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BKS1-1
1.2 Relevant identified uses of the substance or mixture and uses advised against
Relevant identified uses of the substance or mixture:
Coating resin
Uses advised against:
No information on this is available at present.
Manufacturer:
Bodo Moeller Chemie GmbH, Senefelder Straße 176, 63069 Offenbach, Germany
Phone:, Fax: ---
Distributor:
BKS stromschienen ag, Industrie Klus, CH-4710 Balsthal, Switzerland
Phone:, Fax: ---
E-mail address of the competent person: info@chemical-check.de, k.schnurbusch@chemical-check.de - please DO NOT use to
request safety data sheets.
Poisoning Information Centre of Gesundheit Österreich GmbH, Vienna. EMERGENCY CALL Tel.: 01 406 43 43 (from outside Austria
Tel.: +43 1 406 43 43)
Antigifcentrum/Centre Antipoisons (Belgium), a doctor will take your call, 7 days a week, 24 h a day. In Belgium, call toll-free: +32 70
245245
Tox Info Suisse, Freiestrasse 16, CH-8032 Zurich. National 24h emergency number: 145
Attention
H319-Causes severe eye irritation. H315-Causes skin irritation. H317-Can cause allergic skin reactions. H411-Toxic to aquatic
life with long lasting effects.
P273 Avoid release to the environment. P280 Wear protective gloves and eye/face protection.
P305+P351+P338-BEI contact with eyes: Rinse cautiously with water for several minutes. Remove contact lenses if possible.
Continue to rinse. P333+P313-If skin irritation or rash occurs: Get medical advice/attention. P337+P313-If eye irritation persists: Get
medical advice/attention.
Reaction product bisphenol A epichlorohydrin resins with average molecular weight <= 700 bisphenol F
epoxy resin
Oxirane, mono[(C12-C14-alkyloxy)methyl]derivatives
3.1 Fabric
n.a.
3.2 Mixture
Reaction product bisphenol A epichlorohydrin resins with
average molecular weight <= 700
Registration No. (REACH) 01-2119456619-26-XXXX
Index 603-074-00-8
EINECS, ELINCS, NLP 500-033-5 (NLP)
CAS 25068-38-6
% Range 60-80
Classification according to Regulation (EC) No 1272/2008 (CLP) Eye Irrit. 2, H319
Skin Irrit. 2, H315
Skin Sens. 1, H317
Aquatic Chronic 2, H411
Index ---
EINECS, ELINCS, NLP 500-006-8 (NLP)
CAS 9003-36-5
% Range 10-30
Classification according to Regulation (EC) No 1272/2008 (CLP) Skin Irrit. 2, H315
Skin Sens. 1, H317
Aquatic Chronic 2, H411
Oxirane, mono[(C12-C14-alkyloxy)methyl]derivatives
Registration No. (REACH) 01-2119485289-22-XXXX
Index 603-103-00-4
EINECS, ELINCS, NLP 271-846-8
CAS 68609-97-2
% Range 1-20
Classification according to Regulation (EC) No 1272/2008 (CLP) Skin Irrit. 2, H315
Skin Sens. 1, H317
For text of H-phrases and classification abbreviations (GHS/CLP) see section 16.
The substances mentioned in this section are listed with their actual, applicable classification!
This means that for substances listed in Table 3.1/3.2 of Annex VI to Regulation (EC) No 1272/2008 (CLP Regulation), all comments
possibly mentioned there have been taken into account for the classification mentioned here.
5.1 Extinguishing
media Suitable
extinguishing media
Water spray/foam/CO2/dry extinguishing agent
Unsuitable extinguishing agents
Water full jet
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Safety data sheet according to Regulation (EC) No 1907/2006, Annex II
Revised on / Version: 19.05.2016 / 0001
Supersedes Version from / Version: 19.05.2016 /
0001 Comes into force from: 19.05.2016
PDF print date: 20.05.2016
BKS1-1
In addition to the information contained in this section, relevant information can also be found in section 8 and 6.1.
7.1 Protective measures for safe handling
7.1.1 General recommendations
Ensure good room ventilation. Keep
away from sources of ignition - Do not
smoke. Avoid contact with eyes and
skin.
Eating, drinking, smoking and storing food in the working area is prohibited. Observe the
information on the label and the instructions for use.
Apply working procedures according to the operating instructions.
7.1.2 Notes on general hygiene measures at the workplace
The general hygiene measures for handling chemicals must be applied. Wash hands
before breaks and at the end of work.
Keep away from food, drink and animal feed.
Remove contaminated clothing and protective equipment before entering areas where people are eating.
7.2 Conditions for safe storage taking into account incompatibilities
Keep out of reach of unauthorised persons.
Do not store product in passageways and stairways. Store
product only in original packaging and closed. Do not store
together with oxidising agents.
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Safety data sheet according to Regulation (EC) No 1907/2006, Annex II
Revised on / Version: 19.05.2016 / 0001
Supersedes Version from / Version: 19.05.2016 /
0001 Comes into force from: 19.05.2016
PDF print date: 20.05.2016
BKS1-1
Reaction product bisphenol A epichlorohydrin resins with average molecular weight <= 700
Application area Exposure route / Impact on the Descripto Value Unit Bemerku
Environmental Health r ng
compartment
Environment - Freshwater PNEC 0,003 mg/l
Environment - Seawater PNEC 0,0003 mg/l
Environment - PNEC 0,018 mg/l
Water, sporadic
(intermittent)
Release
Environment - PNEC 10 mg/l
Waste water treatment plant
Oxirane, mono[(C12-C14-alkyloxy)methyl]derivatives
Application area Exposure route / Impact on the Descripto Value Unit Bemerku
Environmental Health r ng
compartment
Man - Inhalation Long-term, local DNEL 1,46 mg/m3
Effects
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Safety data sheet according to Regulation (EC) No 1907/2006, Annex II
Revised on / Version: 19.05.2016 / 0001
Supersedes Version from / Version: 19.05.2016 /
0001 Comes into force from: 19.05.2016
PDF print date: 20.05.2016
BKS1-1
Eye/face protection:
Safety goggles with side shields (EN 166).
Respiratory protection:
Normally not required.
In case of insufficient ventilation, wear respiratory
protective equipment. Filter A P2 (EN 14387),
identification colour brown, white Observe wearing time
limits for respiratory protective equipment.
Thermal hazards:
Not applicable
10.1 Reactivity
The product has not been tested.
10.2 Chemical stability
Stable when stored and handled properly.
10.3 Possibility of hazardous reactions
No hazardous reactions occur under normal conditions of storage and handling.
10.4 Conditions to avoid
Strong heating
10.5 Incompatible materials
Avoid contact with strong oxidising agents. Avoid
contact with strong alkalis.
Avoid contact with strong acids.
10.6 Hazardous decomposition products
No decomposition when used as intended.
For possible further information on health effects see section 2.1 (Classification).
BKS1-1
Toxicity / Effect Endpu Value Unit Organism Test method Comment
nkt
Acute toxicity, oral: n.d.v.
Acute toxicity, dermal: n.d.v.
Acute toxicity, inhalation: n.d.v.
Corrosive/irritant effect on the n.d.v.
Skin:
Serious eye damage/ n.d.v.
irritation:
Sensitisation of the n.d.v.
Respiratory tract/skin:
Germ cell mutagenicity: n.d.v.
Carcinogenicity: n.d.v.
Reproductive toxicity: n.d.v.
Specific target organ n.d.v.
Toxicity - single
exposure (STOT-SE):
Specific target organ n.d.v.
toxicity - repeated
Exposure (STOT-RE):
Aspiration hazard: n.d.v.
Symptoms: n.d.v.
Reaction product bisphenol A epichlorohydrin resins with average molecular weight <= 700
Toxicity / Effect Endpu Value Unit Organism Test method Comment
nkt
Acute toxicity, oral: LD50 >2000 mg/kg Rat
Acute toxicity, dermal: LD50 >2000 mg/kg Rabbit
Corrosive/irritant effect Rabbit OECD 404 (Acute Irritant
on the skin: Dermal
irritation/corrosion)
Serious eye damage/irritation: Rabbit OECD 405 (Acute Irritant
Eye
Irritation/Corrosion)
Sensitisation of the respiratory Mouse OECD 429 (Skin Sensitising
tract/skin: Sensitisation -
Local Lymph Node
Assay)
Germ cell mutagenicity: OECD 471 (Bacterial Positive
Reverse Mutation
Test)
Carcinogenicity: Rat OECD 453 Negative
(Combined Chronic
Toxicity/Carcinogenic
ity Studies)
Specific target organ NOAEL 100 mg/kg
Toxicity - repeated exposure bw/d
(STOT-RE):
Specific target organ NOAEL 50 mg/kg
Toxicity - repeated exposure bw/d
(STOT-RE):
Symptoms: Diarrhoea,
Weight loss
Acute toxicity, dermal: LD50 >2000 mg/kg Rabbit OECD 402 (Acute
Dermal Toxicity)
Corrosive/irritant effect Rabbit OECD 404 (Acute Irritant
on the skin: Dermal
irritation/corrosion)
Serious eye damage/irritation: Rabbit OECD 405 (Acute Non-irritant
Eye
Irritation/Corrosion)
Sensitisation of the respiratory Guinea pig OECD 429 (Skin Sensitising
tract/skin: chen Sensitisation -
Local Lymph Node
Assay)
Carcinogenicity: NOAEL 800 mg/kg/d Mouse
Reproductive toxicity: NOEL 540 mg/kg/d Rat OECD 416 (Two-
generation
Reproduction
Toxicity Study)
Reproductive toxicity: NOEL 750 mg/kg/d Rat OECD 416 (Two-
Generation
Reproduction
Toxicity Study)
Aspiration hazard: No
Specific target organ toxicity - NOAEL 250 mg/kg/d Rat OECD 408
repeated exposure (STOT- (Repeated Dose
RE), oral: 90- Day Oral
Toxicity
Study in Rodents)
Oxirane, mono[(C12-C14-alkyloxy)methyl]derivatives
Toxicity / Effect Endpu Value Unit Organism Test method Comment
nkt
Acute toxicity, oral: LD50 >2000 mg/kg Rat
Corrosive/irritant effect on the Rabbit Irritant
Skin:
Serious eye damage/irritation: Rabbit OECD 405 (Acute Slightly irritant
Eye
Irritation/Corrosion)
Sensitisation of the Guinea pig OECD 406 (Skin Yes (skin contact)
Respiratory tract/skin: chen Sensitisation)
Germ cell mutagenicity: Salmonella OECD 471 (Bacterial Negative
typhimurium Reverse Mutation
Test)
Reproductive toxicity: Rat No indications of
such an effect.
Reproductive toxicity NOAL 200 mg/kg Rat OECD 414 (Prenatal Female
(effect on fertility): Developmental
Toxicity Study)
Specific target organ NOAL 1 mg/kg/d OECD 411
toxicity - repeated (Subchronic dermal
exposure (STOT-RE), Toxicity - 90-
dermal: day Study)
For possible further information on environmental effects see section 2.1 (Classification).
BKS1-1
Toxicity / Effect Endpoint Time Value Unit Organism Test method Comment
12.1 Toxicity, fish: n.d.v.
12.1 Toxicity, n.d.v.
Daphnia:
12.1 Toxicity, algae: n.d.v.
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Safety data sheet according to Regulation (EC) No 1907/2006, Annex II
Revised on / Version: 19.05.2016 / 0001
Supersedes Version from / Version: 19.05.2016 /
0001 Comes into force from: 19.05.2016
PDF print date: 20.05.2016
BKS1-1
Reaction product bisphenol A epichlorohydrin resins with average molecular weight <= 700
Toxicity / Effect Endpoint Time Value Unit Organism Test method Comment
12.1 Toxicity, fish: LC50 96h 1,2 mg/l Oncorhynchus U.S. EPA
mykiss ECOTOX
Database
12.1 Toxicity, EC50 48h 1,1 mg/l Daphnia magna OECD 202
daphnia: (Daphnia sp.
Acute
immobilisation
Test)
12.1 Toxicity, algae: EC50 72h 9,4 mg/l Selenastrum U.S. EPA
capricornutum ECOTOX
Database
12.2 Persistence 28d 5 % OECD 301 F Not easily
and degradability: (Ready biodegradable
Biodegradability
- Manometric
Respirometry
Test)
12.3. Log Pow 3,8
Bioaccumulation
potential:
Oxirane, mono[(C12-C14-alkyloxy)methyl]derivatives
Toxicity / Effect Endpoint Time Value Unit Organism Test method Comment
12.1 Toxicity, fish: LC50 96h 5000 mg/l Oncorhynchus OECD 203
mykiss (Fish, Acute
Toxicity Test)
12.1 Toxicity, EC50 48h 1-10 mg/l Daphnia magna
Daphnia:
12.1 Toxicity, EL50 48h 7,2 mg/l Daphnia magna OECD 202
daphnia: (Daphnia sp.
Acute
immobilisation
Test)
12.1 Toxicity, NOELR 48h 1,8 mg/l Daphnia magna OECD 202
daphnia: (Daphnia sp.
Acute
immobilisation
Test)
12.1 Toxicity, algae: IC50 72h 843,75 mg/l Pseudocirchnerie OECD 201
lla subcapitata (Alga, Growth
Inhibition Test)
12.1 Toxicity, algae: NOEC/NO 72h 500 mg/l Pseudocirchnerie OECD 201
EL lla subcapitata (Alga, Growth
Inhibition Test)
12.2 Persistence 28d 87 % OECD 301 F
and degradability: (Ready
Biodegradability
-
Manometric
Respirometry
Test)
12.2 Persistence 28d 87 % OECD 301 F Easily biodegradable
and degradability: (Ready
Biodegradability
- Manometric
Respirometry
Test)
12.3. Log Pow 3,77
Bioaccumulation
potential:
12.3. Log Pow 3,77 Low
Bioaccumulation
potential:
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Safety data sheet according to Regulation (EC) No 1907/2006, Annex II
Revised on / Version: 19.05.2016 / 0001
Supersedes Version from / Version: 19.05.2016 /
0001 Comes into force from: 19.05.2016
PDF print date: 20.05.2016
BKS1-1
General information
14.1. UN no: 3082
Road / rail transport (GGVSEB/ADR/RID)
14.2. UN proper shipping name:
UN 3082 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (BISPHENOL-A/F-EPICHLOROHYDRIN RESINS)
14.3. Transport hazard classes: 9
14.4. Packing group: III
Classification code: M6
LQ (ADR 2015): 5L
14.5. Environmental hazards: Hazardous to the environment
Tunnel restriction code: E
Carriage by seagoing vessels (GGVSee/IMDG Code)
14.2. UN proper shipping name:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (EPOXY RESIN)
14.3. Transport hazard classes: 9
14.4. Packing group: III
EmS: F-A, S-F
Marine pollutant (Marine Pollutant): Yes
14.5. environmental hazards: environmentally hazardous
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Safety data sheet according to Regulation (EC) No 1907/2006, Annex II
Revised on / Version: 19.05.2016 / 0001
Supersedes Version from / Version: 19.05.2016 /
0001 Comes into force from: 19.05.2016
PDF print date: 20.05.2016
BKS1-1
15.1 Safety, health and environmental regulations/specific legislation for the substance or mixture
Classification and labelling see section 2. Observe
restrictions:
Observe the regulations of the employers' liability insurance association/
occupational medicine. Observe the Youth Employment Protection Act
(German regulation).
Observe the Youth Employment Protection Ordinance (ArGV 5, SR 822.115, Switzerland).
Observe the ordinance of the EAER on dangerous work for young people (SR 822.115.2, Switzerland).
Observe the Ordinance on Major Accidents.
Directive 2010/75/EU (VOC): 0 %.
VOC (CH): 0 g/l
MAK/BAT:
See section 8.
Observe the Chemicals Ordinance, ChemO (SR 813.11, Switzerland).
Observe the Chemicals Risk Reduction Ordinance, ChemRRV (SR 814.81,
Switzerland). Observe the Ordinance on Air Pollution Control, LRV (SR 814.318.142.1,
Switzerland).
Observe the Ordinance on Protection against Major Accidents (StFV) (SR 814.012, Switzerland). VbF
(Austria):
Not applicable
Water hazard class (Germany): 2
Self-classification: Yes (VwVwS)
Class A liquid (i.e. liquids that can pollute water in small quantities) according to "Classification of liquids hazardous to water"
(Switzerland, FOEN, 09.03.2009, (I061-0918)).
15.2 Chemical Safety Assessment
A chemical safety assessment is not provided for mixtures.
Classification and methods used to derive the classification of the mixture according to Regulation
(EC) 1272/2008 (CLP):
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Safety data sheet according to Regulation (EC) No 1907/2006, Annex II
Revised on / Version: 19.05.2016 / 0001
Supersedes Version from / Version: 19.05.2016 /
0001 Comes into force from: 19.05.2016
PDF print date: 20.05.2016
BKS1-1
The following phrases represent the full H-phrases, hazard class code (GHS/CLP) of the ingredients (named in section 2
and 3).
H315 Causes skin irritation.
H317 May cause an allergic skin reaction. H319
Causes severe eye irritation.
H411 Toxic to aquatic life with long lasting effects.
CLPClassification , Labelling and Packaging (REGULATION (EC) No 1272/2008 on classification, labelling and
packaging of substances and mixtures)
CMR carcinogenic, mutagenic, toxic for reproduction (carcinogenic, mutagenic, toxic for reproduction) COD
chemical oxygen demand (= chemical oxygen demand - COD)
CTFA Cosmetic, Toiletry, and Fragrance Association
DINGerman Institute for Standardisation
DMEL Derived Minimum Effect Level DNEL Derived No Effect Level
DOC Dissolved organic carbon (= dissolved organic carbon)
DT50 Dwell Time - 50% reduction of start concentration - The DT50 value is the time period in which the initial concentration
of a substance is reduced by half).
DVSDeutscher Verband für Schweißen und verwandte
Verfahren e.V. dwdry weight (= dry weight)
EWC European Waste Catalogue
ECHA European Chemicals Agency (= European Chemicals Agency) EC
European Community
EINECSEuropean Inventory of Existing Commercial Chemical
Substances ELINCSEuropean List of Notified Chemical Substances
EN European standards
EPAUnited States Environmental Protection Agency (United States of
America) ERC Environmental Release Categories (= environmental release
categories)
ES Exposure scenario
etc., etc. etcetera, and so on
EUEuropean Union
EEC European Economic Community EEA
European Economic Area
Fax. Fax number
acc. to
if applicable if applicable
GGVSEGefahrgutverordnung Straße und Eisenbahn (Germany) - This ordinance was replaced or merged with the
GGVSEB.
GGVSEB Dangerous Goods Ordinance for Road, Rail and Inland Navigation (Germany)
GGVSeeGefahrgutverordnung See (Ordinance on the Transport of Dangerous Goods by Sea Vessels, Germany) GHS
Globally Harmonized System of Classification and Labelling of Chemicals (= Globally Harmonized System of Classification and
Labelling of Chemicals)
GTN Glycerol trinitrate
GW / VL GW/ VL = Grenswaarde voor beroepsmatige blootstelling / Valeur limite d'exposition professionnelle
(Belgium) GW-kw / VL-cd GW-kw / VL-cd = Grenswaarde voor beroepsmatige blootstelling - Kortetijdswaarde / Valeur limite
d'exposition professionnelle - Valeur courte durée (Belgium)
GW-M / VL-M "GW-M / VL-M = Grenswaarde voor beroepsmatige blootstelling - ""Ceiling"" / Valeur limite
d'exposition professionnelle - ""Ceiling"" (Belgium)"
GWP Global warming potential (= greenhouse potential)
HET-CAMHen 's Egg Test - Chorionallantoic Membrane
HGWP Halocarbon Global Warming Potential
IARC International Agency for Research on Cancer IATA International Air Transport Association
IBCIntermediate Bulk Container
IBC (Code) InternationalBulk Chemical (Code)
ICInhibitory Concentration
IMDG CodeInternational Maritime Code for Dangerous Goods (= Dangerous Goods in International Maritime Traffic)
incl. inclusive, including
IUCLIDInternational Uniform ChemicaL Information Database
n.d.v. no data available KFZ,
KfzKraftfahrze
ug Konz. Conc.
LC Lethal concentration
LDlethal dose of a chemical LD50 Lethal
Dose, 50% (= median lethal dose)
LFBG Food, Commodities and Feed Code (Germany).
LOEC Lowest Observed Effect Concentration LOEL Lowest Observed Effect Level
LQLimited Quantities (= limited quantities)
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Safety data sheet according to Regulation (EC) No 1907/2006, Annex II
Revised on / Version: 19.05.2016 / 0001
Supersedes Version from / Version: 19.05.2016 /
0001 Comes into force from: 19.05.2016
PDF print date: 20.05.2016
BKS1-1
The information given here is intended to describe the product with regard to the necessary safety precautions, it is not
intended to guarantee specific properties and is based on our current knowledge. Liability excluded.
Issued by:
Chemical Check GmbH, Chemical Check Platz 1-7, D-32839 Steinheim, Phone: +49 5233 94 17 0, Fax:
+49 5233 94 17 90
© by Chemical Check GmbH Gefahrstoffberatung. Modification or reproduction of this document requires the
express consent of Chemical Check GmbH Gefahrstoffberatung.