Dr.

Heider CHM 2045 Practice Final Exam SI Leader Marina

1. Which statement about the following equation is incorrect?

2 NH4NO3 (s)  2 N2 (g) + O2 (g) + 4 H2O (g)
a. For every mole of NH4NO3 that decomposes, 1 mole of N2 is produced
b. If 80.05 g of NH4NO3 decompose, 16.0 g of oxygen gas will be obtained
c. One mole of NH4NO3 will produce 22.4 L of N2 at STP
d. The volume of gases produced from a given mass of NH 4NO3 can be calculated
using the ideal gas equation
2. If 30.0 g of argon and 15.0 g of xenon are placed in a 120.0 mL container at 22.0°C, what
is the partial pressure of xenon, in atm?
a. 8.7
b. 22.9
c. 0.700
d. 174
e. 5.60
3. Place the following gases in order of increasing average velocity at 400 K: Ne, Ar, SO 2,
and N2
a. Ar<Ne<N2<SO2
b. Ne<Ar<N2<SO2
c. N2< SO2 < Ne< Ar
d. Ne< Ar = SO2< N2
4. Of the following gases, which one has the greatest density at 1.0 atm and 23°C?
a. CH4
b. Ne
c. CO
d. N2
e. NO
5. An ideal gas differs from real gas in that the molecules of an ideal gas
a. Have no attraction for one another
b. Have appreciable molecular volumes
c. Have a molecular weight of zero
d. Have no kinetic energy
e. Have an average molecular mass
6. For a fixed amount of gas, what happens to its pressure, if temperature is doubled and
volume is doubled?
a. The pressure will be increased by a factor of 4
b. The pressure will be doubled
c. There will be no change in the pressure
d. The pressure will be halved
e. The pressure will decrease to one-quarter of its initial value
7. Select the expression that is the correct statement of Boyle’s Law
 a. PV=constant
b. P/V = constant
c. V/P = constant
d. V/T = constant
e. n/P = constant
8. Avogadro’s hypothesis states that equal volumes of gases under the same conditions of
temperature and pressure will have equal ____________.
a. Densities
b. Particle velocities
c. Molar masses
d. Number of particles
e. Masses
9. How many moles of gas are there in a 45.0 L, container at 25.0°C and 500.0 mmHg?
a. 0.630
b. 6.11
c. 18.4
d. 1.21
e. 207
10. Calculate the volume of O2 (at STP) formed, when 25.0 g of KClO 3 decomposes according
to the following reaction. Molar mass for KClO 3 is 122.55 g/mol.
2 KClO3 (s)  2KCl (s) + 3 O2 (g)
a. 9.14 L
b. 8.22 L
c. 12.3 L
d. 6.86 L
e. 14.6 L
11. For the combined gas law to hold true, what variable remain unchanged, or is a
constant?
a. Temperature
b. Density
c. Volume
d. Moles of gas
e. Pressure
12. Which of the following are postulates of the kinetic-molcular theory of gases?
1. The distance between gas molecules is large in comparison to their size
2. Gas molecules are in constant, random motion
3. The kinetic energy of gas particles is proportional to the kelvin temperature
a. 1 only
b. 2 only
c. 3 only
d. 1 and 2
e. 1, 2 , and 3
13. Iron reacts with HCl to produce iron (II) chloride and hydrogen gas. The hydrogen gas
from the reaction of 4.4g of iron with excess acid is collected in a 1.0 L flas at 25°C. What
is the H2 pressure, in atm?
Fe (s) + 2 HCl (aq)  FeCl2 (aq) + H2 (g)
a. 1.9
b. 8.3
c. 0.95
d. 0.33
e. 5.6
14. Density of a gas is 4.93 g/L at 785 torr and 155°C. Calculate the molar mass
a. 123 g/mol
b. 437g/mol
c. 212g/mol
d. 168g/mol
e. 493g/mol
15. Rank the following in order of decreasing rate of effusion
F2 SF6 CO Kr
a. Kr>CO>SF6>F2
b. F2>KR>CO>SF6
c. CO>F2>Kr>SF6
d. CO>F2>SF6>Kr
e. SF6>Kr>F2>CO
16. What is the volume of gas at STP in liters?
a. 1.0
b. 22.4
c. 14.7
d. 0.08206
e. 62.36
17. At STP, what volume of N2 will react completely with 22.2L H 2 to produce NH3?
N2(g) + 3 H2(g)  2 NH3 (g)
a. 7.4
b. 14.8
c. 22.2
d. 44.4
e. 66.6
18. What variables must remain constant for Charles’ law to be considered valid?
a. Volume and Pressure
b. Temperature and volume
c. Temperature and amount of gas
d. Pressure and amount of gas
e. Temperature and pressure
19. A cylinder with a moveable piston contains 0.87mol of a gas and a volume of 334 mL.
What is the volume after 0.22mol of the same gas is added to the cylinder
a. 420 mL
b. 310 mL
c. 22.0 L
d. 850 mL
e. 640 mL
20. What is the wavelength of a 6.0 gram bullet travelling at the speed of sound?
a. 2.7x10-34
b. 2.7 x 10-37
c. 3.3 x 10-34
d. 6.6 x 10-31
e. 3.35 x 10-32
21. Of the following electron transitions, which is responsible for the emission of the lowest
amount of energy?
a. n = 1  n=6
b. n = 3  n = 6
c. n = 6  n = 1
d. n = 1  n = 4
e. n = 6  n = 4
22. Which of the following represents the orbital n = 4; l = 1; and m l = 0?
a. 3s
b. 4p
c. 3d
d. 4s
e. 3f
23. From the following, which is a pure substance?
a. Wine
b. Sweat
c. Diamond
d. Sea water
24. Which of the following show a chemical change?
a. Boiling water
b. Cooking eggs
c. Liquid propane evaporates
d. Sugar dissolving in water
40
25. Determine the number of protons, neutrons, and electrons of 19 K +
a. N = 19; P = 40; E = 39
b. N = 19; P = 40; E = 41
c. N = 19; P = 40; E = 18
d. N = 40; P = 19; E = 19
26. An element has 2 naturally occurring isotopes. Isotope 1 has a mass of 120.9038 amu
and a relative abundance of 57.4% and isotope 2 has a mass of 122.9042 amu. Find the
atomic mass of the element.
a. 121.8 amu
b. 120.3 amu
c. 122.4 amu
d. 121.2 amu
27. You need 3 µL of .2 M NaCl, but only have a 5 M stock solution. How much of the stock
solution do you need to make the appropriate dilution?
a. 1.2 x 10-7 µL
b. 7.5 x 10-7 µL
c. 2.4 x 10-7 µL
d. 4.1 x 10-7 µL
28. How much hydrogen chloride is needed to neutralize 4.85 g of sodium hydroxide?
a. 4.24 g
b. 4.42 g
c. 8.25 g
d. 8.52 g
29. Calculate ∆Hrxn for the following reaction:
5 C + 6 H2  C5H12
Using the following reactions:
C5H12 + 8 O2  5 CO2 + 6 H2O ∆Hrxn = -3505.8 kJ
C + O2  CO2 ∆Hrxn = -393.5 kJ
2 H2 + O2  2 H2O ∆Hrxn = -483.5 kJ

a. 84.32 kJ
b. 87.8 kJ
c. 2851.2 kJ
d. 2628.8 kJ
30. Magnesium metal reacts with hydrochloric acid according to the following balanced
equation:
Mg + 2 HCl  MgCl2 + H2

0.158 g of magnesium metal reacted with HCl in 100 mL of solution in a coffee-cup

calorimeter. Temperature of the solution rose from 25.6°C to 32.8°C. Find ∆Hrxn. The
solution has a density of 1.00 g/mL and Cs of solution is 4.18 J/g*°C.

a. 4.6 x 105 J
b. 6.4 x 105 J
c. -6.4 x 105 J
d. -4.6 x 105 J
31. What is the electron configuration of Mg 2+
 a. 1s22s2 2p63s2
b. 1s22s22p63s23p2
c. 1s22s22p6
d. 1s22s22p23s2
32. Which of the following elements would be repelled by a magnetic field?
a. Li
b. Be
c. B
d. C
33. Which is in violation of octet rule?
a. SF4
b. KrF2
c. CBrF3
d. XeF4
e. BCl3
34. Which molecule below is nonpolar?
a. SF4
b. OF2
c. PH3
d. CBrCl3
e. XeCl4
35. What is the hybridization of the N circled?

a. sp
b. sp2
c. sp3
d. sp3d
36. Given the electronegativities below, which covalent single bond is the least polar?

Element H C N O
Electronegativity 2.1 2.5 3.0 3.5
a. C-H
b. N-H
c. O-H
d. O-C
 e. O-N
37. What is the molecular shape of ICl4-
a. Tetrahedral
b. Square pyramidal
c. Square planar
d. Octahedral
38. What type of bonds are involved in the circled bond?

a. σ only
b. π only
c. σ and π
d. σ and 2 π