Professional Documents
Culture Documents
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1.2. Relevant identified uses of the substance or mixture and uses advised against
Company Name
BOSTIK SA
AEC Polymers
ZI d'Eyrialis
6, rue Guy Pellerin
Le Barp, 33114
France
Tel: +33(0)5 57 26 15 15
Fax: +33 (0)5 56 36 75 23
Contains Methyl methacrylate, 2-propenoic acid, 2-methyl,-2-hydroxyethyl ester, phosphate, Bisphenol-A-Epichlorhydrin Epoxy
resin <= 700 MW, Dodecyl methacrylate
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Signal Word
DANGER
Hazard statements
H335 - May cause respiratory irritation
H315 - Causes skin irritation
H317 - May cause an allergic skin reaction
H318 - Causes serious eye damage
H225 - Highly flammable liquid and vapour
Additional information
Please refer also to Safety Data Sheet of Part B
General Hazards
In use may form flammable/explosive vapour-air mixture. Polymerises with evolution of heat.
Mixture
3.2 Mixtures
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Skin Sens. 1
(H317)
Methacrylic acid 201-204-4 79-41-4 1- <2.5 Acute Tox. 4 STOT SE 3 :: C>=1% 01-2119463884-26
(H302) -xxxx
Acute Tox. 3
(H311)
Skin Corr. 1A
(H314)
Acute Tox. 4
(H332)
STOT SE 3 (H335)
Bisphenol-A-Epichlorhydrin 500-033-5 25068-38-6 1- <2.5 Skin Irrit. 2 (H315) Eye Irrit. 2 :: C>=5% 01-2119456619-26
Epoxy resin <= 700 MW Eye Irrit. 2 (H319) Skin Irrit. 2 :: C>=5% -xxxx
Skin Sens. 1
(H317)
Aquatic Chronic 2
(H411)
4-bromo-N,N-dimethylanilin 209-582-2 586-77-6 0.1 - <1 Water-react. 2 No data available
e (H261)
STOT SE 3 (H335)
STOT RE 2
(H373)
Skin Irrit. 2 (H315)
Eye Irrit. 2 (H319)
Skin Sens. 1
(H317)
Acute Tox. 4
(H302)
Acute Tox. 4
(H312)
Acute Tox. 4
(H332)
Aquatic Chronic 4
(H413)
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(H317)
Carc. 2 (H351)
Acute Tox. 4
(H332)
This product does not contain candidate substances of very high concern at a concentration >=0.1% (Regulation (EC) No. 1907/2006
(REACH), Article 59)
General Advice Remove and isolate contaminated clothing and shoes. In case of accident or being
unwell, seek medical advice immediately (show directions for use or safety data sheet if
possible).
Inhalation Move to fresh air in case of accidental inhalation of vapours. If breathing is difficult, give
oxygen. If breathing is irregular or stopped, administer artificial respiration. Avoid direct
contact with skin. Use barrier to give mouth-to-mouth resuscitation. Immediate medical
attention is required.
Skin Contact Wash off immediately with soap and plenty of water while removing all contaminated
clothes and shoes. Wash contaminated clothing before reuse. May cause sensitisation
by skin contact. In the case of skin irritation or allergic reactions see a doctor.
Eye contact In case of contact with substance, immediately flush skin or eyes with running water for
at least 20 minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
Keep eye wide open while rinsing. Call a doctor immediately.
Ingestion Drink plenty of water. Never give anything by mouth to an unconscious person. If
swallowed, do not induce vomiting: seek medical advice immediately and show this
container or label.
Self-Protection of the First Aider Use personal protection recommended in Section 8. Isolate the hazard area and deny
entry to unnecessary and unprotected personnel. Ensure that medical personnel are
aware of the material(s) involved and take precautions to protect themselves. Remove
all sources of ignition.
4.2. Most important symptoms and effects, both acute and delayed
Symptoms Repeated or prolonged skin contact may cause skin irritation and/or dermatitis and
sensitisation in susceptible persons.
4.3. Indication of any immediate medical attention and special treatment needed
Note to doctors Treat symptomatically. May cause sensitisation of susceptible persons. May cause
sensitisation by skin contact.
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Use water spray or fog; do not use straight streams
Carbon monoxide, carbon dioxide and unburned hydrocarbons (smoke). Hazardous polymerisation may take place during a
fire due to heat. Closed containers could violently rupture. Vapours may travel to source of ignition and flash back.
FLAMMABLE. May cause sensitisation by skin contact.
Personal Precautions
Remove all sources of ignition. Use personal protective equipment as required. Evacuate personnel to safe areas. Ensure
adequate ventilation, especially in confined areas. All equipment used when handling the product must be grounded. Stop leak
if you can do it without risk. Keep people away from and upwind of spill/leak. Do not touch or walk through spilled material.
Water spray may reduce vapour; but may not prevent ignition in closed spaces.
Prevent further leakage or spillage if safe to do so. Do not flush into surface water or sanitary sewer system. Prevent entry into
waterways, sewers, basements or confined areas. Do not empty into drains, dispose of this material and its container at
hazardous or special waste collection point. See Section 12 for additional Ecological Information.
Methods for Containment Prevent further leakage or spillage if safe to do so. A vapour suppressing foam may be
used to reduce vapours. Dyke far ahead of spill; use dry sand to contain the flow of
material. Contain and collect spillage with non-combustible absorbent material, (e.g.
sand, earth, diatomaceous earth, vermiculite) and place in container for disposal
according to local / national regulations (see Section 13).
Methods for cleaning up Use personal protective equipment as required. Dam up. Soak up with inert absorbent
material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Use clean
non-sparking tools to collect absorbed material. Pick up and transfer to properly labelled
containers. Clean contaminated surface thoroughly.
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dust/fume/gas/mist/vapours/spray. Avoid contact with skin, eyes or clothing. Eyewash fountains should be provided in areas
where there is any possibility that workers could be exposed to the substances; this is irrespective of the recommendation
involving the wearing of eye protection. After contact with skin, wash immediately with plenty of water and soap. Wash
contaminated clothing before reuse.
Storage Conditions
Keep only in the original container/package in a cool well-ventilated place. Keep container tightly closed and dry. Protect from
sunlight. Keep away from heat, sparks, flame and other sources of ignition (i.e., pilot lights, electric motors and static
electricity). Recommended storage temperature. 5 - 25 °C. Store at temperatures not exceeding 25 °C/ 77 °F.
Specific Use(s)
Observe technical data sheet.
OTHER INFORMATION
Recommendation(s). Observe technical data sheet.
Exposure Limits This product contains substances which in their raw state are powder form, however in
this product they are in a non-respirable form. Inhalation of powder/dust particles is
unlikely to occur from exposure to this product.
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Eye/Face Protection Tight sealing safety goggles. Face protection shield.
Hand Protection Wear protective gloves. The breakthrough time of the gloves depends on the material
and the thickness as well as the temperature.
Skin and Body Protection Antistatic footwear. Wear fire/flame resistant/retardant clothing. Suitable protective
clothing.
Respiratory Protection In case of mist, spray or aerosol exposure wear suitable personal respiratory protection
and protective suit. In case of inadequate ventilation wear respiratory protection.
Recommended filter type: This product should not be used under conditions of poor ventilation unless a protective
mask with an appropriate gas filter (i.e. Type A according to standard EN 14387) is used.
Environmental Exposure Controls Do not allow into any sewer, on the ground or into any body of water.
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Stable under recommended storage conditions. Hazardous polymerisation may occur upon depletion of inhibitor.
Explosion Data
Sensitivity to Mechanical Impact None.
Sensitivity to Static Discharge May be ignited by friction, heat, sparks or flames.
Hazardous Polymerisation
Hazardous polymerisation may occur upon depletion of inhibitor.
Keep away from heat, sparks and flames. Keep at temperatures between 5 and 25 °C.
Acrylates.
Product Information
No information or data specific to the product on this toxicological (health) effect is available.
Delayed and immediate effects as well as chronic effects from short and long-term exposure
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Target Organ Effects Eyes, Respiratory system, Skin, Central Vascular System (CVS).
Acute Toxicity
The following values are calculated based on chapter 3.1 of the GHS document
ATEmix (oral) 9,771.00 mg/kg
ATEmix (dermal) 6,167.00 mg/kg
ATEmix (inhalation-vapour) 684.00 mg/l
Component Information
Component Information
Data obtained on the component(s) include
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e
586-77-6
1,3-bis[12-hydroxy-octadec EC50 (96hr) >100 mg/L Algae LC50 96h >100 mg/L Fish EC50 (48h) >0.64 mg/L
amide-N-methylene]-benze (Daphnia magna)
ne
911674-82-3
2-Hydroxyethyl - LC50 96 h = 227 mg/L -
methacrylate (Pimephales promelas ) LC50
868-77-9 96 h 213 - 242 mg/L
(Pimephales promelas
flow-through)
Propylene glycol - LC50 96 h = 20.8 g/L EC50 48 h = 23300 mg/L
monomethyl ether (Pimephales promelas static) (Daphnia magna )
107-98-2 LC50 96 h 4600 - 10000 mg/L
(Leuciscus idus static)
Benzene, EC50 96 h = 3230 mg/L - EC50 24 h > 1000 mg/L
1,1'-methylenebis[isocyanat (Skeletonema costatum) (Daphnia magna )
o-
26447-40-5
Isocyanic acid, ErC50 (72h) >1640 mg/L CL50 (96h) >1000 mg/L Fish EC50 (24H) >1000 mg/L
polymethylenepolyphenylen Algae (scenedesmus (Danio rerio) Daphnia magna
e ester subspicatus) (OECD 201)
9016-87-9
No information available.
No information available.
The components in this formulation do not meet the criteria for classification as PBT or vPvB.
No information available
Waste from Residues/Unused Disposal should be in accordance with applicable regional, national and local laws and
Products regulations.
Contaminated Packaging Improper disposal or reuse of this container may be dangerous and illegal.
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European Waste Catalogue 08 04 09* waste adhesives and sealants containing organic solvents or other dangerous
substances
OTHER INFORMATION Waste codes should be assigned by the user based on the application for which the
product was used.
IMDG
14.1 UN/ID no UN1133
14.2 Proper Shipping Name Adhesives
14.3 Hazard Class 3
14.4 Packing Group III
Description UN1133, Adhesives, 3, III, (10°C c.c.)
14.5 Marine Pollutant Np
14.6 Special Provisions 223, 955
Limited Quantity (LQ) 5L
EmS-No F-E, S-D
14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code No information available
RID
14.1 UN/ID no UN1133
14.2 Proper Shipping Name Adhesives
14.3 Hazard Class 3
Hazard Labels 3
14.4 Packing Group III
Description UN1133, Adhesives, 3, III
14.5 Environmental Hazard Not applicable
Classification Code F1
14.6 Special Provisions None
Limited Quantity (LQ) 5L
ICAO (air)
14.1 UN/ID no UN1133
14.2 Proper Shipping Name Adhesives
14.3 Hazard Class 3
14.4 Packing Group III
Description UN1133, Adhesives, 3, III
14.5 Environmental Hazard Not applicable
14.6 Special Provisions A3
IATA
14.1 UN/ID no UN1133
14.2 Proper Shipping Name Adhesives
14.3 Hazard Class 3
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14.4 Packing Group III
Description UN1133, Adhesives, 3, III
14.5 Environmental Hazard Not applicable
14.6 Special Provisions A3
Limited Quantity (LQ) 10 L
ERG Code 3L
European Union
Take note of Directive 98/24/EC on the protection of the health and safety of workers from the risks related to chemical agents
at work
Check whether measures in accordance with Directive 94/33/EC for the protection of young people at work must be taken.
Take note of Directive 92/85/EC on the protection of pregnant and breastfeeding women at work
Registration, Evaluation, Authorization, and Restriction of Chemicals (REACh) Regulation (EC 1907/2006)
EU-REACH (1907/2006) - Candidate List of Substances of Very High Concern (SVHC) for Authorization in accordance
with Article 59
This product does not contain candidate substances of very high concern at a concentration >=0.1% (Regulation (EC) No.
1907/2006 (REACH), Article 59)
Dangerous substance category per Seveso Directive (2012/18/EU) P5a - FLAMMABLE LIQUIDS
or
P5b - FLAMMABLE LIQUIDS
or
P5c - FLAMMABLE LIQUIDS
None
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Legend
SVHC: Substances of Very High Concern for Authorisation:
Indication of changes
Training Advice Provide adequate information, instruction, and training for operator
This safety data sheet complies with the requirements of: Regulation (EC) No. 1907/2006
Disclaimer
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of
its publication. The information given is designed only as a guidance for safe handling, use, processing, storage,
transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only
to the specific material designated and may not be valid for such material used in combination with any other materials or in
any process, unless specified in the text.