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United States Patent (19) 11 Patent Number: 4,459,285

Grollier et al. 45 Date of Patent: Jul. 10, 1984


54 COSMETIC COMPOSITION FOR THE 149,262 3/1874 Steelman ............................. 424/364
TREATMENT OF THE HAR AND SKN 375,860 1/1990 Worthington. ... 424/74
COMPRISINGAPOWDER OF FLOWERS OR 378,504 2/1988 Greene ...
FLOWER TOPS AND A COHES ON AGENT 412,769 10/1989 Lyons .........
3,842,847 10/1974 Hewitt et al. .. ... 424/70
75 Inventors: Jean F. Grollier, Paris; Josiane Alec, 3,903,257 9/1975 Arai et al........... ... 424/70
Pierrefitte; Chantal Fourcadier, Paris; 4,358,286 1 1/1982 Grollier et al. ............. vesss seas 424/74
Georges Rosenbaum, Asnieres; FOREIGN PATENT DOCUMENTS
Patrick Darmenton, Villejuif, all of
France 1492134 1/1970 Fed. Rep. of Germany ........ 424/74
73) Assignee: Societe Anonymedite: L'Oreal, Paris, OTHER PUBLICATIONS
France
Steinmetz, Codex Vegetabilis, "Roselle' Abst. 560
21 Appl. No.: 352,105 (1957).
(22 Filed: Feb. 25, 1982 Primary Examiner-Jerome D. Goldberg
30 Foreign Application Priority Data Assistant Examiner-Freda Abramson
Attorney, Agent, or Firm-Cushman, Darby & Cushman
Feb. 27, 1981 (LU Luxembourg ........................... 83173
57 ABSTRACT
51) Int. Cl. ....................... A61K 7/06; A61K 47/00;
A61K 31/00; A61K 47/00 A cosmetic composition for the treatment of the hair
52 U.S.C. ...................................... 424/74; 424/361; and skin comprising, in an aqueous medium, particles of
424/363; 424/364; 424/DIG. 2; 424/168; pulverized flowers or flower tops having a granulome
424/170 try lower than 125 microns and a cohesion agent pres
58 Field of Search ................. 424/74, 361, 363, 364; ent in an amount effective to maintain the homogeneity
8/160, 161 of the composition. The cohesion agent can be a thick
56) References Cited ening agent, a water-in-oil emulsion or an oil-in-water
emulsion.
U.S. PATENT DOCUMENTS
100,934 3/1870 Scruton ............................... 424/364 8 Claims, No Drawings
4,459,285
1 2
many varieties of plants, shrubs or trees and principally
COSMETC COMPOSTON FOR THE from the following:
TREATMENT OF THE HAIR AND SKIN
COMPRISING A POWDER OF FLOWERS OR
5 Wormwood (Artemisia Absinthium)
FLOWER TOPS AND A COHESION AGENT Acacia (Robinia pseudoacacia)
Yarrow (Achillea Millefolium)
The present invention relates to a cosmetic composi Agrimony (Agrimonia Eupatoria)
tion for the treatment of the hair and skin, this composi Amaryllis (Amaryllis)
Colombine (Aquilegia vulgaris)
tion containing, in the presence of a cohesion agent, a Anemone (Anemone spp)
powder resulting from the pulverization of at least one 10 Mugwort (Artemisia vulgaris)
flower or of flower top. Arnica
Sweet Woodruff
(Arnica montana)
(Asperula odorata)
For years both the pharmaceutical industry and the Hawthorn (Crataegus oxyacantha)
cosmetic industry have used in numerous formulations Azalea (Axalea spp)
active substances resulting from the extraction of vege Balsamine
15 Begonia
(Impatiens spp)
tables by different processes such as maceration, diges Bougainvillea
(Begonia spp)
(Bougainvillea spp)
tion, decoction, infusion or lixiviation. Waterelder (Viburnum opulus)
In certain cases, and principally in cosmetics, the Cornflower (Centaurea Cyanus)
vegetables are employed in the form of entire plants Mullein (Verbascum spp)
applied to the skin, or in coarsely pulverized forms so as 20 Common heather
Barbary fig
(Calluna vulgaris)
(Opuntia vulgaris)
to provide cataplasms when diluted with water. Camellia (Camelia japonica)
Representative cataplasms include, in particular, Channonile (Anthemis nobilis)
those obtained from emollient flour or from henna pow Campanula (Campanula spp)
(Tropeolum majus)
der and were used for the coloration of the hair or the Large Indian Cress
Saflower (Carthamus tinctorius)
skin. (Catalpa bignonioides)
These cataplasms exhibit numerous disadvantages 25 Star thistle (Centaurea calcitrapa)
caused essentially by coarse grinding of the plants Rough Cherry (Prunus cerasus)
which most often resulted in lumpy cataplasms which Honeysuckle (Lonicera spp)
Daisy r (Chrysanthemum leucoanthemum)
were difficult to apply to the skin and hair and which Travelle's Joy (Clematis vitalba)
were not easily removed, especially from the hair. Quince (Cydonia vulgaris)
Moreover these known products were difficult to 30 Red poppy
Colchicum or Meadow
(Papaver Rhoeas)
(Colchicum automnale)
preserve which prevented them from being made in a saffron
ready-to-use form. - . . Cornel tree (Cornus spp)
It has now been found that it is possible to signifi (or dogwood)
Crocus
cantly reduce or eliminate the disadvantages mentioned 35 Cyclamen (Crocus spp)
(Cyclamen spp)
above by using finely pulverized flowers or flower tops Dahlia (Dahlia variabilis)
having a determined granulometry in the presence of a Field larkspur (Delphinium consolida)
cohesion agent. . .. Dulcamara (Solanum Dulcamara)
(Leontopodium Alpinum)
The present invention thus relates to a cosmetic con Dog rose (Rosa canina)
position for the treatment of the hair and skin contain Fumitory (Fumaria officinalis)
ing, in an aqueous medium, particles resulting from the Broom (Cytisus scoparius)
(Gentiana spp)
pulverization of at least one flower or flower top, hav Gentian
Geranium (Geranium spp)
ing a granulometry less than 125 microns and, prefera Wallflower (Cheirantus cheiri)
bly, less than 80 microns, in the presence of a cohesion Sword-lily (Gladialus spp)
agent which maintains homogeneity of the composition Marsh Mallow (Althaea officinalis)
the said agent being a thickening substance and/or a 45 Roselle. ..., (Gypsophila spp)
. . (Hibiscus spp) -.
water-in-oil or oil-in-water type emulsion. Hydrangea (Hydrangea spp)
The particularly fine granulometry is obtained by Hops (Humulus lupulus) .
known pulverization processes, such as by crushing or Live everbalsan (Helicrysum arenarium)
(Impatiens spp)
micronization, optionally followed by a sieving opera 50 Garden
Orrice . . . (Iris spp)
tion, this degree of granulometry being critical to the Hyacinthe, (Hyacynthus spp)
production of compositions exhibiting all the requisite Jasmine (Jasminum spp)
characteristics. - - - - Jonquil (Narcissus jonquilla)
The crushing can be carried out dry on the flowers or Oleander (Nerium oleander)
Lavender (Layandula officinalis)
flower tops, previously dried, or can be effected di 55 (Lavatera spp)
rectly on fresh flowers in an appropriate medium. Lilac (Syringa vulgaris)
By the expression "cohesion agent' is meant an agent White lily
Bindweed
(Lilium candidum)
(Conedvulus spp) (
capable: Lupin is (Lupinus albus)
of avoiding decantation of the finely pulverized parti Magnolia ... (Magnolia spp)
cles of the flowers or flower tops, in solution, Daisy (Chrysanthemum leucanthemum)
(Aescilus Hippocastanum)
of facilitating the spreading of the composition on the Horsechestnut
skin or the hair, Wild chamomile . . (Matricaria chamomilla)
Mallows. . . . . (Malva spp) : . . is . . . .
of avoiding the drying out of the composition when it Melilot (Melilotus officinalis) . s
is exposed to free air, and . Mint (Mentha spp)
(Hypericium perforatum)
of facilitating the removal of the composition from 65 St John's Wort
the hair or skin, Minosa . . . . . (Mimos spp) :
Lion's mouth (Antirrhinum majus)
The particles of flowers or flower tops used in the Mugget (éenvallaria maialis)
composition according to the invention can come from Myosotis (Myesotis spp)
4,459,285
3 4.
-continued common comfrey (Symphytum officinale), asparagus,
Daffodil (Narcissus spp)
senna and lichen;
White water Lily (Nymphaea alba) (ii) cellulose derivatives such as methylcellulose, hy
Gillower (Dianthus caryophylus) droxymethyl cellulose, hydroxyethyl cellulose, hydrox
Marigold (Tagetes spp) ypropyl cellulose and hydroxypropylmethyl cellulose;
Sweet orange Tree (Citrus Aurantium) (iii) synthetic polymers such as sodium polyacrylate,
Orchid
Daisy (Bellis perennis) polyvinyl alcohol and carboxylic polymer derivatives
Passion flower (Passiflora spp) of acrylic acid, such as the Carbopols.
Peach-tree (Prunus persica) The emulsion which can be of the oil-in-water or
Pelargonium (Pelargonium spp) 10 water-in-oil type constitutes a particularly preferred
Pansy (Viola spp)
Snowdrop (Galanthus nivalis) cohesion agent for the flower or flower top particles.
Periwinkle (Vinca spp) To constitute the oil phase of the emulsion, a large
Petunia
Phlox
(Petunia spp)
(Phlox spp)
variety of products can be employed, such as:
Field larkspur (Delphinium consolida) 15
(a) hydrocarbon oils including paraffin oil, Purcellin
Garden peony (Paeonia officinalis) oil, perhydrosqualene and solutions of microcrystalline
Sweat pea (Lathyrus odorantes) wax in oils;
(Polygonum spp) (b) animal oils such as whale oil, seal oil, menhaden
Apple tree (Pirus malus) oil, halibut liver oil, cod liver oil, tuna oil, tallow oil,
Primose (Primula spp)
Silver weed (Potentille Anserina) 20 beef oil, horse oil, sheep oil, mink oil, otter oil, and hog
Plum-tree (Prunus domestica) oil;
Pyrethrum (Chrysanthemum cineriaefolium) (c) vegetable oils such as almond oil, peanut oil,
Meadow Sweet (Spiraea Ulmaria) wheat germ oil, flax oil, apricot pit oil, walnut oil, palm
Buttercup (Ranunculus spp)
Rhododendron (Rhododendron ferrugineum) oil, pistachio oil, sesame oil, poppy oil, pine oil, ricin oil,
Rosemary
French Rose
(Rosmarinus officinalis)
(Rose gallica) 25 soy oil, avocado oil, safflower oil, coconut oil, hazelnut
Saffron (Crocus sativus)
oil, olive oil, grape seed oil, turnsole oil, colza oil, cade
Grass polly (Lythrum salicaria) oil, corn germ oil, peach stone oil, coffee oil, jojoba oil
Bloodroot (Sanguinaria canadiensis) and the like;
Saopwort (Saponaria officinalis) (d) mineral oils having a initial distillation point at
Sage (Salvia officinalis) 30 atmospheric pressure of about 250 C. and a final distil
Willow (Salix alba)
Devil's bit scabiou (Scabiosa Succisa) lation point in the order of 410 C.;
Syringa (Philadelphus coronarius) (e) saturated esters such as isopropyl palmitate, alkyl
Serpoilet (Thymus serpyllum) myristrates such as isopropyl myristate, butyl myristate
(Sophora japonica) and cetyl myristate, hexadecyl stearate, ethyl palmitate,
Corne (Sorbus domestica)
Marigold (Calandula officinalis) 35 triglycerides of octanoic and decanoic acids, and cetyl
Spiraea (Spiraea spp) ricinoleate.
Elder
Tamarisk
(Sambucus nigra)
(Tamaris gallica)
There can also, if desired, be added to the "oil" phase,
Tansy (Tanatecum vulgare) silicone oils soluble in other oils such as dimethylpolysi
Garden thyme (Thymus vulgaris) loxane and methylphenylpolysiloxane.
Line (Tilia spp) Further, in order to assist in the retention of the oils,
Clover (Trifolium spp) waxes such as Cornauba wax, Candellila wax, beeswax,
Tulip (Tulipa spp) microcrystalline wax and ozokerite can be used.
Coltsfoot (Tussilago affara)
Speedwell (Veronica officinalis) The emulsifying agent in the water-in-oil emulsions
Common vervain (Verbena officinalis) or oil-in-water emulsions can be of the anionic, cationic
Violet (Viola spp) 45 or non-ionic type.
Yucca (Yucca spp) Representative anionic emulsifying agents include:
alkali or alkaline earth soaps, such as for example, so
In accordance with the present invention the quantity dium stearate or calcium oleate, soaps of organic bases,
of flower or flower top particles must be present in the salts of sulfate or sulfone derivatives, oxyethylenated or
composition of the invention in a fashion to obtain good 50 not, such as sodium lauryl sulfate.
viscosity. This is generally obtained by using an amount Representative cationic emulsifiers include: quater
greater than or equal to 5 weight percent, and prefera nary ammonium salts such as, for example, benzalko
bly between 5 and 25 weight percent, this percentage nium chloride and cetyl pyridinium chloride.
being expressed as dry material. Representative non-ionic emulsifying agents include
The cohesion agent, i.e. thickening agent or substance 55 in particular: aliphatic fatty alcohols, such as cetyl alco
which can be present in an amount of 0.1 to 20 weight hol or stearyl alcohol or a mixture of the two, fatty
percent is selected from alcohols or a-diols, oxyethylenated or poly
(i) water soluble vegetable thickening agents such as glycerolated, such as oleic alcohol polyoxyethylenated
gum arabic, karaya gum, gum tragacanth, guar gum, with 10 moles of ethylene oxide, 2-octadecanediol poly
carobbean gum, taragum, pectines, alginates, carraghe 60 glycerolated with 2 or 7 moles of glycidol, cyclic fatty
nates, agar-agar, furcellaria, starches, the water soluble alcohols, glycol esters of fatty acids, such as ethylene
portions of mucilagenous plants such as those of mullein glycol stearate, mono- or di-stearates of glycerol, polye
(Verbascum spp), wild chamomile (Matricaria chamo thyleneglycol esters offatty acids, such as polyethylene
milla), fenugreek, marsh mallow (Althaea officinalis), glycol stearate, fatty esters of fatty acids of sorbitan,
mallow (Malva spp), flax, lime (Tilia spp), psyllium, 65 oxyethylenated or not, and sold under the tradename
plantain, borge (Borago officinalis), star thistle (Centau "Tweens' or "Spans' by Atlas, sucrose esters of fatty
rea calcitrapa), alder buckthorn (Rhamnus frangula), acids, esters offatty acids with glucose derivatives, such
as methylglucoside sesquistearate and methylglucoside
4,459,285
5 6
sesquistearate polyoxyethylenated with 20 moles of Pat. No. 4,185,087, Japanese patent application No.
ethylene oxide. 80.66506 and Austrian No. 71.01171, or even those men
Generally, the water phase of the emulsions represent tioned in CTFA dictionary under the name
20 to 95%, the oil phase 3 to 80% and the emulsifying “AMODIMETHICONE', such as the product com
agent 1 to 20%, relative to the total weight of the emul mercialized in admixture with other components under
SO. m
the name of cationic emulsion "DOW CORNING
The compositions according to the present invention 929'.
can also contain various cosmetic adjuvants such as pH The compositions according to the present invention
modifiers, perfumes, preservative agents, solvents, anti can also contain 0.05 to 5% by weight of an anionic
oxidant agents, sequesterants or sun screens. 10 polymer having sulfonic, carboxylic or phosphonic
According to the preferred embodiment, the compo groups and principally those mentioned in French Pat.
sitions of the present invention contain 0.05 to 5 percent No. 78.07363.
by weight of a cationic derivative and/or a cationic When the compositions according to the present
polymer. invention are used for the treatment of the skin, these
The cationic derivative is a fatty amine salt such as 15
compositions can be provided in the form of creams,
alkyl amine acetate, a quaternary ammonium salt such milks, gels, make-up, masks for the skin, depilatory,
as chlorides or bromides of alkyl dimethyl benzyl am deodorant or antiperspirant compositions, bath prod
monium, of alkyl trimethyl ammonium, of alkyl di ucts or after shave balm.
methyl hydroxyethyl ammonium, of dimethyl distearyl When the compositions according to the invention
ammonium in which the alkyl radicals have, preferably, 20 are used for the treatment of the hair, they can be pro
between 1 and 22 carbon atoms, a quaternary halide of vided in the form of shampoos, hair dye products, hair
gluconamide such as those described in U.S. Pat. No. rinse treating products for application before or after a
3,766,267, a quaternary halide of amide of mink oil such shampoo, a dye, a bleach, a permanent wave composi
as those described in U.S. Pat. No. 4,012,398, a quater tion or an uncurling composition.
nary derivative offatty halo-alkanoate of dialkylamino 25 These compositions that are employed for the treat
propyl amide such as those described in U.S. Pat. No. ment of the hair or skin can also be packaged in aerosol
4,038,294, a quaternary ammonium derivative of the containers in the presence of a propellant gas.
fatty acids of lanolin such as those described in U.S. Pat. The following non-limiting examples illustrate the
No. 4,069,347, an alkylpyridinum salt or an imidazoline present invention.
derivative. w 30
The cationic polymer is of the polyamine, EXAMPLE 1.
polyaminoamide of quaternary polyammonium type,
the amine or ammonium group being part of the poly
mer chain or being linked to it. :- - - Powder of the flowers of meadow sweet (Spiraea 300 g
The cationic polymers, such as defined above, have a 35 Ulmaria) having a granulometry between 80 microns
and 125 microns
molecular weight between 500 and 3,000,000 and are Vidogum L 175 (Extract of endosperm of 2.0 g
more particularly described in the following French Carob seed) sold by Unipectine
patent and patent application Nos.: 2,077,143; 1,492,597; Preservative, sufficient amount
2,162,025; 2,280,361; 2,252,840; 2,368,508; 1,583,363; Water, sufficient amount for 100.0 g
2,080,759; 2,190,406; 2,320,330; 2,270,846; 2,316,271;
2,336,434; 2,189,434 and 2,413,907, as well as in the This composition, having the appearance of a cream
following U.S. Pat. Nos.: 3,589,978; 4,031,307; is applied to clean hair. After a contact period of 10
3,227,615; 2,961,347; 2,273,780; 2,375,853; 2,388,614; minutes, the hair is rinsed and is soft and shiny.
2,454,547; 3,206,462; 2,261,002; 2,271,378; 3,874,870; EXAMPLE 2
4,001,432; 3,929,990; 3,966,904; 4,005, 193; 4,025,617; 45
4,025,627; 4,025,653; 4,026,945; 4,027,020; 4,185,087 and
4,131,576, incorporated herein by reference. . . . . . Powder of the flowers of mallow (Malva spp) 17.0 g
Representative preferred polymers include: having a granulometry is than 80 microns
(1) The derivatives of cellulose ethers having quater Glycerine 400 g
nary ammonium groups such as those described in 50 "Vidogum L 175" - see Ex. 1 1 g
French Pat. No. 1,492,597 and principally the polymers Preservative, sufficient amount
Water, sufficient amount for 100.0 g
sold under the names JR, such as JR 125, JR 400, JR
30M, and LR such as LR 400 and LR 30M by Union
Carbide; the cationic cellulose derivatives such as CELThis composition is applied to clean hair which is
QUAT L 200 and CELQUAT L 60 sold by National 55 then rinsed after a contact time of 20 minutes. This
Starch and described in U.S. Pat. No. 4,131,576; treatment imparted softness to the hair.
(2) The cyclopolymers such as the homopolymer of EXAMPLE 3
dimethyl diallyl ammonium chloride sold under the
tradename "MERQUAT 100', having a molecular
weight lower than 100,000 and the copolymer of di 60 pseudoacacia)
Powder of the flowers of acacia (Robinia
having a granulometry
200 g
methyl diallyl ammonium chloride and acrylamide hav between 80 microns and 125 microns
ing a molecular weight greater than 500,000 and sold Glucate SS (methylglucoside 5.0 g
under the tradename "MERQUAT 550” by Merck. sesquistearate) sold by Amerchol
These polymers are described in French Pat. No. Glucamate SSE 20 (methylglucoside 3.0 g
2,080,759 and its certificate of addition, French Pat. No. 65 sesquistearate polyoxyethylenated with
2,190,406; and 20 moles of ethylene oxide), sold by
Americho
(3) silicone cationic polymers such as those described Petrolatum oil 5.0 g
in European application Nos. 17,121 and 17,122, in U.S. Preservative, sufficient amount
4,459,285
7 8
-continued -continued
Water, sufficient amount for 1000 g Chemical
Triethanolanine 0.4 g
k Methyl paraoxybenzoate 0.3 g
In this Example, the 20g of the powder of acacia can 5 Perfume, sufficient amount
be replaced by one of the following powders: Water, sufficient amount for 1000 g
powder of the flowers of elder (Sambucus nigra)-12 g
powder of the flowers of mullein (Verbascum spp)-14 The resulting product has the appearance of a beige
9. fluid milk and an unctuous feel.
EXAMPLE 4 The powder of the flowers of cornflower can be
replaced by 5.0 g of the following powders having a
granulometry S80 microns:
Powder of the flowers of roselle (Hibiscus 8.0 g flowers of arnica (arnica montana),
spp) having a granulometry between 80 flowers of apple tree (Pirus malus), or
E. Epis 3 8.0 g flowers of gillower (Dianthus caryophyllus)-red.
Glucamate SSE 20 - see Example 3 3.0 g
Kathon CG, in 1.5% solution (mixture 0.3 g EXAMPLE 7
of 5-chloro-2-methyl 4-isothiazoline- -
3-one, 2-methyl 4-isothiazoline-3-one,
magnesium
Avocado oil
chloride and calcium chloride 3g
20 Powder of the flowers of nulle (Verbascum
spp) having a granulometry S 80 microns
7.50 g
Water, sufficient amount for 100.0 g Cetyl and steary alcohols, 30/70 5.00 g
mixture, sold under the tradename
"SIPOL 16/18 S3" by Henkel
The 8g of the roselle powder can be replaced by one 2:lysis
Colois,
E. and E.
mixture, sold under
i.30 g
of the following powders: s 25 the tradename SIMULSOLCs.
powder of French Rose (Rose gallica)-7g by Seppic
powder of Cornflower (Centaurea Cyanus)-7 g Mixture of glycerol mono- and die 1.85 g
powder of marigold (Calandula officinalis)-7g sterate, noiseiferulsifiable 9.
powder of Lavender (Lavandula officinalis)-10 g song trade name "GELEOL'
powder of the flowers of sweet orange tree (citrus 30 Petrolaturn oil 3.70 g
Aurantium)-10g. Cetyl alcohol 1.40 g
The composition is applied to wet hair. Butylhydroxytoluene 0.025 g
After aftcontact period of 15 minutes the hair is rinsed
and shin Piyyy
Extract w
of the endosperm of leguminous 0.025
0.74 gg
and is soft and shiny. guar, sold under the tradename
35 "Vidogum GH. 75' by Unipectine
EXAMPLE 5 m Preservatives, sufficient amount
Perfume, sufficient amount
Water, sufficient amount for 1000 g
Powder of wild chanomile 15.0 g
(Matricaria chamomilla) . .. . . . . ...
having a granulometry is 125 microns 40 The resulting cream is thick, shiny and unctuous and
Scid - - . . g has a khaki green color.
alcohol 05 In this Example the 7.5g of the powder of the flowers
Oxyethylenated cetylstearyl 2.0 g of mullein can be replaced by:
alcohol, sold under the tradename The powder of the flowers of acacia (Robinia
A Ap" by Henkel 3.0 45 pseudoacacia)-7.5g
Ecol 5s The powder. of the flowers of barbary fig (Opuntia
Preservative, sufficient amount vulgaris)-7.5 g, or
Water, sufficient amount for 1000 g The powder of the flowers of common heather (Calluna
vulgaris)-5g,
This composition is applied to wet hair. After a 50 each having a granulometry S 125 microns.
When the powder of the flowers of acacia is em
contact period of 20 minutes, the hair is rinsed, then ployed
shampooed. The hair thus treated, is particularly soft the cream is thick, has a dull light beige color
and a very unctious feel.
and shiny. When the powder of the flowers of common heather
EXAMPLE 6 55 is employed the cream is thick, has a beigh-gray color,
s and is very smooth to the touch.
Powder of the flowers of cornflower 5.0 g When the powder of the flowers of barbary fig is
(Centaurea Cyanus) having a employed the cream is thick and has a dull light beige
granulometry S 80 microns color.
on-ionic emulsifier havin
R i".5"E ch 1.3 g 60 EXAMPLE 8
CHOH-CH2-O-H wherein
R = C6H33 and n = 2
Non-ionic emulsifier having the same 5g Powder of the flowers of lavender 5.00 g
formula given immediately above wherein (Lavandula officinalis) having a
R = C6H33 and n = 7 65 granulometry S 80 microns
Petroiatum oil 28. g Soy lecithin i 1.80 g
High molecuia weight carboxyvinyl 0.4 g Colza oil it.00 g
polymer, sold under the trade Cocoa butter 2.35 g
name "CARBOPOL 94.1" by Goodrich Cetylalcohol 3.70 g
4,459,285
9 10
-continued -continued
Stearyl alcohol 1.80 g Soy lecithin 0.08 g
Ethylene diamine tetraacetic acid 0.045 g High molecular weight carboxyvinyl 0.30 g
Preservatives, sufficient amount polymer sold under the tradename
NaOH, 10%, sufficient for a pH of 6 - 0.2 5 *CARBOPOL934” by Goodrich Chemical
Perfume, sufficient amount Triethanolamine 0.30 g
Water, sufficient amount for 100.00 g Preservatives, sufficient amount
Perfume, sufficient amount
Water, sufficient amount for 100.00 g
The resulting cream is thick and shiny, has a caramel
color and is very smooth to the touch. 10
The powder of the flowers of lavender can be re The resulting cream is thick and has a greenish light
placed by 5.0 g of the powder of the following flowers, beige color.
the powder in each instance having a granulometry The powder of the flowers of barbary fig can be
S80 microns: replaced by the powder of the following flowers, the
the flowers of safflower (Carthamus tinctorius), 5 powder in each instance having a granulometry is 125
the flowers of honeysuckle (Lonicera spp), and microns:
the flowers of bloodroot (Sanguinaria canadiensis). the flowers of peach tree (Prunus persica),
EXAMPLE 9 the flowers of daisy (Bellis perennis), or
the flowers of live ever (Helicrysum arenarium).
2O
EXAMPLE 1.1
Powder of the flowers of sweet orange tree 13.00 g
(Citrus Aurantium) having a granulometry
S 80 microns
Cetyl and stearyl alcohols in a 30/70 2.10 g. Powder of the flowers of clover (Trifolium spp) 13.0 g
ratio, sold under the name "SIPOL 10/18 S 3' 25 having a granulometry is 125 microns
Gum tragacanth 1.7 g
by Henkel
Oxyethylenated (30 moles of ethylene oxide) 0.5 g Preservatives, sufficient amount
cetyl and stearyl alcohols in a 30/70 Water, sufficient amount for 1000 g
ratio, sold under the tradename
"SIMULSOL C.S.” by Seppic
Mixture of glycerol mono- and di-stearates, 0.9 g The product is a fluid gel having a deep chestnut
non-selfemulsifiable, sold under the
tradename "GELEOL' by Gattefosse
30 color and being smooth to the touch.
Petrolatum oil
Cetyl alcohol
5.20
0.90
g
g :
EXAMPLE 12
Butylhydroxytoluene 0.025 g
Butylhydroxyanisole 0.025 g Powder of the flowers of yarrow 6.5 g
Isopropyl myristate 2.60 g 35 (Achillea Millefolium) having a
Polydimethylsiloxane, sold under the trade- 0.90 g. granulometry is 125 microns
name "Rhodorsi huile 70047 W.300 C' or ,
"47V300C" by Rhone-Poulenc Refined extract of red algae of the
gigartinaceous family, sold under . . .
1.9 g .
Glycerine 4.30 g the tradename "Satiagum Standard'
Perfume, sufficient amount by Ceca. : s, .. v .
Preservative, sufficient amount s . . . 40
Water, sufficient amount for 100.00 g a Preservatives, sufficient amount
Water, sufficient amount for 1000 g
The resulting cream is thick and shiny, has a green The resulting product is a fluid gel which has a green
chestnut color and is very smooth to the touch.
The powder of the flowers of sweet orange tree can 45 ish chestnut color and is shiny
touch. . .
and very smooth to the
be replaced by the powder of the following flowers, the
powder in each instance having a granulometry S80 EXAMPLE. 13
microns:
the flowers of hops (Humulus lupulus), m
the flowers of garden peony (Paeonia officinalis), or 50 Powder of the extraction residue of 4.50 g
the flowers of marigold (Tagetes spp). tung having a granulometry is 125 microns s:
Powder of the flowers of mullein 5. g.
EXAMPLE 10 (Verbascum spp) having a ...
granulometry is 30 microns -
Non-ionic emulsifier having the formula, 1.10 g
Powder of the flowers of barbary fig, 9.00 g R-CHOH-CH2-O-CH2CHOH-CH2-O-His
55 where
having a granulometry between 80 microns R = C6H33 and n = 2 . i
and 25 microns Non-ionic emulsifier having the same 4.40 g
Mixture of the mono- and di-stearate of 1.80 g formula immediately above where . w
methylglucoside, sold under the tradename R = C6H33 and n = 7
Petrolatum oil ; ; , ... 27.30 g
“Glucate SS' by Americhol
Mixture of the mono- and di-stearate of 1.80 g 60 High molecular weight carboxyvinyl 0.36 g .
methyl glucoside, ethoxylated with 20 moles polymer, sold under the tradename
of ethylene oxide and sold under the tradename "CARBOPOL 94.1” by Goodrich Chemical .
"Glucomate SSE 20' by Americhol Triethanolamine 0.36 g
Petrolatum oil 8.10 g Methyl parahydroxybenzoate 0.30 g
Perhydrosqualene, synthetic 8.10 g Perfume, sufficient amount
isopropyi paimulate 2.00 g. 65 Water, sufficient amount for - . . . . .. 100.00 g
3tity is yuzury tuitiene 0.0015 g
?:'y Ytract of egg yolk without additional .30 g The resulting product is a deep green, shiny and ho
tecithin, sold by Laboratoire Industriel
de Biologie mogeneous fluid milk. 3. -:
4,459,285
11 12
EXAMPLE 14 -continued
name "SIPOL 16/18 S3' by Henkel
Cetyl and stearyl alcohols, in a 30/70 1.30 g
Soft wheat flour 6.00 g ratio, oxyethylenated with 33 moles of
Powder of the flowers of allow. 6.00 g ethylene oxide and sold under the tradename
(Malva spp) having a granulometry “SIMULSOL C.S." by Seppic
is 125 microns Mixture of glycerol mono- and di- 1.90 g
Soy lecithin 10.30 g stearates, non-selfemulsifiable and
Colza oil 9.65 g sold under the tradename "GELEOL' by
Cocoa butter 1.20 g Gattefosse
Cetyl alcohol 3.25 g 10 Petrolatum oil 3.70 g
Steary alcohol 1.60 g Cetyl alcohol 1.40 g
Ethylene diaminetetraacetic acid 0.045 g Butylhydroxytoluene 0.025 g
Preservatives, sufficient amount Butylhydroxyanisole 0.025 g
NaOH, 10% solin. sufficient amount for pH = 6 -- 0.2 Propyl parahydroxybenzoate 0.14 g
Perfume, sufficient annount Methyl parahydroxybenzoate 0.14 g
Water, sufficient amount for 100.00 g 5 Distearyl dimethyl ammonium chloride, 0.37 g
sold under the tradename 'GERMINE
DS-DAC’
The resulting cream is thick and dull; it has a violet by Hoechst
Monobutylester of the copolymer of 0.37 g
gray color and is creamy to the touch. methylvinylether/maleic acid, sold (active
EXAMPLE 1.5 20 under the tradename "GANTREZ ES 425' material)
by G.A.F.
Sodium chloride 0.09 g
Soda (1N) 0.86 m
Powder of the flowers of red poppy 9.10 g Perfume, sufficient amount
(Papaver Rhoeas) having a granulometry Water, sufficient amount for 100.00 g
a 20 microns
Hydroxypropyl cellulose, sold under 0.91 g 25
the name “NATROSOL 250 HHR" by The resulting cream is thick, beige and has an unc
Hercules tuous appearance and touch.
Preservatives, sufficient amount
Water, sufficient amount for 100.00 g EXAMPLE 18
30
The resulting gel is fluid and unctuous, and has a
shiny bordeaux color. It is very smooth to the touch. Powder of the flowers of barbary fig 12.00 g
(Opuntia vulgaris) having a granulometry
EXAMPLE 16 is 125 microns
Mixture of mono- and di-stearates of 4.98 g
35 methyl glucoside, sold under the
Powder of the flowers of elder 5.00 g tradename "Glucate SS' by Americhol
Mixture of mono- and distearates of 3.32 g
(Sambucus nigra) having a granulometry methyl glucoside, oxyethylenated
between 80 and 125 microns with 20 moles of ethylene oxide and
Cetyl and stearyl alcohols in a 30/70 5.60 g sold under the tradename "Glucanate SSE 20'
ratio, sold under the tradename by Americhol
"SIPOL 16/18 S3' by Henkel Petrolatum oil 4.15 g
Cetyl and stearyl alcohols in a 30/70 1.40 g Antioxidants, sufficient amount
ratio, oxyethylenated with 33 moles Preservatives, sufficient amount
of ethylene oxide and sold under Cationic cellulose derivative, sold 0.50 g
the tradename "SIMULSOL C.S." by . under the tradename "CELQUAT L200' (active
Seppic by National Starch material)
Mixture of glycerol mono- and di- stearate 200 g 45 Water, sufficient amount for 100.00 g
non-self emulsifiable, sold under the
tradename "GELEOL' by Gattefosse
Petrolaturn oil 4.00 g
Cetyl alcohol 1.50 g The resulting cream is thick, has a khaki color and a
Butylhydroxytoluene 0.025 g homogeneous appearance.
Butylhydroxyanisole 0.025 g 50
Preservatives, sufficient annount EXAMPLE 19
Perfume, sufficient amount
Water, sufficient amount for 100.00 g
Powder of the flowers of French Rose 5.00 g
(Rose gallica) having a granulometry
The resulting cream has a light mustard color, a fine e 80 microns
55 Cetyl and steary alcohols in a 30/70
texture and a homogeneous appearance. 5.60 g
ratio, sold under the tradename
The powder of the flowers of elder can be replaced "SIPOL 16/18 S3' by Henkel
by 5 g of the flowers of tansy (Tanatecum vulgare) hav Cetyl and steary alcohols in a 30/70 1.40 g
ing a granulometry S 125 microns. The resulting cream ratio, oxyethylenated with 33 moles of
is medium beige and has a smooth and unctuous appear ethylene oxide and sold under the trade
60 name "SIMULSOL C.S." by Seppic
ance and touch. Mixture of glycerol mono- and di-stearates, . 2.00 g
EXAMPLE 17 non-selfemulsifiable, sold under the
tradename "GELEOL' by Gattefosse
Petrolaturn oil 4.00 g
Cetyl alcohol 1.50 g
Powder of the flower of acacia 6.50 g 65 Butylhydroxytoluene 0.025 g
(Robinia pseudoacacia) having a Butylhydroxyanisole 0.025 g
granulometry s 125 microns Polymers of hydroxyethyl cellulose and 0.90 g
Cetyl and stearyl alcohols, in a 5.00 g epichlorohydrin quaternized with
30/70 ratio, sold under the trade trimethylamine, having a viscosity
4,459,285
13 14
-continued -continued
of 400 centipoises and sold under granulometry s 120 microns
the name "JR 400' by Union Carbide Powder of the rhizomes of ruscus 8.00 g
Monobutyl ester of the copolymer of 0.36 g having a granulometry between 50
methyl vinyl ether/maleic acid, sold (active 5 and 100 microns W
under the tradename "GANTREZ ES 425' material) Ethyl alcohol 15.0
by G.A.F. Propylene glycol 5.0 g
Distearyl dimethyl ammonium chloride, 0.36 g "CARBOPOL 940" (carboxyvinyl polymer). 1.0 g
sold under the tradename "GERAMINEDS-DAC' sold by Goodrich Chemicals
by Hoechst Triethanolamine 1.0 g
Sodium salt of a polyhydrocarbon acid, 1.17 g 10 Preservative 0.3 g
sold under the tradename "HYDAGEN F' (active Perfume 0.4 g
by Henkel material) Demineralized water, sufficient amount for 100 g
Sodium chloride 3.60 g
Soda (IN) sufficient amount for pH = 7 - 0.5
Perfume, sufficient annount
Preservatives, sufficient amount 5 EXAMPLE 23: Night cream
Water, sufficient amount for 100.00 g
Powder of the flowers of fumitory 2.0 g
The resulting cream is fluid, has a rose-beige color (Fumaria officinalis) having a
granulometry is 120 microns
and a homogeneous appearance. Powder of the flowers of yarrow 13.0 g
20
EXAMPLE 20 (Achillea Millefolium) having a
granulometry between 50 and 120 microns
Mixture of glycerol mono- and di-stearates 100 g
Powder of the flowers of marigold 10.00 g Cetyl alcohol 2.0 g
(Calandula officinalis) having a Stearic acid ester polyoxyethylenated 2.0 g
granulometry is 125 microns 25 with 20 moles of ethylene oxide
Mixture of mono- and di- stearates of 3.90 g Petrolatum oil 200 g
methyl glucoside, sold under the trade Perhydrosqualene 200 g
name "GLUCATE SS' by Amerchol Liquid lanolin 2.0 g
Mixture of Inono- and di- stearates of 2.60 g Soy lecithin 2.0 g
methyl glucoside, oxyethylenated with Polyethylene glycol 400 5.0 g
Preservative 0.3 g
20 moles of ethylene oxide and sold under 30 Perfume 0.4 g
the tradename "GLUCAMATESSE 20'
by Americhol Demineralized water, sufficient amount for 100 g
Pctrolatum oil 3.25 g
Antioxidants, sufficient amount
Preservatives, sufficient amount
Copolymer of dimethyldiallyl ammonium
- - -- -
EXAMPLE 24: Day Cream
chloride and acrylamide, having a (active
molecular weight 2 500,000 and sold material) Powder of the flowers of red poppy 5.0 g
under the tradename "MERQUAT 550" by Merck (Papaver Rhoeas) having a
Water, sufficient amount for 100.00 3. granulometry is 120 microns
Powder of the flowers of nullein 100 g
(Verbascum spp) having a -
The resulting cream is fluid and has a mustard color. 40 granulometry between 50 and 100 microns
EXAMPLE 21: Cream for" . oily
4
skin. . . . . . . . ... Isopropyl, myristate ,
Perhydrosqualene 10.0 g
5.0 g
-- - - -- - -- - - . . . . Stearic acid 1.0 g

Mixture of glycerol mono- and di-stearates 8.0 g


Powder of the flowers of sage 5.00 g 45 Stearic acid ester polyoxyethylenated 1.0 g
(Salvia afficinalis) having a .f with 20 moles of ethylene oxide
granulometry between 50 and 100 Petrolatum oil 15.0 g
microns Cholesterol 1.0 g
Stearic acid ester polyoxyethylenated 6.6 g Allantoin 0.5 g
with 20 moles ethylene oxide, sold Preservative 0.3 g
under the tradename "MYRJ 49' Perfume 0.35 g
by Atlas - 50 Demineralized water, sufficient amount for 100 g
Glycerol mono- and di-stearate 1.2 g
Cetyl alcohol - -- 4.2 g
Mixture of cetylstearyl alcohol and 4.0 g
sodium alkylsulfate, sold under the . .. EXAMPLE 25: Mask For Reddened Skin
tradename "SINNOWAX SX” by Henkel
Petrolatum oil : 5.0 g 55.
Cyclic dimethyl polysiloxane, sold under 5.0 g Powder of the flowers of mallow 15.0 g
the tradename "Volatile Silicone 7158' (Malya spp) having a granulometry
by Union Carbide between 50 and 120 microns -
S-carboxymethyl cysteine 1.0 g Silicate of magnesium and aluminuin 5.0 g
Triethanolamine, sufficient for pH = 6.8 sold under the tradename "WEEGUM HV'
Preservative 0.3 g 60 by Goodrich Vanderbilt
Perfune 0.3 g . . . Refined extract of red algae sold under 1.0 g
Water, sufficient amount for 100 g the tradename “AUBY GUM X2' by
Pierrefitte Auby
Titanium oxide 3.0 g
- Koalin, superior 15.0
EXAMPLE 22: Refreshing gel for the legs 65 Sorbitan Renaurate polyoxyethylenated 2.0
with 20 moles of ethylene oxide (TWEEN 20)
Glycerine 5.0 g
Powder of the flowers of arnica 8.00 g Preservative 0.3 g
(Arnica montana) having a Perfume 0.4 g
4,459,285
15 16
-continued EXAMPLE 30: Eyelid Make-up
Demineralized water, sufficient amount for 100 g
Powder of the flowers of saffron 15.00 g
(Crocus sativus) having a
EXAMPLE 26: Water-in-Oil Emulsion For Dry Skin granulometry is 75 microns
Magnesium lanolate 3.8 g.
Hydrogenated lanolin 5.7 g
Powder of the flowers of marsh mallow 15.0 g Ozokerite 15.00 g
(Althaea officinalis) having a Isopropyl palmitate 1000 g
granulometry S 120 microns 10 Paraffin oil 13.5 g
Mixture of aliphatic alcohols and waxes 200 g Titanium oxide i.5 g.
combined with saturated hydrocarbon Methyl parahydroxybenzoate 0.3 g
oils, sold under the tradename Water, sufficient amount for 100 g
"PROTEGINX” by Goldschmidt
Petrolatum oil 100 g
Glycerine 100 g 15 EXAMPLE 31: Complexion Base-Aqueous Gel
Magnesium sulfate 0.5 g
"Lipoaqualine" - hydrating complex 5.0 g
containing lacticesters of cholesterol Powder of the flowers of red poppy 8.00 g
and squalene derivatives sold by (Papayer Rhoeas) having a
Creachen G.m.b.H. granulometry is 110 microns
Preservative 0.3 g 20 Powder of the flowers of Franch Rose 2.00 g
Perfume 0.4 g (Rose gallica) having a granulometry
Demineralized water, sufficient amount for 100 g is 85 microns
Propylene glycol 1000 g
CARBOPOL 940 0.8 g
EXAMPLE 27: Make-up Remover Milk 25 Polyoxyethylenated sorbitan monolaurate 0.5 g
Ethylene diamine tetraacetic acid 0.05 g
Triethanoamine i.0 g
Mica-titanium 3.0 g
Powder of the flowers of soapwort 5.00 g Dyes, sufficient amount
(Saponaria officinalis) having a Methyl parabenzoate, sufficient amount
granulometry is 80 microns Water, sufficient amount for 100 g
Petrolatum oil 10.00 g 3O
Isopropyl palmitate 5.00 g
Tween 20 2.00 g
Stearic acid 1.4 g EXAMPLE 32: Rinse Mask for Dry Skin
Triethanolamine 0.7 g
CARBOPOL 940 0.6 g
Lysine 0.5g 35 Powder of the flowers of mullein 200 g
Propyl parahydroxybenzoate 0.1 g (Verbascum spp) having a granulometry
Water, sufficient amount for 100 g, S 70 microns
Propylene glycol 12.00 g
Titanium dioxide 0.5 g.
Gelatin 1.0 g
EXAMPLE 28: Body Milk 40 Mucilage from plantain seeds ...)
Preservative, sufficient amount
Perfume, sufficient amount
Powder of the flowers of pansy 10 g Water, sufficient amount for 100 g
(Viola spp) having a granulometry
is microns
Jojoba oil 5g 45. The resulting mask has a green color.
Turnsole oil 4 g If in this Example, the muilein is replaced by red
Avocado nonsaponifiables 6g poppy, the resulting mask has an eggplant color.
Glycerol stearate 2g
Stearic acid 1.4 g EXAMPLE 33
Triethanolanine 1.3 g
CARBOPOL 934 0.6 g 50
Methyl parahydroxybenzoate . 0.25 g . Powder of the flowers of roselle 15.00 g
Butylhydroxyanisole 0.10 g (Hibiscus spp) having a granulometry
Butylhydroxytoluene 0.10 g s 125 microns
Perfume, sufficient amount Cetyl and stearyl alcohols in a 4.60 g
Water, sufficient amount for 100 g 30/70 ratio, sold under the trade
55 name "SIPOL 16/18 S3' by Henkel
Cetyl and steary alcohols in a 1.20 g
30/70 ratio, oxyethylenated with 33
EXAMPLE 29: Hydrating Cream moles of ethylene oxide and sold under
the tradename "SIMULSOL C.S.' by
Seppic
Powder of the flowers of channonile 12 g 60 Mixture of glycerol mono- and di-stearates, i.70 g
(Anthemis nobilis) having a mon-selfemulsifiable, sold under the
granulometry is 85 microns tradename "GELEOL" by Gatefosse
Mineral oil 44 g Petroaturn oil 3.4C
Beeswax 3 g Cetyl alcohol 30
Magnesium lanolate 2.4 g Butylhydroxytoluene 0.025
Lanolin alcohol 0.6 g 65 Butylhydroxyaniisole 5
Methyl parahydroxybenzoate, sufficient amount Disteary dimethyl ammonium citeside S
Water, sufficient amount for 100 g sold under the tradename 'GERAMINES-DAC'
by Hoechst
Polydimethylsiloxane having an amine 2.42 g
4,459,285
17 18
-continued tree or dogwood, roselle, hydrangea, oleander, lilac,
magnolia, Sweet orange tree, rhododendron, syringa,
function emulsified by an emulsifier spiraea, tamarisk and yucca and said thickening agent
having a cationic and non-ionic
character, sold under the tradename being selected from gun arabic, karayagum, gum trag
"DC 92.9" by Dow Corning 5 acanth, guar gum, carbo bean gum, tara gum, pectines,
Preservative, sufficient amount alginates, carraghenates, agar-agar, furcellaria, starches,
Perfume, sufficient amount
Water, sufficient amount for 100.00 g the water soluble portions of mucilagenous plants se
lected from mullein, wild chamomile, fenugreek, marsh
mallow, mallow, flax, lime, psyllium, plantain, borage,
The resulting cream is thick and has a deep rose 10 star thistle, alder buckthorn, common comfrey, aspara
color. The cream has a very smooth and very unctuous gus, senna, lichen, methylcellulose, hydroxymethyl
appearance and texture. cellulose, hydroxyethyl cellulose, hydroxypropyl cellu
EXAMPLE 34 lose, hydroxypropylmethyl cellulose, sodium poly
acrylate, polyvinyl alcohol and carboxylic polymer
15 derivatives of acrylic acid, said particles being present
Powder of the flowers of roselle
(Hibiscus spp) having a granulometry
3.0 g in an amount of at least 5 percent by weight based on
is 125 microns the total weight of said composition and said cohesion
Powder of the roots of marsh mallow 6.5 g agent being present in an amount of 0.1 to 20 weight
(Althaea officinalis) having a percent of said composition.
granulometry s 125 microns 20 2. The composition of claim 1 wherein said particles
Cetyl and stearyl alcohols in a 2.20 g result from the pulverization of flowers or flower tops
30/70 ratio, sold under the trade
name "SIPOL 16/18 S3' by Henkel of roselle. -
Cetyl and stearyl alcohols in a 0.50 g 3. The cosmetic composition of claim 1 wherein said
30/70 ratio, oxyethylenated with cohesion agent is a thickening agent.
33 moles of ethylene oxide and sold 25 4. The composition of claim 1 wherein said particles
under the tradename "SIMULSOL C.S.'
by Seppic of pulverized flowers or flower tops have a granulome
Mixture of glycerol mono- and di-stearates,
non-selfemulsifiable, sold under the
0.90 g try lower than 80 microns.
tradename "GELEOL' by Gattefosse
5. The composition of claim 1 wherein said particles
Petrolatum oil 5.40 g 30 are present in an amount of 5 to 25 percent by weight
Cetyl alcohol s 0.90 g based on the total weight of said composition.
Butylhydroxytoluene 0.025 g 6. The composition of claim 1 wherein said cohesion
Butylhydroxyanisole 0.025 g agent is an emulsion wherein said emulsion comprises
Isopropyl myristate 2.70 g
Polydimethylsiloxane, sold under 0.90 g 20 to 95% water phase, 3 to 80% oil phase and 1 to 20%
the tradename "RHODORSL Huile emulsifying agent, said percentages being expressed
70047 V.300" or "47 V300C" by 35 relative to the total weight of said composition.
Rhone-Poulenc
Glycerine 4.50 g 7. The composition of claim 1 which also includes a
Perfume, sufficient amount cationic derivative selected from an alkyl amine acetate,
Preservative, sufficient amount a chloride or bromide of alkyl dimethylbenzyl ammo
Water, sufficient amount for 100.00 g
40
nium, of alkyl trimethyl ammonium, of alkyl dimethyl
hydroxyethylammonium, or of dimethyl stearyl ammo
The resulting cream is thick and has a very shiny nium, of quaternary halide of gluconamide, a quater
violet rose color as well as a very unctuous appearance. nary halide of mink oil; a quaternary derivative of fatty
What is claimed is: haloalkanoate of dialkylaminopropyl amide, a quater
1. A cosmetic composition for application to the hair 45 nary ammonium derivative of the fatty acids of lanolin,
or skin comprising, in an aqueous medium, particles of an alkylpyridinium salt or an imidazoline derivative.
pulverized flowers or flower tops having a granulome 8. The composition of claim 1 which also includes a
try lower than 125 microns and a cohesion agent pres cationic polymer wherein the said polymer is of the
ent in an amount effective to maintain homogeneity of polyamine, polyaminoamide or quaternary polyam
said composition, said cohesion agent being a thicken- 50 monium type, the amine or ammonium group being a
ing agent, or an emulsion selected from a water-in-oil part of the chain or being linked to it, the said cationic
3fallsion or an oil-in-water emulsion, said particles re polymer having a molecular weight between 500 and
suiting from the pulverization of flowers or flower tops 3,000,000. k. . . . . .
of shrubs selected from the group consisting of corneal
55

65

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