PUNTO 2

clear all
clear all
NC=4 % numero de compuestos

%interaccion

Aij=[0 0 -1.1512 -0.8009;0 0 0 -1.9763; -0.2431 0 0 -3.7198; 3.4578

3.3293 9.4632 0]

Bij=[0 225.476 524.424 246.18; -252.482 0 -235.279 609.889; 282.956

515.821 0 1286.14;-586.081 -723.888 -1705.68 0]

Cij=[0 0.3 0.3 0.3; 0.3 0 0.3 0.3 ; 0.3 0.3 0 0.2; 0.3 0.3 0.2 0]
%antoine

Ai=[5.33675 4.54456 4.13361 5.11564]

Bi=[1648.22 1555.12 1195.13 1687.537]

Ci=[230.98 224.65 212.47 230.17]

%presion de rocio
Yi=[0.1 0.3 0.2 0.4]

T=90+273.15 %°c
R=8.32 % cal/mol K
bij=[1.4 2.5 1.3 1.55;2.5 4.5 2 2.5;1.3 2 0.53 1.3;1.55 2.5 1.3 1.7]

for i=1:NC

Psati(i)= exp(Ai(i)-Bi(i)/((T-273.15)+Ci(i)))

end

for i=1 :NC

for j=1 :NC
dji(i,j)=2*bij(j,i)-bij(j,i)-bij(i,i)
for k=1 :NC
djk(j,k)=2*bij(j,k)- bij(j,j)-bij(k,k)
end
end
end

fi=ones(1,NC)
errorf=10
while errorf>0.00001
%suponer gamma

gi=ones(1,NC)

errorg=10

while errorg>0.00000001
%calculo de presión
for i=1:NC

YifigiPsati(i)=(Yi(i)*fi(i))/(gi(i)*Psati(i))

end

P=1/sum(YifigiPsati)

for i=1:NC

xi(i)=(Yi(i)*fi(i)*P)/(gi(i)*Psati(i))

end

for i=1:NC

Xi(i)=xi(i)/(sum(xi))

end

for i= 1: NC

for j=1: NC

Tij(i,j)=Aij(i,j)+Bij(i,j)/(T)

Gij(i,j)=exp(-Cij(i,j)*Tij(i,j))

end

end

for i =1 :NC

for j =1 :NC

Tij(i,j)=Aij(i,j)+ Bij(i,j)/(T)

Gij(i,j)=exp(-Cij(i,j)*Tij(i,j))

end

end
for i=1:NC

for j =1:NC

TjiGjiXj(j)=Tij(j,i)*Gij(j,i)*Xi(j)

for k=1:NC

GkjXk(k)=Gij(k,j)*Xi(k)

TkjGkjXk(k)=Tij(k,j)*Gij(k,j)*Xi(k)

GkiXk(k)=Gij(k,i)*Xi(k)

end

sumatoria(j)=(Xi(j)*Gij(i,j)/sum(GkjXk))*(Tij(i,j)-
(sum(TkjGkjXk)/sum(GkjXk)))

gic(i)=exp((sum(TjiGjiXj)/sum(GkiXk))+sum(sumatoria))

end

end

for i =1 :NC

errorgi(i)=abs((gi(i)-gic(i))/gic(i))

end

errorg=sum(errorgi)

gi=gic

end

for i=1 :NC

for j=1 :NC
for k=1 :NC
yjykdjidjk(k)=Yi(j)*Yi(k)*(2*dji(j,i)-djk(j,k))
end
sumadoble(j)=sum(yjykdjidjk)
end
sumadobleterm=sum(sumadoble)
end
for i=1 :NC
fic(i)=exp((bij(i,i)*(P-Psati(i))+0.5*P*sumadobleterm)/(R*T))
end

for i=1:NC
errorfi(i)=abs((fi(i)-fic(i))/fic(i))

end

errorf=sum(errorfi)

fi=fic

end