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D. aromaticity
E
a- Over view on hydrocarbons - Nomenclature of hydrocarbons derivatives
b- Types of isomers (structure - geometrical (cis -trans-E,Z)
c- Preparation of methane (dry distillation of sodium acetate)-ethylene-acetylene
d- Reactions of hydrocarbons
I- Combustion in limited and excess amount of oxygen for hydrocarbons.
II- Halogenation of alkane by free radical mechanism,( Methane – propane)
III- Reaction of Alkene
1- Halogenation
2- Catalytic hydration
3- Oxidation – oxidation by cleavage- Ozonolysis.
4- Addition of HX
5- Polymerization
IV- Reaction of Alkyne
1- Halogenation
2- Catalytic hydration
3- Polymerization -trimerization- Aromaticity and benzene structure
1- Preparation of aromatic benzene (from acetylene –hexane)
2- Reactions of Benzene
a- Mono substituted benzene
b- Di-substituted benzene.
3- Distinguish practically between Ethane, Ethene and Acetylene.
F- alcohols:
1- Nomenclature
2- Classification of alcohols according to the functional group, and according to carbinol
group.
3- Prepare experimentally by fermentation
4- Preparation theoretically from alkanes and alkyl halides
5- Oxidation reactions to determine the presence of ethanol
6- Industrial application of:
a- Methanol
b- Ethanol
c- Glycerol
d- Ethylene glycol
7- Differentiate between phenols, methanol, and NaOH
G
1. Nomenclature according to the origin
2. Preparation of aspirin
3. Reactions:
a- Acidic hydrolysis of ethyl acetate
b- Alkaline hydrolysis- preparation of saponification
4. Application of esters in perfumes and food industry.