United States Patent (19) 11 Patent Number: 4,459,285
Grollier et al. 45 Date of Patent: Jul. 10, 1984
54 COSMETIC COMPOSITION FOR THE 149,262 3/1874 Steelman ............................. 424/364 TREATMENT OF THE HAR AND SKN 375,860 1/1990 Worthington. ... 424/74 COMPRISINGAPOWDER OF FLOWERS OR 378,504 2/1988 Greene ... FLOWER TOPS AND A COHES ON AGENT 412,769 10/1989 Lyons ......... 3,842,847 10/1974 Hewitt et al. .. ... 424/70 75 Inventors: Jean F. Grollier, Paris; Josiane Alec, 3,903,257 9/1975 Arai et al........... ... 424/70 Pierrefitte; Chantal Fourcadier, Paris; 4,358,286 1 1/1982 Grollier et al. ............. vesss seas 424/74 Georges Rosenbaum, Asnieres; FOREIGN PATENT DOCUMENTS Patrick Darmenton, Villejuif, all of France 1492134 1/1970 Fed. Rep. of Germany ........ 424/74 73) Assignee: Societe Anonymedite: L'Oreal, Paris, OTHER PUBLICATIONS France Steinmetz, Codex Vegetabilis, "Roselle' Abst. 560 21 Appl. No.: 352,105 (1957). (22 Filed: Feb. 25, 1982 Primary Examiner-Jerome D. Goldberg 30 Foreign Application Priority Data Assistant Examiner-Freda Abramson Attorney, Agent, or Firm-Cushman, Darby & Cushman Feb. 27, 1981 (LU Luxembourg ........................... 83173 57 ABSTRACT 51) Int. Cl. ....................... A61K 7/06; A61K 47/00; A61K 31/00; A61K 47/00 A cosmetic composition for the treatment of the hair 52 U.S.C. ...................................... 424/74; 424/361; and skin comprising, in an aqueous medium, particles of 424/363; 424/364; 424/DIG. 2; 424/168; pulverized flowers or flower tops having a granulome 424/170 try lower than 125 microns and a cohesion agent pres 58 Field of Search ................. 424/74, 361, 363, 364; ent in an amount effective to maintain the homogeneity 8/160, 161 of the composition. The cohesion agent can be a thick 56) References Cited ening agent, a water-in-oil emulsion or an oil-in-water emulsion. U.S. PATENT DOCUMENTS 100,934 3/1870 Scruton ............................... 424/364 8 Claims, No Drawings 4,459,285 1 2 many varieties of plants, shrubs or trees and principally COSMETC COMPOSTON FOR THE from the following: TREATMENT OF THE HAIR AND SKIN COMPRISING A POWDER OF FLOWERS OR 5 Wormwood (Artemisia Absinthium) FLOWER TOPS AND A COHESION AGENT Acacia (Robinia pseudoacacia) Yarrow (Achillea Millefolium) The present invention relates to a cosmetic composi Agrimony (Agrimonia Eupatoria) tion for the treatment of the hair and skin, this composi Amaryllis (Amaryllis) Colombine (Aquilegia vulgaris) tion containing, in the presence of a cohesion agent, a Anemone (Anemone spp) powder resulting from the pulverization of at least one 10 Mugwort (Artemisia vulgaris) flower or of flower top. Arnica Sweet Woodruff (Arnica montana) (Asperula odorata) For years both the pharmaceutical industry and the Hawthorn (Crataegus oxyacantha) cosmetic industry have used in numerous formulations Azalea (Axalea spp) active substances resulting from the extraction of vege Balsamine 15 Begonia (Impatiens spp) tables by different processes such as maceration, diges Bougainvillea (Begonia spp) (Bougainvillea spp) tion, decoction, infusion or lixiviation. Waterelder (Viburnum opulus) In certain cases, and principally in cosmetics, the Cornflower (Centaurea Cyanus) vegetables are employed in the form of entire plants Mullein (Verbascum spp) applied to the skin, or in coarsely pulverized forms so as 20 Common heather Barbary fig (Calluna vulgaris) (Opuntia vulgaris) to provide cataplasms when diluted with water. Camellia (Camelia japonica) Representative cataplasms include, in particular, Channonile (Anthemis nobilis) those obtained from emollient flour or from henna pow Campanula (Campanula spp) (Tropeolum majus) der and were used for the coloration of the hair or the Large Indian Cress Saflower (Carthamus tinctorius) skin. (Catalpa bignonioides) These cataplasms exhibit numerous disadvantages 25 Star thistle (Centaurea calcitrapa) caused essentially by coarse grinding of the plants Rough Cherry (Prunus cerasus) which most often resulted in lumpy cataplasms which Honeysuckle (Lonicera spp) Daisy r (Chrysanthemum leucoanthemum) were difficult to apply to the skin and hair and which Travelle's Joy (Clematis vitalba) were not easily removed, especially from the hair. Quince (Cydonia vulgaris) Moreover these known products were difficult to 30 Red poppy Colchicum or Meadow (Papaver Rhoeas) (Colchicum automnale) preserve which prevented them from being made in a saffron ready-to-use form. - . . Cornel tree (Cornus spp) It has now been found that it is possible to signifi (or dogwood) Crocus cantly reduce or eliminate the disadvantages mentioned 35 Cyclamen (Crocus spp) (Cyclamen spp) above by using finely pulverized flowers or flower tops Dahlia (Dahlia variabilis) having a determined granulometry in the presence of a Field larkspur (Delphinium consolida) cohesion agent. . .. Dulcamara (Solanum Dulcamara) (Leontopodium Alpinum) The present invention thus relates to a cosmetic con Dog rose (Rosa canina) position for the treatment of the hair and skin contain Fumitory (Fumaria officinalis) ing, in an aqueous medium, particles resulting from the Broom (Cytisus scoparius) (Gentiana spp) pulverization of at least one flower or flower top, hav Gentian Geranium (Geranium spp) ing a granulometry less than 125 microns and, prefera Wallflower (Cheirantus cheiri) bly, less than 80 microns, in the presence of a cohesion Sword-lily (Gladialus spp) agent which maintains homogeneity of the composition Marsh Mallow (Althaea officinalis) the said agent being a thickening substance and/or a 45 Roselle. ..., (Gypsophila spp) . . (Hibiscus spp) -. water-in-oil or oil-in-water type emulsion. Hydrangea (Hydrangea spp) The particularly fine granulometry is obtained by Hops (Humulus lupulus) . known pulverization processes, such as by crushing or Live everbalsan (Helicrysum arenarium) (Impatiens spp) micronization, optionally followed by a sieving opera 50 Garden Orrice . . . (Iris spp) tion, this degree of granulometry being critical to the Hyacinthe, (Hyacynthus spp) production of compositions exhibiting all the requisite Jasmine (Jasminum spp) characteristics. - - - - Jonquil (Narcissus jonquilla) The crushing can be carried out dry on the flowers or Oleander (Nerium oleander) Lavender (Layandula officinalis) flower tops, previously dried, or can be effected di 55 (Lavatera spp) rectly on fresh flowers in an appropriate medium. Lilac (Syringa vulgaris) By the expression "cohesion agent' is meant an agent White lily Bindweed (Lilium candidum) (Conedvulus spp) ( capable: Lupin is (Lupinus albus) of avoiding decantation of the finely pulverized parti Magnolia ... (Magnolia spp) cles of the flowers or flower tops, in solution, Daisy (Chrysanthemum leucanthemum) (Aescilus Hippocastanum) of facilitating the spreading of the composition on the Horsechestnut skin or the hair, Wild chamomile . . (Matricaria chamomilla) Mallows. . . . . (Malva spp) : . . is . . . . of avoiding the drying out of the composition when it Melilot (Melilotus officinalis) . s is exposed to free air, and . Mint (Mentha spp) (Hypericium perforatum) of facilitating the removal of the composition from 65 St John's Wort the hair or skin, Minosa . . . . . (Mimos spp) : Lion's mouth (Antirrhinum majus) The particles of flowers or flower tops used in the Mugget (éenvallaria maialis) composition according to the invention can come from Myosotis (Myesotis spp) 4,459,285 3 4. -continued common comfrey (Symphytum officinale), asparagus, Daffodil (Narcissus spp) senna and lichen; White water Lily (Nymphaea alba) (ii) cellulose derivatives such as methylcellulose, hy Gillower (Dianthus caryophylus) droxymethyl cellulose, hydroxyethyl cellulose, hydrox Marigold (Tagetes spp) ypropyl cellulose and hydroxypropylmethyl cellulose; Sweet orange Tree (Citrus Aurantium) (iii) synthetic polymers such as sodium polyacrylate, Orchid Daisy (Bellis perennis) polyvinyl alcohol and carboxylic polymer derivatives Passion flower (Passiflora spp) of acrylic acid, such as the Carbopols. Peach-tree (Prunus persica) The emulsion which can be of the oil-in-water or Pelargonium (Pelargonium spp) 10 water-in-oil type constitutes a particularly preferred Pansy (Viola spp) Snowdrop (Galanthus nivalis) cohesion agent for the flower or flower top particles. Periwinkle (Vinca spp) To constitute the oil phase of the emulsion, a large Petunia Phlox (Petunia spp) (Phlox spp) variety of products can be employed, such as: Field larkspur (Delphinium consolida) 15 (a) hydrocarbon oils including paraffin oil, Purcellin Garden peony (Paeonia officinalis) oil, perhydrosqualene and solutions of microcrystalline Sweat pea (Lathyrus odorantes) wax in oils; (Polygonum spp) (b) animal oils such as whale oil, seal oil, menhaden Apple tree (Pirus malus) oil, halibut liver oil, cod liver oil, tuna oil, tallow oil, Primose (Primula spp) Silver weed (Potentille Anserina) 20 beef oil, horse oil, sheep oil, mink oil, otter oil, and hog Plum-tree (Prunus domestica) oil; Pyrethrum (Chrysanthemum cineriaefolium) (c) vegetable oils such as almond oil, peanut oil, Meadow Sweet (Spiraea Ulmaria) wheat germ oil, flax oil, apricot pit oil, walnut oil, palm Buttercup (Ranunculus spp) Rhododendron (Rhododendron ferrugineum) oil, pistachio oil, sesame oil, poppy oil, pine oil, ricin oil, Rosemary French Rose (Rosmarinus officinalis) (Rose gallica) 25 soy oil, avocado oil, safflower oil, coconut oil, hazelnut Saffron (Crocus sativus) oil, olive oil, grape seed oil, turnsole oil, colza oil, cade Grass polly (Lythrum salicaria) oil, corn germ oil, peach stone oil, coffee oil, jojoba oil Bloodroot (Sanguinaria canadiensis) and the like; Saopwort (Saponaria officinalis) (d) mineral oils having a initial distillation point at Sage (Salvia officinalis) 30 atmospheric pressure of about 250 C. and a final distil Willow (Salix alba) Devil's bit scabiou (Scabiosa Succisa) lation point in the order of 410 C.; Syringa (Philadelphus coronarius) (e) saturated esters such as isopropyl palmitate, alkyl Serpoilet (Thymus serpyllum) myristrates such as isopropyl myristate, butyl myristate (Sophora japonica) and cetyl myristate, hexadecyl stearate, ethyl palmitate, Corne (Sorbus domestica) Marigold (Calandula officinalis) 35 triglycerides of octanoic and decanoic acids, and cetyl Spiraea (Spiraea spp) ricinoleate. Elder Tamarisk (Sambucus nigra) (Tamaris gallica) There can also, if desired, be added to the "oil" phase, Tansy (Tanatecum vulgare) silicone oils soluble in other oils such as dimethylpolysi Garden thyme (Thymus vulgaris) loxane and methylphenylpolysiloxane. Line (Tilia spp) Further, in order to assist in the retention of the oils, Clover (Trifolium spp) waxes such as Cornauba wax, Candellila wax, beeswax, Tulip (Tulipa spp) microcrystalline wax and ozokerite can be used. Coltsfoot (Tussilago affara) Speedwell (Veronica officinalis) The emulsifying agent in the water-in-oil emulsions Common vervain (Verbena officinalis) or oil-in-water emulsions can be of the anionic, cationic Violet (Viola spp) 45 or non-ionic type. Yucca (Yucca spp) Representative anionic emulsifying agents include: alkali or alkaline earth soaps, such as for example, so In accordance with the present invention the quantity dium stearate or calcium oleate, soaps of organic bases, of flower or flower top particles must be present in the salts of sulfate or sulfone derivatives, oxyethylenated or composition of the invention in a fashion to obtain good 50 not, such as sodium lauryl sulfate. viscosity. This is generally obtained by using an amount Representative cationic emulsifiers include: quater greater than or equal to 5 weight percent, and prefera nary ammonium salts such as, for example, benzalko bly between 5 and 25 weight percent, this percentage nium chloride and cetyl pyridinium chloride. being expressed as dry material. Representative non-ionic emulsifying agents include The cohesion agent, i.e. thickening agent or substance 55 in particular: aliphatic fatty alcohols, such as cetyl alco which can be present in an amount of 0.1 to 20 weight hol or stearyl alcohol or a mixture of the two, fatty percent is selected from alcohols or a-diols, oxyethylenated or poly (i) water soluble vegetable thickening agents such as glycerolated, such as oleic alcohol polyoxyethylenated gum arabic, karaya gum, gum tragacanth, guar gum, with 10 moles of ethylene oxide, 2-octadecanediol poly carobbean gum, taragum, pectines, alginates, carraghe 60 glycerolated with 2 or 7 moles of glycidol, cyclic fatty nates, agar-agar, furcellaria, starches, the water soluble alcohols, glycol esters of fatty acids, such as ethylene portions of mucilagenous plants such as those of mullein glycol stearate, mono- or di-stearates of glycerol, polye (Verbascum spp), wild chamomile (Matricaria chamo thyleneglycol esters offatty acids, such as polyethylene milla), fenugreek, marsh mallow (Althaea officinalis), glycol stearate, fatty esters of fatty acids of sorbitan, mallow (Malva spp), flax, lime (Tilia spp), psyllium, 65 oxyethylenated or not, and sold under the tradename plantain, borge (Borago officinalis), star thistle (Centau "Tweens' or "Spans' by Atlas, sucrose esters of fatty rea calcitrapa), alder buckthorn (Rhamnus frangula), acids, esters offatty acids with glucose derivatives, such as methylglucoside sesquistearate and methylglucoside 4,459,285 5 6 sesquistearate polyoxyethylenated with 20 moles of Pat. No. 4,185,087, Japanese patent application No. ethylene oxide. 80.66506 and Austrian No. 71.01171, or even those men Generally, the water phase of the emulsions represent tioned in CTFA dictionary under the name 20 to 95%, the oil phase 3 to 80% and the emulsifying “AMODIMETHICONE', such as the product com agent 1 to 20%, relative to the total weight of the emul mercialized in admixture with other components under SO. m the name of cationic emulsion "DOW CORNING The compositions according to the present invention 929'. can also contain various cosmetic adjuvants such as pH The compositions according to the present invention modifiers, perfumes, preservative agents, solvents, anti can also contain 0.05 to 5% by weight of an anionic oxidant agents, sequesterants or sun screens. 10 polymer having sulfonic, carboxylic or phosphonic According to the preferred embodiment, the compo groups and principally those mentioned in French Pat. sitions of the present invention contain 0.05 to 5 percent No. 78.07363. by weight of a cationic derivative and/or a cationic When the compositions according to the present polymer. invention are used for the treatment of the skin, these The cationic derivative is a fatty amine salt such as 15 compositions can be provided in the form of creams, alkyl amine acetate, a quaternary ammonium salt such milks, gels, make-up, masks for the skin, depilatory, as chlorides or bromides of alkyl dimethyl benzyl am deodorant or antiperspirant compositions, bath prod monium, of alkyl trimethyl ammonium, of alkyl di ucts or after shave balm. methyl hydroxyethyl ammonium, of dimethyl distearyl When the compositions according to the invention ammonium in which the alkyl radicals have, preferably, 20 are used for the treatment of the hair, they can be pro between 1 and 22 carbon atoms, a quaternary halide of vided in the form of shampoos, hair dye products, hair gluconamide such as those described in U.S. Pat. No. rinse treating products for application before or after a 3,766,267, a quaternary halide of amide of mink oil such shampoo, a dye, a bleach, a permanent wave composi as those described in U.S. Pat. No. 4,012,398, a quater tion or an uncurling composition. nary derivative offatty halo-alkanoate of dialkylamino 25 These compositions that are employed for the treat propyl amide such as those described in U.S. Pat. No. ment of the hair or skin can also be packaged in aerosol 4,038,294, a quaternary ammonium derivative of the containers in the presence of a propellant gas. fatty acids of lanolin such as those described in U.S. Pat. The following non-limiting examples illustrate the No. 4,069,347, an alkylpyridinum salt or an imidazoline present invention. derivative. w 30 The cationic polymer is of the polyamine, EXAMPLE 1. polyaminoamide of quaternary polyammonium type, the amine or ammonium group being part of the poly mer chain or being linked to it. :- - - Powder of the flowers of meadow sweet (Spiraea 300 g The cationic polymers, such as defined above, have a 35 Ulmaria) having a granulometry between 80 microns and 125 microns molecular weight between 500 and 3,000,000 and are Vidogum L 175 (Extract of endosperm of 2.0 g more particularly described in the following French Carob seed) sold by Unipectine patent and patent application Nos.: 2,077,143; 1,492,597; Preservative, sufficient amount 2,162,025; 2,280,361; 2,252,840; 2,368,508; 1,583,363; Water, sufficient amount for 100.0 g 2,080,759; 2,190,406; 2,320,330; 2,270,846; 2,316,271; 2,336,434; 2,189,434 and 2,413,907, as well as in the This composition, having the appearance of a cream following U.S. Pat. Nos.: 3,589,978; 4,031,307; is applied to clean hair. After a contact period of 10 3,227,615; 2,961,347; 2,273,780; 2,375,853; 2,388,614; minutes, the hair is rinsed and is soft and shiny. 2,454,547; 3,206,462; 2,261,002; 2,271,378; 3,874,870; EXAMPLE 2 4,001,432; 3,929,990; 3,966,904; 4,005, 193; 4,025,617; 45 4,025,627; 4,025,653; 4,026,945; 4,027,020; 4,185,087 and 4,131,576, incorporated herein by reference. . . . . . Powder of the flowers of mallow (Malva spp) 17.0 g Representative preferred polymers include: having a granulometry is than 80 microns (1) The derivatives of cellulose ethers having quater Glycerine 400 g nary ammonium groups such as those described in 50 "Vidogum L 175" - see Ex. 1 1 g French Pat. No. 1,492,597 and principally the polymers Preservative, sufficient amount Water, sufficient amount for 100.0 g sold under the names JR, such as JR 125, JR 400, JR 30M, and LR such as LR 400 and LR 30M by Union Carbide; the cationic cellulose derivatives such as CELThis composition is applied to clean hair which is QUAT L 200 and CELQUAT L 60 sold by National 55 then rinsed after a contact time of 20 minutes. This Starch and described in U.S. Pat. No. 4,131,576; treatment imparted softness to the hair. (2) The cyclopolymers such as the homopolymer of EXAMPLE 3 dimethyl diallyl ammonium chloride sold under the tradename "MERQUAT 100', having a molecular weight lower than 100,000 and the copolymer of di 60 pseudoacacia) Powder of the flowers of acacia (Robinia having a granulometry 200 g methyl diallyl ammonium chloride and acrylamide hav between 80 microns and 125 microns ing a molecular weight greater than 500,000 and sold Glucate SS (methylglucoside 5.0 g under the tradename "MERQUAT 550” by Merck. sesquistearate) sold by Amerchol These polymers are described in French Pat. No. Glucamate SSE 20 (methylglucoside 3.0 g 2,080,759 and its certificate of addition, French Pat. No. 65 sesquistearate polyoxyethylenated with 2,190,406; and 20 moles of ethylene oxide), sold by Americho (3) silicone cationic polymers such as those described Petrolatum oil 5.0 g in European application Nos. 17,121 and 17,122, in U.S. Preservative, sufficient amount 4,459,285 7 8 -continued -continued Water, sufficient amount for 1000 g Chemical Triethanolanine 0.4 g k Methyl paraoxybenzoate 0.3 g In this Example, the 20g of the powder of acacia can 5 Perfume, sufficient amount be replaced by one of the following powders: Water, sufficient amount for 1000 g powder of the flowers of elder (Sambucus nigra)-12 g powder of the flowers of mullein (Verbascum spp)-14 The resulting product has the appearance of a beige 9. fluid milk and an unctuous feel. EXAMPLE 4 The powder of the flowers of cornflower can be replaced by 5.0 g of the following powders having a granulometry S80 microns: Powder of the flowers of roselle (Hibiscus 8.0 g flowers of arnica (arnica montana), spp) having a granulometry between 80 flowers of apple tree (Pirus malus), or E. Epis 3 8.0 g flowers of gillower (Dianthus caryophyllus)-red. Glucamate SSE 20 - see Example 3 3.0 g Kathon CG, in 1.5% solution (mixture 0.3 g EXAMPLE 7 of 5-chloro-2-methyl 4-isothiazoline- - 3-one, 2-methyl 4-isothiazoline-3-one, magnesium Avocado oil chloride and calcium chloride 3g 20 Powder of the flowers of nulle (Verbascum spp) having a granulometry S 80 microns 7.50 g Water, sufficient amount for 100.0 g Cetyl and steary alcohols, 30/70 5.00 g mixture, sold under the tradename "SIPOL 16/18 S3" by Henkel The 8g of the roselle powder can be replaced by one 2:lysis Colois, E. and E. mixture, sold under i.30 g of the following powders: s 25 the tradename SIMULSOLCs. powder of French Rose (Rose gallica)-7g by Seppic powder of Cornflower (Centaurea Cyanus)-7 g Mixture of glycerol mono- and die 1.85 g powder of marigold (Calandula officinalis)-7g sterate, noiseiferulsifiable 9. powder of Lavender (Lavandula officinalis)-10 g song trade name "GELEOL' powder of the flowers of sweet orange tree (citrus 30 Petrolaturn oil 3.70 g Aurantium)-10g. Cetyl alcohol 1.40 g The composition is applied to wet hair. Butylhydroxytoluene 0.025 g After aftcontact period of 15 minutes the hair is rinsed and shin Piyyy Extract w of the endosperm of leguminous 0.025 0.74 gg and is soft and shiny. guar, sold under the tradename 35 "Vidogum GH. 75' by Unipectine EXAMPLE 5 m Preservatives, sufficient amount Perfume, sufficient amount Water, sufficient amount for 1000 g Powder of wild chanomile 15.0 g (Matricaria chamomilla) . .. . . . . ... having a granulometry is 125 microns 40 The resulting cream is thick, shiny and unctuous and Scid - - . . g has a khaki green color. alcohol 05 In this Example the 7.5g of the powder of the flowers Oxyethylenated cetylstearyl 2.0 g of mullein can be replaced by: alcohol, sold under the tradename The powder of the flowers of acacia (Robinia A Ap" by Henkel 3.0 45 pseudoacacia)-7.5g Ecol 5s The powder. of the flowers of barbary fig (Opuntia Preservative, sufficient amount vulgaris)-7.5 g, or Water, sufficient amount for 1000 g The powder of the flowers of common heather (Calluna vulgaris)-5g, This composition is applied to wet hair. After a 50 each having a granulometry S 125 microns. When the powder of the flowers of acacia is em contact period of 20 minutes, the hair is rinsed, then ployed shampooed. The hair thus treated, is particularly soft the cream is thick, has a dull light beige color and a very unctious feel. and shiny. When the powder of the flowers of common heather EXAMPLE 6 55 is employed the cream is thick, has a beigh-gray color, s and is very smooth to the touch. Powder of the flowers of cornflower 5.0 g When the powder of the flowers of barbary fig is (Centaurea Cyanus) having a employed the cream is thick and has a dull light beige granulometry S 80 microns color. on-ionic emulsifier havin R i".5"E ch 1.3 g 60 EXAMPLE 8 CHOH-CH2-O-H wherein R = C6H33 and n = 2 Non-ionic emulsifier having the same 5g Powder of the flowers of lavender 5.00 g formula given immediately above wherein (Lavandula officinalis) having a R = C6H33 and n = 7 65 granulometry S 80 microns Petroiatum oil 28. g Soy lecithin i 1.80 g High molecuia weight carboxyvinyl 0.4 g Colza oil it.00 g polymer, sold under the trade Cocoa butter 2.35 g name "CARBOPOL 94.1" by Goodrich Cetylalcohol 3.70 g 4,459,285 9 10 -continued -continued Stearyl alcohol 1.80 g Soy lecithin 0.08 g Ethylene diamine tetraacetic acid 0.045 g High molecular weight carboxyvinyl 0.30 g Preservatives, sufficient amount polymer sold under the tradename NaOH, 10%, sufficient for a pH of 6 - 0.2 5 *CARBOPOL934” by Goodrich Chemical Perfume, sufficient amount Triethanolamine 0.30 g Water, sufficient amount for 100.00 g Preservatives, sufficient amount Perfume, sufficient amount Water, sufficient amount for 100.00 g The resulting cream is thick and shiny, has a caramel color and is very smooth to the touch. 10 The powder of the flowers of lavender can be re The resulting cream is thick and has a greenish light placed by 5.0 g of the powder of the following flowers, beige color. the powder in each instance having a granulometry The powder of the flowers of barbary fig can be S80 microns: replaced by the powder of the following flowers, the the flowers of safflower (Carthamus tinctorius), 5 powder in each instance having a granulometry is 125 the flowers of honeysuckle (Lonicera spp), and microns: the flowers of bloodroot (Sanguinaria canadiensis). the flowers of peach tree (Prunus persica), EXAMPLE 9 the flowers of daisy (Bellis perennis), or the flowers of live ever (Helicrysum arenarium). 2O EXAMPLE 1.1 Powder of the flowers of sweet orange tree 13.00 g (Citrus Aurantium) having a granulometry S 80 microns Cetyl and stearyl alcohols in a 30/70 2.10 g. Powder of the flowers of clover (Trifolium spp) 13.0 g ratio, sold under the name "SIPOL 10/18 S 3' 25 having a granulometry is 125 microns Gum tragacanth 1.7 g by Henkel Oxyethylenated (30 moles of ethylene oxide) 0.5 g Preservatives, sufficient amount cetyl and stearyl alcohols in a 30/70 Water, sufficient amount for 1000 g ratio, sold under the tradename "SIMULSOL C.S.” by Seppic Mixture of glycerol mono- and di-stearates, 0.9 g The product is a fluid gel having a deep chestnut non-selfemulsifiable, sold under the tradename "GELEOL' by Gattefosse 30 color and being smooth to the touch. Petrolatum oil Cetyl alcohol 5.20 0.90 g g : EXAMPLE 12 Butylhydroxytoluene 0.025 g Butylhydroxyanisole 0.025 g Powder of the flowers of yarrow 6.5 g Isopropyl myristate 2.60 g 35 (Achillea Millefolium) having a Polydimethylsiloxane, sold under the trade- 0.90 g. granulometry is 125 microns name "Rhodorsi huile 70047 W.300 C' or , "47V300C" by Rhone-Poulenc Refined extract of red algae of the gigartinaceous family, sold under . . . 1.9 g . Glycerine 4.30 g the tradename "Satiagum Standard' Perfume, sufficient amount by Ceca. : s, .. v . Preservative, sufficient amount s . . . 40 Water, sufficient amount for 100.00 g a Preservatives, sufficient amount Water, sufficient amount for 1000 g The resulting cream is thick and shiny, has a green The resulting product is a fluid gel which has a green chestnut color and is very smooth to the touch. The powder of the flowers of sweet orange tree can 45 ish chestnut color and is shiny touch. . . and very smooth to the be replaced by the powder of the following flowers, the powder in each instance having a granulometry S80 EXAMPLE. 13 microns: the flowers of hops (Humulus lupulus), m the flowers of garden peony (Paeonia officinalis), or 50 Powder of the extraction residue of 4.50 g the flowers of marigold (Tagetes spp). tung having a granulometry is 125 microns s: Powder of the flowers of mullein 5. g. EXAMPLE 10 (Verbascum spp) having a ... granulometry is 30 microns - Non-ionic emulsifier having the formula, 1.10 g Powder of the flowers of barbary fig, 9.00 g R-CHOH-CH2-O-CH2CHOH-CH2-O-His 55 where having a granulometry between 80 microns R = C6H33 and n = 2 . i and 25 microns Non-ionic emulsifier having the same 4.40 g Mixture of the mono- and di-stearate of 1.80 g formula immediately above where . w methylglucoside, sold under the tradename R = C6H33 and n = 7 Petrolatum oil ; ; , ... 27.30 g “Glucate SS' by Americhol Mixture of the mono- and di-stearate of 1.80 g 60 High molecular weight carboxyvinyl 0.36 g . methyl glucoside, ethoxylated with 20 moles polymer, sold under the tradename of ethylene oxide and sold under the tradename "CARBOPOL 94.1” by Goodrich Chemical . "Glucomate SSE 20' by Americhol Triethanolamine 0.36 g Petrolatum oil 8.10 g Methyl parahydroxybenzoate 0.30 g Perhydrosqualene, synthetic 8.10 g Perfume, sufficient amount isopropyi paimulate 2.00 g. 65 Water, sufficient amount for - . . . . .. 100.00 g 3tity is yuzury tuitiene 0.0015 g ?:'y Ytract of egg yolk without additional .30 g The resulting product is a deep green, shiny and ho tecithin, sold by Laboratoire Industriel de Biologie mogeneous fluid milk. 3. -: 4,459,285 11 12 EXAMPLE 14 -continued name "SIPOL 16/18 S3' by Henkel Cetyl and stearyl alcohols, in a 30/70 1.30 g Soft wheat flour 6.00 g ratio, oxyethylenated with 33 moles of Powder of the flowers of allow. 6.00 g ethylene oxide and sold under the tradename (Malva spp) having a granulometry “SIMULSOL C.S." by Seppic is 125 microns Mixture of glycerol mono- and di- 1.90 g Soy lecithin 10.30 g stearates, non-selfemulsifiable and Colza oil 9.65 g sold under the tradename "GELEOL' by Cocoa butter 1.20 g Gattefosse Cetyl alcohol 3.25 g 10 Petrolatum oil 3.70 g Steary alcohol 1.60 g Cetyl alcohol 1.40 g Ethylene diaminetetraacetic acid 0.045 g Butylhydroxytoluene 0.025 g Preservatives, sufficient amount Butylhydroxyanisole 0.025 g NaOH, 10% solin. sufficient amount for pH = 6 -- 0.2 Propyl parahydroxybenzoate 0.14 g Perfume, sufficient annount Methyl parahydroxybenzoate 0.14 g Water, sufficient amount for 100.00 g 5 Distearyl dimethyl ammonium chloride, 0.37 g sold under the tradename 'GERMINE DS-DAC’ The resulting cream is thick and dull; it has a violet by Hoechst Monobutylester of the copolymer of 0.37 g gray color and is creamy to the touch. methylvinylether/maleic acid, sold (active EXAMPLE 1.5 20 under the tradename "GANTREZ ES 425' material) by G.A.F. Sodium chloride 0.09 g Soda (1N) 0.86 m Powder of the flowers of red poppy 9.10 g Perfume, sufficient amount (Papaver Rhoeas) having a granulometry Water, sufficient amount for 100.00 g a 20 microns Hydroxypropyl cellulose, sold under 0.91 g 25 the name “NATROSOL 250 HHR" by The resulting cream is thick, beige and has an unc Hercules tuous appearance and touch. Preservatives, sufficient amount Water, sufficient amount for 100.00 g EXAMPLE 18 30 The resulting gel is fluid and unctuous, and has a shiny bordeaux color. It is very smooth to the touch. Powder of the flowers of barbary fig 12.00 g (Opuntia vulgaris) having a granulometry EXAMPLE 16 is 125 microns Mixture of mono- and di-stearates of 4.98 g 35 methyl glucoside, sold under the Powder of the flowers of elder 5.00 g tradename "Glucate SS' by Americhol Mixture of mono- and distearates of 3.32 g (Sambucus nigra) having a granulometry methyl glucoside, oxyethylenated between 80 and 125 microns with 20 moles of ethylene oxide and Cetyl and stearyl alcohols in a 30/70 5.60 g sold under the tradename "Glucanate SSE 20' ratio, sold under the tradename by Americhol "SIPOL 16/18 S3' by Henkel Petrolatum oil 4.15 g Cetyl and stearyl alcohols in a 30/70 1.40 g Antioxidants, sufficient amount ratio, oxyethylenated with 33 moles Preservatives, sufficient amount of ethylene oxide and sold under Cationic cellulose derivative, sold 0.50 g the tradename "SIMULSOL C.S." by . under the tradename "CELQUAT L200' (active Seppic by National Starch material) Mixture of glycerol mono- and di- stearate 200 g 45 Water, sufficient amount for 100.00 g non-self emulsifiable, sold under the tradename "GELEOL' by Gattefosse Petrolaturn oil 4.00 g Cetyl alcohol 1.50 g The resulting cream is thick, has a khaki color and a Butylhydroxytoluene 0.025 g homogeneous appearance. Butylhydroxyanisole 0.025 g 50 Preservatives, sufficient annount EXAMPLE 19 Perfume, sufficient amount Water, sufficient amount for 100.00 g Powder of the flowers of French Rose 5.00 g (Rose gallica) having a granulometry The resulting cream has a light mustard color, a fine e 80 microns 55 Cetyl and steary alcohols in a 30/70 texture and a homogeneous appearance. 5.60 g ratio, sold under the tradename The powder of the flowers of elder can be replaced "SIPOL 16/18 S3' by Henkel by 5 g of the flowers of tansy (Tanatecum vulgare) hav Cetyl and steary alcohols in a 30/70 1.40 g ing a granulometry S 125 microns. The resulting cream ratio, oxyethylenated with 33 moles of is medium beige and has a smooth and unctuous appear ethylene oxide and sold under the trade 60 name "SIMULSOL C.S." by Seppic ance and touch. Mixture of glycerol mono- and di-stearates, . 2.00 g EXAMPLE 17 non-selfemulsifiable, sold under the tradename "GELEOL' by Gattefosse Petrolaturn oil 4.00 g Cetyl alcohol 1.50 g Powder of the flower of acacia 6.50 g 65 Butylhydroxytoluene 0.025 g (Robinia pseudoacacia) having a Butylhydroxyanisole 0.025 g granulometry s 125 microns Polymers of hydroxyethyl cellulose and 0.90 g Cetyl and stearyl alcohols, in a 5.00 g epichlorohydrin quaternized with 30/70 ratio, sold under the trade trimethylamine, having a viscosity 4,459,285 13 14 -continued -continued of 400 centipoises and sold under granulometry s 120 microns the name "JR 400' by Union Carbide Powder of the rhizomes of ruscus 8.00 g Monobutyl ester of the copolymer of 0.36 g having a granulometry between 50 methyl vinyl ether/maleic acid, sold (active 5 and 100 microns W under the tradename "GANTREZ ES 425' material) Ethyl alcohol 15.0 by G.A.F. Propylene glycol 5.0 g Distearyl dimethyl ammonium chloride, 0.36 g "CARBOPOL 940" (carboxyvinyl polymer). 1.0 g sold under the tradename "GERAMINEDS-DAC' sold by Goodrich Chemicals by Hoechst Triethanolamine 1.0 g Sodium salt of a polyhydrocarbon acid, 1.17 g 10 Preservative 0.3 g sold under the tradename "HYDAGEN F' (active Perfume 0.4 g by Henkel material) Demineralized water, sufficient amount for 100 g Sodium chloride 3.60 g Soda (IN) sufficient amount for pH = 7 - 0.5 Perfume, sufficient annount Preservatives, sufficient amount 5 EXAMPLE 23: Night cream Water, sufficient amount for 100.00 g Powder of the flowers of fumitory 2.0 g The resulting cream is fluid, has a rose-beige color (Fumaria officinalis) having a granulometry is 120 microns and a homogeneous appearance. Powder of the flowers of yarrow 13.0 g 20 EXAMPLE 20 (Achillea Millefolium) having a granulometry between 50 and 120 microns Mixture of glycerol mono- and di-stearates 100 g Powder of the flowers of marigold 10.00 g Cetyl alcohol 2.0 g (Calandula officinalis) having a Stearic acid ester polyoxyethylenated 2.0 g granulometry is 125 microns 25 with 20 moles of ethylene oxide Mixture of mono- and di- stearates of 3.90 g Petrolatum oil 200 g methyl glucoside, sold under the trade Perhydrosqualene 200 g name "GLUCATE SS' by Amerchol Liquid lanolin 2.0 g Mixture of Inono- and di- stearates of 2.60 g Soy lecithin 2.0 g methyl glucoside, oxyethylenated with Polyethylene glycol 400 5.0 g Preservative 0.3 g 20 moles of ethylene oxide and sold under 30 Perfume 0.4 g the tradename "GLUCAMATESSE 20' by Americhol Demineralized water, sufficient amount for 100 g Pctrolatum oil 3.25 g Antioxidants, sufficient amount Preservatives, sufficient amount Copolymer of dimethyldiallyl ammonium - - -- - EXAMPLE 24: Day Cream chloride and acrylamide, having a (active molecular weight 2 500,000 and sold material) Powder of the flowers of red poppy 5.0 g under the tradename "MERQUAT 550" by Merck (Papaver Rhoeas) having a Water, sufficient amount for 100.00 3. granulometry is 120 microns Powder of the flowers of nullein 100 g (Verbascum spp) having a - The resulting cream is fluid and has a mustard color. 40 granulometry between 50 and 100 microns EXAMPLE 21: Cream for" . oily 4 skin. . . . . . . . ... Isopropyl, myristate , Perhydrosqualene 10.0 g 5.0 g -- - - -- - -- - - . . . . Stearic acid 1.0 g
Mixture of glycerol mono- and di-stearates 8.0 g
Powder of the flowers of sage 5.00 g 45 Stearic acid ester polyoxyethylenated 1.0 g (Salvia afficinalis) having a .f with 20 moles of ethylene oxide granulometry between 50 and 100 Petrolatum oil 15.0 g microns Cholesterol 1.0 g Stearic acid ester polyoxyethylenated 6.6 g Allantoin 0.5 g with 20 moles ethylene oxide, sold Preservative 0.3 g under the tradename "MYRJ 49' Perfume 0.35 g by Atlas - 50 Demineralized water, sufficient amount for 100 g Glycerol mono- and di-stearate 1.2 g Cetyl alcohol - -- 4.2 g Mixture of cetylstearyl alcohol and 4.0 g sodium alkylsulfate, sold under the . .. EXAMPLE 25: Mask For Reddened Skin tradename "SINNOWAX SX” by Henkel Petrolatum oil : 5.0 g 55. Cyclic dimethyl polysiloxane, sold under 5.0 g Powder of the flowers of mallow 15.0 g the tradename "Volatile Silicone 7158' (Malya spp) having a granulometry by Union Carbide between 50 and 120 microns - S-carboxymethyl cysteine 1.0 g Silicate of magnesium and aluminuin 5.0 g Triethanolamine, sufficient for pH = 6.8 sold under the tradename "WEEGUM HV' Preservative 0.3 g 60 by Goodrich Vanderbilt Perfune 0.3 g . . . Refined extract of red algae sold under 1.0 g Water, sufficient amount for 100 g the tradename “AUBY GUM X2' by Pierrefitte Auby Titanium oxide 3.0 g - Koalin, superior 15.0 EXAMPLE 22: Refreshing gel for the legs 65 Sorbitan Renaurate polyoxyethylenated 2.0 with 20 moles of ethylene oxide (TWEEN 20) Glycerine 5.0 g Powder of the flowers of arnica 8.00 g Preservative 0.3 g (Arnica montana) having a Perfume 0.4 g 4,459,285 15 16 -continued EXAMPLE 30: Eyelid Make-up Demineralized water, sufficient amount for 100 g Powder of the flowers of saffron 15.00 g (Crocus sativus) having a EXAMPLE 26: Water-in-Oil Emulsion For Dry Skin granulometry is 75 microns Magnesium lanolate 3.8 g. Hydrogenated lanolin 5.7 g Powder of the flowers of marsh mallow 15.0 g Ozokerite 15.00 g (Althaea officinalis) having a Isopropyl palmitate 1000 g granulometry S 120 microns 10 Paraffin oil 13.5 g Mixture of aliphatic alcohols and waxes 200 g Titanium oxide i.5 g. combined with saturated hydrocarbon Methyl parahydroxybenzoate 0.3 g oils, sold under the tradename Water, sufficient amount for 100 g "PROTEGINX” by Goldschmidt Petrolatum oil 100 g Glycerine 100 g 15 EXAMPLE 31: Complexion Base-Aqueous Gel Magnesium sulfate 0.5 g "Lipoaqualine" - hydrating complex 5.0 g containing lacticesters of cholesterol Powder of the flowers of red poppy 8.00 g and squalene derivatives sold by (Papayer Rhoeas) having a Creachen G.m.b.H. granulometry is 110 microns Preservative 0.3 g 20 Powder of the flowers of Franch Rose 2.00 g Perfume 0.4 g (Rose gallica) having a granulometry Demineralized water, sufficient amount for 100 g is 85 microns Propylene glycol 1000 g CARBOPOL 940 0.8 g EXAMPLE 27: Make-up Remover Milk 25 Polyoxyethylenated sorbitan monolaurate 0.5 g Ethylene diamine tetraacetic acid 0.05 g Triethanoamine i.0 g Mica-titanium 3.0 g Powder of the flowers of soapwort 5.00 g Dyes, sufficient amount (Saponaria officinalis) having a Methyl parabenzoate, sufficient amount granulometry is 80 microns Water, sufficient amount for 100 g Petrolatum oil 10.00 g 3O Isopropyl palmitate 5.00 g Tween 20 2.00 g Stearic acid 1.4 g EXAMPLE 32: Rinse Mask for Dry Skin Triethanolamine 0.7 g CARBOPOL 940 0.6 g Lysine 0.5g 35 Powder of the flowers of mullein 200 g Propyl parahydroxybenzoate 0.1 g (Verbascum spp) having a granulometry Water, sufficient amount for 100 g, S 70 microns Propylene glycol 12.00 g Titanium dioxide 0.5 g. Gelatin 1.0 g EXAMPLE 28: Body Milk 40 Mucilage from plantain seeds ...) Preservative, sufficient amount Perfume, sufficient amount Powder of the flowers of pansy 10 g Water, sufficient amount for 100 g (Viola spp) having a granulometry is microns Jojoba oil 5g 45. The resulting mask has a green color. Turnsole oil 4 g If in this Example, the muilein is replaced by red Avocado nonsaponifiables 6g poppy, the resulting mask has an eggplant color. Glycerol stearate 2g Stearic acid 1.4 g EXAMPLE 33 Triethanolanine 1.3 g CARBOPOL 934 0.6 g 50 Methyl parahydroxybenzoate . 0.25 g . Powder of the flowers of roselle 15.00 g Butylhydroxyanisole 0.10 g (Hibiscus spp) having a granulometry Butylhydroxytoluene 0.10 g s 125 microns Perfume, sufficient amount Cetyl and stearyl alcohols in a 4.60 g Water, sufficient amount for 100 g 30/70 ratio, sold under the trade 55 name "SIPOL 16/18 S3' by Henkel Cetyl and steary alcohols in a 1.20 g 30/70 ratio, oxyethylenated with 33 EXAMPLE 29: Hydrating Cream moles of ethylene oxide and sold under the tradename "SIMULSOL C.S.' by Seppic Powder of the flowers of channonile 12 g 60 Mixture of glycerol mono- and di-stearates, i.70 g (Anthemis nobilis) having a mon-selfemulsifiable, sold under the granulometry is 85 microns tradename "GELEOL" by Gatefosse Mineral oil 44 g Petroaturn oil 3.4C Beeswax 3 g Cetyl alcohol 30 Magnesium lanolate 2.4 g Butylhydroxytoluene 0.025 Lanolin alcohol 0.6 g 65 Butylhydroxyaniisole 5 Methyl parahydroxybenzoate, sufficient amount Disteary dimethyl ammonium citeside S Water, sufficient amount for 100 g sold under the tradename 'GERAMINES-DAC' by Hoechst Polydimethylsiloxane having an amine 2.42 g 4,459,285 17 18 -continued tree or dogwood, roselle, hydrangea, oleander, lilac, magnolia, Sweet orange tree, rhododendron, syringa, function emulsified by an emulsifier spiraea, tamarisk and yucca and said thickening agent having a cationic and non-ionic character, sold under the tradename being selected from gun arabic, karayagum, gum trag "DC 92.9" by Dow Corning 5 acanth, guar gum, carbo bean gum, tara gum, pectines, Preservative, sufficient amount alginates, carraghenates, agar-agar, furcellaria, starches, Perfume, sufficient amount Water, sufficient amount for 100.00 g the water soluble portions of mucilagenous plants se lected from mullein, wild chamomile, fenugreek, marsh mallow, mallow, flax, lime, psyllium, plantain, borage, The resulting cream is thick and has a deep rose 10 star thistle, alder buckthorn, common comfrey, aspara color. The cream has a very smooth and very unctuous gus, senna, lichen, methylcellulose, hydroxymethyl appearance and texture. cellulose, hydroxyethyl cellulose, hydroxypropyl cellu EXAMPLE 34 lose, hydroxypropylmethyl cellulose, sodium poly acrylate, polyvinyl alcohol and carboxylic polymer 15 derivatives of acrylic acid, said particles being present Powder of the flowers of roselle (Hibiscus spp) having a granulometry 3.0 g in an amount of at least 5 percent by weight based on is 125 microns the total weight of said composition and said cohesion Powder of the roots of marsh mallow 6.5 g agent being present in an amount of 0.1 to 20 weight (Althaea officinalis) having a percent of said composition. granulometry s 125 microns 20 2. The composition of claim 1 wherein said particles Cetyl and stearyl alcohols in a 2.20 g result from the pulverization of flowers or flower tops 30/70 ratio, sold under the trade name "SIPOL 16/18 S3' by Henkel of roselle. - Cetyl and stearyl alcohols in a 0.50 g 3. The cosmetic composition of claim 1 wherein said 30/70 ratio, oxyethylenated with cohesion agent is a thickening agent. 33 moles of ethylene oxide and sold 25 4. The composition of claim 1 wherein said particles under the tradename "SIMULSOL C.S.' by Seppic of pulverized flowers or flower tops have a granulome Mixture of glycerol mono- and di-stearates, non-selfemulsifiable, sold under the 0.90 g try lower than 80 microns. tradename "GELEOL' by Gattefosse 5. The composition of claim 1 wherein said particles Petrolatum oil 5.40 g 30 are present in an amount of 5 to 25 percent by weight Cetyl alcohol s 0.90 g based on the total weight of said composition. Butylhydroxytoluene 0.025 g 6. The composition of claim 1 wherein said cohesion Butylhydroxyanisole 0.025 g agent is an emulsion wherein said emulsion comprises Isopropyl myristate 2.70 g Polydimethylsiloxane, sold under 0.90 g 20 to 95% water phase, 3 to 80% oil phase and 1 to 20% the tradename "RHODORSL Huile emulsifying agent, said percentages being expressed 70047 V.300" or "47 V300C" by 35 relative to the total weight of said composition. Rhone-Poulenc Glycerine 4.50 g 7. The composition of claim 1 which also includes a Perfume, sufficient amount cationic derivative selected from an alkyl amine acetate, Preservative, sufficient amount a chloride or bromide of alkyl dimethylbenzyl ammo Water, sufficient amount for 100.00 g 40 nium, of alkyl trimethyl ammonium, of alkyl dimethyl hydroxyethylammonium, or of dimethyl stearyl ammo The resulting cream is thick and has a very shiny nium, of quaternary halide of gluconamide, a quater violet rose color as well as a very unctuous appearance. nary halide of mink oil; a quaternary derivative of fatty What is claimed is: haloalkanoate of dialkylaminopropyl amide, a quater 1. A cosmetic composition for application to the hair 45 nary ammonium derivative of the fatty acids of lanolin, or skin comprising, in an aqueous medium, particles of an alkylpyridinium salt or an imidazoline derivative. pulverized flowers or flower tops having a granulome 8. The composition of claim 1 which also includes a try lower than 125 microns and a cohesion agent pres cationic polymer wherein the said polymer is of the ent in an amount effective to maintain homogeneity of polyamine, polyaminoamide or quaternary polyam said composition, said cohesion agent being a thicken- 50 monium type, the amine or ammonium group being a ing agent, or an emulsion selected from a water-in-oil part of the chain or being linked to it, the said cationic 3fallsion or an oil-in-water emulsion, said particles re polymer having a molecular weight between 500 and suiting from the pulverization of flowers or flower tops 3,000,000. k. . . . . . of shrubs selected from the group consisting of corneal 55