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Estimate the cooling speed in kW needed to carry 300 kg / min of CO from 450 ° C to 50 ° C,
performing the calculations using:
a) Table B2
b) Table B8
Answer:
(a)
Given information:
T f 50 C 323 K
Final temperature of CO,
m
n
MW
kg 1000 g min
300
min kg 60 s
g
28
mol
mol
178.57
s
dQ nC
p dT
…… (1)
Cp
The value of is dependent on temperature according to the expression:
C p kJ mol C a bT cT 2 dT 3
…… (2)
Here, a, b, c, and d are the coefficients whose values are given in table B.2. For CO, these
values are:
a 28.95 103
b 0.4110 105
c 0.3548 108
d 2.220 1012
C p kJ mol C 28.95 103 0.4110 10 5 T 0.3548 10 8 T 2 2.220 10 12 T 3
Cp
Use this expression of in equation (1) and calculate the cooling rate as;
Tf
dQ n C p dT
Ti
50
Q 178.57
mol
28.95 10 0.4110 10 T 0.3548 10 T 2.220 10
s 450
3 5 8 2
12
T 3 dT
50
T2 T3 T4
178.57 28.95 103 T 0.4110 10 5
2
0.3548 10 8
3
2.220 10 12
4 450
2
5 50 450
2
28.95 10 3
50
450 0.4110 10 2
178.57
3
8 50 450
3
12 50 450
4 4
0.3548 10
3
2.220 10 4
2164.5 kJ s
Q 2164.5 kW
(b)
From table B.8, the value of enthalpy for CO at 50 C and 450 C are calculated using
y2 y1
y y1 x x1
x2 x1
Here, y1 and y2 are known values at x1 and x2 respectively. y is the required value at x . Use
this formula to calculate the value of enthalpy of CO at 50 C as:
T1 25 C
T2 100 C
T f 50 C
Hˆ 1 0.00 kJ mol
Hˆ 2 2.19 kJ mol
Hˆ Hˆ 1
Hˆ f Hˆ 1 2
T2 T1
T f T1
2.19 0
Hˆ f 0 50 25
100 25
Hˆ f 0.73 kJ mol
T3 400 C
T4 500 C
Ti 450 C
Hˆ 3 11.25 kJ mol
Hˆ 4 14.38 kJ mol
Hˆ Hˆ 3
Hˆ i Hˆ 3 4 Ti T3
T4 T3
14.38 11.25
Hˆ i 11.25 450 400
500 400
Hˆ i 12.815 kJ mol
Given information:
m
n
MW
kg 1000 g min
300
min kg 60 s
g
28
mol
mol
178.57
s
Q n Hˆ f Hˆ i
178.57 0.73 12.815
2158.02 kJ s
Q 2158.02 kW