PHYSICAL CHEMISTRY

PART-A
[STRAIGHT OBJECTIVE TYPE]
Q.1 to Q.9 has four choices (A), (B), (C), (D) out of which ONLY ONE is correct.

Q.1 Molar ratio in which He and CH4 should be mixed so that when mixture is allowed to effuse through
pinhole, initially both gases comes out at equal rate?
(A) 4 : 1 (B) 1 : 4 (C*) 1 : 2 (D) 2 : 1
1
Q.2 f KP for a reaction is  10 2 atm 2 at 500 K. Magnitude of KC will be [Take R = 0.08]
9

1 16
(A) 3 × 10–1 (B)  10  2 (C*) (D) Data insufficient
9 9
Q.3 NX is produced by the following steps of reactions
M + X2  MX2
M X2+ X2  M3X8
M3X8+ N2CO3  NX + CO2 + M3O4
How much M (Metal) is consumed to produce 206 gm of NX (Given at. wt. of M = 56, N = 23,
X = 80)
7 14
(A) gm (B) (C) 56 (D*) 42
4 3
Q.4 The atomic weight of two elements A and B are 20 and 40 respectively. Which of the following
statement(s) is/are correct for those two elements?
(A) x gm of A contains y atoms which is equal to atoms present in x gm of B.
(B*) x gm of A contains y atoms which is equal to atoms present in 2x gm of B.
(C) At STP, mass of x L of monoatomic gas A is equal to that of x L of monoatomic gas B.
(D) At STP, ratio of mass of x L monoatomic gas A to mass of gas B is 2 : 1.

Q.5 The density of a mixture of N2 and O2 at 1 atm. and 273 K is 1.34 gm/litre. The partial pressure of O2
in the mixture is
(A) 0.7 atm (B) 0.32 atm (C) 0.28 atm (D*) 0.5 atm

Q.6 At high pressure the density of pure liquid water varies as :

dt°C = d0°C – (0.001 × t°C) ; where
dt°C = density at t°C
d0°C = 1 gm /cc
The magnitude of percent change in molarity of pure liquid water due to change in temperature from
0°C to 100°C.
(A) No change (B) 1 % (C*) 10 % (D) Data insufficient
Q.7 At same temperature N2O4 is dissociated to 40% & 50% at total pressure P1 & P2 atm respectively
in NO2 . Then the ratio of P1 & P2 is
4 7 4
(A) (B*) (C) (D) None of these
5 4 7
Q.8 60 ml of a mixture of equal volume of Chlorine gas & an oxide of chlorine was sparked till increment
in volume is stop. The resulting gaseous mixture was found to have volume of 75ml. The resulting
gaseous mixture was passed through aqueous KOH solution, the volume contracted to 15ml. Assume
that all measurements are made at the same T & P. The oxide of Chlorine on sparking decomposes
quantitatively to O2(g) & Cl2(g). The simplest formula of oxide of Chlorine is
(A) Cl2O3 (B) ClO2 (C*) Cl2O (D) None of these

Q.9 For any orbital (r) = K· e–K'r (r4 + K1r3 + K2r2). Select true statement
(A) Orbital should be " 5s"
(B*) Orbital should be " 5d"
(C) Angular wave function should be independent on (,)
(D) Curve of 2(r) vs 'r' has maximum value at origin.

[COMPREHENSION TYPE]

Q.10 to Q.12 are based upon a paragraph. Each question has four choices (A), (B), (C), (D) out of which
ONLY ONE is correct.
Paragraph for question nos. 10 to 12
RayBan, the goggle (sun glass) producing company produces 100 photochromatic goggles per day.
These goggles have small molecules of AgCl incorporated in the lenses. When the lenses are exposed
to light of appropriated wavelength the following reaction occurs:
AgCl  Ag + Cl H = 248 kJ / mole
The Ag atoms formed produce a uniform gray colour that reduces the glare. Each lens have surface
area 10 cm2 and contains 14.35 gm/cm2 AgCl molecules. To reduce glare completely all the molecules
of AgCl must dissociate. In the absence of sunlight these dissociated atoms combine back to give
AgCl. [NA = 6 × 1023]
Q.10 Calculate the maximum wavelength of photon to reduce glare in the glass.
(A) 48 nm (B*) 4800 Å (C) 560 nm (D) None

Q.11 Total energy required to reduce glare in each goggle completely.

(A) 248 kJ (B) 248 J (C*) 496 kJ (D) None

Q.12 Mass of AgCl required per day in the plant is

(A) 14.35 kg (B) 430.5 kg (C) 861 gm (D*) 28.7 kg
 [MULTIPLE OBJECTIVE TYPE]
Q.13 to Q.15 has four choices (A), (B), (C), (D) out of which ONE OR MORE THAN ONE is/are
correct.

0.05
Q.13 If uncertainty in velocity is 6.62 × 10–2 m/sec. for a particle of mass of gm. Its uncertainty in

position may be
(A*) 0.5 × 10–18 (B*) 10–18 (C*) 0.8 × 10–18 (D*) 0.5 × 10–17

Q.14 An equimolar mixture of alkane, alkene & alkyne having same number of carbon atom per molecule
are burnt just sufficient amount of oxygen at 127°C. The final gaseous mixture contains equal moles of
CO2 and H2O . The value of n may be (where n is number of carbon atom in each molecule)
(A) 1 (B*) 3 (C*) 4 (D) Data insufficient

Q.15.ag A closed container of volume 4.92 litre conatins NH3 gas at 27°C as shown:

H 2S (g) NH3 (g)

38cm

H2S gas is passed inside the container at a rate of 0.01 mole/sec. such that no gas is coming out from
the container. The reaction take place in the container is
2NH3(g) + H2S(g) 100  %
 (NH4)2S(s)
(Assume that there is no time lag in between H2S gas passed and (NH4)2S formed.)
The time at which the difference in Hg column is equal to 38 cm.
(A*) 0 sec. (B) 20 sec. (C*) 10 sec. (D*) 25 sec.

PART-B
[MATCH THE COLUMN]
Q.1 are "Match the Column" type. Column-I contains Three/Four entries and column-II contains Four/Five
entries. Entry of column-I are to be matched with one or more than one entries of column-II or vice versa.

Q.1 Column I Column II

(A) PCl5(g) l PCl3 (g) + Cl2(g) (P) KP > KC

(B) 2NO2 (g) l N2O4(g) (Q) KP < KC

(C) H2 (g) + I2 (g) l 2HI (g) (R) P is increased, reaction moves to right
hand side
 (D) N2(g) + 3H2(g) l 2NH3 (g) (S) Inert gas added at constant volume,
equilibrium will not shift

(T) Inert gas added at constant

pressure, equilibrium will shift
to forward direction
[Ans. (A) P, S, T (B) Q,R,S (C) S (D) Q,R,S]

PART-C
[SUBJECTIVE]
Q.1 to Q.4 is "Subjective" type questions. (The answer to each of the questions are upto 4 digit)
\

Q.1 Given balanced chemical equation for oxidation of phosphorus (III) sulfide by nitric acid. The products
include NO and SO2. Find the value of a,b,c,d,e in the following equation.
a P4S6 + 44H++ b NO3–  cNO + dH3PO4 + e SO2 + 4H2O
Write your answer as (a + b + c + d + e) [Ans. 0121]

Q.2 1292.5 gm of 5 m NaCl solution is kept in a bucket. The bucket is placed under a tap from which a
2m NaCl solution is flowing. Calculate the time (in seconds) after which the bucket will have a
concentration of 4m if rate of flow of solution from tap is 0.5 gm/sec. (Round of the answer to nearest
integer)
[Ans. 1117 ]

Q.3 If Photon having wavelength 6.2 nm was allowed to strike a metal plate having work function 50 eV
then Uncertainity in wavelength of emitted electron with KEmax ,if uncertainity in the momentum is
13.24 × 10–28 kg m/s [Ans. 2 × 10–14 m ]

Q.4 Hey congrats! you have been selected by the NASA for its "Mission to Mars". You are supposed to
bring a sample of air from Mars in a 8.21 lit. rigid container. Which can bear 60 atm pressure. You filled
air at 40 atm pressure and 50 K, but then realised that temperature increases gradually from Mars to
Earth. Then calculate the minimum rate (no.of moles/day) at which moles must be leaked so that
container did not explode if time taken for return trip was 4 days.
Given: TMars = 50K, PEarth surface = 1 atm, TEarth surface = 300 K. [Ans. 15 mol/day ]
 INORGANIC
PART-A
[STRAIGHT OBJECTIVE TYPE]
Q.1 to Q.9 has four choices (A), (B), (C), (D) out of which ONLY ONE is correct.

Q.1 Which of the following is paramagnetic?

(A) Ag (B*)Fe2+ (C) K (D) Mg2+

Q.2 Which of the following is strongest in basic character ?

(A) Be(OH)2 (B*) Mg(OH)2 (C) Al(OH)3 (D) Si(OH)4

Q.3 The correct order of strength of H-bonding is

(A) AH ........ A < A1H ....... A1 < BH ....... B < B1H ...... B1
(B) A1H ........ A1 > AH ....... A < B1H ....... B1 < BH ...... B
(C) AH ........ A > BH ....... B > A1H ....... A1 > B1H ...... B1
(D*) A1H ........ A1 > B1H ....... B1 > BH ....... B > AH ...... A
Where B = First element of group 15
B1 = First element of group 16
A1 = First element of group 17
A = Second element of group 17

Q.4 The total right angled  ClPCl are present in PCl5, PCl4+, PCl6¯ _ , _ , _ respectively.
(A) 0, 1, 4 (B) 6, 0, 4 (C) 2, 4, 0 (D*) 6, 0, 12

Q.5 Atomic radius variation of an unknown group in the periodic table is as below
Atomic radius

• •
• •

A B C D E
The element B & C respectively are :
(A) Cl & Br (B) Be & Mg (C) Si & Ge (D*) Al & Ga

Q.6 The ionisation potential values 54.40 eV & 39.30 eV correspond to

(A) H+ & H (B) Li & Li+ (C) He & He+ (D*) He+ & He

Q.7 Two ice cubes are pressed over each other and unite to form one cube, which force is responsible for
holding them together?
(A) Vander Waal's forces (B) Covalent attraction
 (C*) Hydrogen bond formation (D) Ion - Dipole attraction

Q.8 For last electron of La57 , which of the following values of n, l, m, s are not possible according to
Aufbau principle?
1 1 2 1
(A) 5, 2, –2, (B) 5, 2, –1,  (C*) 5, 2, 0,  (D) 5, 2, 0 , 
2 2 2 2
Q.9 Molecules with See-Saw shape is
(A) CH2F2 (B) XeOF4 (C*) XeO2F2 (D) HgCl2

[COMPREHENSION TYPE]

Q.10 to Q.12 are based upon a paragraph. Each question has four choices (A), (B), (C), (D) out of which
ONLY ONE is correct.
Hybridisation is the chemists attempt to explain the observed molecular shape by constructing hybridised
atomic orbitals with the appropriate inter orbital angles. The molecule for which deviation from normal
bond angle is observed, VSEPR theory suggest electron pair repulsive interaction (p – p > p – bp
> bp – bp ). While from hybridisation point of view that is departure from normal hybridisation because
the angle between any equivalent hybrid orbitals determine the fraction of s and p character of the
hybrid and vice - versa.

Q.10 An element 'A' has outer shell configuration of 5s25p6. If A forms covalent compound AF2 with fluorine.
The orbitals used by 'A' for bonding are
(A) d-orbitals (B) p-orbitals
(C) sp-hybridised orbital (D*) sp3d hybrid orbital

Q.11 In which species number of lone pair on iodine and number of d - orbitals used in hybridisation by
iodine are same
(A) ICl 2 (B) ICl 2 (C) IF7 (D*) ICl 4

Q.12 Which line of properties A, B, C or D correctly listed, properties of the given three compounds.
XeF4 CCl4 Zn2+
(A) Square planar Non-planar µ = 8 BM
(B*) µ=0 Tetrahedral Diamagnetic
(C) Non-planar Polar µ = Zero
(D) Polar Square planar Total number of 12 electrons having m
(Magnetic quantum number) = Zero
 [MULTIPLE OBJECTIVE TYPE]
Q.13 to Q.15 has four choices (A), (B), (C), (D) out of which ONE OR MORE THAN ONE is/are
correct.

Q.13 In which of the following option(s) all species contains X — O — X bond(s) in structure ( X = central
atom)
(A) H2S2O5, S3O9, S2 O62 (B*) P4O10, P4O6, H5P3O10

(C) N2O5, N2O, N2O4 (D*) S3O9, P4O6, Si2 O67

Q.14 Which of the following species are formed by Lewis acid base interaction.
(A) CH4 (B*) NaBF4 (C) PCl4+ (D*) Al(OH)4¯

Q.15 Which of the following molecules are polar as well as planar.

(A*) BFClBr (B) B3N3H6 (C*) ClF3 (D*) CH2 = C = C = CF2

PART-B
[MATCH THE COLUMN]
Q.1 are "Match the Column" type. Column-I contains Three/Four entries and column-II contains Four/Five
entries. Entry of column-I are to be matched with one or more than one entries of column-II or vice versa.

Q.1 Column I Column II

(Number of electron pair (Probable geometry)
around the central atom)
(A) 2 (P) Bent
(B) 3 (Q) Linear
(C) 4 (R) Sea Saw
(D) 5 (S) Trigonal Pyramidal
[Ans. (A) Q (B) P, Q (C) P,Q,S (D) P,Q,R ]

PART-C
[SUBJECTIVE]
Q.1 to Q.4 is "Subjective" type questions. (The answer to each of the questions are upto 4 digit)
\

Q.1 The amount of energy released when one million atoms of iodine in vapour state are converted to I–
ions is 4.9 × 10–13 J. What is the electron affinity of Iodine in eV per atom.
[Ans.3.06]

Q.2 Calculate the total number of valence electrons, lone pairs and p – p bonds. In the given structure
if Y = P atom , X = N atom, Z = Cl atom
 Z Z
Y
X X
Z Z
Y Y
Z Z
X

[Ans.72, 21, 0]

Q.3 Given
Bond energy of F – F bond = 38 Kcal / mol–1
Bond energy of Cl – Cl bond = 58 Kcal / mol–1
Bond energy of Cl – F bond = 61 Kcal / mol–1
Electronegativity of fluorine = 4 eV
Calculate the electronegativity of chlorine atom. [Ans.3.22 eV]

Q.4 If each orbital can accommodate maximum 4 electrons then how many total number of electrons are
present in 3rd energy shell. [Ans.36]