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Electrodynamical modelling of

bidirectional fuel cell systems for


HIL simulations of combined grid systems
Martin Griese, Thomas Pawlik, Thomas Schulte, Jürgen Maas
Ostwestfalen-Lippe University of Applied Sciences
IES – Intelligent Energy Systems
Liebigstraße 87, 32657 Lemgo, Germany

Abstract— For investigating combined grid systems including turnaround in energy policy with an increasing participation of
electrical, thermal and chemical grids, a scientific approach the involved suppliers and consumers.
based on Hardware-in-the-loop simulation is carried out where
models as virtual energy components are coupled with From the technical point of view, efficient mechanisms for
experimental facilities. In this contribution, a bidirectional fuel compensating the fluctuating energies are required. The direct
cell system is described in detail as a virtual energy component storage of electrical energy is limited due to geographical,
considering the bidirectional fuel cell, the power inverter and the topological and geological boundary conditions (e.g. pumped-
local management. For modelling the bidirectional cell, the storage plants) or high invests and saving costs (e.g. battery
electrochemical domain is considered by a physical-based based storage). Therefore, other compensating mechanisms are
approach in a first step. Common models for unidirectional fuel also under investigation and partially already utilized. Beside
cells or electrolysis cells are discussed regarding the applicability dynamic controllable power plants in a small-scale, the
for bidirectional cells. Afterwards, the DC-DC converter as part coupling between various energy grids and the adaption of the
of the overall power inverter is considered for modelling. A novel consumption behavior by smart grids are promising
averaged model for the dual active bridge based on the method approaches, [3].
by Sanders and Verghese is presented. Finally, the overall model
and local management of such systems are discussed. The combined heat and power (CHP) technique is well-
established and used for an efficient utilization of primary
Keywords— Hardware-in-the-loop simulation, modelling of energy carriers (mostly natural gas and biogas). Especially,
energy components, bidirectional fuel cell, power electronics, small and medium-sized CHP plants are suitable for
averaged model compensation effects in electrical grids due to their good
controllability. Since electricity and heat generation of CHP
I. INTRODUCTION facilities are coupled, further mechanisms are required for
providing appropriate thermal and electric energy
The increasing shortage of fossil fuels as well as the
simultaneously. Beside the conversion of electrical energy in
continuing climate change leads to an increasing relevance of
thermal energy (Power-to-Heat), the bidirectional coupling
renewable energy. The current energy system will be
between different forms of energy is possible. The conversion
transformed from a centralized generation by conventional
of electrical energy into chemical energy using Power-to-Gas
power plants to a distributed energy system mainly consisting
technologies is a novel and frequently discussed approach, [4].
of renewable energy generators, [1], [2]. While centralized
Power-to-gas (P2G) units usually comprise electrolysis of
energy systems are approved during the past decades, the
water which decomposes water into hydrogen. Two currently
control and structural expansion of a decentralized energy
discussed cell types for electrolysis and fuel cells are based on
system are rather different due to volatility of the renewable
proton exchange membranes (PEM) and on solid oxide cells
energy and progressive structural changes.
(SOC). PEM cells operate at low temperatures requiring less
Small and medium energy suppliers, like municipal energy thermal energy but offering a lower electrical efficiency. A
supplier, are no longer just operators of local grids, but also higher electrical efficiency can be obtained by using SOC cells
energy producers for electrical and thermal energy. operated at higher temperatures yielding a higher thermal
Furthermore, such small suppliers are already participating in energy demand, [5]. Considering a combined grid system, the
the balancing energy market. Private households and industries overall efficiency, comprising the thermal, chemical and
are also no longer just consumers of energy, but also energy electrical quantities, is relevant and need to be investigated to
producers by photovoltaic systems for example. All mentioned compare both cell types, [6]. Basically, a bidirectional
parties are taking new roles in the fast changing, highly operation of such fuel cells is possible, [7]. In contrast to
competitive and legally regulated energy market. From the battery based storages, such bidirectional cells are promising
economic point of view, it becomes obvious that new energy converters for long-term storages. The produced
marketing and remuneration strategies are required to reach the hydrogen could be stored directly which requires additional
energy for compression due to the low volumetric energy

l-))) 
density of hydrogen. Alternatively, it can be converted to a As an example for the HIL simulation, an experimental
fluid with a higher volumetric density, e.g. methane. In this CHP unit could be used as shown in Fig. 1. The CHP unit is
case the widely established public gas grid can be used for controlled by a simulated energy management system based on
storage which provides a very high capacitance. the demands of simulated virtual consumers. While the
generated thermal and electrical energy is physically fed to the
An additional option for compensation of fluctuations is a grid, the measured values of electrical and thermal energy as
systematic control and adaption of the energy consumption by well as the gas consumption of the CHP unit are used in the
private households and industry. On the one hand the total real-time simulation for balancing the power flows and
energy demand is optimized by energetic optimizations of supplying the virtual consumers.
technical devices while on the other hand the energy peaks are
reduced by using controllable loads and buffers which can be In order to describe the virtual components, models are
disconnected or controlled depending on the available energy, required for the proposed HIL simulation. For modelling of
[3]. Therefore, the demand-oriented energy supply system is these energy components different approaches are possible. On
developing towards a smart and coupled energy grid with a the one hand models based on energy flows result in a simple
strong orientation on the current energy supply. parameterization and fast simulation. On the other hand,
models based on state variables (e.g. voltage and current) are
For investigating and optimizing such smart combined grid
required for a more detailed simulation of both the stationary
systems, a scientific approach based on Hardware-in-the-Loop and transient behaviour. While high eigenvalues need to be
(HIL) simulations is carried out as presented in [8] and avoided in real-time simulations, they have to be considered
summarized in section 2. This approach comprises models for more detailed investigations. For a general applicability
describing the investigated energy components in combination regarding offline and HIL simulations as well as different
with real energy components. As a virtual component, section simulation objectives like optimization of the structure or
3 comprises the modelling of bidirectional fuel cell systems optimization of the strategy, it becomes obvious that the
which includes the fuel cell and the power inverter. Finally, a component models should be scalable with respect to the
conclusion is given in section 4. modelling depth. Furthermore, the component models need to
be real-time capable for the HIL simulation. Methods for
II. SCIENTIFIC APPROACH scaling a CHP model which are partly adaptable to other
The scientific approach presented herein after and models were discussed and evaluated in [10].
schematically illustrated in Fig. 1 is a variant of the HIL Based on the proposed simulation method, a realistic study
simulation. By this approach, various simulated and real of smart energy systems is possible. On the one hand, novel
components are combined to a virtual coupled power grid. By a structural concepts can be evaluated, for example a
virtual coupled power grid, all components are considered to combination of the mentioned P2G technique with the CHP
be coupled via information exchange for balancing their power technique in addition or in comparison to the usage of biogas
quantities while the real power flow is connected to locally plants. On the other hand an optimization of existing structures
available grid structures. In contrast to other approaches [9], by dimensioning the energy components is also possible. First
also spatial distributed and high power facilities can be of all, we start with the offline simulation of different concepts.
included without the necessity of electronic loads. However, by Afterwards potential concepts will be selected and further
electronic loads, detailed effects of electrical grids on the real optimized and evaluated by means of the proposed HIL
components (e.g. change in voltage) are represented which simulation. While a validation of the developed models is
allows more detailed investigations in comparison to the given by the integration of real components, the overall
presented approach here. Beside electrical, thermal and research approach can be proven by applying it to an
chemical components are considered in this approach, as well. optimization study for a new or existing energy system. As a
first project, the proposed approach is applied to an existing
Simulated components Real components energy system near by the university. This so called energy
Control quantities
village is also representing a “LivingLab”. As mentioned
Simulated before, real-time data from generators and consumers of the
Real facility
environment Measured quantities “LivingLab” will be used in combination to the HIL
(Hardware)
(Model) simulation.

Example: CHP unit in the Loop III. MODELLING OF BIDIRECTIONAL FUEL CELL SYSTEMS
* gas Heat grid
PCHP The structure of the considered bidirectional fuel cell
Energy management system for modelling is shown in Fig. 2 incorporating the
Operating data QCHP hydrogen fuel cell with the required auxiliary units (e.g. fluid
* Generator preparation and heat exchangers) as well as the feeding power
Virtual consumer PCHP Engine
electronic. For investigating such systems in a grid connected
mode, all domains need to be considered. The electrochemical
PCHP domain is required to especially model the losses of the fuel
cell as well as of the power electronics while the
Fig. 1. Structure for a HIL simulation for optimizing a smart thermodynamic and fluid dynamic domains need to be
combined grid system. considered for modeling the dynamic behavior of the system.


In this contribution, section III.A describes the modeling amount of energy. These losses are often named as activation
approach of the fuel cell while the model of the power inverter losses and are dominant for low current densities j . Generally,
is presented in section III.B. Finally, the local management is this effect is modeled by the Butler-Volmer equation. Only for
discussed in section III.C. symmetrical conditions where the charge transfer coefficients
Bidirectional fuel cell
of the anodic and cathodic process are equal, an analytic

Local management
solution for the Butler-Volmer equation can be derived with
Thermo- and fluid respect to the describing resistance Ract :
dynamics Auxiliary units

Electrochemical Power inverter 2 ˜ R ˜T § j · 1


 Ract ˜ arcsinh ¨ ¸˜ ,   
dynamics DC-DC inverter A˜ z ˜ F © 2 ˜ j0 ¹ j
Part of the contribution
Grid inverter where j0 is the exchange current density and A is the
active cell area. The model by Eq. 2 can be used for first
Grid simulations and investigations while for detailed investigations
the charge transfer coefficients should be identified
Fig. 2. Overview of the bidirectional fuel cell system. experimentally, [12]. In this case, a numerical solution of the
Butler-Volmer equation could be implemented.
A. Electrodynamical model of bidirectional fuel cells A further kinetic inhibition is obtained by diffusion effects
For modelling the physical behavior of fuel cells, several which occur due to the mass transport of the reactants. In
domains need to be considered as shown in Fig. 2. In this steady-state operation, the mass transport through the porous
contribution, the electrochemical domain is taken into account gas diffusion layers is limited which mainly occurs at high
and a physical-based model is derived. By the proposed model, current densities. A simple and commonly used model for fuel
investigations of fuel cell systems coupled with further energy cells is obtained by combining Fick’s Law with the Nernst
generators and consumers shall be carried out. One possible equation which cannot be simply adapted for the electrolysis
scenario could be the utilization of such a fuel cell system for mode. Considering the hydrogen electrode for example, the
private households where the fuel cell system itself and further diffusion effect changes with the molar fraction of the reactant
storages are optimized with respect to the dimensioning and gases (e.g. water vapour for SOC electrolyzes and hydrogen for
energy management. Therefore, the model needs to describe SOC fuel cells). Such effects are further investigated in [13],
the energy and material balances regarding the electrical and where an extended physical-based model for describing the
thermal behavior while a detailed modelling of chemical stationary diffusion effects of bidirectional cells is proposed
reactions can be avoided. Afterwards, a common model for and validated by experimental measurement results.
unidirectional fuel cells [11] is discussed and extended for From a dynamical point of view, the double layer effect
modelling bidirectional fuel cells. which occurs at the phase boundary between electrode and
Considering the stationary behavior, the open-circuit electrolyte as well as the mass transport through the porous
voltage vOCV and the occurring losses need to be modeled. electrode need to be considered. The double layer effect can be
simplified modeled by a capacitance CDL which values are up
Independent of electrolysis or fuel cell mode, the open-circuit
voltage vOCV describes the lossless voltage which can be to several Farads for each cell due to the comparably high
surface of the porous electrodes but in combination with the
modeled by the Nernst equation as follows comparably low resistances, a moderate time constant is
obtained, [14]. Especially, for large-signal analyses where the
R ˜T § p ˜ pO 2 · maximal current of the power inverter is reached, this effect
 vOCV 0
Vrev  ˜ ln ¨ H 2 ¸,    cannot be neglected.
z˜F ¨ pH 2 O ¸
© ¹
The mass transport has dominant influence on the dynamic
behavior of such cells and should therefore be modeled more
which depends on the temperature T of the cell and the partial accurately. Due to the fact that the gas diffusion layer of the
pressures of the oxygen pO 2 , hydrogen pH 2 and water pH 2O . fuel cell has a finite thickness, this effect can be modeled as an
0
Constant parameters are Vrev as the reversible cell potential at impedance of finite diffusion with absorbing boundary
standard temperature and pressure conditions, R as the conditions, called bounded Warburg impedance, [15], and
universal gas constant, F as the Faraday constant and z as the described by
number of electrons involved in the reaction.
Rdiff D § iZ ·
The model is extended by the losses which are on the one  Z BW i Z ˜ ˜ tanh ¨¨ ldiff ˜ ¸¸ ,  
hand caused by a finite electrical conductivity of the materials ldiff iZ © D ¹
yielding ohmic losses and on the other hand by kinetic
inhibitions as described afterwards. In order to start the where Rdiff is the diffusion resistance according to mentioned
reaction, the charge carriers need to cross the phase boundary
between electrode and electrolyte which requires a specific modelling approach in [13], ldiff is the diffusion layer


thickness and D is the diffusion coefficient of the diffusing for example applied in [18]. In order to include the losses of
species. For transient simulations, such fractional order system the semiconductors as well as of the transformer and the coil, a
cannot be directly discretized by typical simulation tools. more detailed model is required which also considers the
Hence, approximations are required for implementing such semiconductor related current iL and voltages vT 1 and vT 2 (see
diffusion models. Any kind of diffusion model that comprises Fig. 4). In [19], these quantities are approximated by harmonic
equations similar to (3) can be implemented as a so-called oscillations utilizing a quasi-stationary approach. Especially for
transmission line model, combined by several RC-circuits, transient changes, deviations between the model and numerical
[16]. circuit simulations can be observed. Here, a full-dynamical
Beside the modeled effects that occur at the electrodes or model is proposed by utilizing the method by Sanders and
their boundaries, the electrolyte is typically modeled by an Verghese, [20].
ohmic resistance Rohm . Due to the comparably high distance In a first step, the power semiconductors are assumed to be
between the electrodes, the resulting capacitance of the ideal switch devices without losses. Further, the transformer is
electrolyte is usually neglected. In the proposed model, the assumed to be ideal regarding the main inductance, so that the
resistance Rohm further considers the ohmic losses due to the modeled leakage inductances can be summed up with the
finite electrical conductivity of the electrode material and the inductance Ld of the coil. As usual for modelling transformers,
electrical contacts. the quantities of the secondary side are referred to the primary
side considering the turns ratio w . Equally, the ohmic losses
Finally, partial models for each of the electrodes as well as
of the coil and the transformer are summed up and modeled by
for the electrolyte are proposed. Typical unidirectional models
of fuel cells or electrolysis cells consider separate models for a resistance RV as shown in Fig. 4b).
the anode and cathode. By a bidirectional operation, the a)
physical electrodes change their function respectively from iDC icell
anode to cathode during the transition between fuel cell and
electrolysis mode. Instead, the partial models of the electrodes S1 D1 S3 D3 1: w S5 D5 S7 D7
iL Ld
are named and parameterized by their reaction products and
vDC vT 1 vT 2 vcell
their reactants (e.g. hydrogen and oxygen electrodes),
respectively. An overview of the model is given in Fig. 3.
S2 D2 S4 D4 S6 D6 S8 D8

vcell
icell b)
iL LV RV
vDC N1 x, t vT 1 vTc 2 N 2 x, t c
vcell
CDL ,1 CDL ,2
Rohm
vOCV W W
Ract ,1 Ract ,2 Fig. 4. Topology of the DAB (a) and simplified equivalent circuit considered
Z BW ,1 Z BW ,2 for modelling (b).
Hydrogen electrode Oxygen electrode
By the phase-shift control, the output current icell of the
Fig. 3. Electrodynamical model of bidirectional fuel cells. fuel cell can be simply controlled by adapting the phase shift
M between the primary and secondary bridge. The functions
B. Bidirectional inverter N1 and N 2 in Fig. 4b) describe the nonlinear behavior of the
One possible concept for supplying bidirectional fuel cells primary and secondary bridges with pulse patterns shown in
is the dual active bridge (DAB) with the common phase-shift Fig. 5 where ZS is the switching frequency of the power
control as modulation scheme, [17]. The topology of this semiconductors in radians.
inverter is shown in Fig. 4a) where the output of the DAB is
a) N x, t b) N 2 x, t
considered to be connected with the fuel cell while the DC link 1

voltage vDC is maintained by an additional grid-connected x x


M
inverter.
t ZS t
For the discussed investigations, the model shall comprise S 2S S 2S
the occurring losses and the transient electrical behavior for an ZS ZS x ZS ZS
x
accurate energy balancing and dynamic investigations. Further,
a real-time capable approach for the discussed HIL simulation
is required. Common models which fulfill these conditions are Fig. 5. Pulse patterns of the primary bridge (a) and the secondary bridge (b).
based on state-space averaging where only the mean values of
all quantities are modeled. Due to the zero-mean inductor The nonlinearities N1 and N 2 in Fig. 5 as well as the
current iL of the DAB, such approaches are only partly current iL as the state variable of the system are approximated
suitable for this application. Instead of the current iL , the by harmonic oscillations. Based on the simplified equivalent
circuit in Fig. 4b), the equation of state is derived and
power flow without losses could be considered for modeling as


harmonically approximated. By utilizing the first occurring
Local M Bidirectional fuel cell system
harmonic oscillation for approximating the nonlinearities N1
management
and N 2 as well as the current iL , the following differential
equations are derived,
vcell icell
Dual Active Bidirectional vcell
diL , S 1 §4 4 · vDC iDC
c ˜ cos M  RV ˜ iL , S ¸  iL ,C ˜ ZS ,
˜ ¨ ˜ vDC  ˜ vcell Bridge fuel cell
dt LV © S S ¹
  
diL ,C 1 §4 · iDC vDC
c ˜ sin M  RV ˜ iL ,C ¸  iL , S ˜ ZS ,
˜ ¨ ˜ vcell
dt LV ©S ¹ v grid v grid Grid inverter i grid i grid

where iL , S and iL ,C are the slow changing fourier


Fig. 6. Overall electrical model of the bidirectional fuel cell system.
coefficients of the fundamental oscillation of the current iL . In
order to complete the model, the outputs iDC and icell need to The proposed model of a bidirectional fuel cell is
be calculated. For both quantities, the resulting mean values are parameterized and coupled to the model of the DAB. Fig. 7b
considered only which yields shows the cell voltage vcell of the bidirectional fuel cell system
(fuel cell mode) for a step of the DAB output current icell , Fig.
2 7a. The impact of the double layer capacitance CDL is shown in
iDC | ˜ iL , S ,

S    Fig. 7c. It has a significant impact on transient system behavior
2 within the first time period of the step response. When a longer
c |
icell ˜ iL , S ˜ cos M  iL ,C ˜ sin M . timeline is investigated, the Warburg impedance has a
S
significant impact, as well (Fig. 7d). It shows the typical
The averaged model is finally described by Eqs. 4 and 5 creeping voltage that depends on the porous material of the gas
c and M as well as the output
with the input variables vDC , vcell diffusion layer. Similar effects can be observed for Li-Ion cells,
where porous diffusion effect also occurs, [16], [22].
c . The order of the model depends on the
variables iDC and icell
chosen approximation quality and is calculated by O 2 ˜ N H
where N H is the number of harmonic oscillations considered 30
a)
for the harmonic approximations. The proposed model is 25
in A

discretized by the backward Euler method which guarantees a


cell

20
numerical stable simulation, [21].
i

15
C. Overall electrical model and local management 2000 2200 2400 2600 2800 3000

The overall electrical model is shown in Fig. 8 which 26


considers the electrochemical domain of the fuel cell that based b)
on a proton exchange membrane (PEM), the power inverter 24
in V

and the local management for the electrical quantities (cf. c) d)


cell

22
Fig. 2). The modeled grid inverter contains an averaged model
v

of the inverter as well as a DC link capacitor and an LCL grid 20


filter. The grid voltage v grid and current i grid are described in 2000 2200 2400 2600 2800 3000
Time in s
the synchronous dq frame, similar to [8]. The modelling and 26 21
c) d)
control of such inverters are investigated in various 24
20.9
in V

in V

publications (e.g. [22]). 20.8


cell

cell

22
The electrical power of the fuel cell cannot be varied
v

20.7
independent from the fluid- and thermodynamic boundary 20 20.6
conditions. Otherwise, an over- or undersupply of the fuel cell 1980 2000 2020 2000 3000 4000 5000
Time in s Time in s
is given during transient changes due to comparabely low
dynamics of the reactant gas, [23]. This effect yields a shorter
lifetime of the cell, [24]. Currently the local management is Fig.7 Step response of the bidirectional fuel cell system (b) at different
extended with respect to the fluid- and thermodynamic DAB output currents icell (a). Physical effect of the double layer
domains. For model validation and investigations of the capacitance (c) and the bounded Warburg impedance (d).
dynamic behavior as well as control concepts, an experimental
Power-to-X process system is planned which concept and
possible investigations are further described in [6].


IV. CONCLUSION [11] J. Larminie, A. Dicks and M. S. McDonald, “Fuel cell systems
explained,” Vol. 2, New York: Wiley, 2003.
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was modelled with respect to the electrical domain for electrochemistry: An assessment (IUPAC Technical Report),” Pure and
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thermal and chemical grids. The overall model comprises a [13] N. Meng, M. K. Leung and D. Y. Leung. “A modeling study on
bidirectional fuel cell where activation, diffusion and ohmic concentration overpotentials of a reversible solid oxide fuel cell,”
losses are considered. Typical approaches for unidirectional Journal of Power Sources, 163 (1), pp.460-466, 2006.
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distributed generation applications,” Vol. 41, John Wiley & Sons, 2009.
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diffusion effects were discussed and appropriate models were impedance spectroscopy in PEM fuel cells: fundamentals and
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[18] A. R. Alonso, J. Sebastian, D. G. Lamar, M. M. Hernando and A.
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ACKNOWLEDGMENT 2013.
This contribution is accomplished within the research [20] S. R. Sanders, J. M. Noworolski, X. Z. Liu and G. C. Verghese,
priority on “Intelligent energy systems (IES)”, funded by the “Generalized averaging method for power conversion circuits,” IEEE
Transactions on Power Electronics, 6 (2), pp. 251-259, 1991.
Ministry for Innovation, Science and Research of the state of
[21] T. D. Bui, “Some A-stable and L-stable methods for the numerical
North-Rhine Westphalia (NRW) of Germany. integration of stiff ordinary differential equations,” Journal of the ACM
(JACM), 26 (3), pp. 483-493, 1979.
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