Professional Documents
Culture Documents
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1.2. Relevant identified uses of the substance or mixture and uses advised against
Company Name
BOSTIK SA
AEC Polymers
ZI d'Eyrialis
6, rue Guy Pellerin
Le Barp, 33114
France
Tel: +33(0)5 57 26 15 15
Fax: +33 (0)5 56 36 75 23
Contains Methyl methacrylate, 2-propenoic acid, 2-methyl,-2-hydroxyethyl ester, phosphate, Bisphenol-A-Epichlorhydrin Epoxy
resin <= 700 MW
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Signal Word
DANGER
Hazard statements
H315 - Causes skin irritation
H317 - May cause an allergic skin reaction
H319 - Causes serious eye irritation
H335 - May cause respiratory irritation
H225 - Highly flammable liquid and vapour
General Hazards
Polymerises with evolution of heat.
Mixture
3.2 Mixtures
Bisphenol-A-Epichlorhydrin 500-033-5 25068-38-6 0.1 - <1 Skin Irrit. 2 (H315) Eye Irrit. 2 :: C>=5% 01-2119456619-26
Epoxy resin <= 700 MW Eye Irrit. 2 (H319) Skin Irrit. 2 :: C>=5% -xxxx
Skin Sens. 1
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(H317)
Aquatic Chronic 2
(H411)
zinc bis(2-methylacrylate) 236-144-8 13189-00-9 0.1 - <1 Eye Dam. 1 (H318) 01-2119976363-30
Skin Sens. 1 -xxxx
(H317)
Acute Tox. 4
(H302)
Aquatic Acute 1
(H400)
Acrylic Acid 201-177-9 79-10-7 0.1 - <1 Acute Tox. 4 STOT SE 3 :: C>=1% 01-2119452449-31
(H302) -xxxx
Acute Tox. 3
(H311)
Acute Tox. 4
(H332)
Skin Corr. 1A
(H314)
Aquatic Acute 1
(H400)
Flam. Liq. 3 (H226)
STOT SE 3 (H335)
2-Propanol, 254-075-1 38668-48-3 0.1 - <1 Acute Tox. 2 01-2119980937-17
1,1'-[(4-methylphenyl)imino] (H300) -xxxx
bis- Eye Irrit. 2 (H319)
Aquatic Chronic 3
(H412)
This product does not contain candidate substances of very high concern at a concentration >=0.1% (Regulation (EC) No. 1907/2006
(REACH), Article 59)
General Advice Remove and isolate contaminated clothing and shoes. In case of accident or being
unwell, seek medical advice immediately (show directions for use or safety data sheet if
possible).
Inhalation Move victim to fresh air. If breathing is irregular or stopped, administer artificial
respiration. Administer oxygen if breathing is difficult.
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Skin Contact Wash skin with soap and water.
Eye contact In case of contact with substance, immediately flush skin or eyes with running water for
at least 20 minutes.
Ingestion Do NOT induce vomiting. Drink plenty of water. Immediate medical attention is not
required. Rinse mouth. Clean mouth with water and drink afterwards plenty of water.
Never give anything by mouth to an unconscious person. Call a doctor.
Self-protection of the first aider Ensure that medical personnel are aware of the material(s) involved and take
precautions to protect themselves.
4.2. Most important symptoms and effects, both acute and delayed
4.3. Indication of any immediate medical attention and special treatment needed
Vapours may form explosive mixtures with air. Vapours may travel to source of ignition and flash back. Most vapours are
heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Runoff to
sewer may create fire or explosion hazard. Hazardous polymerisation may take place during a fire due to heat. Closed
containers could violently rupture.
Wear self-contained breathing apparatus and protective suit. Use personal protective equipment as required.
Personal Precautions
ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area). All equipment used when handling
the product must be grounded. Do not touch or walk through spilled material. Stop leak if you can do it without risk.
Water spray may reduce vapour; but may not prevent ignition in closed spaces.
Prevent entry into waterways, sewers, basements or confined areas. See Section 12 for additional Ecological Information.
Methods for Containment A vapour suppressing foam may be used to reduce vapours. Absorb or cover with dry
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earth, sand or other non-combustible material and transfer to containers.
Methods for cleaning up Use clean non-sparking tools to collect absorbed material. Dyke far ahead of liquid spill
for later disposal.
Storage Conditions
Keep tightly closed in a dry and cool place. Keep in properly labelled containers. Keep containers tightly closed in a cool,
well-ventilated place. Keep away from heat, sparks, flame and other sources of ignition (i.e., pilot lights, electric motors and
static electricity). Protect from sunlight. Store at temperatures not exceeding 30 °C/ 86 °F. Recommended storage
temperature. 5 - 25 °C.
Other Information
Recommendation(s). Observe technical data sheet.
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Environmental Exposure Controls Do not allow into any sewer, on the ground or into any body of water.
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9.2. Other information
Softening Point No information available
Molecular Weight No information available
Solvent content (%) No information available
Solid content (%) No information available
Density 0.98 g/cm³
Bulk Density No Data Available
VOC content (%)
Explosion Data
Sensitivity to Mechanical Impact None.
Sensitivity to Static Discharge May be ignited by friction, heat, sparks or flames.
Hazardous Polymerisation
Hazardous polymerisation may occur upon depletion of inhibitor.
Heat, flames and sparks. UV-radiation/sunlight. Store at temperatures not exceeding 30 °C/ 86 °F.
Product Information
No information or data specific to the product on this toxicological (health) effect is available.
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Serious eye damage/eye irritation Not applicable.
Target Organ Effects Eyes, Respiratory system, Skin, Central Vascular System (CVS).
Acute Toxicity
The following values are calculated based on chapter 3.1 of the GHS document
ATEmix (oral) 18,619.00 mg/kg
ATEmix (dermal) 7,592.00 mg/kg mg/l
Component Information
Component Information
Data obtained on the component(s) include
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Methyl methacrylate EC50 96 h = 170 mg/L LC50 96 h > 79 mg/L EC50 48 h = 69 mg/L
80-62-6 (Pseudokirchneriella (Oncorhynchus mykiss static) (Daphnia magna )
subcapitata) Lepomis macrochirus 96h
=191-283 mg/l
Bisphenol-A-Epichlorhydrin - 1.2 mg/l 96Hr (Oncorhynchus 2.7 mg/l 48hr Daphia Magna
Epoxy resin <= 700 MW mykiss)
25068-38-6
zinc bis(2-methylacrylate) 0.53-0.56 mg/L - -
13189-00-9 (Pseudokirchneriella
subcapitata)
Acrylic Acid EC50 72 h = 0.04 mg/L LC50 96 h = 27 mg/L LC50 24 h = 270 mg/L
79-10-7 (Desmodesmus subspicatus) (Oncorhynchus mykiss) (Daphnia magna Static) EC50
EC50 96 h = 0.17 mg/L 48 h = 95 mg/L (Daphnia
(Pseudokirchneriella magna )
subcapitata)
1,3-bis[12-hydroxy-octadec EC50 (96hr) >100 mg/L Algae LC50 96h >100 mg/L Fish EC50 (48h) >0.64 mg/L
amide-N-methylene]-benze (Daphnia magna)
ne
911674-82-3
Methacrylic acid - LC50 (96h) = 833 mg/L Fish EC50 (48h) =210 mg/L
79-41-4 (Scophthalmus maximus) Daphnia magna
Propylene glycol - LC50 96 h 4600 - 10000 mg/L EC50 48 h = 23300 mg/L
monomethyl ether (Leuciscus idus static) LC50 (Daphnia magna )
107-98-2 96 h = 20.8 g/L (Pimephales
promelas static)
No information available.
No information available.
The components in this formulation do not meet the criteria for classification as PBT or vPvB.
No information available
Waste from Residues/Unused Disposal should be in accordance with applicable regional, national and local laws and
Products regulations.
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Contaminated Packaging Improper disposal or reuse of this container may be dangerous and illegal.
Other Information Waste codes should be assigned by the user based on the application for which the
product was used.
IMDG
14.1 UN/ID no UN1133
14.2 Proper Shipping Name Adhesives
14.3 Hazard Class 3
14.4 Packing Group III
Description UN1133, Adhesives, 3, III, (10°C c.c.)
14.5 Marine Pollutant Np
14.6 Special Provisions 223, 955
Limited Quantity (LQ) 5L
EmS-No F-E, S-D
14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code No information available
RID
14.1 UN/ID no UN1133
14.2 Proper Shipping Name Adhesives
14.3 Hazard Class 3
Hazard Labels 3
14.4 Packing Group III
Description UN1133, Adhesives, 3, III
14.5 Environmental Hazard Not applicable
Classification Code F1
14.6 Special Provisions 640E
Limited Quantity (LQ) 5L
ICAO (air)
14.1 UN/ID no UN1133
14.2 Proper Shipping Name Adhesives
14.3 Hazard Class 3
14.4 Packing Group III
Description UN1133, Adhesives, 3, III
14.5 Environmental Hazard Not applicable
14.6 Special Provisions A3
IATA
14.1 UN/ID no UN1133
14.2 Proper Shipping Name Adhesives
14.3 Hazard Class 3
14.4 Packing Group III
Description UN1133, Adhesives, 3, III
14.5 Environmental Hazard Not applicable
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14.6 Special Provisions A3
Limited Quantity (LQ) 10 L
ERG Code 3L
European Union
Take note of Directive 98/24/EC on the protection of the health and safety of workers from the risks related to chemical agents
at work
Check whether measures in accordance with Directive 94/33/EC for the protection of young people at work must be taken.
Take note of Directive 92/85/EC on the protection of pregnant and breastfeeding women at work
Registration, Evaluation, Authorization, and Restriction of Chemicals (REACh) Regulation (EC 1907/2006)
EU-REACH (1907/2006) - Candidate List of Substances of Very High Concern (SVHC) for Authorization in accordance
with Article 59
This product does not contain candidate substances of very high concern at a concentration >=0.1% (Regulation (EC) No.
1907/2006 (REACH), Article 59)
Dangerous substance category per Seveso Directive (2012/18/EU) P5a - FLAMMABLE LIQUIDS
or
P5b - FLAMMABLE LIQUIDS
or
P5c - FLAMMABLE LIQUIDS
None
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H302 - Harmful if swallowed
H400 - Very toxic to aquatic life
H335 - May cause respiratory irritation
H314 - Causes severe skin burns and eye damage
H315 - Causes skin irritation
H319 - Causes serious eye irritation
H411 - Toxic to aquatic life with long lasting effects
H300 - Fatal if swallowed
H412 - Harmful to aquatic life with long lasting effects
H311 - Toxic in contact with skin
H332 - Harmful if inhaled
H226 - Flammable liquid and vapour
H225 - Highly flammable liquid and vapour
H413 - May cause long lasting harmful effects to aquatic life
Legend
SVHC: Substances of Very High Concern for Authorisation:
Indication of changes
This safety data sheet complies with the requirements of: Regulation (EC) No. 1907/2006
Disclaimer
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of
its publication. The information given is designed only as guidance for safe handling, use, processing, storage, transportation,
disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific
material designated and may not be valid for such material used in combination with any other materials or in any process,
unless specified in the text.