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Lightweight ceramic composite armour system

E. Medvedovski
The development of lightweight armour systems for ballistic protection is under continuing
attention of the manufacturers and users. A new design of the composite armour systems has
been developed and ballistically tested. A new armour system consists of a ceramic plate, an
intermediate ceramic–polymer layer and a polymer fibre lining as a backing material. The
proposed composite armour systems prepared with a use of specially selected compositions of
the intermediate layer promoting the absorption of the kinetic energy of projectiles provide
adequate ballistic protection to National Institute of Justice (NIJ) level III and level IV, and they
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successfully withstand multiple hits.


Keywords: Ceramics, Composites, Armour, Ballistic performance

Introduction such as Kevlar or Twaron (the number of aramid fabric


layers depends on the ballistic requirements, type of
During the last decade, intensive studies are devoted to fabrics and ceramic performance) can stop a variety of
the development of lightweight armour systems for projectiles. In general, the thinner the ceramic plate, the
personnel and vehicular applications, which are desig- greater the number of aramid fabric layers or other
nated for multihit situations.1–5 Advanced ceramics is backing materials is required. Some examples of the
one of the important components of the armour ballistic protection of armour systems consisted of
systems; ceramics assist to defeat projectiles through alumina ceramic plates and Kevlar backing with
the ballistic impact energy dissipation. Usually ceramic different thicknesses are performed by Ravid et al.5
armour systems consist of a front monolithic ceramic Practical experience shows that a decrease in a ceramic
plate covered by ballistic nylon and bonded with a lining plate thickness of 0.5–1 mm, when the thickness ranges
from high tensile strength fibres, such as Kevlar, Twaron from 5 to 7 mm, may require a significant increase in
and Spectra; in some cases, soft metallic layers may be aramid backing. The systems based on 5–5.5 mm
used. Upon ballistic impact (projectile velocity .700– ceramic plates (all types of ceramics) require thick
800 m s21), the hard ceramic body used is cracked and aramid backing. In this case, aramid backing made of
broken, and the residual energy is absorbed by the soft flexible fibres with a small diameter of filaments (the
reinforced backing material. This backing material also materials, such as Kevlar 129 or KM or Twaron T-flex
must support the post-impact fracturing of the ceramic with 1000–600 denier v. Kevlar 29) are preferable. The
body and the defeated bullet. systems based on thin ceramic plates with a thickness of
Different ceramics are used as armour materials; they 4.5–5.5 mm bonded with laminated polyethylene back-
include some oxide ceramics (mostly, alumina ceramics ing, e.g. Spectra (20–25 mm thickness) have been shown
with different Al2O3 contents) and non-oxide ceramics to successfully defeat even armour piercing (AP)
(carbides, nitrides, borides, such as materials based on projectiles with a tungsten carbide (WC) core. In many
B4C, SiC, Si3N4, AlN and some others). These materials cases, more complicated designs based on the face
have high mechanical properties (e.g. hardness, Young’s ceramics and backing made from different materials
modulus, strength). Also ceramic matrix composite (e.g. aluminium plus Kevlar or some other combina-
materials, which may be reinforced with whiskers, fibres, tions) increase performance; however, it may decrease
particulates, or cermets prepared by the infiltration manufacturing productivity and, hence, increase the cost
routes may be used owing to their mechanical properties of the armour. In general, armour systems are designed
and impact energy dissipation ability. based on the requirements of performance, weight,
Ceramic armour systems may be designed taking into application and manufacturing ability.
consideration several different factors, including the Fracturing of ceramic armour systems upon ballistic
properties of the armour components. The nature and impacts was studied by a number of authors.5–9 They
thickness of backing materials may have a significant noted several stages of ceramic fracturing. As noted,6
influence on crack propagation owing to their own this process includes: initial impact with hydrodynamic
abilities to reduce the stress. Ceramic plates with flow of penetrator and armour ceramics; breakup and
thicknesses of 7–9 mm bonded with aramid fabrics, continued flow of penetrator and high speed jetting of
debris; ceramic fracture, formation of Hertzian cone
cracks and tensile cracks on the back face with
Umicore Indium Products, 50 Sims Ave., Providence, RI 02909, USA continued penetrator breakup and flow; erosion of
(formerly with Ceramic Protection Corporation, Canada) penetrator and widespread fracture of the ceramics. At
*Corresponding author, email emedvedovski@cox.net increased bullet velocities, the energy transmission

ß 2006 Institute of Materials, Minerals and Mining


Published by Maney on behalf of the Institute
Received 21 January 2006; accepted 21 April 2006
DOI 10.1179/174367606X113537 Advances in Applied Ceramics 2006 VOL 105 NO 5 241
Medvedovski Lightweight ceramic composite armour system

through ceramic armour and across boundaries via Armour system design and
shock waves becomes more valuable, i.e. the ability of
ceramics to dissipate the bullet kinetic energy and to
manufacturing
prevent the crack propagation is very important. During A new lightweight composite armour system design has
the ballistic impact, the disintegration of the ceramic been proposed. This system consists of the following
plate into particles ranging from a very fine powder to three major components:
relatively large fragments (up to several square centi- (i) an armour face plate made from ceramics with
metres) is occurring. The impact area of a ceramic is high hardness and mechanical properties in order
comminuted and compacted under the compressive to brake the bullet and to dissipate its impact
action of the projectile. energy
Different kinds of cracks may be formed during the (ii) an aramid based backing material for impact
ballistic impact. A locus of conoidal coaxial cracks starts energy absorption and for stopping the bullet
at the impact point; while radial tensile cracks are and occurred fragments
initiated at the back surface close to the axis of impact. (iii) a ceramic–polymer ‘separating’ layer.
Star cracks are formed at the side of conoids. Tangential As the face component, ballistic grade plates made from
spall cracks occur owing to shear stress waves reflected high alumina ceramics, alumina–mullite ceramics and
from the edges of a plate and owing to the formation of reaction bonded silicon carbide ceramics (RBSC) with a
the cone cracks; lateral spall cracks may also form owing high level of mechanical properties (hardness, strength,
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to the longitudinal stress waves reflected from the etc.), relatively low brittleness, optimised microstructure
backing support. Fragments of damaged ceramics with and ballistic impact energy dissipation ability were used.
different sizes ranging from big chunks to a fine powder The properties (summarised in Table 1), structures and
are noted after fracturing. As noted, cracks formation manufacturing features of these ceramic materials were
owing to the wave reflection from the backing may have described earlier.4 These selected ceramic materials
a significant effect on the ceramic destruction. provide multihit ballistic performance of the armour
Especially, it is important when a ceramic front plate systems, and they are relatively inexpensive; because of
has a small thickness, e.g. ,6 mm. In this case, the these reasons the mentioned materials were selected
armour system is generally weak owing to insufficient among other armour ceramics. Ceramic plates were used
erosion of the projectile penetrating through a thin as two types of thicknesses, i.e. ‘thin’ plates made from
ceramic. A shock wave reflection from the backing alumina AL98, alumina–mullite AM2 and RBSC
results in the weakening of the armour system. In order ceramics with a thickness of 4.0–4.5 mm (such type of
to provide the adequate ballistic protection, a relatively plates should significantly reduce weight of armour
thick layer of the backing is required. If ceramic plates systems) and ‘thick’ plates made from alumina and
are relatively thin (,6 mm) and in the case of the use of alumina–mullite ceramics with a thickness of 8.0–
aramid backing, the fabric based on the filaments with 8.5 mm. The alumina or alumina–mullite plates of 8.5–
small diameters (1000–600 denier) and a high flexibility 9 mm were used for the AP testing. The plates had a
should be used. Such types of aramid backing are rather single curve configuration with a general format of
expensive, and a use of very many plies of these aramid approximately (200–270)6(2506320) mm, i.e. nor-
fabrics requires, as practical experience shows, intensive mally used for personnel protection. Also flat tiles of
labour involvement. However, even in this case, the similar formats and above mentioned thicknesses were
adequate protection is hardly achieved, especially, if a used.
thickness of the ceramic plates is in the range of 4– As the backing materials, commercially used Kevlar
4.5 mm, i.e. when a decrease in the weight of armour or Twaron ballistic fabrics were used. Types and
systems is attained by a decrease in a thickness of thicknesses of these backing materials were selected
ceramics. depending on the thickness of the face ceramic plates.
A use of more complex armour may increase ballistic The compositions of the intermediate ceramic–
protection; however, the weight of armour systems is polymer layer have been developed. As the ceramic
still one of the critical factors. As one of the directions of ingredient of these compositions, either lightweight solid
the lightweight armour system design, a ‘separation’ of ceramic filler, such as relatively coarse boron carbide or
the front ceramic plate and aramid based backing may silicon carbide powders, or hollow (bubble) alumina
be effective. However, in this case, a whole system ceramic spheres (manufactured by PEM-Pechiney,
should be bond properly, and a ‘separating’ layer should France) were used. The particle size distribution of the
not decrease the armour system performance. used ingredients was taken into consideration in order to

Table 1 General properties of ceramics used for studied composites

Properties AL98 AM2 RBSC

Density, g cm23 3.80–3.82 3.52–3.56 3.0–3.05


Young’s modulus, GPa 325–360 230–245 320–350
Sonic velocity, km s21 10.0–10.5 8.6–8.7 10.5–11.0
Vickers hardness*, GPa 12.2–12.9 11.0–11.2 23.0–24.0
3.0–3.3 2.5–2.6 2.2–2.5
.
Fracture toughness KIc, MPa m0 5
Flexural strength, MPa 300–350 330–350 190–240
Brittleness B, 61026 m21 370–430 400–420 –
Ballistic energy dissipation criterion D, 610212 s21 (calculated) 1.50–1.60 1.20–1.40 –
*Tested at the load of 10 kg for AL98 and AM2 ceramics and at 1 kg for RBSC ceramics for the major grains.

242 Advances in Applied Ceramics 2006 VOL 105 NO 5


Medvedovski Lightweight ceramic composite armour system

trauma after shooting was evaluated using a Roma


Plastilina modelling clay placed behind the armour
system; the trauma in clay shows the transient deforma-
tion of the composite on the back of the system. The
damage zone of the ceramics, including ceramic
fragmentation, and the subsequent post-impact condi-
tion of the bullet, were observed. Multihit performance
of the armour systems was evaluated, i.e. the plates were
shot using 3 or 6 rounds of NATO Ball and LPS
ammunitions with a required distance between shots.
Armour systems were selected for testing depending on
the ammunition. The armour systems based on ‘thin’
alumina, alumina–mullite and RBSC plates were tested
for NATO Ball and LPS threats, while armour systems
based on ‘thick’ alumina and alumina–mullite plates
were tested for NATO Ball and AP threats.

Ballistic testing results


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1 Ballistic test results (7.62654R LPS, 3 rounds) for the


The composite armour systems of the proposed designs
proposed armour system based on 4.5 mm AM2 single
tested in accordance with the mentioned procedure
curve ceramic plate (left – front face, right – back
demonstrated satisfactory multihit (3 or 6 rounds)
face)
ballistic performance defeating projectiles (NATO Ball
and LPS ammunition) and one AP round. The example
of the ballistic test results is exhibited in Fig. 1 and
achieve adequate compaction of the ceramic particles at
Table 2. The plates with optimised designs and bonding
acceptable ability to mix them. From the weight
technique did not exhibit delamination of the backing
concern, hollow spheres are preferable. These composi-
material after ballistic testing. Upon ballistic impacts,
tions can be easy prepared by the mixing of selected
the front ceramic plates were fracturing. They had the
fillers (solid or hollow particles) with proper polymeric
cracks described above; however, the cracks related to
ingredients. A number of special compositions consisted the shock wave reflection practically were not observed.
of lightweight ceramic fillers and polymer substances The crack formation of the ballistically impacted
were prepared; these mixes cured and hardened pretty ceramic plates may be observed in Figs. 2 and 3.
fast; however, there was enough time between mixing In comparison with a ‘conventional’ design (front
and hardening, i.e. these compositions provided an ceramic plates bonded with aramid backing consisted of
acceptable workability. The curing did not require a selected amount of laminated plies), the proposed
special expensive thermal equipment. designs demonstrated improved ballistic performance.
The manufacturing of these armour systems includes The proposed design with a use of ‘thick’ ceramic plates
bonding of the ceramic armour plates with a ‘separating’ (8–8.5 mm) allowed to reduce substantially the quantity
layer and then bonding with a backing. Prepared mix for of the backing material layers (comparatively with a
the intermediate layer was placed onto the back face of ‘conventional’ design) with adequate ballistic perfor-
ceramic plates wrapped with fibreglass (prepreg). In mance (successfully defeated 3 or 6 rounds of NATO
order to maintain a consistent thickness of this layer and Ball and LPS ammunitions and 1 round of the AP
also for its use for the body armour plates with special ammunition) that resulted in a cost reduction in the
curvatures, special polymeric (aramid) honeycomb materials utilised for the manufacturing (the backing
structures were used. After the curing of the intermedi- materials such as Kevlar or Twaron have the highest
ate ‘separating’ layer, the bonding of the backing was cost among the used armour system components). In the
carried out in the autoclave using a commercial case of ‘thin’ ceramic armour plates (4.0–4.5 mm), the
procedure for the bonding of armour ceramics with effect of the proposed design was even more significant.
backing materials. The ‘conventional’ armour systems based on such
ceramic plates bonded with aramid backing could not
Ballistic testing defeat 3 rounds of the projectile (both NATO Ball and
LPS ammunitions) or required an extremely high
The ballistic performance of the proposed composite number of the plies. In general, velocity and energy of
armour systems was tested using weapons such as the the projectile are reduced by the solid hard ceramic front
M16, AK47 and some others (caliber 0.30). Depending plate; however, in the case of ‘thin’ ceramic plate, the
on the application and the required level of protection, residual velocity and energy of the projectile are still
the ammunition 7.62651 mm NATO Ball full metal high enough for penetration in the case of the
jacket (FMJ) with a lead core, 7.62654R light ‘conventional’ design. Opposite to them, the proposed
penetrating steel (LPS) with a steel core and systems with even lower numbers of aramid plies
7.62663 mm AP M2 with a WC core were used. successfully defeated both NATO and LPS projectiles
Depending on the ammunition, the bullet weight, (3 rounds of each to one plate) with acceptable trauma
velocity and energy were varied, e.g. the bullet velocities (i.e. not greater than 40 mm). At the same time, the
for the mentioned projectiles were 830–870, 700–730 and weights of the armour systems were not greater than
820–870 m s21 respectively. The bullet velocity during 2.5 kg. For example, the armour systems based on
testing was measured using an optical chronograph. The 4.5 mm alumina–mullite (AM2) ceramic plates bonded

Advances in Applied Ceramics 2006 VOL 105 NO 5 243


Medvedovski Lightweight ceramic composite armour system

2 Crack formation at AM2 ceramic plate after ballistic 3 Crack formation at RBSC ceramic plate after ballistic
impact (7.62651 mm NATO Ball FMJ); backing material impact (7.62651 mm NATO Ball FMJ); backing material
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was removed was removed

protection against the ‘shock waves from the backing,


with a ceramic (bubble alumina)–polymer ‘separating’ promotes to the overall structure a capacity to plastic
layer and aramid backing had a total weight of 2000– deformation. The hard ceramic grits compacted by a
2100 g. It should be noted that, despite lower mechan- proper manner or, especially, hollow ceramic spheres
ical properties (hardness, fracture toughness, sonic provide to the structure a multiplicity of surfaces and
velocity) of alumina–mullite ceramics in comparison thus a multiplicity of cracks initiation sites. Owing to the
with high alumina ceramics, the armour systems made hollow shape of spheres, the cracks initiated cannot
with a use of these materials require the same thickness propagate within these spheres, i.e. these spheres
of backing material and have the same level of ballistic significantly improved the energy dissipation upon the
performance; but the use of AM2 ceramics provides ballistic impact. The projectile is thus always facing new
some decreases in weight of the armour systems owing surfaces of the hard material. Because of these particles
to its lower density (3.52–3.56 versus 3.8–3.85 g cm23). (grains or spheres), the part of residual energy of the
In the case of the use of RBSC ceramics, the armour projectile is used to initiate a multiplicity of cracks at the
systems required some increase in thickness of the surface of those particles. This intermediate layer
ceramic plates (up to 5.0–5.5 mm) to obtain adequate promotes the absorption of kinetic energy of the
ballistic performance. The ‘conventional’ system design projectile. Honeycomb used for the intermediate layer
also required thicker RBSC plates (5.5–6.0 mm) and preparation provides rigidity of the structure of this
more backing. layer and reduces deformation of the armour system.
The improved performance of the proposed designs The erosion of the projectile against the surfaces of
relies on the point that the ‘separating’ layer, besides the the ceramic grits or fragmented microspheres also

Table 2 Ballistic test results of some armour systems*{

Armour system Weight, g Testing Trauma, mm Penetration

Plate AM (4.5 mm)zbacking 1980–2080 NATO Ball, 3 rounds 25 Complete penetration of the second
and third rounds
Plate AM (4.5 mm)zcp (SiC)zbacking 2050–2150 NATO Ball, 3 rounds 25–33 No complete penetration
(thinner than no. 1)
Plate AM (4.5 mm)zcp (BA)zbacking 2000–2100 NATO Ball, 3 rounds 20–26 No complete penetration
(thinner than no. 1)
Plate RBSC (5.5 mm)zbacking 2250–2300 NATO Ball, 3 rounds 33–38 Complete penetration of the
third round
Plate RBSC (5.2 mm)zcp (SiC)zbacking 2350–2450 NATO Ball, 3 rounds 28–40 No complete penetration
(thinner than no. 4)
Plate RBSC (5.2 mm)zcp (BA)zbacking 2300–2400 NATO Ball, 3 rounds 30–38 No complete penetration
(thinner than no. 4)
Plate AL98 (8.5 mm)zbacking 2150–2200 NATO Ball, 6 rounds 25–40 No complete penetration
Plate AL98 (8.5 mm)zcp (BA)zbacking 2200–2250 NATO Ball, 6 rounds 20–35 No complete penetration
(thinner than no. 7)
Plate AL98 (9 mm)zbacking 2700–2750 AP, 1 round 35 No complete penetration
Plate AL98 (9 mm)zcp (BA)zbacking 2750–2800 AP, 1 round 30 No complete penetration
*cp – ceramic–polymer layer, BA – bubble alumina.
{
In the case of penetration, trauma was not measured. The weight comparison between armour systems may be possible only for the
same types of systems (e.g. based on AM thin plates with different backings); the comparison between thin and thick plate systems is
not possible owing to different system designs and different formats of plates (e.g. AL98 plates shot with AP had large formats and
another backing system than AL98 plates shot with NATO Ball). The systems based on thin plates had similar performance in the case
of shooting with NATO and LPS projectiles.

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Medvedovski Lightweight ceramic composite armour system

greatly promotes limiting the capacity of this projectile of the intermediate layer with the selected lightweight
to further penetrate within the armour. Hard sharp ceramic filler promoted the formation of multiplicity of
ceramic grits’ or fragmented ceramic spheres have a high surfaces upon ballistic impact and increased kinetic
level of abrasiveness that additionally destroys the energy absorption, the decrease in the crack propaga-
projectile during its penetration to the armour system. tion, especially shock wave induced cracks, and addi-
The particle size distribution of the ceramic grits or tional erosion of the projectile. The developed armour
microspheres was specially selected to provide a higher systems are lightweight; the weight of the composite
compaction between these particles to decrease the systems based on thin alumina–mullite ceramic plates of
volume occupying by the bonding phase, and, therefore, actual format provided acceptable multihit protection
to increase the erosion of the projectiles. It was noted that against NATO Ball and LPS ammunitions may be
in the case of the use of hard SiC or B4C grits as the filler, decreased up to 2000–2100 g. The proposed composite
the erosion of the projectiles tended to be visually greater design may be used for armour systems for personnel,
than in the case of the use of bubble alumina. It may be vehicular and structural protection.
easy explained by the comparison of hardness and
abrasiveness of these materials. This erosion was easy Acknowledgement
observed for the NATO Ball projectiles, which have a
‘mushroom’ shape after ballistic impacts. Also increased The participation of the specialists of Ceramic
fragmentation was observed for the AP projectiles if the Protection Corporation (Calgary, AB, Canada), which
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proposed systems with SiC or B4C grits were used. the author worked with, is appreciated greatly.

Summary References
A new proposed armour system design consisted of a 1. W. A. Gooch, Jr: Brit. Ceram. Trans., 2002, 134, 3–21.
front ceramic plate, intermediate lightweight ceramic– 2. B. A. Gama, T. A. Bogetti, B. K. Fink, C. J. Yu, T. D. Claar and
polymer layer and aramid backing’ demonstrated a high H. H. Eifert: Compos. Struct., 2001, 52, 381–395.
level of ballistic performance defeating 7.62651 mm 3. R. A. W. Mines: Compos. Struct., 2004, 64, 55–62.
NATO Ball FMJ, 7.62 54R LPS and 7.62663 mm AP 4. E. Medvedovski: Brit. Ceram. Trans., 2006, 178, 3–17.
5. M. Ravid, S. Chocron and S. R. Bodner: Brit. Ceram. Trans., 2003,
M2 projectiles depending on the thickness of the front 151, 145–152.
ceramic plate. The proposed armour systems demon- 6. D. J. Viechnicki, M. J. Slavin and M. I. Kliman: Am. Ceram. Soc.
strated higher ballistic performance comparatively with Bull., 1991, 70, (6), 1035–1039.
‘conventional’ armour systems based on front ceramic 7. V. D. Frechette and C. F. Cline: Am. Ceram. Soc. Bull., 1970, 49,
(11), 994–997.
plates and aramid backing that allows to reduce the
8. D. Sherman and D. G. Brandon: J. Mater. Res., 1997, 12, (5),
thickness (a number of plies) of the backing. The 1335–1343.
improved ballistic performance is achieved owing to the 9. E. B. Zaretsky, V. E. Paris, G. I. Kanel and A. S. Savinykh: Brit.
three component design with the developed composition Ceram. Trans., 2003, 151, 105–115.

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