SAFETY DATA SHEET

This safety data sheet was created pursuant to the requirements of:
Regulation (EC) No. 1907/2006 and Regulation (EC) No. 1272/2008

Issuing Date 19-Sep-2019 Revision Date 19-Sep-2019 Revision Number 1

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier

Product Code(s) 999 AVI

Product Name Lacomit Lacquer 1 Litre

Contains Xylene, Butan-1-ol, n-butyl acetate, Acetone

1.2. Relevant identified uses of the substance or mixture and uses advised against

Recommended use Plating remover

Uses advised against Use only for intended applications

1.3. Details of the supplier of the safety data sheet

Supplier
Cookson Precious Metals Ltd
59-83 Vittoria Street
Birmingham
B1 3NZ
United Kingdom
+44 (0) 121 200 2120

For further information, please contact

E-mail address info@cooksongold.com

1.4. Emergency telephone number

Emergency Telephone +44 (0)121 200 2120 (Monday - Friday 08:00 - 20:00, Saturday - Sunday 10:00 - 16:00)

Emergency Telephone - §45 - (EC)1272/2008

Europe 112

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture
Regulation (EC) No 1272/2008
Aspiration hazard Category 1 - (H304)
Acute toxicity - Dermal Category 4 - (H312)
Acute toxicity - Inhalation (Vapours) Category 4 - (H332)
Skin corrosion/irritation Category 2 - (H315)
Serious eye damage/eye irritation Category 1 - (H318)
Specific target organ toxicity — single exposure Category 3 - (H335,H336)
Specific target organ toxicity — repeated exposure Category 2 - (H373)
Chronic aquatic toxicity Category 3 - (H412)
Flammable liquids Category 2 - (H225)

2.2. Label elements

Contains Xylene, Butan-1-ol, n-butyl acetate, Acetone

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Signal word
Danger

Hazard statements
H304 - May be fatal if swallowed and enters airways
H312 - Harmful in contact with skin
H315 - Causes skin irritation
H318 - Causes serious eye damage
H332 - Harmful if inhaled
H335 - May cause respiratory irritation
H336 - May cause drowsiness or dizziness
H373 - May cause damage to organs through prolonged or repeated exposure
H412 - Harmful to aquatic life with long lasting effects
H225 - Highly flammable liquid and vapour

Precautionary Statements - EU (§28, 1272/2008)

P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking
P260 - Do not breathe vapour
P280 - Wear protective gloves/protective clothing and eye/face protection
P301 + P310 - IF SWALLOWED: Immediately call a POISON CENTER or doctor
P331 - Do NOT induce vomiting
P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to
do. Continue rinsing
P314 - Get medical advice/attention if you feel unwell
P501 - Dispose of contents/containers in accordance with local regulations

2.3. Other hazards

The product does not contain any substance(s) classified as PBT or vPvB

SECTION 3: Composition/information on ingredients

3.1 Substances

Not applicable

3.2 Mixtures

Chemical name EC No CAS No Weight-% Classification REACH

according to registration
Regulation (EC) No. number
1272/2008 [CLP]
Xylene 215-535-7 1330-20-7 30-60 Acute Tox. 4 (H312) -
Acute Tox. 4 (H332)
Skin Irrit. 2 (H315)
Eye Irrit. 2 (H319)
Asp. Tox. 1 (H304)
STOT SE 3 (H335)
STOT RE 2 (H373)
Aquatic Chronic 3
(H412)
Flam. Liq. 3 (H226)
Butan-1-ol 200-751-6 71-36-3 10-30 Acute Tox. 4 (H302) -
Skin Irrit. 2 (H315)
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Lacomit Lacquer 1 Litre
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n-butyl acetate
Acetone
1-methoxy-2-propanol
Amines, rosin, compds. with
9-(2-carboxyphenyl)-3,6-bis(diet
hylamino)xanthylium chloride
and disodium hydrogen
bis[4-[(4,5-dihydro-3-methyl-5-o
xo-1-phenyl-1H-pyrazol-4-yl)azo
]-3-hydroxy-1-naphthalenesulfo
nato(3-)]chromate(3-)
Full text of H- and EUH-phrases: see section 16
SECTION 4: First aid measures
4.1. Description of first aid measures
General advice
Inhalation
Eye contact
Skin contact
Ingestion
Self-protection of the first aider
4.2. Most important symptoms and effects, both acute and delayed
Symptoms
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(M)SDS Number UL-COO-015
Revision Date: 19-Sep-2019
Eye Dam. 1 (H318)
STOT SE 3 (H335)
STOT SE 3 (H336)
Flam. Liq. 3 (H226)
204-658-1 123-86-4 10-30 STOT SE 3 (H336) -
(EUH066)
Flam. Liq. 3 (H226)
200-662-2 67-64-1 1-5 Eye Irrit. 2 (H319) -
STOT SE 3 (H336)
(EUH066)
Flam. Liq. 2 (H225)
203-539-1 107-98-2 1-5 STOT SE 3 (H336) -
Flam. Liq. 3 (H226)
308-114-5 97862-65-2 0.1-1 Acute Tox. 4 (H302) -
Aquatic Chronic 2
(H411)
Show this safety data sheet to the doctor in attendance. Immediate medical attention is
required.
Remove to fresh air. Aspiration into lungs can produce severe lung damage. If breathing
has stopped, give artificial respiration. Get medical attention immediately. Avoid direct
contact with skin. Use barrier to give mouth-to-mouth resuscitation. If breathing is difficult,
(trained personnel should) give oxygen. Get immediate medical advice/attention. Delayed
pulmonary edema may occur.
Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Keep
eye wide open while rinsing. Do not rub affected area. Get immediate medical
advice/attention. Remove contact lenses, if present and easy to do. Continue rinsing.
Wash off immediately with soap and plenty of water while removing all contaminated
clothes and shoes. If symptoms persist, call a doctor.
Do NOT induce vomiting. Clean mouth with water and drink afterwards plenty of water.
Never give anything by mouth to an unconscious person. Aspiration hazard if swallowed -
can enter lungs and cause damage. If vomiting occurs spontaneously, keep head below
hips to prevent aspiration. Get immediate medical advice/attention.
Remove all sources of ignition. Ensure that medical personnel are aware of the material(s)
involved, take precautions to protect themselves and prevent spread of contamination. Use
personal protective equipment as required. See section 8 for more information. Avoid
contact with skin, eyes or clothing. Avoid direct contact with skin. Use barrier to give
mouth-to-mouth resuscitation. Avoid breathing vapours or mists.
Burning sensation. Difficulty in breathing. Coughing and/ or wheezing. Dizziness. Inhalation
of high vapour concentrations may cause symptoms like headache, dizziness, tiredness,
nausea and vomiting.
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4.3. Indication of any immediate medical attention and special treatment needed

Note to doctors Treat symptomatically. Because of the danger of aspiration, emesis or gastric lavage
should not be used unless the risk is justified by the presence of additional toxic
substances.

SECTION 5: Firefighting measures

5.1. Extinguishing media

Suitable Extinguishing Media Dry chemical. Carbon dioxide (CO2). Water spray. Alcohol resistant foam.

Unsuitable extinguishing media Do not scatter spilled material with high pressure water streams.

5.2. Special hazards arising from the substance or mixture

Specific hazards arising from the Risk of ignition. Keep product and empty container away from heat and sources of ignition.
chemical In the event of fire, cool tanks with water spray. Fire residues and contaminated fire
extinguishing water must be disposed of in accordance with local regulations.

Hazardous combustion products Carbon oxides.

5.3. Advice for firefighters

Special protective equipment for Firefighters should wear self-contained breathing apparatus and full firefighting turnout
fire-fighters gear. Use personal protection equipment.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

Personal precautions
Evacuate personnel to safe areas. Use personal protective equipment as required. See
section 8 for more information. Avoid contact with skin, eyes or clothing. Ensure adequate
ventilation. Keep people away from and upwind of spill/leak. ELIMINATE all ignition sources
(no smoking, flares, sparks or flames in immediate area). Pay attention to flashback. Take
precautionary measures against static discharges. All equipment used when handling the
product must be grounded. Do not touch or walk through spilled material. Avoid breathing
vapours or mists.

Other information Ventilate the area. Refer to protective measures listed in Sections 7 and 8.

For emergency responders Use personal protection recommended in Section 8.

6.2. Environmental precautions

Environmental precautions Refer to protective measures listed in Sections 7 and 8. Prevent further leakage or spillage
if safe to do so. Prevent product from entering drains.

6.3. Methods and material for containment and cleaning up

Methods for containment Stop leak if you can do it without risk. Do not touch or walk through spilled material. A
vapour suppressing foam may be used to reduce vapours. Dyke far ahead of spill to collect
run-off water. Keep out of drains, sewers, ditches and waterways. Absorb with earth, sand
or other non-combustible material and transfer to containers for later disposal.

Methods for cleaning up Take precautionary measures against static discharges. Dam up. Soak up with inert
absorbent material. Pick up and transfer to properly labelled containers.

Prevention of secondary hazards Clean contaminated objects and areas thoroughly observing environmental regulations.
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6.4. Reference to other sections

Reference to other sections See section 8 for more information. See section 13 for more information.

SECTION 7: Handling and storage

7.1. Precautions for safe handling

Advice on safe handling
Use personal protection equipment. Avoid breathing vapours or mists. Keep away from
heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Use with
local exhaust ventilation. Use spark-proof tools and explosion-proof equipment. Keep in an
area equipped with sprinklers. Use according to package label instructions. Handle in
accordance with good industrial hygiene and safety practice. Avoid contact with skin, eyes
or clothing. Do not eat, drink or smoke when using this product. Take off contaminated
clothing and wash it before reuse. In case of insufficient ventilation, wear suitable
respiratory equipment.

General hygiene considerations Do not eat, drink or smoke when using this product. Contaminated work clothing should not
be allowed out of the workplace. Regular cleaning of equipment, work area and clothing is
recommended. Wash hands before breaks and immediately after handling the product.
Avoid contact with skin, eyes or clothing. Wear suitable gloves and eye/face protection.

7.2. Conditions for safe storage, including any incompatibilities

Storage Conditions Keep containers tightly closed in a dry, cool and well-ventilated place. Keep away from
heat, sparks, flame and other sources of ignition (i.e., pilot lights, electric motors and static
electricity). Keep in properly labelled containers. Do not store near combustible materials.
Keep in an area equipped with sprinklers. Store in accordance with the particular national
regulations. Store in accordance with local regulations. Store locked up. Keep out of the
reach of children. Store away from other materials.

7.3. Specific end use(s)

Risk Management Methods (RMM) The information required is contained in this Safety Data Sheet.

SECTION 8: Exposure controls/Personal protection

8.1. Control parameters

Exposure Limits .

Chemical name European Union United Kingdom France Spain Germany

Xylene TWA: 50 ppm TWA: 50 ppm TWA: 50 ppm TWA: 50 ppm TWA: 100 ppm
1330-20-7 TWA: 221 mg/m3 TWA: 220 mg/m3 TWA: 221 mg/m3 TWA: 221 mg/m3 TWA: 440 mg/m3
STEL: 100 ppm STEL: 100 ppm STEL: 100 ppm STEL: 100 ppm H*
STEL: 442 mg/m3 STEL: 441 mg/m3 STEL: 442 mg/m3 STEL: 442 mg/m3
* Sk* * vía dérmica*
Butan-1-ol - STEL: 50 ppm STEL: 50 ppm TWA: 20 ppm TWA: 100 ppm
71-36-3 STEL: 154 mg/m3 STEL: 150 mg/m3 TWA: 61 mg/m3 TWA: 310 mg/m3
Sk* STEL: 50 ppm
STEL: 154 mg/m3
n-butyl acetate - TWA: 150 ppm TWA: 150 ppm TWA: 150 ppm TWA: 62 ppm
123-86-4 TWA: 724 mg/m3 TWA: 710 mg/m3 TWA: 724 mg/m3 TWA: 300 mg/m3
STEL: 200 ppm STEL: 200 ppm STEL: 200 ppm
STEL: 966 mg/m3 STEL: 940 mg/m3 STEL: 965 mg/m3
Acetone TWA: 500 ppm TWA: 500 ppm TWA: 500 ppm TWA: 500 ppm TWA: 500 ppm
67-64-1 TWA: 1210 mg/m3 TWA: 1210 mg/m3 TWA: 1210 mg/m3 TWA: 1210 mg/m3 TWA: 1200 mg/m3
STEL: 1500 ppm STEL: 1000 ppm

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STEL: 3620 mg/m3 STEL: 2420 mg/m3

1-methoxy-2-propanol TWA: 100 ppm TWA: 100 ppm TWA: 50 ppm TWA: 100 ppm TWA: 100 ppm
107-98-2 TWA: 375 mg/m3 TWA: 375 mg/m3 TWA: 188 mg/m3 TWA: 375 mg/m3 TWA: 370 mg/m3
STEL: 150 ppm STEL: 150 ppm STEL: 100 ppm STEL: 150 ppm
STEL: 568 mg/m3 STEL: 560 mg/m3 STEL: 375 mg/m3 STEL: 568 mg/m3
* Sk* * vía dérmica*
Amines, rosin, compds. with - TWA: 0.5 mg/m3 - - -
9-(2-carboxyphenyl)-3,6-bis(diet
hylamino)xanthylium chloride
and disodium hydrogen
bis[4-[(4,5-dihydro-3-methyl-5-o
xo-1-phenyl-1H-pyrazol-4-yl)azo
]-3-hydroxy-1-naphthalenesulfo
nato(3-)]chromate(3-)
97862-65-2
Chemical name Italy Portugal Netherlands Finland Denmark
Xylene TWA: 50 ppm TWA: 50 ppm TWA: 210 mg/m3 TWA: 50 ppm TWA: 25 ppm
1330-20-7 TWA: 221 mg/m3 TWA: 221 mg/m3 STEL: 442 mg/m3 TWA: 220 mg/m3 TWA: 109 mg/m3
STEL: 100 ppm STEL: 100 ppm H* STEL: 100 ppm H*
STEL: 442 mg/m3 STEL: 442 mg/m3 STEL: 440 mg/m3
pelle* P* iho*
Butan-1-ol - TWA: 20 ppm - TWA: 50 ppm Ceiling: 50 ppm
71-36-3 TWA: 150 mg/m3 Ceiling: 150 mg/m3
STEL: 75 ppm H*
STEL: 230 mg/m3
iho*
n-butyl acetate - TWA: 150 ppm - TWA: 150 ppm TWA: 150 ppm
123-86-4 STEL: 200 ppm TWA: 720 mg/m3 TWA: 710 mg/m3
STEL: 200 ppm
STEL: 960 mg/m3
Acetone TWA: 500 ppm TWA: 500 ppm TWA: 1210 mg/m3 TWA: 500 ppm TWA: 250 ppm
67-64-1 TWA: 1210 mg/m3 TWA: 1210 mg/m3 STEL: 2420 mg/m3 TWA: 1200 mg/m3 TWA: 600 mg/m3
STEL: 750 ppm STEL: 630 ppm
STEL: 1500 mg/m3
1-methoxy-2-propanol TWA: 100 ppm TWA: 100 ppm TWA: 375 mg/m3 TWA: 100 ppm TWA: 50 ppm
107-98-2 TWA: 375 mg/m3 TWA: 375 mg/m3 STEL: 563 mg/m3 TWA: 370 mg/m3 TWA: 185 mg/m3
STEL: 150 ppm STEL: 150 ppm H* STEL: 150 ppm H*
STEL: 568 mg/m3 STEL: 568 mg/m3 STEL: 560 mg/m3
pelle* iho*
Amines, rosin, compds. with - TWA: 0.5 mg/m3 - TWA: 0.5 mg/m3 TWA: 0.005 mg/m3
9-(2-carboxyphenyl)-3,6-bis(diet
hylamino)xanthylium chloride
and disodium hydrogen
bis[4-[(4,5-dihydro-3-methyl-5-o
xo-1-phenyl-1H-pyrazol-4-yl)azo
]-3-hydroxy-1-naphthalenesulfo
nato(3-)]chromate(3-)
97862-65-2
Chemical name Austria Switzerland Poland Norway Ireland
Xylene TWA: 50 ppm TWA: 100 ppm STEL: 200 mg/m3 TWA: 25 ppm TWA: 50 ppm
1330-20-7 TWA: 221 mg/m3 TWA: 435 mg/m3 TWA: 100 mg/m3 TWA: 108 mg/m3 TWA: 221 mg/m3
STEL 100 ppm STEL: 200 ppm STEL: 37.5 ppm STEL: 100 ppm
STEL 442 mg/m3 STEL: 870 mg/m3 STEL: 135 mg/m3 STEL: 442 mg/m3
H* H* Sk*
Butan-1-ol TWA: 50 ppm TWA: 100 ppm STEL: 150 mg/m3 Ceiling: 25 ppm TWA: 20 ppm
71-36-3 TWA: 150 mg/m3 TWA: 310 mg/m3 TWA: 50 mg/m3 Ceiling: 75 mg/m3 STEL: 60 ppm
STEL 200 ppm STEL: 100 ppm H* Sk*
STEL 600 mg/m3 STEL: 310 mg/m3
n-butyl acetate TWA: 100 ppm TWA: 100 ppm STEL: 720 mg/m3 TWA: 75 ppm TWA: 150 ppm
123-86-4 TWA: 480 mg/m3 TWA: 480 mg/m3 TWA: 240 mg/m3 TWA: 355 mg/m3 TWA: 710 mg/m3
STEL 100 ppm STEL: 200 ppm STEL: 112.5 ppm STEL: 200 ppm

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STEL 480 mg/m3 STEL: 960 mg/m3 STEL: 443.75 STEL: 950 mg/m3
Ceiling 100 ppm mg/m3
Ceiling 480 mg/m3
Acetone TWA: 500 ppm TWA: 500 ppm STEL: 1800 mg/m3 TWA: 125 ppm TWA: 500 ppm
67-64-1 TWA: 1200 mg/m3 TWA: 1200 mg/m3 TWA: 600 mg/m3 TWA: 295 mg/m3 TWA: 1210 mg/m3
STEL 2000 ppm STEL: 1000 ppm STEL: 156.25 ppm STEL: 1500 ppm
STEL 4800 mg/m3 STEL: 2400 mg/m3 STEL: 368.75 STEL: 3630 mg/m3
mg/m3
1-methoxy-2-propanol TWA: 50 ppm TWA: 100 ppm STEL: 360 mg/m3 TWA: 50 ppm TWA: 100 ppm
107-98-2 TWA: 187 mg/m3 TWA: 360 mg/m3 TWA: 180 mg/m3 TWA: 180 mg/m3 TWA: 375 mg/m3
STEL 50 ppm STEL: 200 ppm STEL: 75 ppm STEL: 150 ppm
STEL 187 mg/m3 STEL: 720 mg/m3 STEL: 225 mg/m3 STEL: 568 mg/m3
Ceiling 50 ppm H*
Ceiling 187 mg/m3
H*
Amines, rosin, compds. with - TWA: 0.5 mg/m3 TWA: 0.5 mg/m3 TWA: 0.005 mg/m3 TWA: 2 mg/m3
9-(2-carboxyphenyl)-3,6-bis(diet TWA: 0.5 mg/m3 STEL: 6 mg/m3
hylamino)xanthylium chloride STEL: 0.015
and disodium hydrogen mg/m3 STEL: 1.5
bis[4-[(4,5-dihydro-3-methyl-5-o mg/m3
xo-1-phenyl-1H-pyrazol-4-yl)azo
]-3-hydroxy-1-naphthalenesulfo
nato(3-)]chromate(3-)
97862-65-2

Biological occupational exposure limits

Chemical name European Union United Kingdom France Spain Germany

Xylene - 650 mmol/mol - 1 g/g Creatinine - 2000 mg/L - urine
1330-20-7 creatinine urine urine (Methylhippuric(tol
(Methyl hippuric (Methylhippuric ur-)acid) - end of
acid) - post shift acids) - end of shift shift
Butan-1-ol - - - 10 mg/g - urine
71-36-3 (1-Butanol) - end
of shift
2 mg/g - urine
(1-Butanol) -
before beginning
of next shift
Acetone - - - 50 mg/L - urine 80 mg/L - urine
67-64-1 (Acetone) - end of (Acetone) - end of
shift shift
1-methoxy-2-propanol - - - 15 mg/L - urine
107-98-2 (1-Methoxypropan-
2-ol) - end of shift
Chemical name Italy Portugal Netherlands Finland Denmark
Xylene - - - 5.0 mmol/L - urine
1330-20-7 (Methylhippuric
acid) - after the
shift
Chemical name Austria Switzerland Poland Norway Ireland
Xylene 1.5 g/L - urine 2 g/L - urine - - 1.5 g/g Creatinine
1330-20-7 (Methylhippuric (Methylhippuric Medium: urine
acid) - after end of acid) - end of shift Time: end of shift
work day, at the Parameter:
end of a work Methylhippuric
week/end of the acids
shift
Butan-1-ol - 10 mg/g creatinine - - -
71-36-3 - urine (n-Butanol)
- end of shift

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2 mg/g creatinine -
urine (n-Butanol) -
at least 3 months
exposure
Acetone - 80 mg/L - urine - - 50 mg/L Medium:
67-64-1 (Acetone) - end of urine Time: end of
shift shift Parameter:
Acetone
(non-specific)
1-methoxy-2-propanol - 20 mg/L - urine - - -
107-98-2 (1-Methoxypropan
ol-2) - end of shift

Derived No Effect Level (DNEL) No information available.

Predicted No Effect Concentration No information available.
(PNEC)
8.2. Exposure controls

Engineering controls Showers

Eyewash stations
Ventilation systems.

Personal protective equipment

Eye/face protection Tight sealing safety goggles.

Eye protection must conform to standard EN 166.

Hand protection Wear suitable gloves. Nitrile rubber. Viton™. Ensure that the breakthrough time of the glove
material is not exceeded. Refer to glove supplier for information on breakthrough time for
specific gloves.

Gloves must conform to standard EN 374.

Skin and body protection Wear suitable protective clothing. Long sleeved clothing. Chemical resistant apron.
Antistatic boots.

Respiratory protection In case of insufficient ventilation, wear suitable respiratory equipment.

General hygiene considerations Do not eat, drink or smoke when using this product. Contaminated work clothing should not
be allowed out of the workplace. Regular cleaning of equipment, work area and clothing is
recommended. Wash hands before breaks and immediately after handling the product.
Avoid contact with skin, eyes or clothing. Wear suitable gloves and eye/face protection.

Environmental exposure controls Prevent product from entering drains.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties
Appearance Clear, liquid
Physical state Liquid
Colour Pink. Red
Odour Organic solvent
Odour threshold No information available

Property Values Remarks • Method

pH No data available None known
Melting point / freezing point No data available None known
Boiling point / boiling range > 100 °C
Flash point 16 °C
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Evaporation rate No data available None known

Flammability (solid, gas) No data available None known
Flammability Limit in Air None known
Upper flammability or explosive No data available
limits
Lower flammability or explosive No data available
limits
Vapour pressure No data available None known
Vapour density No data available None known
Relative density 0.88 - 0.93 @20°C
Water solubility No data available None known
Solubility(ies) slightly soluble
Partition coefficient No data available None known
Autoignition temperature No data available None known
Decomposition temperature No data available None known
Kinematic viscosity No data available None known
Dynamic viscosity No data available None known
Explosive properties No information available.
Oxidising properties No information available.

9.2. Other information

Softening point No information available
Molecular weight No information available
VOC Content (%) No information available
Liquid Density No information available
Bulk density No information available

SECTION 10: Stability and reactivity

10.1. Reactivity

Reactivity None under normal use conditions.

10.2. Chemical stability

Stability Stable under normal conditions.

Explosion data
Sensitivity to mechanical impact None.
Sensitivity to static discharge Yes.

10.3. Possibility of hazardous reactions

Possibility of hazardous reactions None under normal processing.

10.4. Conditions to avoid

Conditions to avoid Heat, flames and sparks. Excessive heat.

10.5. Incompatible materials

Incompatible materials Strong acids. Strong bases. Strong oxidising agents.

10.6. Hazardous decomposition products

Hazardous decomposition products None known based on information supplied.

SECTION 11: Toxicological information

11.1. Information on toxicological effects
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Information on likely routes of exposure

Product Information

Inhalation Specific test data for the substance or mixture is not available. Aspiration into lungs can
produce severe lung damage. May cause pulmonary edema. Pulmonary edema can be
fatal. May cause irritation of respiratory tract. May cause drowsiness or dizziness. Harmful
by inhalation. (based on components).

Eye contact Specific test data for the substance or mixture is not available. Severely irritating to eyes.
Causes serious eye damage. May cause burns. May cause irreversible damage to eyes.
(based on components).

Skin contact Specific test data for the substance or mixture is not available. Repeated exposure may
cause skin dryness or cracking. Causes skin irritation. (based on components).

Ingestion Specific test data for the substance or mixture is not available. Ingestion may cause
gastrointestinal irritation, nausea, vomiting and diarrhoea. Potential for aspiration if
swallowed. May cause lung damage if swallowed. Aspiration may cause pulmonary edema
and pneumonitis. May be fatal if swallowed and enters airways.

Symptoms related to the physical, chemical and toxicological characteristics

Symptoms Redness. Burning. May cause blindness. Difficulty in breathing. Coughing and/ or
wheezing. Dizziness. May cause redness and tearing of the eyes. Inhalation of high vapour
concentrations may cause symptoms like headache, dizziness, tiredness, nausea and
vomiting.

Numerical measures of toxicity

.

Acute toxicity

The following values are calculated based on chapter 3.1 of the GHS document
ATEmix (oral) 2,265.90 mg/kg
ATEmix (dermal) 1,753.40 mg/kg
ATEmix (inhalation-vapour) 19.60 mg/l

Component Information
Chemical name Oral LD50 Dermal LD50 Inhalation LC50
Xylene = 3523 mg/kg ( Rat ) = 1100 mg/kg (cATpE) = 11 mg/L (cATpE)

Butan-1-ol = 790 mg/kg ( Rat ) = 3430 mg/kg ( Rabbit ) > 17.76 mg/L ( Rat ) 4 h

n-butyl acetate = 10768 mg/kg ( Rat ) > 17600 mg/kg ( Rabbit ) = 390 ppm ( Rat ) 4 h

Acetone = 5800 mg/kg ( Rat ) > 15700 mg/kg ( Rabbit ) = 50100 mg/m3 ( Rat ) 8 h

1-methoxy-2-propanol = 5000 mg/kg ( Rat ) = 13 g/kg ( Rabbit ) > 7559 ppm ( Rat ) 6 h

Amines, rosin, compds. with = 525 mg/kg ( Rat )

9-(2-carboxyphenyl)-3,6-bis(diethylami
no)xanthylium chloride and disodium
hydrogen
bis[4-[(4,5-dihydro-3-methyl-5-oxo-1-p
henyl-1H-pyrazol-4-yl)azo]-3-hydroxy-
1-naphthalenesulfonato(3-)]chromate(
3-)

Delayed and immediate effects as well as chronic effects from short and long-term exposure

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Skin corrosion/irritation Classification based on data available for ingredients. Irritating to skin.

Serious eye damage/eye irritation Classification based on data available for ingredients. Causes burns. Risk of serious
damage to eyes.

Respiratory or skin sensitisation Based on available data, the classification criteria are not met.

Germ cell mutagenicity Based on available data, the classification criteria are not met.

Carcinogenicity Based on available data, the classification criteria are not met.

Reproductive toxicity Based on available data, the classification criteria are not met.

STOT - single exposure May cause respiratory irritation. May cause drowsiness or dizziness.

STOT - repeated exposure May cause damage to organs through prolonged or repeated exposure.

Aspiration hazard May be fatal if swallowed and enters airways.

SECTION 12: Ecological information

12.1. Toxicity

Ecotoxicity Harmful to aquatic life with long lasting effects.

Chemical name Algae/aquatic plants Fish Toxicity to Crustacea

microorganisms
Xylene EC50: =4.9 mg/L (72h, LC50: =8.4 mg/L (96h, NOEC: =16 mg/L (28d, EC50: =3.82 mg/L (48h,
Pseudokirchneriella Oncorhynchus mykiss) Activated sludge) water flea)
subcapitata) NOEC: >1.3 mg/L (56d, NOEC: =0.96 mg/L (7d,
Oncorhynchus mykiss) Ceriodaphnia dubia)
Butan-1-ol EC50: =225mg/L (96h, LC50: 1376 mg/L (96h, EC10: =2476 mg/L EC50: =1328 mg/L
Pseudokirchneriella Pimephales promelas) (17h, Pseudomonas (48h, Daphnia magna)
subcapitata) putida) NOEC: =4.1 mg/L (21d,
Daphnia magna)
n-butyl acetate EC50: =674.7mg/L LC50: =18 mg/L (96h, IC50: =356mg/L )40h, EC50: =44 mg/L (48h,
(72h, Desmodesmus Pimephales promelas) Tetrahymena pyriformis) Daphnia magna)
subspicatus)
Acetone - LC50: 6210 - 8120 mg/L EC50: =61.15 mg/L EC50: =8800 mg/L
(96h, Pimephales (30min, Activated (48h, Daphnia pulex)
promelas) sludge) NOEC: =2212 mg/L
(28d, Daphnia magna)
1-methoxy-2-propanol EC50: >1000 mg/L LC50: 4600 - 10000 - EC50: =23300 mg/L
(7d, mg/L (96h, Leuciscus (48h, Daphnia magna)
Pseudokirchneriella idus)
subcapitata)

12.2. Persistence and degradability

Persistence and degradability No information available.

12.3. Bioaccumulative potential

Bioaccumulation There is no data for this product.

Component Information
Chemical name Partition coefficient
Xylene 2.77 - 3.15
Butan-1-ol 1
n-butyl acetate 2.3
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Acetone -0.24
1-methoxy-2-propanol 0.37
Amines, rosin, compds. with 3.2
9-(2-carboxyphenyl)-3,6-bis(diethylamino)xanthylium chloride
and disodium hydrogen
bis[4-[(4,5-dihydro-3-methyl-5-oxo-1-phenyl-1H-pyrazol-4-yl)azo]
-3-hydroxy-1-naphthalenesulfonato(3-)]chromate(3-)

12.4. Mobility in soil

Mobility in soil No information available.

Mobility Miscible in water.

12.5. Results of PBT and vPvB assessment

PBT and vPvB assessment The product does not contain any substance(s) classified as PBT or vPvB.

Chemical name PBT and vPvB assessment

Xylene The substance is not PBT / vPvB
Butan-1-ol The substance is not PBT / vPvB
n-butyl acetate The substance is not PBT / vPvB
Acetone The substance is not PBT / vPvB
1-methoxy-2-propanol The substance is not PBT / vPvB

12.6. Other adverse effects

Other adverse effects No information available.

SECTION 13: Disposal considerations

13.1. Waste treatment methods

Waste from residues/unused Should not be released into the environment. Dispose of in accordance with local
products regulations. Dispose of waste in accordance with environmental legislation.

Contaminated packaging Empty containers pose a potential fire and explosion hazard. Do not cut, puncture of weld
containers.

Waste codes / waste designations According to the European Waste Catalogue, Waste Codes are not product specific, but
according to EWC / AVV application specific. Waste codes should be assigned by the user based on the application
for which the product was used.

SECTION 14: Transport information

IMDG
14.1 UN number UN1263
14.2 UN proper shipping name PAINT
14.3 Transport hazard class(es) 3
14.4 Packing group II
Description UN1263, PAINT, 3, II, (16°C c.c.)
14.5 Marine pollutant Not applicable
14.6 Special Precautions for Users
Special Provisions 163, 367
EmS-No F-E, S-E
14.7. Transport in bulk according to No information available
Annex II of MARPOL and the IBC
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Code

RID
14.1 UN number UN1263
14.2 UN proper shipping name PAINT
14.3 Transport hazard class(es) 3
Labels 3
14.4 Packing group II
Description UN1263, PAINT, 3, II
14.5 Environmental hazards Not applicable
14.6 Special Precautions for Users
Special Provisions None
Classification code F1

ADR
14.1 UN number UN1263
14.2 UN proper shipping name PAINT
14.3 Transport hazard class(es) 3
Labels 3
14.4 Packing group II
Description UN1263, PAINT, 3, II
14.5 Environmental hazards Not applicable
14.6 Special Precautions for Users
Special Provisions 163, 640C, 650, 367
Classification code F1
Tunnel restriction code (D/E)

IATA
14.1 UN number UN1263
14.2 UN proper shipping name Paint
14.3 Transport hazard class(es) 3
14.4 Packing group II
Description UN1263, Paint, 3, II
14.5 Environmental hazards Not applicable
14.6 Special Precautions for Users
Special Provisions None
ERG Code 3L

SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

National regulations

France
Occupational Illnesses (R-463-3, France)
Chemical name French RG number Title
Xylene RG 4bis,RG 84 -
1330-20-7
Butan-1-ol RG 84 -
71-36-3
n-butyl acetate RG 84 -
123-86-4
Acetone RG 84 -
67-64-1
1-methoxy-2-propanol RG 84 -
107-98-2

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European Union

Take note of Directive 98/24/EC on the protection of the health and safety of workers from the risks related to chemical agents
at work

Authorisations and/or restrictions on use:

This product does not contain substances subject to authorisation (Regulation (EC) No. 1907/2006 (REACH), Annex XIV) This
product does not contain substances subject to restriction (Regulation (EC) No. 1907/2006 (REACH), Annex XVII)

Persistent Organic Pollutants

Not applicable

Dangerous substance category per Seveso Directive (2012/18/EU)

P5a - FLAMMABLE LIQUIDS
P5b - FLAMMABLE LIQUIDS
P5c - FLAMMABLE LIQUIDS

Ozone-depleting substances (ODS) regulation (EC) 1005/2009 Not applicable

International Inventories
TSCA Contact supplier for inventory compliance status
DSL/NDSL Contact supplier for inventory compliance status
EINECS/ELINCS Contact supplier for inventory compliance status
ENCS Contact supplier for inventory compliance status
IECSC Contact supplier for inventory compliance status
KECL Contact supplier for inventory compliance status
PICCS Contact supplier for inventory compliance status
AICS Contact supplier for inventory compliance status

Legend:
TSCA - United States Toxic Substances Control Act Section 8(b) Inventory
DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List
EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances
ENCS - Japan Existing and New Chemical Substances
IECSC - China Inventory of Existing Chemical Substances
KECL - Korean Existing and Evaluated Chemical Substances
PICCS - Philippines Inventory of Chemicals and Chemical Substances
AICS - Australian Inventory of Chemical Substances

15.2. Chemical safety assessment

Chemical Safety Report No information available

SECTION 16: Other information

Key or legend to abbreviations and acronyms used in the safety data sheet

Full text of H-Statements referred to under section 3

EUH066 - Repeated exposure may cause skin dryness or cracking
H225 - Highly flammable liquid and vapour
H226 - Flammable liquid and vapour
H302 - Harmful if swallowed
H304 - May be fatal if swallowed and enters airways
H312 - Harmful in contact with skin
H315 - Causes skin irritation
H318 - Causes serious eye damage
H319 - Causes serious eye irritation
H332 - Harmful if inhaled
H335 - May cause respiratory irritation
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H336 - May cause drowsiness or dizziness

H373 - May cause damage to organs through prolonged or repeated exposure
H411 - Toxic to aquatic life with long lasting effects
H412 - Harmful to aquatic life with long lasting effects

Legend
SVHC: Substances of Very High Concern for Authorisation:

Legend Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION

TWA TWA (time-weighted average) STEL STEL (Short Term Exposure Limit)
Ceiling Maximum limit value * Skin designation

Classification procedure
Calculation method

Key literature references and sources for data used to compile the SDS
U.S. Environmental Protection Agency ChemView Database
European Food Safety Authority (EFSA)
EPA (Environmental Protection Agency)
Acute Exposure Guideline Level(s) (AEGL(s))
U.S. Environmental Protection Agency Federal Insecticide, Fungicide, and Rodenticide Act
U.S. Environmental Protection Agency High Production Volume Chemicals
Food Research Journal
Hazardous Substance Database
International Uniform Chemical Information Database (IUCLID)
Japan GHS Classification
Australian National Industrial Chemicals Notification and Assessment Scheme (NICNAS)
NIOSH (National Institute for Occupational Safety and Health)
National Library of Medicine's ChemID Plus (NLM CIP)
National Toxicology Program (NTP)
New Zealand's Chemical Classification and Information Database (CCID)
Organisation for Economic Co-operation and Development Environment, Health, and Safety Publications
Organisation for Economic Co-operation and Development High Production Volume Chemicals Programme
Organisation for Economic Co-operation and Development Screening Information Data Set
RTECS (Registry of Toxic Effects of Chemical Substances)
World Health Organization

Issuing Date 19-Sep-2019

Revision Date 19-Sep-2019

Revision Note Initial Release.

This material safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006

Disclaimer
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the
date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage,
transportation, disposal and release and is not to be considered a warranty or quality specification. The information
relates only to the specific material designated and may not be valid for such material used in combination with any other
materials or in any process, unless specified in the text.

End of Safety Data Sheet

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