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FIITJEE Admission Test

for students

Class 12 Appeared / Pass


Paper 2
Time: 3 Hours (1:45 pm – 4:45 pm) Maximum Marks: 270

Instructions:

1. This Question paper consists of 3 sections. All questions will be multiple choice single correct out of four
choices with marking scheme in table below:

Section – I, II & III Marking Scheme for each question


Question no.
(PCM) correct answer wrong answer
1 to 2, 6, 31 to 32, 38, 61 +3 –1
PHYSICS 3 to 4, 7 to 9, 33 to 36, 39, 62 +4 –1
5, 10, 37, 40, 63 +5 –2
11 to 12, 16, 41 to 42, 48, 64 +3 –1
CHEMISTRY 13 to 14, 17 to 19, 43 to 46, 49, 65 +4 –1
15, 20, 47, 50, 66 +5 –2
21 to 22, 26, 51 to 52, 58, 67 +3 –1
MATHEMATICS 23 to 24, 27 to 29, 53 to 56, 59, 68 +4 –1
25, 30, 57, 60, 69 +5 –2

2. Answers have to be marked on the OMR sheet. The Question Paper contains blank spaces for your rough
work. No additional sheets will be provided for rough work.
3. Blank papers, clip boards, log tables, slide rule, calculator, cellular phones, pagers and electronic devices, in
any form, are not allowed.
4. Before attempting paper write your OMR Answer Sheet No., Registration Number, Name and Test
Centre in the space provided at the bottom of this sheet.
5. See method of marking of bobbles of the back of cover page for question no. 31 to 69.

Note: Please check this Question Paper contains all 69 questions in serial order. If not so, exchange for the correct Question Paper.

OMR Answer Sheet No. : _____________________________________________________________

Registration Number : _____________________________________________________________

Name of the Candidate : _____________________________________________________________

Test Centre : _____________________________________________________________

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For questions 31 to 60
Numerical based questions single digit answer 0 to 9

Example 1:
If answer is 6.
Correct method:

0 1 2 3 4 5 6 7 8 9

Example 2:
If answer is 2.
Correct method:

0 1 2 3 4 5 6 7 8 9

For questions 61 to 69
Numerical answer type questions with answer XXXXX. XX
Correct bubbles to be darkened below the boxes for your answer.

If answer is 348.4 / 251.37 / 213


Correct Method :
3 4 8 . 4 0
2 5 1 . 3 7

2 1 3 . 0 0

Wrong Method :
3 4 8 . 4
3 4 8 . 4
3 4 8 . 4

3 4 8 . 4
2 5 1 . 3 7

2 1 3 .

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Section-I Science & Mathematics

Physics (Part – A)
Straight Objective Type
Question numbers 1 to 2 are 2 passage based Multiple Choice Questions. Each question has 4 choices
(A), (B), (C) and (D), out of which ONLY ONE is correct.

In figure shown, the graph shows the variation of a unidirectional F(N)


force F acting on a body of mass 10 kg (In gravity free space), with
time t. The velocity of the body at t = 0 is zero.
20
1. The power of the force at t = 12 sec is
(A) 225.0 W 10
(B) 217.6 W
t(S)
(C) 226.7 W 0 10 15 25 30
(D) none of these

2. The change in momentum of the body between the time t = 10 sec to 15 sec is
(A) 100 kg m/s (B) 75 kg m/s
(C) 125 kg m/s (D) none of these
Space for Rough Work

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Straight Objective Type


Question numbers 3 to 5 are 3 multiple choice questions single correct. Each question has 4 choices (A),
(B), (C) and (D), out of which ONLY ONE is correct.

3. An open pipe is in resonance in 2nd harmonic with frequency f 1. Now one end of the tube is
closed and frequency is increased to f 2 such that the resonance again occurs in nth harmonic.
Choose the correct option.
3 5
(A) n = 3, f2  f1 (B) n = 3, f2  f1
4 4
3 5
(C) n = 5, f2  f1 (D) n = 5, f2  f1
4 4

4. An electron, charge e, mass m, enters a uniform magnetic field B  B ˆi with an initial velocity

v  v x ˆi  v y ˆj . What is the velocity of the electron after a time interval of t second?
e e
(A) v x ˆi  v y ˆj  v yB t kˆ (B) v x ˆi  v y ˆj  v yB t kˆ
m m
 e   e 
(C) v x ˆi   v y  v yB t  ˆj (D) v x ˆi   v y  v yB t  ˆi  v y ˆj
 m   m 

5. A conducting sphere of radius R and charge Q is placed near a 


uniformly charged nonconducting infinitely large thin plate + +Q
A
having surface charge density  . Then find the potential at +
point A (on the surface of sphere) due to charge on sphere + 0
O
1  +
(here K = , 0  ) + 4R
4 0 3 +
Q 
(A) K  R
R 4 0
Q R
(B) K 
R 0
Q
(C) K
R
(D) none of these
Space for Rough Work

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Straight Objective Type


Question numbers 6 to 10 are 5 multiple choice questions multi correct. Each question has 4 choices (A),
(B), (C) and (D), out of which ONE or More is correct.

6. In the circuit shown, the switch is closed at t  0; L1


I1
(A) at t  0,I1  I2  0
I2 L2
I L
(B) at any t, 1  2
I2 L1 S

 
(C) at any t, I1  I2  R
R

(D) at t  , current flowing through the resistor is
R

4F
7. Consider the circuit shown in figure after switch S is closed
(A) Amount of charge that will flow through the battery is 20
C
(B) Amount of charge that will flow through the switch is 60 C 4F
(C) Amount of charge that will flow through the battery is 40
C
(D) Amount of charge that will flow through the switch is zero
15 V

8. The diagram shows the basic setup for the production of P Q


X-rays. A1 and A2 are two ammeters, reading 2.55 A
and 2.566 A respectively. F is a filament which is also
called the cathode. The potential difference applied
between P and Q is 50000 V. Assume that all X-ray A2
photons have the maximum possible energy and that
one X-ray photon is emitted for every 100 electrons F
incident on the target. You may assume that the kinetic A1
energy of the other electrons reappear as heat in the
tube.
(A) The rate at which heat is produced in the X-ray tube is approximately 400 W
(B) The number of X-ray photons produced per second is approximately 1015
8
(C) The momentum of each X-ray photon is approximately  10 23 kgms1
3
(D) The rate at which heat is produced in the X-ray tube is approximately 800 W
Space for rough work

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9. The main scale of a vernier callipers reads in millimetre and its vernier is divided into
10 divisions which coincide with 9 divisions of the main scale. When the two jaws of the
instrument touch each other the seventh division of the vernier scale coincide with a scale
division and the zero of the vernier lies to the right of the zero of main scale. Furthermore, when a
cylinder is tightly placed along its length between the two jaws, the zero of the vernier scale lies
slightly to the left of 3.2 cm; and the fourth vernier division coincides with a scale division. Choose
from following the correct option.
(A) The least count of the apparatus is 0.01 cm
(B) The zero error in the apparatus is 0.07 cm
(C) The measured value of the length of the cylinder is 3.07 cm
(D) The zero error in the apparatus is 3.17 cm

10. A boy of mass m climbs up a conveyor belt B


with a constant acceleration. The speed of
gh
the belt is v  and the coefficient of
6
friction between the boy and conveyor belt
5
is  
3 3
. The boy starts from A and

moves with the maximum possible


acceleration till he reaches the highest

A
h

 = 300
point B. Then,

(A) Work done by gravity on the boy relative to ground is -mgh


1
(B) Work done by gravity on the boy relative to conveyer belt is - mgh
2
4
(C) The time taken by the boy to reach the height h is
g
6h
(D) The time taken by the boy to reach the height h is
g
Space for Rough Work

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Chemistry ( P ar t – B )
Straight Objective Type
Question numbers 11 to 12 are 2 passage based questions Multiple Choice Questions. Each question
has 4 choices (A), (B), (C) and (D), out of which ONLY ONE is correct.

Thermodynamics deals with various energy changes involved in physical and chemical processes. First
law of thermodynamics deals with law of energy conservation while second law predicts about the
feasibility of a process. If Stotal  0 , then a process is feasible but to calculate Stotal , we need to
consider both Ssys as well as Ssurr ; so another function ‘ G ’ is introduced.
G  H  TS
 TS total

11. What will be the free energy change (kJ/mole) which accompanies the expansion of one mole of
mercury vapour (in equilibrium with its liquid) at 433 K to a pressure of 1 atm at the same
temperatures (Given (Vapour pressure)Hg = 4.19 mm of Hg at 433K)
(A) 18.725 (B) zero
(C) 1 (D) 2.05

12. If 1 mole of ideal gas kept in a piston (massless & frictionless) that is placed in an evacuated
chamber expands to double its volume then for such expansion process

Large
evacuated
chamber

(A) Ssurr.  Ssys  0


(B) Ssurr.  Ssys  1.3864 cal/mol.
(C) Ssurr.  0 & Ssys  1.3864 cal
(D) Ssurr.  1.3864 cal & Ssys  1.3864 cal
Space for Rough Work

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Straight Objective Type


Question numbers 13 to 15 are 3 multiple choice questions single correct. Each question has 4 choices
(A), (B), (C) and (D), out of which ONLY ONE is correct.

13. For the given reactions :


(i) Hg (OAc)2 / H2O
I: CH2 CH CH2 CH2 CH2 OH J (major)
(ii) NaBH4
product
H+
II : O O H K (major)
product
J & K respectively are
O O
CH3 CH3
(A) & CHO CHO
(B) &
CHO

(C) CH3 CH CH2 CH2 CH2 OH (D) CH2 (CH 2)3 CH2 OH

OH & OH &

OH O

14. The correct order of acidic strength of the following chloro-substituted phenols is -
OH OH OH OH
Cl
(a) (b) (c) (d)

Cl
Cl
(A) (b) > (c) > (d) > (a) (B) (d) > (b) > (c) > (a)
(C) (c) > (b) > (d) > (a) (D) (c) > (a) > (b) > (d)

15. Which of the following has maximum bond energy?


(A) He2 (B) O2
(C) O 22 (D) O 2
Space for Rough Work

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Straight Objective Type


Question numbers 16 to 20 are 5 multiple choice questions multi correct. Each question has 4 choices
(A), (B), (C) and (D), out of which ONE or More is correct.

16. Which of the following is not extensive property?


(A) G (B) CP, m
(C) P (D) T

17. Which of the following interaction form non-bonding molecular orbital when z-axis is the bonding
axis?
(A) dyz  dz2
(B) dyz  dxy
(C) dx2  y2  dxy
(D) all the above will form non bonding molecular orbitals

18. Identify the correct statement.


(A) cis-1, 2- dimethyl cyclohexane has non superimposable mirror image
(B) cis-1, 2, dimethyl cyclohexane shows no optical activity
(C) Benzene and naphthalene both can give electrophillic aromatic substitution
(D) In naphthalene C – C are of equal lengths

19. Which of the following regarding radioactive decay is/are correct?


(A)  -decay always results in transmutation
(B) Internal pair production is a type of  -decay
(C) In  -decay, a nucleus changes from a higher to lower energy state through the emission of
photons
(D)  -decay is accompanied by the emission of neutrino

20. Which of the following is/are incorrect option?


(A) HOCl < HClO2 < HClO3 < HClO4 (acidic strength)
(B) HOCl < HClO2 < HClO3 < HClO4 (thermal stability)
(C) NH3 > PH3 > AsH3 (basic strength)
(D) BiH3 > NH3 > SbH3 > AsH3 > PH3 (boiling point)
Space for Rough Work

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Mathematics ( P ar t – C )
Straight Objective Type
Question numbers 21 to 22 are 2 passage based questions Multiple Choice Questions. Each question
has 4 choices (A), (B), (C) and (D), out of which ONLY ONE is correct.

A cubic f(x) = ax 3 + bx2 + cx + d vanishes at x = -2 and has relative minimum/maximum at x = -1 and x =


1
1 14
and if  f(x) dx  .
3 1
3

21. The function f(x) is


(A) x3 + x2 + x – 2 (B) x3 – x2 + x – 2
(C) x3 – x2 – x + 2 (D) x3 + x2 – x + 2

22. f(x) decreases in the interval


 1   1 
(A)   ,1 (B)   , 1
 3   3 
 1  3
(C)  1,  (D)  1, 
 3  2

Space for Rough Work

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Straight Objective Type


Question numbers 23 to 25 are 3 multiple choice questions single correct. Each question has 4 choices
(A), (B), (C) and (D), out of which ONLY ONE is correct.

2
23. From the origin, chords are drawn to the circle  x  1  y 2  1, then the locus of middle points of
these chords will be
x
(A) x 2  y  x  0 (B) x 2  y 2  0
2
x
(C) x 2  y 2  x  0 (D) x 2  y 2   0
2

24. The period of f  x   ecosx  sin   x  is ([.] & {.} denotes greatest integer function and fractional
part function respectively)
(A) 1 (B) 2
(C)  (D) 2

sec 2 x

 f  t  dt
2
25. The value of lim is
x
  2 2 
4
x  
 16 
2 2  1
(A) f 2 (B) f 
  2
4 8
(C) f  2 (D) f 2
 

Space for Rough Work

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Straight Objective Type


Question numbers 26 to 30 are 5 multiple choice questions multi correct. Each question has 4 choices
(A), (B), (C) and (D), out of which ONE or More is correct.

26. If n C   n C2 then it may be true that


(A)   2 (B)     2n
(C)   2  n (D) All above

27. The general solution of tan 3 tan   1 is given by  n  I 


 
(A)    2n  1 (B)    2n  1
2 4
 3 
(C)   n  , n  (D)    2n  1
8 8 8

28.  
6 sin1 x 2  6x  8.5   , if
(A) x  1 (B) x  2
(C) x  3 (D) x  4



29. If y = f(x) and y = g(x) are symmetrical about the line x = , then  f(x) g'(x)dx is equal to
2 
 

(A)  f '(x) g(x)dx (B)  f '(x) g(x)dx


 
 
1 1
(C) (f(x) g'(x)  f '(x) g(x))dx (D) (f(x) g'(x)  f '(x) g(x))dx
2  2 

x
30. Let f(x) =  e t [t] dt (x > 0), where [x] denotes greatest integer function less than or equal to x, is
0

(A) continuous and differentiable  x  [0, 3)


(B) continuous but not differentiable  x  [0, 3)
(C) f(1) = e
(D) f(2) = 2(e – 1)

Space for Rough Work

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Section-II Physics, Chemistry & Mathematics

Physics (Part – A)
Numerical Based Questions
Question numbers 31 to 40 are 10 numerical based questions single digit answer 0 to 9.

31. In the potentiometer circuit shown in figure, E


the balance point with R  10.0  when
switch S1 is closed and S 2 is open is 50 cm,
while that when S 2 is closed and S1 is open
is 60 cm. What is the value of X (in  )?

E’

32. The acceleration of block A of mass 5 kg at given instant is (in F = 60N


m/s2):- (Pulley and thread are ideal)

m
A

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33. A glass tube of 1.0 m length is filled with water. The water can be drained out slowly at the
bottom of the tube. A vibrating tuning fork of frequency 500 Hz is brought at the upper end of the
tube. Find the number of resonances that can be obtained. (Ignore end correction. Velocity of
sound is 300 m/s)

34. A particle hanging by a light string of length l is projected horizontally from its lowest point with
7gl n
velocity = , If the string slacks after swinging through an angle , then n =
2 6

35. Coefficient of restitution e which will allow the ball


to bounce down the steps as shown. The trend
and riser dimensions are same for each step
equal to d and the ball bounces the same
distance h above each step. (Friction between
n
the ball and the steps is zero). If e  find n.
3

36. An ideal gas having initial pressure P, volume V and temperature T is allowed to expand
T
adiabatically until its volume becomes 5.66 V while its temperature falls to . Calculate the
2
degrees of freedom of the gas molecules. Given log e  5.66   1.73log e  2   0.70 .

Space for rough work

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37. The switch (SW ) in the figure closes when VC > 2V/3 and
R
opens when VC  V/3. The voltmeter reads a voltage as
plotted in the figure. The period T of the waveform of the V
voltage is nRT ln2 . Find n. Voltmeter is ideal. R
VC
C
SW

VC

2V
3
V
3
t
T

38. Two soap bubbles A and B are kept in a closed chamber where the air is maintained at pressure
8 Nm–2. The radii of bubbles A and B are 2 cm and 4 cm, respectively. Surface tension of the
nB
soap water used to make bubbles is 0.04 Nm –1. Find the ratio , where nA and nB are the
nA
number of moles of air in bubbles A and B, respectively. (assume TA = TB)

39. A proton is fired from very far away towards a nucleus with charge = 120 e, where e
is the electronic charge. It makes a closest approach of 10 fm to the nucleus. The
de Broglie wavelength (in units of fm) of the proton at its start is: (take the proton mass,
1
mp = (5/3) × 10–27 kg ; h/e = 4.2 × 10–15 J.s./C; = 9 × 109 m/F; 1 fm = 10–15 m)
40

40. A ball of mass 1 kg is projected with velocity 7 m/s 1kg 7m/s


horizontally from a tower of height 3.5 m. It collides
elastically with a wedge of mass 3 kg and inclination
450 placed on smooth horizontal surface. Ball collides
the wedge at a height of 1 m above the ground. Find
the velocity (in m/s) of the wedge after the collision. 3.5m

3kg
1m
450

Space for Rough Work

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Chemistry ( P ar t – B )
Numerical Based Questions
Question numbers 41 to 50 are 10 numerical based questions single digit answer 0 to 9.

41. 20 ml 0.1 M K2Cr2O7 is mixed with 40 ml 0.1 N KMnO4 in presence of H2SO4. If this solution is
treated with excess of a mixture of H2C2O4 and NaHC2O4 then number of milli moles of CO2
evolved will be 2a. Find a.

M
42. Equivalent mass of reducing agent in the following reaction is , where n is
n
H2S + SO2  S + H2O

43. How many of the following options are incorrect?


(i)   S    S ; H     ve
(ii)   S    S ; H     ve
(iii) Red P  Black P, H     ve
(iv) Black P  White P, H     ve
(v) Graphite  Diamond, H     ve
(vi) If C (diamond) + O2  CO2, HC   x
C (graphite) + O2  CO2, HC   y
then, x  y

44. How many stereoisomers of the following compound are possible?


OH O

OH O OH
Space for rough work

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45. The number of moles of acidified KMnO4 required to convert five mole of sulphite ion
into sulphate ion is :

46. If the shortest wavelength of H-atom in Lyman series is λ, then longest wavelength in Balmer
a
series of He+ ion is . Find a.
5

47. After SrCO3 was equilibrated with a buffer of pH 8.60, the solution was found to have [Sr+2] =
2.2  104 . The solubility product for SrCO3 is 8.9  102 x . x is (Given:  log  8.6   2.51 10 5 ,
Ka1 H2CO3   2  105 and Ka2 H2CO 3   4.7  10 11 )

48. 24 cm

P atm = 75 cm of Hg

10 cm 10 cm, d = 20.4 gm/ml


of
Hg
If above tube is placed vertically with the open end upward then the length of the air column is 2a.
Find a. (density of Hg = 13.6 gm/ ml)

49. 0.685 gm of an alloy of copper-zinc-lead containing 1% lead (w/w) was dissolved in nitric acid
and diluted to 250 cm3. After that 100 ml of this diluted solution was electrolyzed with a current of
1.47 mA for 1 hr & 20 min. which ensured that all the lead was completely converted to lead
dioxide. (Given: In the process, nitrated ions are reduced to ammonium ions which at the same
time prevents the liberation of hydrogen at cathode). The percentage of total current passed that
a
is used in the formation of PbO2 is ‘a’. Find (approx.).
9

CH3

NBS
50. 
CCl4 ,  Peroxide , 
 How many mono-brominated products are
obtained (excluding stereoisomers)?

Space for Rough Work

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Mathematics ( P ar t – C )
Numerical Based Questions
Question numbers 51 to 60 are 10 numerical based questions single digit answer 0 to 9.

 x x
51.  
f  x   a2  3a  2  cos2  sin2    a  1 x  cos1 does not passes critical point then the
 4 4 
number of integral values of a are

52. If the equation cot 4 x  2cosec 2 x  a 2  0 has at least one solution, then the sum of all possible
integral values of ‘a’ is equal to

53. If  is non real fifth root of unity then 101  102  103  104  105 is ___________

54. f  x  y   f  x   f  y   xy  1  x, y  R & f 1  1 , then the number of solutions of f  n   n


n  N is

n
55. If Pn denotes the product of all the coefficients of 1  x  and 8! Pn 1  98 Pn then n is equal to

56. There are 3 different pairs (i.e. 6 units say a, a, b, b, c, c) of shoes in a lot. Now three person
come & pick the shoes randomly (each gets 2 units). Let p be the probability that no one is able
13 p
to wear shoes (i.e. no one gets a correct pair), then is
4 p

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d 1
57. Let f :  2, 5  2, 5  be a bijective function such that f  x   0  x  2, 5 then
dx
5

  f  x   f  x  dx is equal to 7k, then value of k is


1

1
58. If the equation ax 2  bx  c  x3  (a, b, c  0) has only real roots and all the roots are integers
x
a  b  c
then the value of ( ) is
7

59. Given that a, b, c are the sides of a triangle ABC which is right angled at C, then the minimum
2
c c
value of    is
a b

60. If S  127  227  327  427......  199 27 and a, b are unit digit and digit at ten’s place of S then a +
b is equals to
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Section-III Physics, Chemistry & Mathematics

Physics (Part – A)
Numerical Answer Type
Question numbers 61 to 63 are 3 numerical answer type questions with answer XXXXX.XX.

61. Determine the force P required to impend the motion


of the block B shown in figure. Take coefficient of m=3 kg
friction = 0.3 for all surfaces in contact. T
A
P
B m = 5 kg
C
m=4 kg

62. A smooth track in the form of a quarter 6m


circle of radius 6m lies in the vertical plane
(as shown in figure). A particle of weight 4N P2
2
moves from P1 to P2 under the action of
   
forces F1, F2 , and F3 . Force F1 is always
towards P2 and is always 20N in magnitude,

force F2 always acts horizontally and is 6m

always 30N in magnitude, force F3 always F1 = 20N
acts tangentially to the track and is of  F3  15  10s N
magnitude 15  10s  N when s is in meters.
F2= 30N
If the particle has speed 4 m/s at P1, what
will its speed be at P2? s
P1 w = 4N

63. What is the amount of power delivered by the ac XC  12 R1  5


source in the circuit shown (in watts).
XL  8  R2  6


Rrms = 130V

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Chemistry ( P ar t – B )
Numerical Answer Type
Question numbers 64 to 66 are 3 numerical answer type questions with answer XXXXX.XX.

64. The density of equilibrium mixture of N2O4 (g) and NO2 (g) at 2 atm is 4 gm/lt. at 17oC. Find the
vapour density of equilibrium mixture.

65. A solution of specific gravity 1.6 is 67% by weight. What will be the percentage by weight of the
solution of same acid if it is diluted to specific gravity 1.2?

-1
4B
-3 sec
0
66. For the following parallel chain reaction, what will be the value of
2 x1
overall half-life of A in minutes? K 1=
 Bt 16  A
Given the   K2 =
Ct 9  1.5
 x 1 -3
0
sec -1 3C

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Mathematics ( P ar t – C )
Numerical Answer Type
Question numbers 67 to 69 are 3 numerical answer questions with answer XXXXX.XX.

67. Let ,  be real roots of the equation x 2   k  2  x   k 2  3k  5   0 . Then the maximum value
of  2  2 is
2F  n   1
68. Suppose that F  n  1  for n = 1, 2, 3, … and F(1) = 2. Then, F(101) equals
2

69. If 2p2  3q2  4pq  p  0 and a variable line px  qy  1 always touches a parabola whose axis is
2
parallel to x-axis and the equation of the parabola is  y  4   k  x  2 , then k is

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FIITJEE Admission Test


for students

Class 12 Appeared / Pass


Paper 2
ANSWERS
1. B 2. B 3. D 4. A
5. A 6. ABD 7. AB 8. BCD
9. ABC 10. ABD 11. A 12. C
13. A 14. A 15. D 16. BCD
17. ABCD 18. ABC 19. BCD 20. D
21. D 22. C 23. C 24. A
25. D 26. AC 27. CD 28. BD
29. BC 30. BD 31. 2 32. 7
33. 3 34. 4 35. 2 36. 5
37. 2 38. 6 39. 7 40. 4
41. 8 42. 2 43. 3 44. 2
45. 2 46. 9 47. 5 48. 9
49. 4 50. 3 51. 2 52. 0
53. 0 54. 1 55. 8 56. 2
57. 3 58. 2 59. 8 60. 0
61. 32.34 62. 11.30 63. 1514.00 64. 23.80
65. 29.80 66. 3.30 67. 19.00 68. 52.00
69. 12.00

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