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Cement kiln dust and fly ash blends as an alternative binder for the
stabilization of demolition aggregates
Arul Arulrajah a,⇑, Alireza Mohammadinia b, Angelo D’Amico c, Suksun Horpibulsuk d,a,⇑
a
Department of Civil and Construction Engineering, Swinburne University of Technology, Hawthorn, Victoria 3122, Australia
b
Department of Infrastructure Engineering, The University of Melbourne, Melbourne, Victoria 3010, Australia
c
Montdami Constructions Pty Ltd & Retic Pipelines Pty Ltd, Dandenong South, Victoria 3175, Australia
d
School of Civil Engineering and Center of Innovation in Sustainable Infrastructure Development, Suranaree University of Technology, Nakhon Ratchasima 30000, Thailand
h i g h l i g h t s
Cement kiln dust and fly ash blends evaluated as an alternative binder.
Cement kiln dust in combination with fly ash to stabilize demolition wastes.
Strength and stiffness testing.
20% cement kiln dust with 10% fly ash found to be optimum content for stabilizing demolition wastes.
a r t i c l e i n f o a b s t r a c t
Article history: Cement kiln dust (CKD) is an industrial by-product formed during the manufacture of cement. Fly Ash
Received 27 February 2017 (FA) is the by-product of coal-fired electricity generation. Construction and Demolition (C&D) materials
Accepted 3 April 2017 are alternative aggregates used in construction applications. CKD is calcium-rich whereas FA is silica-
Available online 8 April 2017
rich, hence the unique combination of these two pozzolanic materials (CKD + FA) were investigated as
an alternative binder to stabilize C&D materials. The usage of CKD + FA to stabilize C&D aggregates com-
Keywords: prised of Recycled Concrete Aggregate (RCA), Crushed Brick (CB) and Reclaimed Asphalt Pavement (RAP)
Cement
will have environmental and economic benefits. The strength characterization of CKD + FA stabilized C&D
Kiln dust
Demolition
materials was evaluated by undertaking Unconfined Compressive Strength (UCS) tests. The durability of
Stabilization the CKD + FA stabilized C&D materials under simulated loadings was evaluated by Repeated Load Triaxial
Construction (RLT) tests to determine the resilient modulus (MR). The optimum performance for stabilizing C&D mate-
rials was obtained at the mix design with 20%CKD + 10%FA.
Ó 2017 Elsevier Ltd. All rights reserved.
http://dx.doi.org/10.1016/j.conbuildmat.2017.04.007
0950-0618/Ó 2017 Elsevier Ltd. All rights reserved.
A. Arulrajah et al. / Construction and Building Materials 145 (2017) 218–225 219
the free lime content can be used as a controlling parameter to F type FA. CKD + FA stabilized C&D aggregates with up to 30% bin-
measure the competence of CKD products [1]. In addition, the sul- der contents were evaluated to ascertain the optimum CKD con-
fate content, alkali content and pH of the solution and the fineness tent. The C&D materials used in this research were collected
of the CKD dust powder can potentially significantly influence the from a local recycling site near Melbourne with a nominal size of
stabilization process. It should be noted that calcium based binders 20 mm.
perform best when mixed with highly plastic soils. The high con- An extensive laboratory characterization was performed on the
tent of free lime (CaO) in CKD increases the alkalinity of the solu- CKD + FA stabilized C&D materials to characterize these waste
tion. Fly Ash (FA) is the by-product of coal-fired electricity materials. Tests undertaken included particle size distribution,
generation in many developed and developing countries, and is pH, modified compaction, permanent deformation, Repeated Load
traditionally stockpiled as a waste material at power plants. Triaxial (RLT) and Unconfined Compressive Strength (UCS). The
The demand for natural aggregates in construction projects is size distribution of the aggregates were determined according to
consistently rising with the rapid increase in infrastructure pro- Australian standards [27]. Due to relatively high water absorption
jects in developed and developing countries. Natural quarry mate- of CKD, the optimum moisture content and maximum dry density
rials are increasingly scarce and furthermore, the environmental of the CKD + FA stabilized C&D materials were determined with
concerns and economic costs of using these limited resources is use of modified compactive energy to simulate the high density
increasing rapidly. In recent years, there has been increased utiliza- of the stabilized materials [28].
tion of Construction and Demolition (C&D) materials in civil engi- The pH value of the unbound as well as the stabilized materials
neering projects as replacement for conventional construction after mixing were measured according to Australian standards [29]
aggregates [7]. Utilization of C&D materials has been pursued to investigate the alkalinity of the environment. The stabilized
increasingly, as this approach enables the preservation of natural samples were compacted in a split mold, to avoid possible damage
aggregates [8] as well as significant environmental and economic to samples during the removal of the specimen, with diameter of
savings for the community [9]. In addition to lower cost and envi- 100 ± 1 mm and 200 ± 1 mm in height. Samples were compacted
ronmental burden of using recycled C&D materials such as crushed in 8 layers with modified compactive energy obtained from com-
brick (CB) and recycled concrete aggregates (RCA) [10], the in situ paction test. the surface of each layer was deeply scarified to
recycling of Reclaimed asphalt Pavement (RAP) has been reported achieve interlocking between the layers and avoid anisotropy in
to yield savings of up to $1 million per kilometer length of each the sample. The samples were cured in a humidity box for 7 days
highway lane [11]. at room temperature and at a relative humidity of 97% to 99%.
The hitherto unknown properties of C&D materials requires fur-
ther fundamental understanding in order to utilize these waste
materials in geotechnical applications [9,12]. Partial inclusion of 100 20
C&D aggregates as conventional construction materials has been CKD
adopted in recent years [13,14]. Improving the strength and stiff-
80 16
Cumulative Passing Percentage, %
0 0
2. Materials and methods 3 6.5 8.5 12 16 20 32 45 63 85 106
Particle Size (µm)
CKD was obtained locally from a cement manufacturing com-
pany. The FA used in this research was black coal, low calcium class Fig. 1. Particle size distribution of (a) CKD and (b) FA.
220 A. Arulrajah et al. / Construction and Building Materials 145 (2017) 218–225
Table 2
Geotechnical properties of unbound C&D aggregates.
a) b) c)
CB RCA
2.25 2.25 RCA + 30% CKD 2.25
CB + 30% CKD
RCA + 20% CKD + 10% FA
CB + 20% CKD + 10% FA
RCA + 15% CKD + 15% FA
2.15 CB + 15% CKD + 15% FA 2.15 RCA + 10% CKD + 20% FA
2.15
Dry Density (Mg/m3)
Dry Density (Mg/m3)
Fig. 3. Compaction curves of CKD + FA stabilized C&D materials: (a) CB, (b) RCA and (c) RAP.
A. Arulrajah et al. / Construction and Building Materials 145 (2017) 218–225 221
RAP ing that the total binder content is limited to 30% by weight.
Increasing the content of spherical FA particles not only facilitates
8 2.6
the compaction process, but also reduces the amount of CKD pow-
der particles in the mixture.
6 2.4
Fig. 5 presents the scanning electron microscope images of the
clumps of the CKD powder which is about 100 times finer than
4 RAP 2.2 average FA particles compared to the spherical particles of FA.
The significantly higher specific area of the CKD powder leads to
2 RCA 2.0 a higher water absorption during the process of hydration, which
causes the reduction of optimum water content. It also should be
CB
0 1.8 noted that despite lower specific gravity of FA compared to that
0 5 10 15 20 25 30 of CKD, the dry density of the CKD + FA blends increases with
FA Content, % higher percentages of FA which is due to increasing the compatibil-
ity of blends caused by the increase of spherical FA particles.
Fig. 4. Variation of dry density by moisture content of CKD + FA stabilized C&D
The development of average UCS for different binder content is
materials.
presented in Fig. 6. The UCS of the CKD + FA stabilized C&D
Uniaxial Strength
Young Modulus Stiffness
4 8
7
Average UCS values (MPa)
5
Class L
2 4
3
Class M
1 2
0 0
CB - Unbound
CB + 30% CKD
CB + 30% FA
RCA - Unbound
RCA + 30% FA
RAP - Unbound
RAP + 30% FA
materials compared to unbound C&D materials increases by almost The pH of the mixture is found to almost reach the saturation
12, 4 and 2-fold respectively for CB, RCA and RAP relatively at the point after addition of 10% CKD as shown in Fig. 7. The pH value
best combination of the CKD + FA binder. It is evident that the CKD stays almost constant after this point. The optimum performance
+ FA binders performed better than individual binders with just for stabilizing C&D materials is obtained at the mix design of 20%
CKD or just FA. The low calcium content of the FA hinders the CKD + 10%FA. RCA and CB mixed with any of the suggested combi-
hydration process and bonding of the aggregates and barely nations of CKD and FA can be used as a road base material [35].
impacts strength development. On the other end, scarcity of fine Although RAP exhibits a higher unbound strength compared to
fraction along with lack of plasticity in the limited fine content of CB, the stabilized CB materials show a higher strength. The visual
C&D material limits the creation of bonds with the stabilized mate- observation reveals that the thin layer of bitumen coating the
rials. However, the combination of CKD + FA increases the pH of RAP aggregates prevents sufficient surface adhesion between the
the blends significantly and the abundance of calcium in the blend RAP aggregates and the mortar, causing premature failure in the
provides an ideal environment for creation of C-A-S-H gel. This specimen. However, the stabilized RAP aggregates can be consid-
product is similar to calcium silicate hydrate gel (C-S-H) that is ered as an alternative in construction of road subbases [35].
produced in activation process of cement [34]. The secant stiffness modulus at 50% of failure strength (E50) was
measured for each sample and is plotted along with the UCS value
FA content (%) of the stabilized materials in Fig. 8 for comparison of the strength
30 25 20 15 10 5 0 and elastic rigidity of the samples. The static Young’s modulus is
14
relatively close and comparable with the UCS of the stabilized
materials. Fig. 8 shows the goodness of fit for comparison of the
secant Young’s modulus compared to axial strength. The static
13
secant modulus of stabilized materials was shown to be closely
related to UCS value of the materials [36].
12 The resilient modulus (MR) of stabilized C&D materials is shown
in Fig. 9. The confining pressure and cyclic axial stress of each of
pH Value
5
CB - Unbound
CB + 30% CKD
CB + 20% CKD + 10% FA
1200
a) 400
Unbound CB
CB + 30% CKD
CB + 20% CKD + 10% FA
1000
600 200
400
100
200
0 0
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15
Stress Stage Number
1800
b) 400
Unbound RCA
RCA + 30% CKD
1600
RCA + 20% CKD + 10% FA
Resilient Modulus, MR (MPa)
600
100
400
200
0 0
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15
Stress Stage Number
1200
c) 400
Unbound RAP
RAP + 30% CKD
RAP + 20% CKD + 10% FA
1000
Resilient Modulus, MR (MPa)
RAP + 30% FA
800 Cyclic Axial Stress
Confining Pressure
600 200
400
100
200
0 0
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15
Stress Stage Number
Fig. 9. Resilient modulus of CKD + FA stabilized C&D materials after 7 days of curing for (a) CB (b) RCA and (c) RAP.
strain on unbound C&D aggregates that exhibits unstable behavior were investigated as an alternative binder to stabilize three types
for all C&D aggregates to the point that unbound CB has failed dur- of common C&D materials.
ing the third stage. However, the C&D + 20%CKD + 10%FA shows a The strength and resilient modulus properties of CKD/FA stabi-
very stable behavior. lized C&D materials was evaluated in this research to develop an
understanding of the properties and efficiency of CKD in construc-
tion stabilization activities.
4. Conclusions The strength and stiffness characterization of CKD + FA stabi-
lized C&D materials were evaluated by undertaking UCS and RLT
CKD is an industrial by-product formed during the manufacture tests at room temperature. The optimum performance for stabiliz-
of cement and is a waste material that is traditionally destined for ing C&D materials was obtained at the mix design of 20%CKD + 10%
landfills. CKD is calcium-rich whereas FA is silica-rich, hence the FA. RCA showed the highest strength and stiffness gain followed by
unique combination of these two pozzolanic materials (CKD + FA) CB and RAP. RCA and CB stabilized with CKD + FA can be utilized
224 A. Arulrajah et al. / Construction and Building Materials 145 (2017) 218–225
6000
4000
2000
0
0 5000 10000 15000 20000 25000 30000
Loading Cycles
Fig. 10. Comparison of permanent strain results for unbound and CKD + FA stabilized C&D materials.
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