ENCH-633 Tutorial -2

1) Show for Redlich-Kwong EoS,

𝑅 2 𝑇𝑐2.5
𝑎 = 0.42748
𝑃𝑐
𝑏 = 0.08664 𝑅𝑇𝑐 /𝑃𝑐

2) Show for Peng-Robinson EoS

𝑅 2 𝑇𝑐2.5
𝑎 = 0.45724
𝑃𝑐
𝑅𝑇𝑐
𝑏 = 0.0778
𝑃𝑐

and express the EoS as a following cubic equation

𝑍 3 − (1 − 𝐵)𝑍 2 + (𝐴 − 3𝐵2 − 2𝐵)𝑍 − (𝐴𝐵 − 𝐵2 − 𝐵3 ) = 0
𝑎𝛼(𝑇)𝑃 𝑏𝑃
𝐴= 𝑎𝑛𝑑 𝐵 =
𝑅2𝑇 2 𝑅𝑇

3) Show the following relation between virial coefficients and van der Waals parameters
𝑎
𝐵=𝑏− 𝑎𝑛𝑑 𝐶 = 𝑏 2
𝑅𝑇

𝜕𝑃
4) Show that 𝑑ℎ = [𝑇 ( ) − 𝑃] 𝑑𝑣 + 𝑑(𝑃𝑣) + 𝑐𝑣 𝑑𝑇
𝜕𝑇 𝑣

5) Calculate residual properties (𝐾 𝑟𝑒𝑠𝑖𝑑𝑢𝑎𝑙 (𝑃, 𝑇) = 𝐾(𝑃, 𝑇) − 𝐾 𝑖𝑑𝑒𝑎𝑙 𝑔𝑎𝑠 (𝑃, 𝑇)) using EoS

𝑉 𝜕𝑃
a. Show that 𝐻𝑅 = ∫∞ [𝑇 ( ) − 𝑃] 𝑑𝑉 + 𝑃𝑉 − 𝑅𝑇
𝜕𝑇 𝑣
b. For SRK-EoS, Derive an expression for 𝐻 𝑅

6) Problem numbers: 4.10, 4.15, 4.31, 4.49, Chapter 4 from “Engineering and Chemical
Thermodynamics”, 2nd Ed., by Koretsky, M.D., John Wiley & Sons, USA (2013).