InnoPlus Product

OVERVIEW

1
Introduction
• Polyethylene introduction

• LLDPE
• Classification
• InnoPlus LLDPE
• LLDPE Fabrication Processes
• Application

• LDPE introduction
• InnoPlus LDPE

• InnoPlus HDPE
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How to produce Polyethylene
Animal, Plant
Accumulation

Crude oil Natural gas

Distillation Separation

Naphtha Ethane
Cracking

Ethylene
Polymerization

Polyethylene
3
Polyethylene Type
ชนิดพอลิเอทิลีน LLDPE MDPE HDPE LDPE
วิธีการสังเคราะห์ กระบวนการ
กระบวนการแบบความดันปานกลางหรือต่า แบบความดันสูง
(Polymerization)
โครงสร้างโมเลกุล

ความหนาแน่น (g/cm3) 0.915-0.930 0.930-0.940 0.940-0.970 0.915-0.930

อุณหภูมิการขึ้นรูป °C 170-190 170-190 180-210 150-170

ความโปร่งใส โปร่งแสง ทึบแสงจนถึง ทึบแสง โปร่งแสง

(การยอมให้แสงผ่าน) โปร่งแสง
- ฟิ ล์ ม ส่ า หรั บ บรรจุ - ถังขนาดใหญ่ - ถุงชอปปิ้ง - ฟิ ล์ ม ส่ า ห รั บ บ ร ร จุ
การใช้งาน อาหาร - ท่อน้่า - ถุงขยะ อาหาร
- ฟิ ล์ ม ส่ า หรั บ หี บ ห่ อ - ฉนวนหุ้ม - ถัง ตะกร้า ลัง - ฟิ ล์ ม ส่ า หรั บ หี บ ห่ อ
อย่างหนา - ฯลฯ - ขวดใส่น้่ามันเครือง อย่างหนา
- ฟิ ล์ ม ส่ า ห รั บ ง า น - ขวดแชมพู - ฉนวนหุ้มสายไฟ
เกษตรกรรม - ขวดน้่าดืม ขวดนม - ฝาจุกขวด
- ฝาปิดกระป๋อง - เชือก แห อวน - โฟม
- ฯลฯ - ฉนวนหุ้มสายไฟ - ฯลฯ
- ฯลฯ 4
InnoPlus LLDPE
OVERVIEW
LLDPE Classification
Tensile
1. Catalyst types : strength
5
Ziegler-Natta Metallocene 4
3
1% Secant 2 Elongation
Modulus 1
0

Tear Dart drop

resistance impact
2. Co-monomer : C-4 LLDPE C-6 LLDPE C-6 matallocene

- C4 - Butene
- C6 - Hexene Co-monomer
- C8 - Octene

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 Down Guaging Ability
* * * * *
LLDPE Co-monomer
Lower Price
* * * * *
Multi-Attribute Analysis for LLDPE
Market Segment : Comonomer
LLDPE - Butene 1 C4
1 2 3 4 5
LLDPE - Hexene 1 C6
Less Desirable More Desirable
LLDPE - Octene 1 C8

Impact Strength
* * * * *
Tensile Strength
* * * * *
Organolaptic
* * * * *
Clarity
* * * * *
Down Guaging Ability
* * * * *
Lower Price
* * * * *
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PTT LLDPE process and Advantage
Gas phase technology is popularly used for producing
LLDPE. The process is capable to produce broader melt
index and density than others. Therefore, it can adjust to
follow market needs.

World LLDPE technology

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LLDPE APPLICATIONS
Mostly LLDPE are produced for film applications such as
general film and food packaging.

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InnoPlus LLDPE Products
Applications Grades Density MFR

Film LL7410A 0.918 1

LL7410D 0.918 1 ** High AB/S
LL7410D1 0.918 1 ** Low AB/S
LL7420A 0.918 2
LL7420D 0.918 2 ** High AB/S
LL7420D1 0.918 2 ** Low AB/S
LL7610A 0.918 1

LLDPE LL7632A 0.917 3.2

LL7910A 0.920 1 ** m-LLDPE

LL7907A 0.927 0.7 ** m-LLDPE

LL8420A 0.924 20
Injection Molding
LL8435A 0.926 35
LL8450A 0.926 50

Rotomolding LL9650U 0.934 5

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 LLDPE Nomenclature
Grade Name InnoPlus LLDPE
Catalyst types : Co-monomer :
XXXXXXX Additive Package :
- Ziegler-Natta - C4 – Butene
- Metallocene - C6 - Hexene
A = None Slip & Antiblock
D = With high Slip & Antiblock
InnoPlus LLDPE
D1 = With Low Slip & Antiblock
U = UV Stabilizer C4 comonomer
- LL7410A - LL8420A
Melt Index :
- LL7410D/D1 - LL8435A
MI for Injection
- LL7420A - LL8450A
MI x 10 for film & Roto
- LL7420D/D1
Comonomer & Catalyst :
4 = C4-ZN, 6 = C6-ZN, 9 = C6-Metallocene
C6 comonomer
- LL7610A - LL7632A
Application : - LL9650U
7 = Film, 8 = Injection, 9 = Rotational Molding C6 comonomer/ metallocene
Polymer Type : LL = LLDPE - LL7910A - LL7907A
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Metalloce InnoPlus LLDPE
InnoPlus LL7910A
High Strength Film,
Multi-layer packaging film,
Lamination film,
Rice bag
Tensile
strength
5
4
3
C-8 LLDPE/LDPE
COF 2 Elongation (75:25)
1
0 Alternative
C-6 matallocene
InnoPlus
C-6 matallocene
Dart drop
Clarity impact 12
LLDPE Fabrication Process
1. Blown film extrusion - เป่าผ่านลม

2. Water quench - เป่าผ่านน้า

3. Cast film - การหล่อฟิล์ม

4. Lamination - การผลิตฟิล์มเชิงซ้อน

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LLDPE Fabrication Process
Blown Film Extrusion
Blown Film : Air quench Blown Film : Water quench

Item Air quench Water quench

Antiblock/Slip content Low High

Clarity Low High
LLDPE with D1 Series e.g. LLDPE with D Series e.g.
Recommend grade InnoPlus LL7410D1 InnoPlus LL7410D
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LLDPE Fabrication Process
Cast Film Extrusion

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LLDPE Fabrication Process
Lamination

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LLDPE APPLICATIONS
Our LLDPE products can be applied in several
applications: Food Packaging
All of InnoPlus film grades
Film • General purpose film,
• Frozen food packaging,
Injection • Ice bag, Dairy packaging

Others
Non-Food Packaging
All of InnoPlus film grades
Stretch Wrap Film Liners, Agricultural film, Garbage bag,
Garment bag and Grocery bag
InnoPlus
LL7420A and LL7910A Industrial bag, Heavy duty bag,
Stretch Wrap Film Multi-layer packaging film,
Cling Film Lamination film, Pouch packaging
LLDPE APPLICATIONS
Our LLDPE products can be applied in several
applications:
Film
Injection Injectin & Masterbatch
InnoPlus LL8420A
Others General purpose injection molding,
Lids, Housewares, Trash bins
and Masterbatch
LLDPE APPLICATIONS
Our LLDPE products can be applied in several
applications:
Film
Injection
Others All of InnoPlus film grades can
blend with HDPE and LDPE

Wire & Cable

 Flexible Tube
 Cosmetic Tube
 Monofilament
InnoPlus LDPE
OVERVIEW

20
LDPE Process and Technology
• High Pressure Reactor

Pressure 3,000 bar Pressure < 2,500 bar

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LDPE Process and Technology
Tubular vs Autoclave
Tubular Autoclave
 Conversion up to 35-40%  Conversion up to 20%
 Low cash cost  High cash cost
 Narrower MWD  Broader MWD
 Density 0.918-0.930 g/cm3  Density 0.914-0.925 g/cm3
Suitable for high clarity film and  Suitable for extrusion coating
general purpose film

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InnoPlus LDPE Nomenclature
InnoPlus LD2426K Melt Flow Rate :
D = 0.2-0.35
F = 0.6-0.9
H = 1.7-2.2
K = 3.4-4.6
M = 6.0-8.0
T = 33-39

Additive Package :
0 = None Slip & Antiblock
6 = With Slip & Antiblock

Internal code

Density

Polymer Type : LD = LDPE

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Heavy Duty Application
MFR 0.3 – 0.8 g/10 min

InnoPlus LD2420D
MFR 0.3 g/10 min
No Slip, No Antiblock

 Application :
 Heavy duty film
 Liner bag
 Agricultural film
 Shrink film
 Drain irrigation pipe
 Cosmetic tube 24
General Purpose Application
MFR 2 – 5 g/10 min
InnoPlus LD2426H InnoPlus LD2426K
MFR 1.9 g/10 min MFR 4 g/10 min
Slip, Antiblock Slip, Antiblock
 Application :
 General purpose film
 Shrink film
 Lamination film

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Coating Application
MFR 7 – 9 g/10 min
 Application :
InnoPlus LD2420M  Can be coated on a
MFR 7 g/10 min variety of substrates
including paper, foil,
No Slip, No Antiblock woven sack and other
base stocks.

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Injection Application
MFR 30 – 50 g/10 min

InnoPlus LD2420T
MFR 36 g/10 min
No Slip, No Antiblock

 Application :
 Toys
 Artificial flower
 Cap and Closure
 Masterbatch
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InnoPlus HDPE
OVERVIEW

28
HDPE Grade Introduction

MFR Density
Grade Feature Application
(g/10 min) (g/cm3)

High productivity, Milk bottles,

HD4200B 0.6 0.965
good appearance Personal care containers

Drinking water bottles,

HD5200B 0.45 0.966 Excellent stiffness juice bottle
HD6200B 0.45 0.962
High ESCR, good Detergent & chemical
impact strength containers, Lubricant oil
HD6600B 0.4 0.957 containers

NEW
Optimum balance of Lubricant containers,
HD6800B 0.17 0.966 stiffness and impact Personal care containers,
strength Food packaging

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HDPE Grade Introduction

MFR Density
Grade Feature Application
(g/10 min) (g/cm3)

HD7200B 0.04 0.956 Big drum size 20-120 L

Excellent ESCR
and impact strength
HD8200B 0.03 0.955 Big drum size 20-200 L

Thin film, bags on roll,

HD6000F 0.16 0.956 Good processability plastic glove,
general purpose bags

General purpose bags,

HD7000F 0.04 0.956 Excellent mechanical
garbage bags
strength

HD8000F 0.03 0.95 Excellent impact Industrial films, liner films

strength

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HDPE Grade Introduction

MFR Density
Grade Feature Application
(g/10 min) (g/cm3)

Toy, Auto part,

HD1100J 18 0.958 Cap and closure
Master batch
HD1200J 28 0.96 High flow injection carrier
Toy, Auto part,
HD1600J 12 0.958 Cap and closure

Industrial product,
HD2208J 4 0.961 High impact strength with Crate, garbage bin,
UV resistance injection Pallet
Industrial products,
HD2209J 3.7 0.954 Ultra high UV resistance Garbage bin

Industrial product,
HD2308J 6 0.962 High impact strength with garbage bin
UV resistance injection

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HDPE Grade Introduction

MFR Density
Grade Feature Application
(g/10 min) (g/cm3)

Organoleptic Properties Caps and Closures for

HD1600JP 12 0.958 High purity -mineral and stilled water
Good processability -sparkling water
HD2200JP 3.7 0.961 -carbonated water

Outstanding mechanical
strength
- Low shrinkage Truck bed-Liner
HD7000H 0.1 0.952 - High weathering resistance Fuel tank
- Excellent product
appearance

Excellent tenacity,good
HD5000S 0.8 0.954 Rope, fishing net, tarpaulin,
processability, high
woven sack
production rate.

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HDPE Grade Introduction

MFR Density
Grade Feature Application
(g/10 min) (g/cm3)

HD6366M 0.06 0.952

HD6366MB 0.06 0.961

Excellent creep resistance, Drinking water pipes,
excellent chemical resistance industrial pipes, sewer pipes
HD8100M 0.04 0.952

HD8100MB 0.03 0.962

Excellent weathering
Resistance
HD6376EB 0.05 0.962
Fiber optic jacket
Excellent weathering
resistance and tracking
HD6396EB 0.05 0.962
resistance

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Step Beyond Together
with InnoPlus

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