
Address Zhuhai Free Trade Zone, Lianfeng Road, ZHUHAI 519030, Guangdong Province – China
Phone/Fax +86 756 881 9318/+86 756 881 9328
Factory Tadiran Batteries Ltd.
Address 34 Y. Rabin Avenue – KIRYAT EKRON 76950 - Israel
Phone/Fax +972 894 44374/+972 894 13066
Factory Tadiran Batteries GmbH
Address Industriestrasse 22, D-63654 BÜDINGEN – Germany
Phone/Fax +49 (0)6 042 954 599/+49 (0)6 042 954 190

1.3 Emergency contact For chemical emergency ONLY (in case of spill, leak, fire, exposure or accident) call CHEMTREC at:
International: +1-703-527-3887 for English
Within the USA: +1-800-424-9300
In France, INRS Orfila : +33(0) 1 45 42 59 59 for French

November 2012 – Version 1.1 – Li-SOCl2 single cells and multi-cell battery systems Page 1
2. HAZARD IDENTIFICATION

The Li-SOCl2 batteries described in this Battery Information Sheet are sealed units which are not hazardous under normal
operating conditions in accordance with manufacturer’s recommendations, as stated in the user’s manual or other similar
documentation. Under normal use, the battery integrity is maintained and the active components it contains are isolated
from the outside.
In particular, the battery should not be submitted to any mechanical (opening, puncture, immersion), thermal (burning,
heating to temperatures above the normal temperature range of the product) or electrical abuse (short-circuit, recharge,
forced discharge), which will lead to the activation of safety valves and/or the rupture of the battery container.
Any accidental release of the inner components of the cell, or their combustion products could be highly hazardous.
Battery content exposition to air humidity/liquid water may be followed by severe battery vent/explosion/fire, depending
on the hazard causes and circumstances.

Protection from charging:


Whenever lithium batteries are not the single power source in a circuit, the following measures recommended by
Underwriters Laboratories are relevant. The cells should not be connected in series with an electrical power source that
would increase the load through the cells. The electronic circuit shall include one of the following:

A. Two suitable diodes or the equivalent in series with the cells to prevent any reverse (charging) current. The second
diode is used to provide protection in the event that one would fail. Quality control, or equivalent procedures,
shall be established by the device manufacturer to check that the diode polarity is correct for each unit.
or
B. A blocking diode or the equivalent to prevent any reverse (charging) current and a resistor to limit current in case
of diode failure. The resistor should be sized to limit the reverse (charging) current to the maximum value
according to the data sheet of the cell.

3. COMPOSITION, INFORMATION OR INGREDIENTS

Each unit cell consists of a hermetically sealed metallic can containing a number of chemicals and materials of construction
of which the following are potentially hazardous upon release to air.

Component CAS Number EINECS/ELINCS Content (wt. %)*


Lithium metal 7439-93-2 231-102-5 2-6
Thionyl dichloride 7719-09-7 231-748-8 18-47
Aluminium chloride 7446-70-0 231-208-1 1-5
Gallium chloride 13450-90-3 236-610-0 0-2
Lithium chloride 7447-41-8 231-212-3 1-2
Carbon 1333-86-4 215-609-9 2-5
PTFE 9002-84-0 N/A 0-1
Stainless steel, Nickel and inert material N/A N/A remainder
* Quantities may vary with cell model

4. HANDLING AND STORAGE

IMPORTANT NOTICE: Lithium-thionyle chloride batteries are not rechargeable and should not be tentatively charged or
recharged. Manufacturer’s recommendations should be followed regarding maximum current and operating
temperature range. Applying pressure or deforming the battery may lead to disassembly and cause eye, skin and throat
irritation.

November 2012 – Version 1.1 – Li-SOCl2 single cells and multi-cell battery systems Page 2
STORAGE: Store in a cool, regulated (preferably below 21°C and in any case below 30°C), dry and ventilated area, away
from possible sources of heat, open flames, food and drink. Avoid exposure to direct sunlight for long periods.
Temperatures above 100°C (or higher for High Temperatures cells and batteries such as the LSH20-150 cell- refer to
individual data sheets for maximum temperatures) may cause leakage and rupture, and result in shortened battery service
life. Keep proper clearance space between batteries and walls. Since short circuit can cause burn hazard, leakage or
explosion hazard, keep batteries in original packaging until use and do not mix them.

HANDLING:
 Do not open the battery system.
 Do not crush or pierce the cells.
 Do not short (+) or (-) terminal with conductors.
 Do not reverse the polarity.
 Do not submit to excessive mechanical stress.
 Do not mix batteries of different types or mix new and old ones together.
 Do not use the unit without its electronic management system.
 Do not expose the unit to water or condensation.
 Do not directly heat, solder or throw into fire. Such unsuitable use can cause leakage or spout vaporized
electrolyte fumes and may cause fire or explosion.

5. PHYSICAL AND CHEMICAL PROPERTIES

The lithium-thionyl chloride cell or battery described by this Battery Information Sheet is a sealed unit when offered for
sale. It is a manufactured “article” and does not expose the user to hazardous chemicals when used in accordance with
manufacturer specifications.

Appearance – Cylindrical shape


Odour – If leaking, gives off a pungent corrosive odour
Flash point – Not applicable Flammability – Not applicable
Boiling Point – Not applicable Melting Point – Not applicable
Vapor Pressure – Not applicable Vapor Density – Not applicable
pH – Not applicable Specific Gravity – Not applicable
Solubility (in water) – Not applicable Solubility (other) – Not applicable

6. STABILITY AND REACTIVITY

The battery system is stable when handled and stored according to section 4.

MATERIALS TO AVOID: Oxidizing agents, bases, water. Avoid electrolyte contact with aluminium of zinc.

CONDITIONS TO AVOID: Do not heat above 100°C (or higher (150°C) for High Temperatures cells and batteries such as the
LSH20-150 cell- refer to individual data sheets for maximum temperatures) or incinerate. Do not disassemble, crush,
pierce, short, charge or recharge. Avoid mechanical or electrical abuse.

HAZARDOUS DECOMPOSITION PRODUCTS: Hydrogen (H2) as well as lithium oxide (Li 2O) and lithium hydroxide (LiOH) dust
are produced in case of reaction of lithium metal with water (hydrolysis).
Chlorine (Cl2), sulfur dioxide (SO2) and disulfur dioxide (S2Cl2) are produced in case of thermal decomposition of thionyl
dichloride above 100°C. Hydrochloric acid (HCl) and sulfur dioxide (SO2) are produced in case of reaction of thionyl
dichloride with water at room temperature.

November 2012 – Version 1.1 – Li-SOCl2 single cells and multi-cell battery systems Page 3
Hydrochloric acid (HCl) fumes, lithium oxide (Li 2O), lithium hydroxide (LiOH) and aluminium hydroxide (Al(OH) 3) dust are
produced in case of reaction of lithium tetrachloroaluminate (LiAlCl 4) with water.

7. TOXICOLOGICAL INFORMATION

There is no risk, unless the battery ruptures. In the event of accidental exposure to internal contents, corrosive fumes will
cause severe skin, eye and mucous membrane irritation. Medical conditions are generally aggravated by exposure to
battery internal contents: eczema, skin allergies, lung injuries, asthma and other respiratory disorders may occur.
Overexposure may cause symptoms of non-fibrotic lung injury and ingestion can cause tissue damage to throat and gastro-
respiratory tract.

8. ECOLOGICAL INFORMATION

The batteries do not contain mercury, cadmium or other heavy metals.


Eco-toxicity None known if used/disposed of correctly.
Mammalian affects None known if used/disposed of correctly.
Bioaccumulation potential None known if used/disposed of correctly.
Environmental fate None known if used/disposed of correctly.

9. DISPOSAL CONSIDERATIONS

Batteries do not contain hazardous materials according to EC Directives 91/157/EEC, 93/86/EEC, and 2002/95/EC (RoHS)
Directive). Battery recycling is either mandatory or recommended: The European Directive 2006/66/EC has been
implemented by most EC member states.
Dispose of in accordance with local laws and regulations. Store material for disposal as indicated in Section 4. A disposal
service is offered upon request by Tadiran Batteries.
Do not incinerate, or subject cells to temperatures in excess of 100°C (or 150°C for LSH20-150 cells and the battery packs
assembled from them). Such abuse can result in loss of seal, electrolyte leakage and/or violent disassembly with risk of
material projections.
For additional information a Technical Notice is available upon request.
See:
http://www.saftbatteries.com/TheSaftGroup/Environment/Takebackpolicy/tabid/104/Language/en-US/Default.aspx
http://www.saftbatteries.com/TheSaftGroup/Environment/BringBackPoints/tabid/435/Language/en-US/Default.aspx

10. TRANSPORTATION INFORMATION

Note: when manufacturing a new battery pack, one must assure that it has fulfilled the tests according to the UN Model
Regulations, Manuel of Tests and Criteria, Part III, subsection 38.3.

10.1 United Nations Class

For the single cell batteries and multi-cell battery packs that are non-restricted to transport (non-assigned to the
Miscellaneous Class 9), use lithium batteries inside label.
For the single cell batteries and multi-cell battery packs which are restricted to transport (assigned to Class 9), use Class 9
Miscellaneous Dangerous Goods and UN Identification Number Labels.
In all cases, refer to the product transport certificate issued by the manufacturer.

November 2012 – Version 1.1 – Li-SOCl2 single cells and multi-cell battery systems Page 4
UN Numbers: 3090 LITHIUM METAL BATTERIES: Shipment of cells and batteries in bulk
3091 LITHIUM METAL BATTERIES CONTAINED IN EQUIPMENT or LITHIUM METAL
BATTERIES PACKED WITH EQUIPMENT: Cells and batteries contained in
equipment or packed with it

Shipping name LITHIUM METAL BATTERIES


Hazard Classification: 9
Depending on their lithium metal content, some single cells and small multi-cell battery
packs may be non-assigned to Class 9. Refer to Transport Certificate.
Packaging: Group II

10.2 International agreements


By Air International: IATA/ICAO: UN 3090 or UN3091
By Sea International: IMDG: UN 3090 or UN 3091
European road transportation: ADR
European rail transportation: RID

11. REGULATORY INFORMATION

Regulations specifically applicable to the product:


- ACGIH and OSHA: see exposure limits of the internal components of the battery in section 14.
- IATA/ICAO (air transportation): UN 3090 or UN 3091.
- IMDG (sea transportation) : UN 3090 or UN 3091.
- Transportation within the US-DOT, 49 Code of Federal Regulations
- UK regulatory references: Classified under CHIP.
- Battery Directive (2006/66/EC): see section 9

12. FIRST AID MEASURES (not anticipated under normal use)

12.1. Electrolyte contact

EYE CONTACT: Immediately flush with plenty of water for at least 15 minutes and get medical attention.

SKIN CONTACT: Remove contaminated clothing and immediately flush with plenty of water for at least 15 minutes. In
severe cases, get medical attention.

INHALATION: Contents of an opened cell may cause respiratory tract and mucus membrane irritation. Remove from
exposure, rest and keep warm. Immediately inhale Cortisone spray. In severe cases, track medical surveillance for 48 hours.

INGESTION: Wash out mouth thoroughly with water and give plenty of water to drink. Get medical attention.

FURTHER TREATMENT: All cases of eye contamination, persistent skin irritation and casualties who have swallowed this
substance or have breathed its vapours should be seen by a Doctor.

12.2. Lithium metal contact


EYE CONTACT: Immediately flush with large quantities of water for at least 15 minutes, with open eyelids, and get medical
attention.

SKIN CONTACT: Remove particles of lithium from skin as quick as possible. Immediately flush with plenty of water for at
least 15 minutes and get medical attention.

November 2012 – Version 1.1 – Li-SOCl2 single cells and multi-cell battery systems Page 5
INHALATION/INGESTION: Contents of an opened cell may cause respiratory tract and mucus membrane irritation. Remove
from exposure, rest and keep warm. Immediately inhale Cortisone spray. In severe cases, track medical surveillance for 48
hours.

13. FIRE FIGHTING MEASURES (not anticipated under normal use)

ESTINGUISHING MEDIA:
 During a fire with lithium batteries, using large amounts of cold water or water-based foam has some cooling
effect and is effective to prevent fire expansion as long as the extent of the fire has not progressed to the point
that the lithium metal they contain is exposed (as marked by appearance of deep red flames). Do not use warm or
hot water.
 Lith-X Class D extinguishers are effective on fires involving only a few lithium batteries.
 Do not use CO2 or Halon-type extinguishers.
 Do not use sand, dry powder or soda ash, graphite powder or fire blankets.
 Use only class D metal extinguishers on raw lithium metal.

SPECIAL FIRE FIGHTING PROCEDURES:


 Fire fighters should wear approved/certified positive pressure self-contained breathing apparatus.
 Full protective clothing is necessary to prevent potential body contact with electrolyte solution.
 During water spraying, caution is advised as burning pieces of lithium may be ejected from the fire.
 It is permissible to use any class of extinguishing medium, specified above, on these batteries or their packing
material. Cool exterior of batteries if exposed to fire to prevent rupture.
 If the cells or batteries are not located at the center of the fire, copious amounts of water may be supplied using a
diffuser type nozzle so that the cells remain cool during the fire containment and extinction. A sprinkler system
should be suitable for this purpose, the critical factor being that the lithium cells do not experience temperatures
above the melting point of lithium (180°C).
 Small amounts of water should never be used such as the volumes contained within portable fire extinguishers.
Standard dry powder extinguishers are ineffective. It should be kept in mind that a hazard of hydrogen formation
exists whenever hot lithium metal comes into contact with water.

14. EXPOSURE CONTROLS AND PERSONAL PROTECTION* (not anticipated under normal use)

Respiratory
In all fire situations, use self-contained breathing apparatus
protection
Hand
In case of leakage wear protective gloves
protection
Eye
Safety glasses are mandatory during handling
protection

Other In the event of leakage or ruptured cells, wear a rubber apron and protective clothes.

*AFNOR pictograms
Occupational exposure standard:
Compound 8 hour TWA 15 min TWA SK
Sulfur Dioxide 1 ppm 1 ppm -
Hydrogen chloride 1 ppm 5 ppm -

November 2012 – Version 1.1 – Li-SOCl2 single cells and multi-cell battery systems Page 6
15. ACCIDENTAL RELEASE MEASURES (not anticipated under normal use)

INDIVIDUAL PRECAUTIONS: Evacuate the employees from area until fumes dissipate. In case of electrolyte leakage from a
cell or battery, do not inhale vapors or touch liquid with bare hands. In case of skin or eye contact, inhalation or ingestion,
follow the measured described in section 12.

ENVIRONMENTAL PRECAUTION: Avoid sewage, surface water and underground water contamination. Avoid ground and
atmosphere contamination.

WAYS OF CLEANING: With protective glasses and gloves, use absorbent material (sand, earth, chalk (CaCO3) or lime (CaO)
powder or Vermiculite) to absorb any exuded material. Seal leaking battery (unless hot) and contaminated absorbent
material tight in plastic bag, and dispose of as hazardous waste in accordance with local regulations. Electrolyte traces may
be wiped off dryly using household paper. Rinse with water afterwards.

16. OTHER INFORMATION

This information has been compiled from sources considered to be dependable and is, to the best of our knowledge and
belief, accurate and reliable as of the date compiled. However, neither exhaustively nor perfect reliability can be granted.
Information does not imply implicit or specific warranty of it.

This information relates to the specific products designated and may not be valid for such products used in combination
with any other materials or in any process. It is the user’s responsibility to satisfy himself as to the suitability and
completeness of this information for his particular use.

Saft does not accept liability for any loss or damage that may occur, whether direct, indirect, incidental or consequential,
from the use of this battery information sheet provided as a service to our customers. Saft does not offer warranty against
patent infringement.

Doc N˚ BIS04-11-12
12, rue Sadi Carnot
Edition: November 2012
93170 Bagnolet – France Version 1.1
Tel.: +33 (0)1 49 93 19 18
Fax: +33 (0)1 49 93 19 69 Data in this document is subject to
www.saftbatteries.com change without notice and
becomes contractual only after
written confirmation.

November 2012 – Version 1.1 – Li-SOCl2 single cells and multi-cell battery systems Page 7
Operational Information and Safety Safety Manual
Precautions for General Equipment Issue B1

A.2 Lithium-ion Cells and Batteries

Saft Lithium-ion Safety Information 32

Appendix A – Safety Datasheets/Battery Information Sheets 31


Battery Information Sheet
Rechargeable lithium-ion cells, modules and battery systems

According to REACH regulation (EC 1907/2006, Art 31) and to OSHA regulation (29 CFR 1910.1200),
batteries are ARTICLES with no intended release. As such, they are not covered by legal requirements
to generate and supply an SDS or an MSDS.

This Battery Information Sheet is provided solely as an informational


document for the purpose of assisting our customers.

1. IDENTIFICATION
1.1 Product
Lithium-Ion rechargeable cells and modules or battery systems composed of these cells

1.2 Supplier
Headquarter Saft S.A.S.
Address 12 rue Sadi Carnot, 93170 BAGNOLET – France
Phone/Fax Phone/Fax: +33 (0)1 49 93 19 18 /+33 (0)1 49 93 19 50
Factory Saft Bordeaux
Address 111-113, boulevard Alfred Daney, 33074 BORDEAUX - France
Phone/Fax +33 (0)5 57 10 64 00 /+33 (0)5 57 10 68 77
Factory Saft Jacksonville
Address 13575, Waterworks street, JACKSONVILLE, FL 32221 - USA
Phone/Fax +1 904 861 1501/+1 904 772 1463
Factory Saft Nersac
Address Zone industrielle, 16440 NERSAC - France
Phone/Fax +33 (0)5 45 90 50 26 /+33 (0)5 45 90 50 71
Factory Saft Raskovice
Address Raskovice 247, 73904 PRAZMO - Czech Republic
Phone/Fax +420 558 426 257/+420 558 692 226
Factory Saft Poitiers
Address Rue Geoges Leclanché – BP n°1039, 86060 POITIERS Cedex 9 - France
Phone/Fax +33 (0)5 49 55 48 48 /+33 (0)5 49 55 48 50
Factory Saft Cockeysville
Address 107 Beaver Court, COCKEYSVILLE, MD 21030 - USA
Phone/Fax +1 410 771 3200/+1 410 771 1144
Factory Saft Valdese
Address 313 Crescent Street, VALDESE, NC 28690 - USA
Phone/Fax +1 828 874 4111/+1 828 874 2431
Factory Friemann & Wolf Batterietechnik GmbH (a company of the Saft Group)
Address Industriestrasse 22, 63654 BÜDINGEN - Germany
Phone/Fax +49 (0)6042 954 150 / +49 (0)6042 954 490

December 2014 – Version 1.2 – Rechargeable Li-ion cells, modules or battery systems Page 1
1.3 Emergency contact

Chemtrec US Service within USA-Canada: +800 424 93 00/outside : +1-703-527-3887


In case of an incident and/or accident involving the battery, this telephone number is available 24 hours a day and is
monitored at all times by a person who has comprehensive emergency response and accident mitigation information for
the battery or can immediately call upon a person who possesses such knowledge and information.
If needed, the fire brigade may also be called in case of an incident/accident involving the battery.

2. HAZARD IDENTIFICATION

2.1 At cell level


Not chemically dangerous during normal use in accordance with Saft recommendations as stated in the user manuals or
other similar documentation. In particular, the battery should not be opened or burned. Exposure to the ingredients
contained inside the cells or combustion products could be harmful.

EYE CONTACT: contents of an opened cell inside a battery can cause eye irritation. Dust may cause inflammation of eyelids

SKIN CONTACT: Electrolyte solution contained inside cells can cause skin irritation. Contact with positive active material
may in addition cause allergic dermatitis or irritation to skin.

INHALATION: Contents of an opened cell can cause respiratory tract and mucus membrane irritation. Overexposure to
lithiated nickel compounds may cause an allergic response. If gas is generated during battery disassembly, throat irritation
may occur.

2.2 At module and battery system level


HIGH VOLTAGE: Always use the large battery systems in a restricted access area. Only authorized people aware of high
voltage hazards and trained to work on such systems are allowed to enter in the battery area.

TEMPERATURE: Do not place the batteries on or near fires or other high-temperature locations (> 70°C for VL and VES
cells, > 85°C for extended temperature MP range [with xtd extension] and > 125°C for high temperatures VL cells [with –
125 extension]). Doing so may cause the batteries to overheat or ignite. Using the batteries in this manner may also result
in a loss of performance and a shortened battery life.

3. COMPOSITION, INFORMATION OR INGREDIENTS

3.1 At cell level

Component CAS Number EINECS/ELINCS Content (wt. %)*


Lithiated metal compounds (NCA,NMC, LFP, LCO) N/A N/A 15-30
Organic Electrolyte N/A N/A 10-20
Carbon, as Graphite 7440-44-0 231-153-3 10-25
Copper 7440-50-8 231-159-6 1-30
Aluminium 7429-90-5 231-072-3 1-20
Stainless, Nickel and inert material N/A N/A remainder
* Quantities may vary a little with cell model

3.2 At module and battery system level

Depending on the type of battery system, the battery may contain either a glycol ethylene based coolant or a refrigerated
coolant.

December 2014 – Version 1.2 – Rechargeable Li-ion cells, modules or battery systems Page 2
4. HANDLING AND STORAGE

IMPORTANT NOTICE: The battery should not be opened without Saft approval. The battery should not be destroyed or
incinerated since the battery may cause fire or the ingredients contained in the cells could be harmful if exposed.

STORAGE : Store in a cool, dry and ventilated area. Elevated temperatures can shorten battery life. Since short circuit can
cause burn hazard, leakage or venting hazard, keep batteries in original packaging until use and do not jumble them.

HANDLING :
 Do not short (+) and (-) terminal with conductors.
 Do not short (-) terminal and the can of aluminium can cells with conductors
 Do not short (+) terminal and the can of stainless steel can cells with conductors
 Do not reverse the polarity
 Do not mix different type batteries or mix new and old ones together.
 Do not open the battery system or modules
 Do not use the unit without its electronic management system.
 Do not submit to excessive mechanical stress.
 Do not expose the unit to water or condensation
 Do not directly heat, do not solder or throw into fire. Such unsuitable use can cause leakage or spout vaporized
electrolyte fumes and may cause fire or explosion.
 Immediately disconnect the batteries if, during operation, they emit an unusual smell, feel hot, change shape, or
appear abnormal in any other way. Contact Saft if any of these problems are observed.

CHARGING/DISCHARGING : Charge with charger designed specifically for this battery. Do not overcharge as venting and
combustion can occur. Do not over-discharge. Discharge limits are dependent on the specific product. Refer to Saft
Instructions.

5. PHYSICAL AND CHEMICAL PROPERTIES

The lithium-Ion cell or battery described by this Battery Information Sheet is a sealed unit when offered for sale. It is a
manufactured “article” and does not expose the user to hazardous chemicals when used in accordance with the
manufacturer specifications.

Boiling Point – Not applicable Melting Point – Not applicable


Vapor Pressure – Not applicable Vapor Density – Not applicable
Specific Gravity – Not applicable

6. STABILITY AND REACTIVITY – the battery system is stable when handled and stored according to
section 4

MATERIALS TO AVOID: Oxidizing agents, acids, bases and reducing agents.

CONDITIONS TO AVOID: Avoid exposing battery to fire or high temperature. Do not disassemble, crush or short or install
with incorrect polarity. Avoid mechanical or electrical abuse.

HAZARDOUS DECOMPOSITION PRODUCTS: Lithium hexafluorophosphate may react with water in the atmosphere and
produce some traces of hydrogen fluoride, which do not worsen the gas toxicity. Thermal decomposition of the cell may
release of electrolyte liquid and vapour, harmful materials, and dusts.

December 2014 – Version 1.2 – Rechargeable Li-ion cells, modules or battery systems Page 3
7. TOXICOLOGICAL INFORMATION

Risk of irritation occurs only if the cell is mechanically, thermally or electrically abused to the point of compromising the
integrity of the enclosure. If this occurs, irritation to the skin, eyes and respiratory tract may occur.

8. ECOLOGICAL INFORMATION

None known if used/disposed of correctly

9. DISPOSAL CONSIDERATIONS

Battery recycling is either mandatory (European Directive 2006/66/EC) or recommended.


Batteries should be fully discharged prior to disposal and terminals should be protected.
Dispose in accordance with local laws and regulations. Store material for disposal as indicated in Section 4.
Do not dump into any sewers, on the ground or into any body of water.
See the section on “Sustainability & Environment” on http://www.saftbatteries.com

10. TRANSPORTATION INFORMATION

10.1 Regulatory Framework

Shipment of new and used Lithium-ion cells and batteries are classified as Dangerous Goods under the UN model
regulation.
 If shipped as such, UN Dangerous Goods Entry is: UN 3480
 If shipped contained in equipment or packed with equipment, UN Dangerous Goods Entry is: UN 3481
 If shipped contained in a vehicle, the vehicle is category UN3171 (battery powered vehicle for full electrical type)
or UN3166 (flammable… powered vehicle for hybrid type).

Packaging Group II applies in most situations.

Modal international and national regulations governing transportation by air, sea, road and rail (ICAO/IATA, IMDG, ADR,
RID…) are legally binding and persons offering lithium-ion cells and batteries for transport must comply with all
requirements governing such activity, including but not limited to special provisions, packing instructions, labelling and
training.

10.2 Overview

Persons offering Lithium cells or batteries for transport need to properly determine the applicable provisions and
instructions. More information is available in the official documentation for this purpose
(http://www.unece.org/trans/danger/danger.html ).
Consideration must inter alia be given to:
 The mode of transport: air (IATA), sea (IMDG) , road (ADR) or rail (RID),
 The country of origin and of destination,
 The applicable UN code and related description: Lithium-ion cells or batteries shipped as such, shipped contained
in equipment, or packed with equipment, or shipped in a vehicle,
 The status of the good: new cells or batteries, spent or waste cells or batteries, damaged or defective cells or
batteries, prototype for testing, short production run or commercial series product,
 UN test certification status of the cell or the battery.

December 2014 – Version 1.2 – Rechargeable Li-ion cells, modules or battery systems Page 4
11. REGULATORY INFORMATION

Marking Consideration
European Union: According to directive 2006/66/EC, the batteries have to be marked with the crossed-out wheel bin
symbol.
Lithium-ion batteries, which contain electronic modules (e.g. PCM) and which are subjected to the EMC directive
93/97/EEC, must be approved and must be marked with the CE marking.

International safety standards: Cells are approved according to UL 1642.

12. FIRST AID MEASURES (not anticipated under normal use)

EYE CONTACT: Immediately flush eyes with copious amount of water for at least 15 minutes. Seek immediate medical
attention.

SKIN CONTACT: Remove contaminated clothing and flush affected areas with plenty of water for at least 15 minutes. Wash
skin with soap and water. If skin irritation persists, call for a medical attention.

INHALATION: Remove to fresh air and seek immediate medical attention. Obtain medical advice.

INGESTION: Clear mouth with water and afterwards drink plenty of water. Do not induce vomiting. Seek immediate
medical attention.

13. FIRE FIGHTING MEASURES (not anticipated under normal use)

ESTINGUISHING MEDIA:
 Small fires: use D type fire extinguisher, inert gas (for instance blend of argon and nitrogen), CO 2, dry chemical
powder or foam extinguishers
 Large fires: use large quantities of water for the surrounding fire and to prevent propagation. If water is used on
batteries in operation, caution should be taken to avoid the electrical hazard that may be present.

SPECIAL FIRE FIGHTING PROCEDURES: Fire fighters should wear self-contained breathing apparatus.
Use approved / certified vapour respirator to avoid breathing toxic fumes. Wear protective clothing and equipment to
prevent potential body contact with electrolyte solution. It is permissible to use any class of extinguishing medium,
specified above, on these batteries or their packing material. Cool exterior of batteries if exposed to fire to prevent
rupture.

PARTICULAR HAZARDS RESULTING FROM EXPOSURE TO THE SUBSTANCE/PREPARATION, TO COMBUSTION AND GAS
PRODUCTS: The cell can spout vaporized or decomposed electrolyte fumes with fire when being heated over +100°C
(+212°F) (over 125°C for high temperatures VL cells [with – 125 extension]) or disposed in fire. Solvents within the
electrolyte are flammable liquids and must be kept away from any kind of ignition source.

14. EXPOSURE CONTROLS AND PERSONAL PROTECTION* (not necessary under normal use)

Handle an opened battery only in a well ventilated place.

In case of incident or after an abusive use, in case of leaking or ruptured cells, use a gas mask which covers the
Respiratory
whole face and equipped with ABEK type filters or an escape mask such as a Self-Contained Breathing Apparatus.
protection Fire fighters should wear self-contained breathing apparatus.

December 2014 – Version 1.2 – Rechargeable Li-ion cells, modules or battery systems Page 5
Hand
Use polypropylene, polyethylene, rubber or Viton gloves when handling leaking or ruptured cells.
protection
Eye In case of incident or after an abusive use, in case of leaking or ruptured cells, wear safety glasses with protected
protection side shields or a mask covering the whole face when handling leaking or ruptured cells

Other In the event of leaking or ruptured cells, wear a rubber apron and protective clothes.

*AFNOR pictograms

15. ACCIDENTAL RELEASE MEASURES (not anticipated under normal use)

INDIVIDUAL PRECAUTIONS: Evacuate the employees from the contaminated area until fumes dispersal. In case of
electrolyte leakage from a cell or battery, do not inhale the gas as possible. In case of skin or eye contact, inhalation or
ingestion, follow the measures described in section 4.

ENVIRONMENTAL PRECAUTION: Avoid sewage, surface water and underground water contamination. Avoid ground and
atmosphere contamination.

CLEANING PROCEDURE: Use protective glasses and gloves, use absorbent material (sand, earth or vermiculite) to absorb
any exuded material. Seal leaking battery (unless hot) and contaminated absorbent material in plastic bag and dispose of as
Special waste in accordance with local regulations.

16. OTHER INFORMATION

This information has been compiled from sources considered to be dependable and is, to the best of our knowledge,
accurate and reliable as of the date compiled. However, neither complete exhaustiveness nor perfect reliability can be
granted. The communication of this information does not constitute an implicit or specific warranty.

This information relates to the specific products it is applicable to and may be invalid for these products when used in
combination with any other equipment or in any process. It is the user’s responsibility to satisfy himself as to the suitability
and completeness of this information for his particular use.

Saft does not accept liability for any loss or damage that may occur, whether direct, indirect, incidental or consequential,
from the use of this battery information sheet provided as a service to our customers. Saft does not offer warranty against
patent infringement.

Doc N˚ BIS01-2-12
12, rue Sadi Carnot
Edition: December 2014
93170 Bagnolet – France Version 1.2
Tel.: +33 (0)1 49 93 19 18
Fax: +33 (0)1 49 93 19 69 Data in this document is subject to
www.saftbatteries.com change without notice and
becomes contractual only after
written confirmation.

December 2014 – Version 1.2 – Rechargeable Li-ion cells, modules or battery systems Page 6
Operational Information and Safety Safety Manual
Precautions for General Equipment Issue B1

Appendix B – Cell Datasheets


B.1 Lithium Cells

Saft LS33600 39
Saft LS26500 41
Saft LSH20 43
Saft LSH14 45
Saft LSH14 Light 47
Saft LS14500 49

Appendix B – Cell Datasheets 38


Primary lithium battery
LS 33600

3.6 V Primary lithium-thionyl chloride (Li-SOCl2)


High energy
D-size bobbin cell

Benefits
Cell size references D
l 
High voltage response, stable
during most of the lifetime of the Electrical characteristics
application (typical values relative to cells stored for one year or less at + 30°C max.)
l 
Wide operating temperature
Nominal capacity 17.0 Ah
range (- 60°C/85°C) (at 5 mA + 20°C 2.0 V cut-off. The capacity restored by the cell varies
l 
Easy integration in compact according to current drain, temperature and cut-off)
system Open circuit voltage (at + 20°C) 3.67 V
l 
Low self-discharge rate
Nominal voltage (at 0.7 mA + 20°C) 3.6 V
(less than 1 % after 1 year of
Nominal energy 61.2 Wh
storage at + 20°C)
Pulse capability: Typically up to 400 mA
(400 mA/0.1 second pulses, drained every 2 mn at + 20°C from undischarged cells with 10 µA
Key features
base current, yield voltage readings above 3.0 V. The readings may vary according to the pulse
l Stainless steel container characteristics, the temperature, and the cell’s previous history. Fitting the cell with a capacitor
may be recommended in severe conditions. Consult Saft)
l Hermetic glass-to-metal sealing
l Built-in safety vent Maximum recommended continuous current 250 mA
(to maintain cell heating within safe limits. Battery packs may imply lower
l 
Finish with or without flat
level of maximum current and may request specific thermal protection.
positive end Consult Saft)
l Non-flammable electrolyte
Storage (recommended) + 30°C (+ 86°F) max
l 
Compliant with IEC 60086-4 (for more severe conditions, consult Saft)
safety standard and Operating temperature range - 60°C/+ 85°C
IEC 60079-11 intrinsic safety (Operation above ambient T may lead to reduced capacity and (- 76°F/+ 185°F)
standard lower voltage readings at the beginning of pulses. Consult Saft)
l Underwriters Laboratories (UL)
Physical characteristics
Component Recognition
(File Number MH 12609) Diameter (max) 33.4 mm (1.32 in)

l Restricted for transport (Class 9) Height (max) 60.2 or 61.6 mm


(2.37 in or 2.42 in)
depending on finish type
Main applications
Typical weight 90 g (3.2 oz)
l Utility
metering
Li metal content approx. 4.5 g
l Automatic meter readers

l Buoys Available termination suffix


CN, CNR radial tabs
l Measuring equipment
CNA (AX) axial leads
l Industrial applications FL flying leads... etc.
l Professional electronics
l Marine equipment

Optional upon request


l Low magnetic version

July 2010
LS 33600 3.6
3.6
Voltage plateau versus Current and Temperature (at mid-discharge)

3.5
3.6
3.5
Ø 33.1 ± 0.3
3.4
3.5
3.4
Ø 9.3 ± 0.1
Ø 33.1
(on ± 0.3
flat surface) 3.3
3.4 +
3.3 + 55°C
55°C

Cell voltage (V)


Ø 9.3 ± 0.1
3.2
3.3
3.2 + 55°C
(on flat surface)
3.1
3.2
3.1
2.1 ± 0.2
3.0
3.1
3.0
2.1 ± 0.2 2.9
3.0
2.9
-- 20°C
20°C
2.8
2.9
2.8
61.0 ± 0.6 2.7 - 20°C
2.8
2.7 +
+ 20°C
20°C
2.6
2.7
2.6 -- 40°C
61.0 ± 0.6 40°C + 20°C
2.5
2.6
2.5 - 40°C
0.5
2.50.1 1 11 10 100 1000
0.1 1 10 100 1000
0.1 1 1 10 100 1000
0.5
Current (mA)
Ø 18.0 ± 0.2
(on flat surface)
Ø 18.0 ± 0.2
(on flat surface)

Typical discharge profiles at + 20°C


Finished version with
protruding positive end cap
3.5
3.5
Ø 33.1 ± 0.3 3.5
3.3
3.3
Ø 13.8 ± 0.2
(on flat surface) 3.3
3.1
Cell voltage (V)

Ø 33.1 ± 0.3 3.1

mA
Ø 13.8 ± 0.2

mAmA
mA
3.1

mA
2.9

mA

mAmA
(on flat surface)

mAmA
2.9

mAmA

Ohms/3.5
Ohms/3.5
Ohms/6.9
Ohms/107
2.9

Ohms/200
2.7

Ohms/6.9
30Ohms/107
15Ohms/200
0.6 ± 0.2 2.7

Ohms/3.5
Ohms/6.9
Ohms/107
Ohms/200
2.7
2.5
0.6 ± 0.2 2.5
2.5
2.3

1000
2.3

1000
515
515
2.3
2.1

30 30
59.6 ± 0.6

15 15

1000
2.1

515
59.6 ± 0.6 2.1
1.9
1.9
1.7
1.9
1.7
0.5 1.70.1 1 10 100 1000 10000
0.1 1 10 100 1000 10000
0.5 0.1 1 10 Time (hours)100 1000 10000
Ø 18.0 ± 0.2
(on flat surface)
Ø 18.0 ± 0.2
Finished version with
(on flat surface)
Restored Capacity versus Current and Temperature (2.0 V cut-off)
flat positive end cap

Dimensions in mm. 16.0


16.0
16.0
14.0
14.0
Storage 14.0
12.0
Capacity (Ah)

12.0
• The storage area should be clean, 12.0
10.0
10.0
cool (preferably not exceeding 10.0
8.0 +
+ 20°C
20°C
8.0
+ 30°C), dry and ventilated. 8.0 -- 20°C
20°C
+ 20°C
6.0
6.0
- 20°C
Warning 6.0
4.0
4.0
• Fire, explosion and burn hazard. 4.0
2.0
-- 40°C
40°C
2.0
• Do not recharge, short circuit, 2.0
0
- 40°C
0
crush, disassemble, heat above 00.1
0.1 1
1 10
10 100
100 1000
1000
100°C (212°F), incinerate, Current
0.1 1 10 (mA) 100 1000
or expose contents to water.
• Do not solder directly to the cell
(use tabbed cell versions instead).

Doc. No 31007-2 -0710


Saft Information in this document is subject to change without notice
and becomes contractual only after written confirmation by Saft.
Specialty Battery Group
For more details on primary lithium technologies please refer to
12, rue Sadi Carnot Primary Lithium Batteries Selector Guide Doc No 31048-2.
93170 Bagnolet - France Published by the Communications Department.
Tel.: +33 (0)1 49 93 19 18 Photo credit: Saft
Fax : +33 (0)1 49 93 19 69 Société anonyme au capital de 31 944 000
RCS Bobigny B 383 703 873
www.saftbatteries.com Produced by Arthur Associates Limited.
Primary lithium battery
LS 26500

3.6 V Primary lithium-thionyl chloride (Li-SOCl2)


High energy density
C-size bobbin cell

Benefits
Cell size references C
l 
High voltage response, stable
during most of the lifetime of the Electrical characteristics
application (typical values relative to cells stored for one year or less at + 30°C max.)
l 
Wide operating temperature
range (- 60°C/+ 85°C) Nominal capacity 7.7 Ah
(at 4 mA + 20 °C 2.0 V cut-off. The capacity restored by the cell varies
l 
Low self-discharge rate according to current drain, temperature and cut-off)
(less than 1 % after 1 year of
Open circuit voltage (at + 20°C) 3.67 V
storage at + 20°C)
Nominal voltage (at 0.5 mA + 20°C) 3.6 V
l 
Easy integration into compact
systems Nominal energy 27.72 Wh
l 
Superior resistance to Pulse capability: Typically up to 300 mA
atmospheric corrosion (300 mA/0.1 second pulses, drained every 2 mn at + 20°C from undischarged cells with 10 µA
base current, yield voltage readings above 3.0 V. The readings may vary according to the pulse
characteristics, the temperature, and the cell’s previous history. Fitting the cell with a capacitor
Key features may be recommended in severe conditions. Consult Saft)
l Stainless steel container Maximum recommended continuous current 150 mA
and end caps (Higher currents possible, consult Saft)
(low magnetic signature) Storage (recommended) + 30°C (+ 86°F) max
l Hermetic glass-to-metal sealing (for more severe conditions, consult Saft)

l Non-flammable electrolyte Operating temperature range - 60°C/+ 85°C


l Underwriters Laboratories (UL) (Operation above ambient T may lead to reduced capacity and (- 76°F/+ 185°F)
lower voltage readings at the beginning of pulses. Consult Saft)
Component Recognition
l Compliant with IEC 60086-4 Physical characteristics
safety standard and Diameter (max) 26.0 mm (1.02 in)
IEC 60079-11 intrinsic safety
Height (max) 49.1 mm or 50.4 mm
standard (1.93 in or 1.98 in)
l Restricted for transport (Class 9) depending on finish type
Typical weight 48 g (1.7 oz)
Main applications Li metal content approx. 2.0 g
l Utility metering Available termination suffix
l Automatic meter readers CNR radial tabs
3 PF, 3 PF RP radial pins
l Buoys
CNA (AX) axial leads
l Measuring equipment FL flying leads... etc.
l Industrial
applications
l Professional electronics

Optional upon request


l Low magnetic version

May 2010
LS 26500 3.6
Voltage plateau versus Current and Temperature (at mid-discharge)

3.6
3.6
3.5
3.5
3.5 + 70ºC
Ø 25.8 ± 0.2 3.4 +
+ 70ºC
70ºC
3.4
3.4

Cell voltage (V)


Ø 6.0 ± 0.1 3.3
3.3
3.3
(on flat surface) + 20ºC
3.2 +
3.2 + 20ºC
20ºC
3.2
3.1
3.1
3.1
3.0
3.0
3.0
2.0 ± 0.2
2.9
2.9
2.9
2.8
2.8
2.8 - 20ºC
49.8 ± 0.6 2.7 -- 20ºC
2.7 20ºC
2.7 - 40ºC
2.6 -- 40ºC
40ºC
2.6
2.60.1 1 10 100 1000
0.4
0.1
0.1 1
1 10
10 100
100 1000
1000

Current (mA)

Ø 18.0 ± 0.2
(on flat surface)
Typical discharge profiles at + 20°C
Finished version with
protruding positive end cap 3.9
3.9
3.9
Ø 25.8 ± 0.2 3.7
3.7
3.7
Ø 13.4 ± 0.2 3.5
3.5
Cell voltage (V)

(on flat surface) 3.5


3.3

mA
3.3
3.3

mA
mA
mA
mA
3.1

mA
mA

mA
3.1

Ohms/0.7
mA
mA
3.1

mA

Ohms/0.7
mA

Ohms/0.7
Ohms/14
Ohms/125
2.9

Ohms/14
Ohms/125
2.9

Ohms/35

Ohms/14
Ohms/125
2.9

Ohms/35
0.8 ± 0.2

Ohms/35
2.7
2.7
2.7
2.5
2.5

5000
2.5

5000
250
48.7 ± 0.5 2.3

5000
250
75
25
2.3

250
2.3

75
25

75
25
2.1
2.1
2.1
0.4 1.9
1.9
1.90.01 0.1 1 10 100 1000 10000 100000
0.01
0.01 0.1
0.1 1
1 10
10 100
100 1000
1000 10000
10000 100000
100000
Time (hours)
Ø 18.0 ± 0.2
(on flat surface)

Finished version with Restored Capacity versus Current and Temperature (2.0 V cut-off)
flat positive end cap

Dimensions in mm.
7.0
7.0
7.0

Storage 6.0
Capacity (Ah)

6.0
6.0
+ 70ºC
+
+ 70ºC
l 
The storage area should be clean, 5.0 70ºC
5.0
5.0
cool (preferably not exceeding
4.0
+ 30°C), dry and ventilated. 4.0
4.0 + 20ºC
+
+ 20ºC
20ºC
3.0
Warning 3.0
3.0 - 20ºC
- 40ºC -- 20ºC
20ºC
l 
Fire, explosion and severe burn 2.0 -- 40ºC
40ºC
2.0
2.0
hazard.
1.0
l 
Do not recharge, short circuit, 1.0
1.0 1 10 100 1000
1
1 10
10 100
100 1000
1000
crush, disassemble, heat above Current (mA)
100°C (212°F), incinerate,
or expose contents to water.
l 
Do not solder directly to the cell
(use tabbed cell versions instead).

Saft Doc. No 31016-2-0510


Specialty Battery Group Information in this document is subject to change without notice
12, rue Sadi Carnot and becomes contractual only after written confirmation by Saft.
For more details on primary lithium technologies please refer to
93170 Bagnolet - France Primary Lithium Batteries Selector Guide Doc No 31048-2.
Tel.: +33 (0)1 49 93 19 18 Photo credit: Saft
Fax : +33 (0)1 49 93 19 69 Société anonyme au capital de 31 944 000
RCS Bobigny B 383 703 873
www.saftbatteries.com Produced by Arthur Associates Limited.
Primary lithium battery
LSH 20

3.6 V Primary lithium-thionyl chloride (Li-SOCl2)


High power
D-size spiral cell

Benefits
Cell size references UM1 – R20 – D
● High voltage response, stable during
most of the lifetime of the application Electrical characteristics
● High drain/pulse capability (typical values relative to cells stored for one year or less at + 30°C max.)
● Wide operating temperature range
Nominal capacity 13.0 Ah
(-60°C/+85°C)
(at 15 mA + 20°C 2.0 V cut off. The capacity restored by the cell varies
● Easy integration into compact according to current drain, temperature and cut off)
systems Open circuit voltage (at + 20°C) 3.67 V
● Low self-discharge rate
Nominal voltage (at 2 mA + 20°C) 3.6 V
(less than 3% after 1 year of storage
at +20°C) Pulse capability: Typically up to 4000 mA
(4000 mA/0.1 second pulses, drained every 2 mn at + 20°C from
undischarged cells with 10 µA base current, yield voltage readings above
Key features 3.0 V. The readings may vary according to the pulse characteristics, the
temperature, and the cell's previous history. Fitting the cell with a capacitor
● Stainless steel container may be recommended in severe conditions. Consult Saft)
● Hermetic glass-to-metal sealing
Maximum recommended continuous current 1800 mA
● Built-in safety vent (to maintain cell heating within safe limits. Battery packs may imply lower
● Finish with 5 A fuse level of maximum current and may request specific thermal protection.
● Non-flammable electrolyte Consult Saft)

● Underwriters Laboratories (UL) Storage (recommended) + 30°C (+ 86°F) max


Component Recognition (for more severe conditions, consult Saft)

(File Number MH 12609) Operating temperature range - 60°C/+ 85°C


● Restricted for transport (Class 9) (Operation above ambient T may lead to reduced capacity and (- 76°F/+ 185°F)
lower voltage readings at the beginning of pulses. Operation with
current continuously above 1 A may restrict upper T range. Consult Saft)
Main applications
● Radiocommunication and other Physical characteristics
military applications Diameter (max) 33.4 mm (1.32 in)
● Alarms and security systems
Height (max) 61.6 mm (2.42 in)
● Beacons and emergency location
transmitters Typical weight 100 g (3.5 oz)

● GPS Li metal content approx. 3.8 g


● Metering systems Available termination suffix
● Sonobuoys CN, CNR radial tabs
CNA (AX) axial leads
● Tracking systems
FL flying leads ...etc.
● GSM communication

NATO stock number


6135 14 440 1213

October 2006
LSH 20

Cell voltage (V)


Ø 33.1 ± 0.3
Ø 9.3 ± 0.1
(on flat surface)

Current (mA)
2.1 ± 0.2
Voltage plateau versus Current and Temperature (at mid-discharge)

61.0 ± 0.6
Cell voltage (V)

0.5

Ø 18.0 ± 0.2
(on flat surface)

Dimensions in mm.

Time (hours)
Typical discharge profiles at + 20°C

Storage
• The storage area should be
clean, cool (preferably not
exceeding + 30°C), dry and
ventilated.
Capacity (Ah)

Warning
• Fire, explosion and burn hazard.
• Do not recharge, short circuit,
crush, disassemble, heat above
100°C (212°F), incinerate,
or expose contents to water.
• Do not solder directly to the cell Current (mA)
(use tabbed cell versions instead). Restored Capacity versus Current and Temperature (2.0 V cut off)

Doc. No 31015-2- 1006


Saft Information in this document is subject to change without notice
Specialty Battery Group and becomes contractual only after written confirmation by Saft.

12, rue Sadi Carnot For more details on primary lithium technologies please refer to
Primary Lithium Batteries Selector Guide Doc No 31048-2.
93170 Bagnolet - France Published by the Communications Department.
Tel +33 (0)1 49 93 19 18 Photo credit: Saft
Fax +33 (0)1 49 93 19 69 Société anonyme au capital de 31 944 000 €
RCS Bobigny B 383 703 873
www.saftbatteries.com Produced by Arthur Associates
Primary lithium battery
LSH 14

3.6 V Primary lithium-thionyl chloride (Li-SOCl2)


High power
C-size spiral cell

Benefits
Cell size references UM2 – R14 – C
● High voltage response, stable during
most of the lifetime of the application Electrical characteristics
● High drain/pulse capability (typical values relative to cells stored for one year or less at + 30°C max.)
● Wide operating temperature range
Nominal capacity 5.8 Ah
(- 60°C/85°C) (at 15 mA + 20°C 2.0 V cut-off. The capacity restored by the cell varies
● Easy integration in compact system according to current drain, temperature and cut-off)
● Low self-discharge rate Open circuit voltage (at + 20°C) 3.67 V
(less than 3 % after 1 year of storage
Nominal voltage (at 1mA + 20°C) 3.6 V
at + 20°C)
Pulse capability: Typically up to 2000 mA
(2000 mA/0.1 second pulses, drained every 2 mn at + 20°C from
Key features undischarged cells with 10 µA base current, yield voltage readings above
3.0 V. The readings may vary according to the pulse characteristics, the
● Stainless steel container
temperature, and the cell's previous history. Fitting the cell with a capacitor
● Hermetic glass-to-metal sealing may be recommended in severe conditions. Consult Saft)
● Built-in safety vent
Maximum recommended continuous current 1300 mA
● Finish with 5 A fuse (to maintain cell heating within safe limits. Battery packs may imply lower
● Non-flammable electrolyte level of maximum current and may request specific thermal protection.
Consult Saft)
● Underwriters Laboratories (UL)
Component Recognition Storage (recommended) + 30°C (+ 86°F) max
(for more severe conditions, consult Saft)
(File Number MH 12609)
● Compliant with IEC 60086-4 Operating temperature range - 60°C/+ 85°C
(Operation at extreme T may lead to reduced capacity and lower voltage (- 76°F/+ 185°F)
● Restricted for transport (Class 9) readings at the beginning of pulses. Consult Saft)

Main applications Physical characteristics


● Radiocommunication and other Diameter (max) 26.0 mm (1.02 in)
military applications
Height (max) 50.4 mm (1.98 in)
● Alarms and security systems
Typical weight 51 g (1.8 oz)
● Beacons and emergency location
transmitters Li metal content approx. 1.7 g
● GPS Available termination suffix
● Metering systems CN, CNR radial tabs
3PF, 3 PF RP radial pins
● Sonobuoys
CNA (AX) axial leads
● Automotive telematics FL flying leads ...etc.
● Pipeline inspection

NATO stock number


6135 12 306 4125

June 2007
LSH 14

Cell voltage (V)


Ø 25.8 ± 0.2

Ø 6.0 ± 0.2
(on flat surface)

Current (mA)

2.0 ± 0.2
Voltage plateau versus Current and Temperature (at mid-discharge)

49.8 ± 0.6

0.4
Cell voltage (V)

Ø 18.0 ± 0.2
(on flat surface)

Dimensions in mm.

Time (hours)

Typical discharge profiles at + 20°C


Storage
• The storage area should be clean,
cool (preferably not exceeding
+ 30°C), dry and ventilated.
Warning
Capacity (Ah)

• Fire, explosion and burn hazard.


• Do not recharge, short circuit,
crush, disassemble, heat above
100°C (212°F), incinerate,
or expose contents to water.
• Do not solder directly to the cell
(use tabbed cell versions instead).
Current (mA)

Restored Capacity versus Current and Temperature (2.0 V cut-off)

Doc. No 31013-2-0607

Saft Information in this document is subject to change without notice


and becomes contractual only after written confirmation by Saft.
Specialty Battery Group
For more details on primary lithium technologies please refer to
12, rue Sadi Carnot Primary Lithium Batteries Selector Guide Doc No 31048-2.
93170 Bagnolet - France Published by the Communications Department.
Tel +33 (0)1 49 93 19 18 Photo credit: Saft
Fax +33 (0)1 49 93 19 69 Société anonyme au capital de 31 944 000
RCS Bobigny B 383 703 873

www.saftbatteries.com Produced by Arthur Associates


Primary lithium battery
LSH 14 “light”

3.6 V Primary lithium-thionyl chloride (Li-SOCl2)


High power
C-size spiral cell
(non-restricted for transport)

Benefits
Cell size references UM2 – R14 – C
● High voltage response, stable
during most of the lifetime of the Electrical characteristics
application
(typical values relative to cells stored for one year or less at + 30°C max.)
● High drain/pulse capability
● Wide operating temperature range Nominal capacity 3.6 Ah
(at 15 mA + 20°C 2.0 V cut off. The capacity restored by the cell varies
(-60°C/85°C) according to current drain, temperature and cut off)
● Easy integration in compact system
Open circuit voltage (at + 20°C) 3.67 V
● Low self-discharge rate
(less than 3% after 1 year of storage Nominal voltage (at 1mA + 20°C) 3.6 V

at +20°C) Pulse capability: Typically up to 2000 mA


● Non-restricted for transport (2000 mA/0.1 second pulses, drained every 2 mn at + 20°C from
undischarged cells with 10 µA base current, yield voltage readings above
3.0 V. The readings may vary according to the pulse characteristics,
Key features the temperature, and the cell's previous history. Fitting the cell with a
capacitor may be recommended in severe conditions. Consult Saft)
● Stainless steel container
Maximum recommended continuous current 1300 mA
● Hermetic glass-to-metal sealing
(to maintain cell heating within safe limits. Battery packs may imply lower
● Built-in safety vent level of maximum current and may request specific thermal protection.
● Finish with 5 A fuse Consult Saft)
● Non-flammable electrolyte Storage (recommended) + 30°C (+ 86°F) max
(for more severe conditions, consult Saft)

Main applications Operating temperature range - 60 °C/+ 85°C


(Operation at extreme T may lead to reduced capacity and (- 76°F/+ 185°F)
● Radiocommunication and other lower voltage readings at the beginning of pulses. Consult Saft)
military applications
● Alarms and security systems Physical characteristics
● Beacons and emergency location Diameter (max) 26.0 mm (1.02 in)
transmitters Height (max) 50.4 mm (1.98 in)
● GPS
Typical weight 51 g (1.8 oz)
● Metering systems
● Sonobuoys Li metal content below 1 g

Available termination suffix


CN, CNR radial tabs
3 PF, 3 PF RP radial pins
CNA (AX) axial leads
FL flying leads ...etc.

October 2006
LSH 14 “light”

Cell voltage (V)


Current (mA)

Voltage plateau versus Current and Temperature (at mid-discharge)

Cell voltage (V)

Dimensions in mm.

Time (hours)

Typical discharge profiles at + 20°C

Storage
• The storage area should be clean,
cool (preferably not exceeding
+ 30°C), dry and ventilated.
Capacity (Ah)

Warning
• Fire, explosion and burn hazard.
• Do not recharge, short circuit,
crush, disassemble, heat above
100°C (212°F), incinerate,
or expose contents to water.
• Do not solder directly to the cell
(use tabbed cell versions instead). Current (mA)

Restored Capacity versus Current and Temperature (2.0 V cut off)

Doc. No 31046-2-1006
Saft Information in this document is subject to change without notice
Specialty Battery Group and becomes contractual only after written confirmation by Saft.

12, rue Sadi Carnot For more details on primary lithium technologies please refer to
Primary Lithium Batteries Selector Guide Doc No 31048-2.
93170 Bagnolet - France
Published by the Communications Department.
Tel +33 (0)1 49 93 19 18
Photo credit: Saft
Fax +33 (0)1 49 93 19 69
Société anonyme au capital de 31 944 000
RCS Bobigny B 383 703 873

www.saftbatteries.com Produced by Arthur Associates


Primary lithium battery
LS 14500

3.6 V Primary lithium-thionyl chloride (Li-SOCl2)


High energy density
AA-size bobbin cell

Benefits
Cell size references R6 - AA
l 
Enhanced capacity
l High voltage response, stable Electrical characteristics
during most of the lifetime of (typical values relative to cells stored for one year or less at + 30 °C max.)
the application
Nominal capacity 2.6 Ah
l Wide operating temperature (at 2 mA + 20 °C 2.0 V cut-off. The capacity restored by the cell varies
range (- 60 °C/+ 85°C) according to current drain, temperature and cut-off)
l Low self-discharge rate Open circuit voltage (at + 20°C) 3.67 V
(less than 1 % after 1 year of Nominal voltage (at 0.2 mA + 20°C) 3.6 V
storage at + 20 °C)
Nominal energy 9.36 Wh
l Easy integration into compact
systems Pulse capability: Typically up to 250 mA
(250 mA/0.1 second pulses, drained every 2 mn at + 20 °C from
l Superior resistance to undischarged cells with 10 µA base current, yield voltage readings above
atmospheric corrosion 3.0 V. The readings may vary according to the pulse characteristics, the
temperature, and the cell’s previous history. Fitting the cell with a capacitor
Key features may be recommended in severe conditions. Consult Saft)

l 
Stainless steel container Maximum recommended continuous current 50 mA
and end caps (Higher currents possible, consult Saft)

(low magnetic signature) Storage (recommended) + 30°C (+ 86°F) max


l 
Hermetic glass-to-metal sealing (for more severe conditions, consult Saft)

l 
Non-flammable electrolyte Operating temperature range - 60°C/+ 85°C
l 
Compliant with IEC 60086-4 (Operation above ambient T may lead to reduced capacity and (- 76°F/+ 185°F)
lower voltage readings at the beginning of pulses. Consult Saft)
safety standard and
IEC 60079-11 intrinsic safety Physical characteristics
standard (class T3 assignment)
Diameter (max) 14.55 mm (0.57 in)
l Underwriters Laboratories (UL)
Height (max) 50.3 mm (1.98 in)
Component Recognition
l 
Non-restricted for transport/ Typical weight 16.7 g (~ 0.6 oz)
Non-assigned to Class 9 Li metal content approx. 0.7 g
according to the UN Available termination suffix
Recommendations on the CN, CNR radial tabs
transport of dangerous goods 2 PF, 3 PF, 3 PF RP, 4 PF radial pins
CNA (AX) axial leads
– Model Regulations FL flying leads...etc.
l Manufactured in France, UK, China
Main applications
l Utilitymetering
l Automatic meter reading
l Alarms and security devices

l Tollgate systems

l Memory back-up

l Tracking systems

l Automotive electronics

l Professional electronics

September 2009
LS 14500 3.8
Voltage plateau versus Current and Temperature (at mid-discharge)

3.6

3.4 + 70ºC

Cell voltage (V)


+ 55ºC
3.2

3.0 + 20ºC

2.8

Ø 4.2 min 2.6


5.5 max - 20ºC
(flat area) 2.4
- 40ºC
2.2
0.1 1 10 100 1000

Current (mA)
1.35 ± 0.3

Typical discharge profiles at + 20°C


Ø 14.44 ±
50 ± 0.3 3.8
0.11
3.6

3.4
0.4 ± 0.1
Cell voltage (V)

3.2

1000 Ohms/3.6 mA
3.0

400 Ohms/8.6 mA

3600 Ohms/1 mA
57 Ohms/55 mA
2.8
Ø 7.5 ± 0.1
2.6
Dimensions in mm.
2.4

2.2

2.0
0.1 1 10 100 1000 10000
Time (hours)

Storage Restored Capacity versus Current and Temperature (2.0 V cut-off)


l 
The storage area should be 3.0
2.8
clean, cool (preferably not 2.6
exceeding + 30°C), dry and 2.4
2.2
ventilated.
Capacity (Ah)

2.0
1.8
Warning 1.6
1.4
l 
Fire, explosion and burn hazard. 1.2
1.0
l 
Do not recharge, short circuit,
0.8
crush, disassemble, heat above 0.6
100°C (212°F), incinerate, 0.4
0.2
or expose contents to water. 0.0
l 
Do not solder directly to the cell 0.01 0.1 1 10 100 1000
(use tabbed cell versions instead). Current (mA)

Doc. No 31064-2-0909
Saft Information in this document is subject to change without notice
and becomes contractual only after written confirmation by Saft.
Specialty Battery Group
For more details on primary lithium technologies please refer to
12, rue Sadi Carnot Primary Lithium Batteries Selector Guide Doc No 31048-2.
93170 Bagnolet - France Published by the Communications Department.
Tel.: +33 (0)1 49 93 19 18 Photo credit: Saft
Fax : +33 (0)1 49 93 19 69 Société anonyme au capital de 31 944 000
RCS Bobigny B 383 703 873
www.saftbatteries.com Produced by Arthur Associates Limited.
Operational Information and Safety Safety Manual
Precautions for General Equipment Issue B1

B.2 Lithium-ion Cells

allbatteries - Enix Energy 292393 52


Molicel ICR18650H 53
Saft MP144350 55
VARTA LLP50379DL 57
Inspired Energy NL2024 58

Appendix B – Cell Datasheets 51


PRODUCT DATA SHEET
LITHIUM-ION RECHARGEABLE BATTERY MODEL ICR18650H

nCELL SPECIFICATIONS
Shape / Can material Cylindrical / Steel
Max. 18.4mm
Typical Capacity 2200mAh
Minimum Capacity 2100mAh
Nominal Capacity 2100mAh
Nominal Voltage 3.7V
Charge Voltage 4.2V ± 0.05V
Charge Current Less than 1250mA
(Recommendation)
Charge Time 3.0 hrs
5.0 A (≤ 45 oC)
Discharging current (Max.)
4.0 A (≤ 60 oC)
Discharge Cutoff Voltage 3.0V Max.
65.15mm
Charge 0oC to 45oC
Temperature Discharge -20oC to 60oC
Storage -20oC to 60oC
Weight (Max.) 47.1g
Diameter 18.40mm
Dimensions (Max)
Height (Max.) 65.15mm
Gravimetric 496 Wh/l
Energy Volumetric 182 Wh/kg
Density

Note: The ICR18650H cylindrical cell consists of a lithium cobalt oxide positive electrode and a
graphitic carbon negative electrode providing 3.7volts and 2200mAh. This cell design requires pack
control circuitry. Various protection circuit modules are available for applications of multiple series and
parallel configurations. For multi-cell application, the over-current protective devices (PTC or thermal
fuse) is NEEDED on each cell or between cells connected in parallel. In order to ensure safe use of cell,
be sure to consult with E-One Moli Energy regarding charging and discharging specifications and
contact E-One Moli Energy in advance when designing a device with this cell.

2005/1 1/2
PRODUCT DATA SHEET
LITHIUM-ION RECHARGEABLE BATTERY MODEL ICR18650H

nCharge Characteristics nDischarge Rate Characteristics


4.0 5.0 120 5.0
Charge:
Constant Current-Constant Voltage Charge to 4.2V at 23oC.
3.5
100
4.0 4.0
3.0

1.25A
80
2.5 2.2A

Capacity (%)
3.0 3.0
Voltage (V)

Voltage (V)
Current (A)

4.4A 3.3A 2.2A 1.1A 0.44A

2.0 60

2.0 2.0
1.5 Charge: Constant Current-Constant Voltage, 1.25A, 4.2V, 3hr.
40 Discharge: Cut 0ff at 3.0V.
1.0 Temperature: 21oC.
1.0 1.0
20
0.5

0.0 0.0 0 0.0


0.0 0.5 1.0 1.5 2.0 2.5 0 200 400 600 800 1000 1200 1400 1600 1800 2000 2200 2400
Time (hrs) Capacity (mAH)

nDischarge Temperature Characteristics nCycle Characteristics


120 120

100 100
23oC
0.44A

45oC
80 80
Capacity (%)

Capacity (%)

1.1A

60 60
2.0A

40 40
Charge: CC-CV, 1.25A, 4.2V, 3 hrs. Charge: Constant Current-Constant Voltage, 1.25A, 4.2V, 3hr
Discharge: Cut off at 3.0V. Discharge: Constant Current, 2.0A, Cut off at 3.0V
The discharge capacity at 21oC is taken as 100%.
20 20

0 0
-20 0 20 40 60 0 50 100 150 200 250 300
Temperature (oC) Cycle Number (times)

Molicel ICR18650H Applications:


* Notebook * Portable VCD/DVD player
* HID handy flash * Camcorder
* Medical devices

E-One Moli Energy, a pioneer in lithium ion battery development and manufacturing in Taiwan/Canada, is capable of
providing lithium ion cells with absolute safety, maturely size, high power, and long life.

© E-One Moli Energy Corp. © E-One Moli Energy (Canada) Ltd. © Sales & Marketing Office © Agency:
10 Dali 2nd Rd., Shan-Hwa, 20,000 Stewart Crescent 7F, 113, Sec.2, Zhung Shan N Rd.,
Tainan County, Taiwan, R.O.C. Maple Ridge, B.C., Canada, V2X 9E7 Taipei, Taiwan, R.O.C.
Tel: 886-6-505-0666 Tel: 1-604-466-6654 Tel: 886-2-2567-3500
Fax: 886-6-505-0777 Fax: 1-604-466-6600 Fax: 886-2-2567-6500
http://www.e-one.com.tw http://www.molienergy.com

2005/1 2/2
Rechargeable lithium-ion battery
MP 144350

High performance
Medium Prismatic cell
Saft always supplies MP cells
in assemblies or as customized
battery system constructions

Benefits Electrical characteristics


l 
Extended autonomy and life for Nominal voltage 3.75 V
(0.5 A rate at 20°C)
mobile systems
l A broad operating temperature Typical capacity 2.6 Ah
(at 0.5 A 20°C 2.5 V cut-off)
range
l 
Recommended for ruggedized Nominal energy 9.75 Wh
designs Mechanical characteristics (Sleeved 100 % charged cell)
l 
Easy integration into compact
Thickness 14.9 mm
and light systems (Thickness tends to increase with cycling,
l 
Very high energy density typically obtained after 500 cycles. Consult Saft)
(344 Wh/l and 143 Wh/kg) (At beginning of life 14.6 mm)
l 
Unrivalled low temperature Width (max) 43.9 mm
performance Height (max) 54.5 mm
Typical weight 68 g
Key features
Lithium equivalent content 0.78 g
l 
Excellentcharge recovery after
Volume 28 cm3
long storage, even at high
temperature Operating conditions
l 
Maintenance-free Charge method Constant Current/Constant Voltage
l 
Long cycle life
Charge voltage 4.20 +/– 0.05 V
(over 80 % initial capacity after
Maximum recommended charge current** 2.6 A (C rate)
500 cycles at 100 % DoD)
l 
Non-restricted for transport/ Charge temperature range* – 20°C to + 60°C
Non-assigned to Class 9 Charge time at 20°C To be set as a function of the charge current:
according to the UN C rate ➡ 2 to 3 h
Recommendations on the C/2 rate ➡ 3 to 4 h
transport of dangerous goods - C/5 rate ➡ 6 to 7 h
Model Regulations Maximum continuous discharge current** 5.0 A (~2C rate)
l 
Underwriters Laboratories (UL) Pulse discharge current up to 10 A (~4C rate)
Component Recognition
Discharge cut-off voltage 2.5 V
(File Number MH 12609)
Discharge temperature range* – 50°C to + 60°C

Main applications * For optimized charging below 0°C, 60°C and discharging at – 50°C, consult Saft.
** Electronic protection circuits within battery packs may limit the maximum
l 
Mobile asset tracking charge/discharge current allowable. Consult Saft.
l 
Small UPS
l Soldier of the future equipment

l 
Portable radios
l 
Professional portable lighting
l 
Bar code readers
l Portable payment terminal

October 2009
MP 144350 Capacity versus current at + 20°C

Battery assembly
In order to operate properly, individual Li-ion cells

Voltage (V)
are mechanically and electrically integrated in battery
assemblies specific to each application. The battery
assembly incorporates electronics for performance,
thermal and safety management.
Technology
l Graphite-based anode
l Lithium Cobalt oxide-based cathode
l Electrolyte: organic solvents
l 
Built-in redundant safety protections Capacity (Ah)
(shutdown separator, circuit breaker, safety vent)
l 
Batteries assembled from MP cells feature an
Typical discharge profiles (0.5 A - C/5 rate)
electronic protection circuit
Electrolyte
filling hole Positive terminal

Safety vent
Cover (stainless steel) Voltage (V)

Circuit breaker
Insulator

Separator
Can (stainless steel)

Jelly roll
Negative terminal
Capacity (Ah)

Built-in protection devices ensure safety in case of:


Charge characteristics to 4.2 V at + 20°C
l Exposure to heat
l 
Exposure to direct sunlight for extended periods of time
l Short circuit
Voltage (V) / Current (A)

l Overcharge

State of charge (%)


l Overdischarge

When handling Saft MP batteries:


l Do not solder directly to cell terminal
l Do not disassemble
l Do not remove the protection circuit
l Do not incinerate

Transportation and storage:


l 
Store in a dry place at a temperature preferably not
exceeding 30°C
l 
For long-term storage, keep the battery within a
(30 ± 15) % state of charge Charge time (hours)

Saft
Specialty Battery Group
12, rue Sadi Carnot
93170 Bagnolet - France
Tel. : +33 (0)1 49 93 19 18
Fax : +33 (0)1 49 93 19 69 Doc. No 54044-2-1009
Information in this document is subject to change without notice
313, Crescent Street and becomes contractual only after written confirmation by Saft.

Valdese, NC 28690 - USA Published by the Communications Department.


Tel. : +1 (828) 874 41 11 Photo credit: Saft.
Fax : +1 (828) 879 39 81 Société anonyme au capital de 31 944 000€
RCS Bobigny B 383 703 873
www.saftbatteries.com Produced by Arthur Associates Limited.
LPP 503759 DL
Rechargeable Lithium-Ion Pouch

1)
Preliminary Data Sheet

Type Designation LPP 503759 DL


Type Number 56478

System Li-Ion

UL Recognition UL1642

Nominal Voltage 3.7V


Nominal Capacity, C 1300mAh
Minimum Capacity 1240mAh (at 0.2C and 20°C)

Dimensions
Length (l) 59.5mm Max. (without tabs)
Width (w) 37.5mm Max.
Height (h) 5.2mm Max. (full charge)

Weight, approx. 23.0g

Charging Method Constant Current + Constant Voltage


Charge Voltage 4.20V (+/- 50 mV)
Initial Charge Current Standard Charge: 620mA
Rapid Charge: 1240mA
Charging Cut-Off ( a) or b))
a) by time Standard Charge: 5h
Rapid Charge: 2.5h
b) by min. current 0.02C

Discharge Cut-Off voltage 3.0 V

Max. Continuous Discharge Current 2480mA

Operating Temperature Charge: 0°C to 45°C


Discharge: -20°C to 60°C

Storage Temperature 1 Year at -20°C to 35°C >80%


2)
Capacity Recovery Rate 3 Month at -20°C to 45°C >80%
1 Month at -20°C to 60°C >80%

Impedance Initial <60mΩ @ 1kHz at 4.2V


3)
Life Expectancy 300 Cycles for ≥80% of C
500 Cycles for ≥70% of C

1)
Prior to use read Handling Precaution and Prohibitions for VARTA Li-ion Batteries.
2)
After storage at initial cell voltage of 3.6 to 3.9 V/cell; capacity 0.2C measured at 20°C.
3)
Cell is to be charged at 0.5C to 4.2V with cutoff at 0.02C and discharged at 0.5C with cutoff at 3.0V, at 20°C
Fo_171/01

VARTA Microbattery GmbH


Date of Issue: 2010-07-02/RH 699239 Subject to change without prior notice ! Daimlerstraße 1, 73479 Ellwangen, Germany
Tel.: +49 79 61 921-0
Telefax: +49 79 61 921-553
Operational Information and Safety Safety Manual
Precautions for General Equipment Issue B1

Inspired Energy NL2024


Click or enter the following website address to view the NL2024 Datasheet.
http://www.inspired-energy.com/Standard_Products/NL2024/NL2024.htm

Appendix B – Cell Datasheets 58


Operational Information and Safety Safety Manual
Precautions for General Equipment Issue B1

Appendix C – Cell Transportation Certificates


Battery cell manufacturer transportation certificates are shown in this Appendix. Sonardyne
International Ltd battery pack transportation certificates are available on request.

C.1 Lithium Cell and Battery Transportation Certificates

Saft LS33600 60
Saft LS26500 61
Saft LSH20 62
Saft LSH14 63
Saft LSH14 Light 64
Saft LS14500 65

Appendix C – Cell Transportation Certificates 59


Operational Information and Safety Safety Manual
Precautions for General Equipment Issue B1

C.2 Lithium-ion Cell and Battery Transportation Certificates

Saft MP 144350 67
allbatteries - Enix Energy 292393 68
allbatteries - Enix Energy 292661 69
allbatteries - Enix Energy 700006 70
Inspired Energy Li-ion 71
VARTA 72

Appendix C – Cell Transportation Certificates 66


General Declaration of Conformance:
UN 38.3 Transportation of Dangerous Goods
Lithium Ion Batteries
PRODUCT: Inspired Energy Rechargeable Battery Packs
CHEMICAL SYSTEM: Lithium Ion

SECTION I – MANUFACTURER INFORMATION

Inspired Energy, Inc. Telephone: (888) 5-INSPIRE (888-546-7747)


25440 NW 8th Place,
Newberry, FL 32669 Date Prepared: January 20, 2016

SECTION II – CONFORMANCE INFORMATION

The products listed below have been tested in accordance with the UN Document
ST/SG/AC.10/C.3/2010: “Amendments to the Fifth Revised Edition of the Recommendations
on the Transport of Dangerous Goods, Manual of Tests & Criteria” and have been found to
Comply with the stated Criteria.

SECTION III – PRODUCTS

3-cell 4-cell 6-Cell 7-Cell 8-Cell 9-cell 12-cell


Batteries Batteries Batteries Batteries Batteries Batteries Batteries
NC2040xxxx ND2053xxxx NF2040xxxx PG3665xxxx NH2054xxxx Ni2020xxxx NL2020xxxx
10.8V 3.6V 10.8V 25.2V 14.4V 10.8V 10.8V
NC2560xxxx ND2054xxxx NH2057xxxx Ni2040xxxx NL2024xxxx
10.8V 14.4V 7.2V 10.8V 14.4V
ND2057xxxx RH2024xxxx NL2044xxxx
7.2V 14.4V 14.4V
NL2050xxxx
10.8V
NL2054xxxx
14.4V
Where “xxxx” indicates all different custom & standard model variants identified by alphanumeric suffixes .

Signed- Thomas Rush


Compliance Administrator

The information contained within is provided for your information only. This battery is an article pursuant to 29 CFR 1910.1200 and, as such, is
not subject to the OSHA Hazard Communication standard requirement for preparation of a material safety data sheet. The information and
recommendations set forth herein are made in good faith and are believed to be accurate as of the date of preparation. However, INSPIRED
ENERGY, INC. MAKES NO WARRANTY, EITHER EXPRESSED OR IMPLIED, WITH RESPECT TO THIS INFORMATION AND DISCLAIMS ALL LIABILITY FROM
RELIANCE ON IT.

Inspired Energy, Inc.


25440 NW 8th Place,
Newberry, FL 32669
1. IDENTIFICATION Initi l release
Rechargeable
Re sed per JCS lithium-ion single cells,, modules
Milwaukee requirements
Product
Re sed Document Number, Formerly battery packs
and multi-cell
Lo
Synonyms / Common Name Sealed Lithium Ion Battery
Ad d qualifying statement to Transport Information ( f: Section 11).
Chemical Family/Classification Re oved Electric Storage Battery
Add
Ad metal
etal oxide exposure limit info for NMC & NCA, p per OSHA 1910.1000.
Sealed Lithium
Re ove UN 3090 Classification Ion Battery
Shipping Compli ce info;
Health –
rec mmended storage 0 Flammability
temperature range –SOC
0 React
Recotivity –0
mendation
HMIS Rating
Organic Electrolyte
Health – 3 Flammability – 3 Reacttivity - 2
UN3480 PG II classification for Lithium Batte eries (all modes).
Cells have been tested to UN Manual of Test Criteria Part III, sub-
USDOT, IATA and IMO s
section 38.3. Consult Johnson Controls forr Declaration of
Description
Conformity documentation, as ne eeded.

Johnson Controls, Inc. – United Sttates


5757 North Green Bay Avenue e
Milwaukee
Company Name Wisconsin 53209
USA 0 Reac ity
Tel. No. (414) 524-2459
Fax. No. (414) 524-2800
3 Reac ity
Emergency contacts
s (703) 527-3887 (CHEMTREC
classification for US Service
Lithium Center)
Batt ies
Within the USA (800) 424-9300 Account UN12008
Manual of Test iteria Part III, sub
Consult Johnson Controls fo eclaration of
Conformity documentation, as n ded.

United S tes
5757 North Green Bay Avenu
CAUTION

Emergency contact (CHEMTREC US Service nter

NOTE: The Johnson Controls sealed


ealed cell/battery is considered an article
art le as defined by
29 CFR 1910.1200 (OSHA Hazard
Haz d Communication Standard). The inf information
ation contained
supplied at the
t customer’s request for information only.
onl

short circuit,
cir t, puncture, incinerate, crush, immers
immerse,, force discharge
Do not over charge, short
or expose to temperatures circ
c u it, puncture, incinerate, crush,
e the declared operating temperaimmerseee , force
rangedischarge
of the
or expose to temperatures
sk of firea b ove the declared operating temperattu re
f e or rapid component disassembly. The rechargeable range of the
production- batteries
possibledescribed
risk of fir
describe ire or rapid
in this component
Material Safety Datadisassembly. T he rechargeable
Sheet are sealed
aled units which
lithium-ion batteries described d
are not hazardous when used accordingin this Material Safety Data Sheet
ccording to the recommendations of the are s e aled units which
t manufacturer.
are not hazardous when used according to the recommendations of the e manufacturer.
TRANSPORT INFORMATIO
ON
Note: Transportation requirem ments do not apply once the battery packk has been
installed in a vehicle as part of the vehicle’s functional components.
For the single ce
cell batteries and multi-cell battery packs that are non-restrricted to transport, use
lithium-ion batter
eries inside label.
of ce
For the single use,
se,
cell the and
batteries electrode materials
multi-cell battery and
packs which are liqui
liquid
restrictted electrolyte
to transport they
contain are not exposed
(assignedtotothe
ththe outside, provided
e Miscellaneous the
Class 9), use battery
Class integrity
9 Miscellaneous Dannis maintained
gerous and
Goods and UN
Information
seals remain &intact.
Identification
Risk ofNuuexposure
mber labels. only in case of abuse (me
xposure (mechanical,
hanical, thermal,
Labels for
conveyance to the
Packages activation
musttb
betivation of safety
marked “Cargo Aircraftvalves and/or
Only”. Only trained,the ru
rupture
personne el ure of inthe
certified battery
packing,
container. Electrolyte leakage,
leaka
shipping and doc, contamination
ocumenting Dangerous Goods of may
electrode materi
materials,
offer this material for trals, mixture with
nsport.
moisture/water or battery vent/fire/rapid
vent ire/rapid component disassembly may follow, ollow, depending
NOTE: Cells tha
hat are non-intact, breeched, vented or physically damage
ed may not be shipped.

fer to the product transport certificate issued by the Manufa


In all cases, refe acturer.
UN number
HAZARDOUS UN 3480 PG II (all modes)
INGREDIEN
Shipping name Lithium Ion Batatteries
hermeticall sealed container enclosing a number of chemi als and materials of
construction
Hazardof which theDepending
following co
on d potentially
n their be lithium
equivalent hazardous upon release.
compound content, some siingle cells and small
classification multicell batter
ery packs may be non- assigned to Class 9 (refer to Transport Certificate).

Packing group II
IMDG Code 9033
CAS Not applicable
le
EmS No. 4.1-06
Marine pollutant No

, S22, S24, S26, S36,

R ,

,
Operational Information and Safety Safety Manual
Precautions for General Equipment Issue B1

Definitions
Definitions of Loads, Loading and General Terms
Term Definition
Breaking Load / The load that induces structural failure in one or more parts of the instrument causing the
Static Failure Load load to part from the release mechanism.
Competent Person An individual who, by way of training and/or experience, is knowledgeable of applicable
standards, is capable of identifying workplace hazards relating to the specific operation,
is designated by the employer, and has authority to take appropriate actions.
Dynamic Load A time varying load resulting from the motion and inertia of connected masses and forcing
functions such as wave action on the vessel. This may include transient and steady state
harmonically alternating loads.
Maximum The maximum in-line load the whole assembly can release whilst guaranteeing safe and
Buoyancy for reliable operation. Note that as the load is released in water this is determined by the
Release / Release maximum up-thrust from the buoyancy.
Loads The maximum in-line load the instrument can withstand and successfully release without
overloading any part of the release mechanism or demanding an unsupportable quantity of
energy from the battery supply (at its specified end point).
Proof Load The load to which the actual unit has been tested in the factory. This load should be
periodically applied to demonstrate the unit is still in a safe condition. This is usually twice
the WLL.
Responsible Body The Responsible Body is the organisation responsible for Health and Safety for lifting
operations at the worksite.
Safe Working Load The maximum load (as determined by a competent person) that an item of lifting
(SWL) equipment may raise, lower or suspend under particular service conditions, e.g. the SWL
can be lower than, but can never exceed the WLL.
Shock Load or A time transient load generally caused by the sudden acceleration (positive or negative) of
Snatch Load the load. Examples are the sudden snatch of a load off the deck or a sudden arrest of a
load falling under gravity.
Static Load An unvarying long term load
Working Load Limit The maximum recommended working load. This is set as a maximum 25% of the
(WLL) Breaking Load and allows for factors such as corrosion, fatigue shock loads, harmonic
loads, manufacturing defects and material defects. Please note this does not account for
extreme offshore service conditions.

Abbreviations
Abbreviation Definition
AC/DC Alternating Current/Direct Current
Ah Amperes per hour
A/R As Required
Assy Assembly
Aux Auxiliary
Bd Baud
BIS  Battery Information Sheet

Definitions 74
Operational Information and Safety Safety Manual
Precautions for General Equipment Issue B1

Abbreviation Definition
BOP Blow Out Preventer
bps bits per second
BS British Standard
Cg/COG Centre of Gravity
cm centimetre
COR Centre of Rotation
COSHH Control of Substances Hazardous to Health
dB Decibel
°C Degree Centigrade/Celsius
°F Degree Fahrenheit
DWG Drawing
f frequency
Fig. Figure
g gram
GA General Arrangement
HDR High Data Rate
Hz Hertz
in. inch
kg kilogram
kHz kilo Hertz
kN kilo Newton
lb pound
lbf in. pounds force inch
lbf/in2 pounds force / square inch
Lith-X Ansul Lith-X Class D extinguishing agent was developed for use on lithium fires and will
also extinguish magnesium, sodium, and potassium fires
mi metre
m/s metres per second
Max. Maximum
µs Microsecond
mg milligram
Min. Minimum
mm millimetre
ms millisecond
mW milliwatt
Nm Newton metre
No. Number
OEM Original Equipment Manufacture

Definitions 75
Operational Information and Safety Safety Manual
Precautions for General Equipment Issue B1

Abbreviation Definition
OIM Offshore Installation Manager
UM User Manual
PM Phase Modulation
PPE Personal Protective Equipment
ppm parts per million
psi pounds per square inch
s second
SDS Safety Datasheet
STBD Starboard
SV Sound Velocity
SWL Safe Working Load
T Tonne
V Volt
WEEE Waste from Electrical and Electronic Equipment Directive 2002/96/EC
Wh Watt hour

Definitions 76
Operational Information and Safety Safety Manual
Precautions for General Equipment Issue B1

This page intentionally left blank.


Global Headquarters, UK Rio das Ostras, Brasil Singapore, Asia
Blackbushe Business Park Av. Zen lotes 05 e 06 34 Loyang Crescent
Yateley Quadra D Block B
Hampshire Zen, Rio das Ostras – RJ Singapore
GU46 6GD, UK CEP 28.890-000, Brasil 508993

T. +44 (0)1252 872288 T. +55 22 2123 4950 T. +65 6542 1911


F. +44 (0) 1252 876100 F. +55 22 2123 4951 F. +65 6542 6937
sales@sonardyne.com brasil.sales@sonardyne.com asia.sales@sonardyne.com

Houston, USA Aberdeen, UK 24/7 Emergency Helpline


8280 Willow Place Drive North Units 12–13, T. +44 (0) 01252 877600
Suite 130 The Technology Centre
Email Support
Houston, Texas Claymore Drive
support@sonardyne.com
77070, USA Bridge of Don, Aberdeen
AB23 8GD, UK Website
T. +1 281 890 2120
www.sonardyne.com
F. +1 281 890 7047 T. +44 (0) 1224 707875
usa.sales@sonardyne.com F. +44 (0) 1224 707876 Twitter
sales@sonardyne.com @sonardyne

You might also like